07-05-2020 дата публикации
Номер: US20200146142A1
Принадлежит:
The present invention relates to architected liquid metal networks and processes of making and using same. The predetermined template design technology of such architected liquid metal networks provides the desired spatial control of electrical, electromagnetic, and thermal properties as a function of strain. Thus, resulting in improved overall performance including process ability. 1. An article comprising a substrate having an average particle attachment strength of from about 2.8 micro-newtons to about 1 newton and a strain at failure of from about 5% to about 10 ,000%; and a plurality of encapsulates comprising a liquid metal core having an external surface , a metal oxide shell that encapsulates said liquid metal core , said shell having an external shell surface; and optionally one or more ligands and/or multi-functional ligands covalently bound to said shell's external surface and/or coordinatively bound to said liquid metal core's external surface:a) said liquid metal core comprising a liquid metal selected from the group consisting of Hg, Pb, Sn, Sb, Cd, Bi, Ga, In, Al, Zn, Ag, Au, Tl and mixtures thereof;b) said shell comprising a metal oxide comprising a cation derived from a metal selected from the group consisting of Ga, In, Sn, Pb, Sb, Cd, Al, Zn, Tl, Bi, Ca, Sc, Ti, V, Cr, Sr, Y, Zr, Nb, Mo, Te, Gd, Hf, Pr, Nd, Pt, Sm, Eu, Dy, Ho, Er, Yb, Pu and mixtures thereof; andc) said one or more ligands comprising a head group that comprises a material selected from the group consisting of thiols, amines, phosphonic acids, alkoxysilanes, halosilanes, carboxylic acids, nitriles, and mixtures thereof;d) said one or more multi-functional ligands comprising a head group that comprises a material selected from the group consisting of thiols, amines, phosphonic acids, alkoxysilanes, halosilanes, carboxylic acids, nitriles, and mixtures thereof.2. The article according to wherein said encapsulates' are chemically bound via a linkage comprising a residue of said ...
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