ENVIRONMENTALLY-FRIENDLY SEALING MATERIAL FOR VACUUM WINDOW WITH EXCELLENT SEALING PERFORMANCE AND DURABILITY
The present invention relates to vacuum glass for the sealant composition, more particularly PbO and Bi2 O3 While no and environment-friendly, sealable and environment-friendly vacuum glass with excellent durability for the sealant composition are disclosed. The invention also relates to the output of the using environment-friendly vacuum glass and a manufacturing method thereof are disclosed. Involved in mining and viewing human happiness and basic request, the building window is essential factors are disclosed. However, a wide variety of material occupies 35% or more of total energy loss and building window is among other things, 60% or more in some building occupies substrate. In particular, cookies name is Freon gas, such as CO2 in order to reduce the amount of effort and ongoing, the monitor etc. in the databases of the more various environmental regulations and energy saving. In most of the countries represented Germany Europe forward to a tight wall relatively low compared to an insulating material by parking brake by adverse summer an air con dontrol therefore transparent material like a window or enhanced coefficient overall heat transmission criteria than domestic managing disclosed. In the case of total energy of the country interferometer 98% or more, more preferably include 50 even when only 10% energy saving can be save hundred million fires country budget, 1 °C can save energy even where the indoor control only 7%. Also, when a window or building, approximately 3 coefficient overall heat transmission. 0W/m2, in k 1. 5W/m2, approximately 20 - 30% can be saved even if only lowered degree k building energy is disclosed. On the other hand, in the case of general window glass of a single layered structure, and the tempering and ultraviolet solar through a, due to the amount of solar heat is at least one internal suction 1,750,000. In the case of resonance to waterproof strength window glass, use of a heater is the supply pipe 1,750,000. If the double-layered glass such, triple glass, glass Low provided E triple glass, vacuum glass developed in the nanometer range. An inner vacuum vacuum glass is performed substantially 5. 5 × 10-4 About glass as torr, double-layered glass excellent contrast 2 times 0. 54W/m2, insulation performance of the k efficacy. Figure 1 shows a conventional system for sealing and a wire connects a vacuum window favor quickly to explain the drawing, Figure 2 1 photographs to the output of the coil spring are disclosed. The reference also 1 and 2 also, conventional vacuum window (1) in the case of, containing lead (Pb) environmental pollutant shilling reconsideration etc. due to the use for use in the constraint. The, lead (Pb) that does not contain a lead seal (30) and aluminum effort to be replaced, such lead-free seal (30) of flat panel display for use in making a etc.. Of flat panel display for use in making cookies which lead-free sealing material (30) using vacuum window (1) be making an attempt is in progress. The, conventional vacuum window (1) upper and lower vacuum glass (10, 20) outermost along an edge lead-free sealing material (30) by applying vacuum firing direction against upper and lower vacuum glass (10, 20) etc. joining faces. However, an upper flat display panel for use in making a seal (30) is not vacuum comprises vacuum chucks window (1) applied to the input device, possible low relationship for sealing vacuum calcination temperature (30) into the auxiliary vacuum is quickly into refresh bubbles due a lower lubricity and durability and airtightness is low also is equal to, when outside channel (channel) is formed due to severe alkyl groups include methyl serves not able to perform vacuum window favor to be coated. A first transparent conductive background related to a compensation public Patent perforation 10 - 2009 - 0036709 call (2009. 04. 15. Public) flow tides. The synthesized vacuum window glass and its process is disclosed. The aim of the present invention Bi PbO and2 O3 Is not intentionally added, sealable and environment-friendly to the output for providing vacuum glass with excellent durability are disclosed. It is another object of the present invention the sealing of vacuum glass are disclosed. Another object of the present invention the method for producing a glass by applying vacuum to the output are disclosed. Embodiment of the present invention attain the object for seals in accordance with excellent durability and weight % to vacuum glass for environment-friendly re-shilling, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 The intentionally not characterized. The, the vacuum glass softening temperature (Ts) is not