01-11-2018 дата публикации
Номер: US20180312722A1
Принадлежит:
A crosslinkable composition, a coating made therefrom, a process for producing a coating with reduced odor, and a method of reducing the odor of a coating. 1. A crosslinkable composition comprising:(a) a polyol, a polycarbamate, or mixtures thereof; having an average of 2 or more functional groups;(b) a polyaldehyde, an acetal or hemiacetal of the polyaldehyde, an aminoplast resin, or mixtures thereof;(c) an acid catalyst having a pKa of less than 6.0;(d) a hindered phenol having a molecular weight of 300 or more; and(e) optionally an organic solvent.2. The crosslinkable composition of claim 1 , wherein the molecular weight of the hindered phenol is 400 or more.3. The crosslinkable composition of claim 1 , wherein the hindered phenol is selected from 3-(3 claim 1 ,5-ditert-butyl-4-hydroxyphenyl)-N′-[3-(3 claim 1 ,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide; pentaerythritol tetrakis(3-(3 claim 1 ,5-di-tert-butyl-4-hydroxyphenyl)propionate); octadecyl-3-(3 claim 1 ,5-di-tert-butyl-4-hydroxyphenyl)-propionate; ethylenebis(oxyethylene)bis-3 claim 1 ,5-tert-butyl-4-hydroxy-m-tolyl)-propionate; 4-[[3 claim 1 ,5-bis[(3 claim 1 ,5-di-tert-butyl-4-hydroxyphenyl)methyl]-2 claim 1 ,4 claim 1 ,6-trimethylphenyl]methyl]-2 claim 1 ,6-di-tert-butylphenol; 4 claim 1 ,4-methylene-bis(3 claim 1 ,5-di-tert-butylphenol); or mixtures thereof.4. The crosslinkable composition of claim 1 , wherein the hindered phenol is present in an amount of from 0.2% to 20% by weight claim 1 , based on the total weight of the polyaldehyde claim 1 , the acetal or hemiacetal of the polyaldehyde claim 1 , and the aminoplast resin.5. The crosslinkable composition of claim 1 , wherein the polyol or polycarbamate is an acrylic claim 1 , styrene-acrylic claim 1 , styrene-butadiene claim 1 , saturated polyester claim 1 , urethane claim 1 , alkyd claim 1 , polyether or polycarbonate.6. The crosslinkable composition of claim 1 , wherein the polyaldehyde has from 2 to 20 carbon atoms.7. The ...
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