01-10-2015 дата публикации
Номер: US20150273445A1
Принадлежит:
A process for preparing a propane oxidation catalyst, the process comprising pre-calcining the catalyst precursor in an oxygen-containing gas at a temperature of less than 330° C. until the weight of the precursor stabilizes to obtain a pre-calcined precursor; then calcining the pre-calcined precursor to obtain the catalyst. 1. A process for preparing a propane oxidation catalyst , the process comprising: (a) preparing a catalyst precursor; (b) pre-calcining the catalyst precursor in an oxygen-containing gas at a temperature of less than 330° C. until the weight of the precursor stabilizes to obtain a pre-calcined precursor; then (c) calcining the pre-calcined precursor to obtain the catalyst.2. The process of wherein step (b) is maintained for at least 4 hours.3. The process of wherein step (c) is maintained for at least 6 hours.4. The process of wherein step (c) is maintained for at least 8 hours.5. The process of claim 1 , wherein the amount of phase M2 in the catalyst is less than 12%.6. The process of claim 1 , wherein the amount of phase M2 in the catalyst is less than 10%.7. The process of claim 1 , wherein the amount of phase M2 in the catalyst is less than 8%.8. The process of claim 1 , wherein the amount of phase M2 in the catalyst is less than 7%.9. The process of claim 1 , wherein the temperature of step (b) is less than 310° C.10. The process of claim 1 , wherein the catalyst is represented by the formula AaVbNcXdZeOf wherein A is at least one element selected from the group consisting of Mo and W claim 1 , N is at least one element selected from the group consisting of Te and Sb claim 1 , X is at least one element selected from the group consisting of Nb claim 1 , Ta claim 1 , Ti claim 1 , Al claim 1 , Zr claim 1 , Cr claim 1 , Mn claim 1 , Fe claim 1 , Ru claim 1 , Co claim 1 , Rh claim 1 , Ni claim 1 , Pt claim 1 , Sb claim 1 , Bi claim 1 , B claim 1 , In claim 1 , As claim 1 , Ge claim 1 , Sn claim 1 , Hf claim 1 , Pb claim 1 , P claim 1 , Pm claim ...
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