more than 450 °C re-shilling, coefficient of thermal expansion in 50 provided 300 °C 71 × 10-7 /K can be not more than disclosed. Also, in the vacuum glass for re-shilling 500 °C 6 g/cm, s may have a viscosity of at least. The other purposes according to an embodiment of the present invention for achieving vacuum glass on one side edge having a first evacuation ports through 1 glass; the glass wall portion spaced apart opposed to 1 2 glass; 1 and 2 inserted into the space between the spaced glass, glass 2 1 and the spacer maintaining a spacing; the outermost glass 1 or 2 arranged along the edge, and a second 1 2 1 2 the black glass and glass sealing a space between the sealing material; and a second seal disposed between the glass and the second 1 2 1 glass vacuum exhaust port vacuum to remain in cap sealing material; wherein, the re-shilling to weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 The intentionally not characterized. For achieving other purposes according to an embodiment of the present invention make the vacuum glass process is a 1 glass upper surface spacer on the array; the glass along the edge of the upper surface 1 to the output on the array; a second glass member 2 1 glass sealing material spacer arranged first liquid crystal including step; first by firing the glass seal between the sealing glass 2 1 second; and wherein the first exhausted between 2 glass glass 1, the re-shilling to weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 The intentionally not characterized. The, preferably sealant dispensing arrangement (dispensing) method is performed. For the yet another embodiment of the present invention is characterized vacuum glass making is arranged on the upper surface of spacer 1 glass, glass 1 along the edge of the upper surface to the output on the array; and vacuum atmosphere, spacer and a sealing material to the output first by firing the first source of the first glass member 2 1 glass black glass 1 step 2 glass seal between and vacuum; and, to the re-shilling weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 The intentionally not characterized. The, preferably sealant dispensing arrangement (dispensing) method is performed. According to the invention with excellent durability and sealing vacuum glass for environment-friendly re-shilling Bi PbO and2 O3 Intentionally adding while not environment-friendly, as well as sealing and excellent durability can be provides many benefits. Also, according to the present invention when vacuum shilling reconsideration, dispensing method applied to glass by applying and sintering it thus, existing bar (bar) to the output in the form of sintered glass arranged relative to adjust is used as the flange. Figure 1 shows a conventional vacuum glass seal quickly phenomenon to explain surface are disclosed. Figure 2 shows a of Figure 1 of the coil spring to the output photographs are disclosed. Figure 3 shows a cross-section an embodiment of the invention can be applied vacuum glass indicating are disclosed. Figure 4 shows a dispensing method also sealing surface arranged to explain process are disclosed. Figure 5 the output of using schematic represents a problem in bar form are disclosed. Figure 6 according to example 1 in 20 minutes compared to the output 500 °C fired photograph representing the result are disclosed. Figure 7 representing the result in 20 minutes according to embodiments 1 to the output 500 °C fired photograph disclosed. Figure 8 sealing material applied according to comparison example 1 sample photograph representing the result for acceleration test mung beans are disclosed. Figure 9 for sealing material applied according to embodiments 1 sample photograph representing the result of acceleration test mung beans are disclosed. Advantage of the present invention and features, and an electronic component connected to the drawing appended with the achieving activitycopyright will reference the carry in particular embodiments. However, the present invention are described in which an embodiment may be a limited but various different embodied in the form of percussion, only complete and can be utilized for the present embodiment of the present disclosure, this invention is in consultation with a knowledge of the confirming button to complete and has provided for transmitting the, the invention relates to construe defined by category only disclosed. The same references refer to the same components herein throughout. The HTML page through a preferred embodiment of the present invention rotating seals in accordance with excellent durability and sealing vacuum glass vacuum glass for environment-friendly and detailed described as follows. For environment-friendly sealant having a vacuum glass Lead (Pb) according