CHARACTERISTICS OF TUNABLE ADSORBENTS FOR RATE SELECTIVE SEPARATION OF NITROGEN FROM METHANE

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: 2. The process according to wherein said adsorbent has an isosteric heat of adsorption for methane that is from about 50 to about 125% of the adsorbent's heat of adsorption for N.3. The process according to where the feed stream may contain additional gas species such as ethane claim 2 , propane claim 2 , butane and hydrocarbons with more than 4 carbon atoms and may include adsorbents to remove said hydrocarbons.4. A process according to where the feed stream may contain additional gas species such as water claim 2 , carbon dioxide or sulfur species and may include adsorbents to remove said species.5. The process of wherein said adsorbent is selected from zeolite A claim 1 , chabazite claim 1 , mordenite claim 1 , clinoptilolite claim 1 , ZSM-5 claim 1 , or combinations thereof.6. The process of wherein the adsorbent is a zeolite exchanged with one or more cations selected from Li claim 5 , Na claim 5 , K claim 5 , Mg claim 5 , Ca claim 5 , Sr claim 5 , Ba claim 5 , Cu claim 5 , Ag claim 5 , Zn claim 5 , NH and combinations or mixtures thereof.7. The process of wherein said adsorbent is Zeolite A.9. The process according to where the feed stream may contain additional gas species such as ethane claim 8 , propane claim 8 , butane and hydrocarbons with more than 4 carbon atoms and may include adsorbents to remove said hydrocarbons.10. The process according to where the feed stream may contain additional gas species such as water claim 8 , carbon dioxide or sulfur species and may include adsorbents to remove said species.11. The process of wherein the feed gas temperature claim 8 , product gas temperature and bed temperatures range from about ...

CHARACTERISTICS OF TUNABLE ADSORBENTS FOR RATE SELECTIVE SEPARATION OF NITROGEN FROM METHANE

The present invention generally relates to a process that utilizes tunable zeolite adsorbents in order to reduce the bed size for nitrogen removal from a methane (or a larger molecule) containing stream. The adsorbents are characterized by the rate of adsorption of nitrogen and methane and the result is a bed size that is up to an order of magnitude smaller with these characteristics (in which the rate selectivity is generally 30) than the corresponding bed size for the original tunable zeolite adsorbent that has a rate selectivity of >100x. 1. A pressure swing adsorption process for kinetic separation of Nfrom a feed stream comprising at least methane and N , said process comprising feeding the feed stream to an adsorbent bed comprising adsorbent having:{'sub': '2', 'a rate of adsorption of at least 0.036 mmol/g/min for Nas determined by the Hiden method and'}{'sup': th', 'th, 'sub': '2', "a rate of adsorption of methane that is ⅙to 1/10000the adsorbent's adsorption rate for Nas determined by the Hiden method"}{'sub': '2', 'and recovering a product stream containing said at least methane gas with a reduced level of N.'}2. The process of wherein the adsorbent has an adsorption rate of at least 0.143 mmol/g/min for Nimpurity as determined by the Hiden method and an adsorption rate for methane that is 1/10to 1/1000of the adsorption rate for Nas determined by the Hiden method.3. The process of wherein said adsorbent comprises zeolite A claim 1 , X claim 1 , Y claim 1 , chabazite claim 1 , mordenite claim 1 , faujasite claim 1 , clinoptilolite claim 1 , ZSM-5 claim 1 , L claim 1 , Beta claim 1 , or combinations thereof.4. The process of wherein said adsorbent is a zeolite exchanged with at least one cation selected from Li claim 3 , Na claim 3 , K claim 3 , Mg claim 3 , Ca claim 3 , Sr claim 3 , Ba claim 3 , Cu claim 3 , Ag claim 3 , Zn claim 3 , NH4+ and combinations or mixtures thereof5. The process of wherein said adsorbent is zeolite A.6. The process according to ...

RATE/KINETIC SELECTIVE MULTIPLE BED ADSORPTION PROCESS CYCLE

The present invention is directed to an intensified process cycle that utilizes the adsorption beds present to a substantially greater degree allowing the processing of significantly more gas and/or the generation of significantly more product. The elimination of purge steps, reduction in equalization step times, and introduction of overlapping feed and equalization steps which normally cause a degradation in performance for equilibrium-based cycles, frees extra step for other actions to be taken, such as additional equalization steps, etc. 1. A pressure swing adsorption process for separating a pressurized feed supply gas containing at least one more rapidly adsorbable component and at least one less rapidly adsorbable product gas component which comprises continuous feeding of a supply gas into a feed input end of an adsorber bed containing at least one solid adsorbent which kinetically adsorbs the more rapidly adsorbable component and withdrawing the least rapidly adsorbable component from an exit end of the adsorber bed , which has a at least 2 beds in service in which the continuous feeding of the supply gas sequentially through each of the adsorber beds produces product gas by using continuous feed gas , constant product gas step , a product pressurization step , a high pressure equalization step wherein there is a product make step that overlaps with feeding the bed , at least one equalization up step and one equalization down step , a blow down step to depressurize the bed , wherein there is substantially no purge provided to any bed during any step in the PSA process.2. The process of wherein the equalization steps are conducted in 10 seconds or less.3. The process of wherein feed pressurization overlaps with the last equalization up step.4. The process of wherein there is at least one rest step where a bed in the process is isolated from all gas streams.5. The pressure swing adsorption process of wherein the less rapidly adsorbable component is the product ...

