08-08-2013 дата публикации
Номер: US20130200554A1
Silicone fibers suitable for use as optical fibers are prepared by crosslinking an extruded mixture of a silicone resin and an organopolysiloxane, both containing aliphatically unsaturated groups, an organopolysiloxane bearing Si—H groups, and a light activatable trimethyl(methylcyclopentadienyl) platinum catalyst. 15.-. (canceled)6. A transparent silicone mixture crosslinkable under the influence of light , comprising [{'br': None, 'sub': 3', '1/2, 'RSiO\u2003\u2003(I),'}, {'br': None, 'sub': 2', '2/2, 'RSiO\u2003\u2003(II),'}, {'br': None, 'sub': '3/2', 'RSiO\u2003\u2003(III),'}, {'br': None, 'sub': '4/2', 'SiO\u2003\u2003(IV),'}, 'in which, '(A) at least one organosiloxane resin comprising units of the formulae I, II, III and IV'} with the proviso that', 'at least 20 mol % of the units are selected from units of the general formulae III and IV,', 'at least 2 of the R radicals are alkenyl radicals having 1-10 carbon atoms and', 'at most 2% by weight of the R radicals are —OH radicals,, 'R are saturated hydrocarbyl radicals optionally substituted by halogens, and having 1-40 carbon atoms, or —OH,'}(B) at least one polyorganosiloxane containing at least two alkenyl groups per molecule and having a chain length of the longest chain of 200 to 10,000 siloxy units,(C) at least one organosilicon compound containing at least two SiH functions per molecule and{'sub': '3', '(D) as one catalyst, MeCp(PtMe) activatable by light from 200 to 500 nm.'}7. The silicone mixture of claim 6 , in which at least one organosiloxane resin (A) is an MQ silicone resin containing at least 80 mol % of units of the formulae I and IV.8. The silicone mixture of claim 6 , in which at least one polyorganosiloxane (B) corresponds to the average formula V{'br': None, 'sup': 1', '2, 'sub': x', 'y', '(4−x−y)/2, 'RRSiO\u2003\u2003(V)'}in which{'sup': '1', 'sub': 1', '10, 'Ris a monovalent, optionally halogen- or cyano-substituted C-Chydrocarbyl radical optionally bonded to silicon via an organic ...
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