to an embodiment of the present invention vacuum glass for environment-friendly re-shilling by not added, as well as environment-free, dispensing method utilizing high vacuum glass sealing finishing material formed by applying a vacuum through the high temperatures during the possible quickly can be prevent. To this end, the vacuum glass for environment-friendly re-shilling % by weight to a, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total equal to or less than 6% CuO and 1 in 2000. In addition, the vacuum glass according to the invention for environment-friendly re-shilling Bi PbO and2 O3 Intentionally does not include. PbO is lowering the softening temperature can be significantly contribute to, and Bi2 O3 Water resistance is compressed but, as an environmental pollutant, a not intentionally added. Wherein, the sealing material is not completely encompassed in that intentionally do not require the addition as well as, e.g. 0. 01% by weight may be included as impurities of less than return electrode substrate. Or less, the vacuum glass for each component included in the refrigerating environment-friendly sealant composition according to the invention is described content to less than 1000. P2O5 : 17 - 23% by weight P2 O5 Glass forming is acting as and, also contribute to lowering the melting point of the substrate. The P2 O5 17 - 23% by weight based on the total weight of the sealing material is preferably a compound having at least. P2 O5 Content of less than 17% by weight when, its addition effect is insufficient disclosed. On the contrary, P2 O5 Content of 23% by weight is exceeded, be water glass can be significantly reduced. V2O5 : 45 - 55% by weight V2 O5shilling reconsideration is based, and glass forming acting as, lower softening temperature also contribute to substrate. The V2 O5 45 - 55% by weight based on the total weight of the sealing material is preferably a compound having at least. V2 O5 Content of less than 45% by weight when, glass forming for P2 O5 Wherein adding a good water resistance to excessive free of being bailed up. On the contrary, V2 O5 Content of 55% by weight is exceeded, the devitrification is formation of glass can be difficult. Sb2O3 : 15 - 20% by weight Sb2 O3 Includes a glass stabilization could be bonded each other. The Sb2 O3 15 - 20% by weight based on the total weight of the sealing material is preferably a compound having at least. Sb2 O3 Content of less than 15% by weight when, its addition effect is insufficient disclosed. On the contrary, Sb2 O3 Content of 20% by weight is exceeded, glass transition temperature can be significantly increased. Fe2O3 : 4 - 8% by weight Fe2 O3 To improve the water resistance of the glass could be bonded each other. The Fe2 O3 4 - 8% by weight based on the total weight of the sealing material is preferably a compound having at least. Fe2 O3 Content of less than 4% by weight when, water resistance effect is insufficient disclosed. On the contrary, Fe2 O3 Content of 8% by weight is exceeded, glass transition temperature can be significantly increased. Other addition component: 6 weight % or less The sealing material according to the invention there is a low coefficient of thermal expansion, low softening temperature, glass stabilizing, for the purposes of durability such as, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 1 comprises CuO and in at least one. 0% by weight to 6% by weight based on the total weight of those components is polyimide exceeds total preferably incorporated below. These components is 6% by weight is exceeded, the devitrification is selected from the function as the sealing material cannot be charges can be a programmable. According to the invention in addition to the components for improving low temperature sealing vacuum glass for environment-friendly re-shilling ceramic filler can be added. The, cordierite ceramic filler (cordierite), type [khu[khu][lip[lip] Tie [thu[thu] (eucryptite), alumina (aluminum titanate) titanate, zirconate (zircon), the [tyu[tyu] it pushed spotter (spodumene), mullite (mulite) [wil[wil] E [thu[thu] (willemite) and can be selected including at least one 1, 100 parts by weight of these glass polyimide content, can be is 50 parts by weight or less. Ceramic filler glass components of 50 parts by weight of the top cover, or improved low temperature sealing properties, can be significantly degrading the durability. The environment-friendly re-shilling vacuum glass having a pair to weighing components content, alumina crucible or platinum crucible or molten glass frit is placed in a furnace jacket is fixed to melt behind can be at the same temperature. On the other hand, the low-temperature bake in vacuum glass softening temperature (Ts) is environment-friendly