17-04-2014 дата публикации
Номер: US20140106223A1
A high-voltage lithium-ion battery cathode material includes LiNiMnMO(0≦x≦0.2, M═Mg, Zn, Co. Cu, Fe, Ti, Zr, Ru, and Cr), which is coated with a coating material, which may be a carbon coating material, a metal phosphate coating material, or a combination thereof. The carbon coating material may be acetylene black, graphene oxide, conductive graphite, glucose, sucrose, starch, lactose, maltose, phenolic resins, polyvinyl alcohol, or a combination thereof, and the metal phosphate coating material may be FePO, LiFePO, CoPO, Mn(PO), LnPO. The coating material may account for 1 to 10% (wt %). Products of the present invention have high reversible capacities. Synthesis methods are disclosed that are simple and controllable, can produce uniform coating, and are suitable for industrial scale production. 1. A cathode material , comprising:{'sub': 0.5-x', '1.5', 'x', '4, 'substrate particles comprising a substance having the formula: LiNiMnMO, wherein 0≦x≦0.2, and M is Mg, Zn, Co, Cu, Fe, Ti, Zr, Ru, or Cr; and'}a coating material coated on surfaces of the substrate particles, wherein the coating material comprises a carbon material, a metal phosphate material, or a combination thereof.2. The cathode material according to claim 1 , wherein the coating material is the carbon material.3. The cathode material according to claim 1 , wherein the coating material is the metal phosphate material.4. The cathode material according to claim 1 , wherein the coating material is a mixture of the carbon material and the metal phosphate material.5. The cathode material according to claim 1 , wherein the coating material is acetylene black claim 1 , graphene oxide claim 1 , conductive graphite claim 1 , glucose claim 1 , sucrose claim 1 , starch claim 1 , lactose claim 1 , maltose claim 1 , a phenolic resin claim 1 , a polyvinyl alcohol claim 1 , FePO claim 1 , LiFePO claim 1 , Co(PO) claim 1 , Mn(PO) claim 1 , LnPO claim 1 , or a mixture thereof.6. The cathode material according to claim 1 ...
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