02-08-2022 дата публикации
Номер: US11401356B2
Автор:
Bingyi Li,
Hongxu Yang,
Jie Lin,
Junling Zhou,
Lunjia Xie,
Meiyan Fu,
Peng Kou,
Qingqiang Gou,
Ting Huang,
Tingjie HUANG,
Xiaofan Zhang,
Yonghua MA,
Zhufang Sun,
Zifang Guo
The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M1, M2, M3, M4, M5, M6, M1′, M2′, M3′, M4′, M5′ and M6′ are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, —R1 and —OR2, wherein R1 and R2 are each independently a C1-C10 hydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C1-C10 alkoxy and heteroatoms; and wherein, when among M1-M6 and M1′-M6′, any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of R1 and —OR2, the two adjacent groups may optionally be linked to form a ring, with a proviso that M1, M2, M3, M4, M5, M6, M1′, M2′, M3′, M4′, M5′ and M6′ are not simultaneously hydrogen.
Подробнее