re-shilling 450 °C or less capable, a coefficient of thermal expansion in 50 provided 300 °C 71 × 10-7 /K can be not more than disclosed. Also, according to the present invention is slightly higher than the softening point of the glass vacuum environment-friendly re-shilling 470 provided 500 °C at about may be calcined disclosed. In particular, according to the invention in a vacuum glass for environment-friendly re-shilling 500 °C 6 g/cm, s may have a viscosity of at least. This plate is made vacuum glass from the interior of the air suctioned from the vacuum state, possible must be high temperature lead-free sealing material into which the quickly lead-free shilling reconsideration capacitor's oldest. Vacuum glass and manufacturing method thereof Figure 3 shows a cross-section vacuum glass according to embodiments of the invention and indicating, Figure 4 shows a lead-free sealing dispensing polymer for the process of Figure 3 is to explain the are disclosed. The reference also 3 and 4 also, embodiment of the present invention seals in accordance with excellent durability and shown vacuum glass (100) has a glass 1 (110), 2 second glass (120), spacer (130), cap sealing material (140) and V2 O5 Based environment-friendly seal (150) having a predetermined wavelength. First glass 1 (110) is through evacuation ports having one side edge, the first 2 glass (120) has a 1 glass (110) spaced apart and opposed to disposed thereon. The first container 1 and 2 glass (110, 120) each may have a plate shape, but each other can be designed at a lower plane, and not are not limited to, the configurations and area that are different in the insulating layer has the form of there disclosed. The, second glass 1 (110) and a second glass 2 (120) between 1. 0 x 10-4 Torr - 5. 5 x 10-5 Torr vacuum can be formed. Also, second glass 2 (120) is using the deployment can be glass (Low provided E glass). The deployment that specific metal layer inside glass infrared high reflectivity coating, the microbalance insulation performance of the building can be. 1 first glass (120) also the deployment can be glass, soda lime glass using a second glass 1 can be general in addition. Spacer (130) has a 1 and 2 glass (110, 120) are inserted into the space between spaced apart, first and 2 1 glass (110, 120) of maintaining interval could be bonded each other. The, spacer (130) is, when viewed in plane, arranging the bigger matrix array (matrix arrangement), and the second panel 1 and 2 glass (110, 120) in the central portion and edge portions for minimizing plating process are disclosed. Cap sealing material (140) has a 1 glass (110) formed of evacuation ports for sealing purposes. Such a cap sealing material (140) is formed to cover the vacuum outlet, first glass 1 (110) is equal to vacuum exhaust port seal. The, second glass 2 1 and vacuum vents (110, 120) by joining of the first and 1 2 glass (110, 120) to between an empty space of the air suctioned from the apply lines are for the purpose of obtaining formed in an inner, second glass 1 (110) preferably but attached to one side of the edge, are not limited to are not correct. V2 O5 Based environment-friendly seal (150) has a 1 glass (110) or 2 glass (120) arranged and calcined to outermost along an edge dispensing method, 1 and 2 first glass (110, 120) aligns a could be bonded each other. The, sealant (150) is, as aforementioned, lead (Pb) and bismuth (Bi) by not added, without fear of environmental pollution as well as, dispensing method by applying vacuum glass (100) utilizing a high temperature calcination through the vacuum sealing finishing material quickly to prevent possible is equal to or higher. To this end, sealant (150) is to weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 Intentionally does not include. The, composition in the environment-friendly re-shilling dispenser (200) dispensing (dispensing) using the second method 2 glass (120) for sealing on a lead-free (150b) after applying a scan, 1 and 2 by first sintered glass (110, 120) is at sealing a substrate. In this way, dispensing simplify work lead-free polyimide (150b) when to apply, as well as to reduce time and costs for carrying out the process in an automated manner possible as irrational. To the W-CDMA, on one shown in fig. 5, the output arranged in bar form, are arranged in the end firing must bar process time increases and, arranged in a position after the process often generating bar, shown in dispensing cost in one aspect also 4 temporal, and the reject can be the lowering side than in those views. Also, the lead-free composition in polyimide (150b) lead (Pb) is not added and bismuth (Bi), possible even after calcination temperature high vacuum low since the high temperature shrinkage which does not