30-05-2023 дата публикации
Номер: CN116190633A
Принадлежит:
The invention relates to a layered oxide positive electrode material, a preparation method thereof, a positive electrode composition, a sodium ion secondary battery and application. The positive electrode material is NaxCuyMnzMaO2 + n delta, wherein x is equal to 0.6-1.2, y is equal to 0.05-0.4, z is equal to 0.3-0.8, a is equal to 0-0.6, y + z + a is equal to 0.95-1.05, n is more than 0 and less than or equal to 0.05, delta is equal to-1 to 3, and x * y/z is more than 0.15 and less than 0.4; m is a doping element; the positive electrode material is of an O3 or P2 structure, gamma is equal to d-d0/(x * y2 * z), d is an average value of crystal face interlayer spacing of an O3 material (003) or a P2 material (002), when x is equal to 0.6-0.8, d0 is equal to 5.6076 angstroms, and gamma is smaller than or equal to 2.7; when x is greater than 0.8 and less than or equal to 0.95, d0 is 5.3435 angstroms, and gamma is less than or equal to 3.0 When x is greater than 0.95 and less than or equal ...
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