21-08-2014 дата публикации
Номер: US20140234714A1
A negative active material and a lithium battery are provided. The negative active material includes a composite core, and a coating layer formed on at least part of the composite core. The composite core includes a carbonaceous base and a metal/metalloid nanostructure disposed on the carbonaceous base. The coating layer includes a metal oxide coating layer and an amorphous carbonaceous coating layer. 1. A negative active material , comprising:a composite core comprising a carbonaceous base, and a metal or metalloid nanostructure on the carbonaceous base; anda coating layer formed on at least part of the composite core and comprising a metal oxide coating layer and an amorphous carbonaceous coating layer.2. The negative active material of claim 1 , wherein the metal oxide coating layer comprises an oxide of at least one metal selected from the group consisting of elements of Group 2 to Group 13 of the periodic table of elements.3. The negative active material of claim 1 , wherein the metal oxide coating layer comprises an oxide of at least one metal selected from the group consisting of zinc (Zn) claim 1 , zirconium (Zr) claim 1 , nickel (Ni) claim 1 , cobalt (Co) claim 1 , manganese (Mn) claim 1 , boron (B) claim 1 , magnesium (Mg) claim 1 , calcium (Ca) claim 1 , strontium (Sr) claim 1 , barium (Ba) claim 1 , titanium (Ti) claim 1 , vanadium (V) claim 1 , iron (Fe) claim 1 , copper (Cu) claim 1 , and aluminum (Al).4. The negative active material of claim 1 , wherein the metal oxide coating layer comprises a metal oxide represented by Formula I below:{'br': None, 'sub': a', 'b, 'MO\u2003\u2003'}wherein, in Formula 1, 1≦a≦4, 1≦b≦10, and M is at least one selected from the group consisting of zirconium (Zr), nickel (Ni), cobalt (Co), manganese (Mn), boron (B), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), titanium (Ti), vanadium (V), iron (Fe), copper (Cu), and aluminum (Al).5. The negative active material of claim 1 , wherein the metal oxide ...
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