easily generate bubbles, lead-free sealing material (150) and a second glass 2 1 (110, 120) into the interior of the lubricity and durability quickly into inner are combined each other. The, the lead-free sealing material (150) having a softening temperature of less than 450 °C (Ts) is preferred. Lead-free seal (150) is exceeded outputs a low softening temperature of 450 °C is substantially sealing are disclosed. As well as, adding the filler sealing low temperature but, if in excess filler into lead-free seal (150) has poor fluidity of the sealing action of a sealing and the durability is performed after lowering vacuum glass, low temperature sealing for lead-free seal (150) is preferably above the softening temperature of 450 °C or less. Also, lead-free seal (150) is in 500 °C 6 g/cm, having a viscosity of at least s bigger, this vacuum glass (100) with the air pumped out from the interior of a vacuum when lead-free state of the sealing material (150) possible must be high temperature lead-free seal (150) is quickly into into the capacitor's oldest. The first edge of the upper surface 1 1 glass vacuum glass the glass arranged along upper surface spacer arranged after the output, the first glass member and second glass sealing material spacer 2 1 arranged within the vacuum chamber, a first seal between the first sealing glass 2 glass 1 after firing, which can be can be made via process. Alternatively, the first edge of the upper surface arranged glass 1 1 glass vacuum glass first spacer arranged along upper surface after the output, vacuum atmosphere, first and second glass sealing material to the output black glass member arranged spacer 1 1 2 2 glass seal between the first and second glass is baked to exhausted process can be made via. The method of, bonding, plastic and vacuum validation process vacuum glass exposed can be installed. The aforementioned embodiment of the present invention seals in accordance with excellent durability and environmental regulations (Pb) and bismuth (Bi) vacuum glass lead material added which the V2 O5 A major component design an optimum system for bone grafting, without fear of environmental pollution as well as, dispensing method utilizing high temperature calcination possible vacuum glass sealing finishing material by applying a vacuum section and the center-line average surface can be quickly and prevent leakage. Embodiments Below, a preferred embodiment of the present invention configuration and action to explain more particularly less than 1000. But, this is the preferred form of the invention the present invention presented as the example which interprets any meaning capable of limited free. This content is not described herein in the art sufficiently technically described in the literature can be described splicing which the plural V-shaped less than 1000. 1. Seal manufacturing Embodiments 1 To weight %, P2 O5 : 20%, V2 O5 : 50%, Sb2 O3 : 18%, Fe2 O3 : Comprising 6%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 1% by weight of CuO and placed in a platinum crucible melt furnace behind each weighing with a composition according to embodiments 1 to the output rapidly cooling the mixture prepared. Comparison example 1 Weight % to sealant, Bi2 O3 76%, B2 O3 9%, ZnO 4%, BaO 7%, Co3 O4 3%, NiO 1% except for the output in the same manner and in embodiments 1 prepared. 2. Properties evaluation (1) estimating the characteristic The output according to embodiments 1 and comparison example 1 DTA (glass transition temperature (Tg) and a softening temperature (Ts) when the measuring through Differential Thermal Analysis, TMA (Thermomechanical Analysis) 50 provided 300 °C through measuring the table in 1 shown to a coefficient of thermal expansion. [Table 1] Also, according to embodiments 1 and comparison example 1 in 20 minutes 500 °C firing-gate to the output. Also 6 and 7 also have shown to result. The reference also 6, when firing the output according to comparison example 1, surface crystallization occurs but, also the reference 7, is not be crystallized it is. (2) sealable and sealing durability evaluation According to embodiments 1 and comparison example 1 disposed within 20 minutes by firing in sealing off the hollow glass sealing and 470 °C, pottery box [sup[sup] acceleration test specimen 5 time manner by dielectrophoresis. Also 8 and 9 also have shown to result. 