05-09-2013 дата публикации
Номер: US20130230975A1
A method of forming a germanium thin film on an underlying film includes forming a germanium seed layer by absorbing a germanium on a surface of the underlying film using an aminogermane-based gas, and forming a germanium thin film on the germanium seed layer using a germane-based gas. 1. A method of forming a germanium thin film on an underlying film , the method comprising:forming a germanium seed layer by absorbing a germanium on a surface of the underlying film using an aminogermane-based gas; andforming a germanium thin film on the germanium seed layer using a germane-based gas.2. The method of claim 1 , wherein the surface of the underlying film contains moisture.3. The method of claim 1 , further comprising applying moisture on the surface of the underlying film before forming the germanium seed layer.4. The method of claim 3 , wherein applying the moisture includes exposing the underlying film to a moisture-containing gas.5. The method of claim 4 , wherein the moisture-containing gas is atmosphere.6. The method of claim 3 , wherein applying moisture includes washing the underlying film with water.7. The method of claim 2 , wherein the moisture is selected from a hydroxyl group.8. The method of claim 1 , wherein the aminogermane-based gas includes at least one selected from a group consisting of the following gases:{'sub': 2', '3, 'GeH(NMe),'}{'sub': '3', 'GeH(NMeEt),'}{'sub': 2', '3, 'GeH(NEt),'}{'sub': '3', 'GeH(NHEt),'}{'sub': '3', 'GeH(NHi-Pr),'}{'sub': '3', 'GeH(NHt-Bu),'}{'sub': 2', '2', '2, 'GeH(NMe),'}{'sub': 2', '2, 'GeH(NMeEt),'}{'sub': 2', '2', '2, 'GeH(NEt),'}{'sub': 2', '2, 'GeH(NHi-Pr),'}{'sub': 2', '2, 'GeH(NHt-Bu),'}{'sub': 3', '2, 'GeH(NMe),'}{'sub': '3', 'GeH(NMeEt),'}{'sub': 3', '2, 'GeH(NEt),'}{'sub': '3', 'GeH(NHEt),'}{'sub': '3', 'GeH(NHi-Pr), and'}{'sub': '3', 'GeH(NHt-Bu).'}9. The method of claim 1 , wherein the germane-based gas includes at least one selected from a group consisting of the following gases:{'sub': '4', 'GeH,'}{'sub': 2 ...
Подробнее