8 also reference surface, the center of the comparison example 1 are added to the output portion when it is applied according to can be generated. While, also the reference 9, the center of the cup is not applied according to embodiments 1 are added to the output when it is be. Thus, when the sealable and sealing durability according to embodiments 1 than the center of the can be the good. (3) attachment strength evaluation Also, according to embodiments 1 and comparison example 1 in 20 minutes after the output glass batch and 470 °C fired, side impact and vertical impact sample to improve adhesion strength was assessed. As a result, both embodiments 1 and comparison example 1 100 times to have good impact or more respectively. Thus, in the case of embodiments 1, comparison example 1 while having a coefficient of thermal expansion as compared to the relatively low adhesion eastern east have shown the result. In embodiments of the present invention are described but more about, this invention is in consultation with knowledge of various change and deformation at the level descriptors can be applied. The present invention feature a wider such change and modifications are not themselves a can. If rights range will be determined by the claims range described below. 100: vacuum glass 110:1 first glass 120:130 first glass 2: spacer 140: cap encapsulant 150: lead-free sealing material 200: dispenser Disclosed in the present invention is an environmentally-friendly sealing material for vacuum windows which is environmentally-friendly due to not containing PbO and Bi2O3 and yet, has excellent sealing performance and durability. According to the present invention, the environmentally-friendly sealing material for vacuum windows comprises, in wt%: 17-23% of P_2O_5; 45-55% of V_2O_5; 15-20% of Sb_2O_3; and 4-8% of Fe_2O_3, and further comprises 6% or less in total of one or more selected among BaO, Al_2O_3, Na_2O, TiO_2, ZrO_2 and CuO, and excludes PbO and Bi_2O_3. COPYRIGHT KIPO 2017 Dispensing (dispensing) construction method for vacuum glass arranged in environment-friendly sealant composition, the re-shilling to weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 Intentionally and does not, in 500 °C 6 g/cm, has a viscosity of at least s, vacuum glass vacuum state is formed, into which the sealing material characterized quickly into pattern including a vacuum environment-friendly glass polyimide. According to Claim 1, the vacuum glass softening temperature (Ts) is not more than 450 °C environment-friendly re-shilling, coefficient of thermal expansion in 50 provided 300 °C 71 × 10-7 Characterized/K or less sealed vacuum glass for environment-friendly and excellent in durability and sealing. Deletion One side edge having a first evacuation ports through 1 glass; the glass wall portion spaced apart opposed to 1 2 glass; 1 and 2 inserted into the space between the spaced glass, and the glass 2 1 maintaining a spacing spacer; the outermost glass 1 or 2 arranged along an edge, 1 2 1 2 and a second space between the glass and black glass enclosed seal; and a second seal disposed between the glass and the second 1 2 1 glass vacuum exhaust port vacuum to remain in cap sealing material; wherein, the re-shilling to weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 Intentionally and does not, in the re-shilling 500 °C 6 g/cm, has a viscosity of at least s, dispensing (dispensing) arranged construction method, vacuum glass vacuum state is formed, into which the sealing material characterized and quickly into pattern including a sealed vacuum glass with excellent durability. 1 glass upper surface arranged first spacer, along the edge of the upper surface glass 1 to the output on the array; a second glass member 2 1 glass sealing material spacer arranged first liquid crystal including step; first by firing the glass seal between the sealing glass 2 1 second; wherein the first and the second glass 1 exhausted between 2 glass, to the re-shilling % by weight, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 Intentionally and does not, in the re-shilling 500 °C 6 g/cm, has a viscosity of at least s, dispensing (dispensing) arranged construction method, vacuum glass vacuum state is formed, into which the sealing material characterized quickly into pattern including a vacuum glass making. First upper surface arranged spacer 1 glass, glass 1 to the output on the array along the edge of the upper surface; and vacuum atmosphere, spacer and a sealing material to the output first by firing the first source of the first glass member 1 2 1 2 black glass glass seal between glass and vacuum step; and, to the re-shilling weight %, P2 O5 : 17 - 23%, V2 O5 : 45 - 55%, Sb2 O3 : 15 - 20%, Fe2 O3 : Comprising 4 - 8%, BaO, Al2 O3 , Na2 O, TiO2 , ZrO2 At least one total and equal to or less than 6% in 1 and CuO, PbO and Bi2 O3 Intentionally and does not, in the re-shilling 500 °C 6 g/cm, has a viscosity of at least s, dispensing (dispensing) arranged construction method, vacuum glass vacuum state is formed, into which the sealing material characterized quickly into pattern including a vacuum glass making. Deletion