SUPERIOR CORE-IN-SHELL COMPONENT COMPOSITE ADSORBENTS FOR VSA/VPSA/PSA SYSTEMS

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. 2. The composite of having an attrition loss of less than or equal to 5 wt %.3. The composite of wherein said adsorbent shell comprises one or more of zeolites claim 1 , aluminas claim 1 , silicas claim 1 , carbons claim 1 , activated carbons claim 1 , molecular organic frameworks (MOFs) claim 1 , transition metal substituted silicas claim 1 , zincosilicates claim 1 , titanosilicates and mixtures thereof.4. The composite of wherein said adsorbent shell comprises one or more zeolites.5. The composite of wherein said zeolite is selected from LSX claim 4 , Y claim 4 , A claim 4 , L claim 4 , ZSM-5 claim 4 , Mordenite claim 4 , Clinoptilolite claim 4 , Chabazite and mixtures thereof.6. The composite of wherein said zeolite has a SiO2/AlOratio of from about 1.9 to 10 claim 5 , and wherein the zeolite contains cations selected from H claim 5 , Li claim 5 , Na claim 5 , K claim 5 , Mg claim 5 , Ca claim 5 , Sr claim 5 , Ba claim 5 , Ag claim 5 , Cu and mixtures thereof.7. The composite of wherein the adsorbent is LiX wherein the extent of Li exchange is greater than or equal to 90% on an equivalents basis.8. The composite of wherein said adsorbent shell comprises from about 1-20 wt % binder.9. The composite of wherein said adsorbent shell comprises from about 2-12 wt % binder.10. The composite of wherein said adsorbent shell comprises 0-5 wt % of at least one coating aid.11. The composite of wherein the binder is selected from clays claim 8 , aluminas claim 8 , silicas claim 8 , alumina-silica reagents and hydroxides that claim 8 , upon calcination become alumina-silica.12. The composite of ...

CRYOGENIC ADSORPTION PROCESS FOR XENON RECOVERY

An adsorption process for xenon recovery from a cryogenic liquid or gas stream is described wherein a bed of adsorbent is contacted with the aforementioned xenon containing liquid or gas stream and adsorbs the xenon selectively from this fluid stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. Operating the adsorption bed to near full breakthrough with xenon, prior to regeneration, enables production of a high purity product from the adsorption bed and further enables oxygen to be used safely as a purge gas, even in cases where hydrocarbons are co-present in the feed stream. 1. An adsorption process for the recovery of xenon from a cryogenic feed stream containing xenon which comprises:i. feeding the feed stream at cryogenic temperatures into the inlet of an adsorption vessel having an inlet and an outlet and containing an adsorbent bed therein, wherein said adsorbent bed contains at least one adsorbent selective for xenon,ii. maintaining said adsorbent bed on feed until the xenon concentration at the outlet of said bed is greater than or equal to 70% of the xenon concentration at the inlet to said adsorbent bed,iii. ending the feed to the adsorption bed and purging same with a purge gas,iv. increasing the temperature of said adsorbent bed to a temperature effective to desorb substantially all of said xenon from the adsorbent in said adsorbent bed,v. recovering the xenon product desorbed from said adsorbent bed,vi. cooling said adsorbent bed to cryogenic temperatures with a cryogenic fluid, andrepeating steps i.-vi. in a cyclic manner.2. The process of wherein said cryogenic feed stream is an oxygen feed stream which claim 1 , in addition to xenon claim 1 , comprises at least one other adsorbable component.3. The process of wherein said at least one other adsorbable component is a hydrocarbon or krypton.4. The process of ...

PROCESS FOR HANDLING VARIABLE FLOW RATES AND COMPOSITIONS IN PRESSURE SWING ADSORPTION SYSTEMS

The present invention generally relates to a process for responding to feed flow variations by changing the process cycle and thereby increasing the productivity and capacity of the system significantly over constant process systems. This increases the flexibility a PSA system for customers that do not require a constant or uniform product flow rate and/or for processes and applications that experience feed streams that vary in flow, temperature, and/or composition. 1. A method for maximizing product production under variable feed conditions in a PSA system adapted for separating a pressurized feed supply gas containing at least one more readily adsorbable component from at least one less readily adsorbable product gas component to produce a stream of product gas enriched with said less readily adsorbable component and a stream of offgas that is enriched in said more readily adsorbable component , wherein said PSA system comprises a feed gas step , product gas make step , a product pressurization step , a high pressure equalization step , product make step that overlaps with feeding the bed , at least one equalization up step and one equalization down step , and a blow down step to depressurize the bed , wherein when the Required Processing Power of said PSA system is greater than 1 , the PSA process cycle is modified by making at least one of the following cycle changes:a. Substitute at least one feed step for an equalization step provided that the cycle retains at least one equalization step pair; orb. Substitute at least one blow down step or purge step pair for an equalization step pair provided that the cycle retains at least one equalization step pair; orc. Substitute at least one feed step for at least one blow down step or purge step pair provided that the cycle retains at least one blow down step or purge step pair;d. Substitute an overlap feed and product pressurization step for a product pressurization step; ore. Substitute a purge step pair for at least ...

TUNABLE ADSORBENTS

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5A for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products. 2. The method of wherein prior to calcining claim 1 , the mixture is shaped into agglomerates claim 1 , beads claim 1 , extrudates claim 1 , or pellets.3. The method of wherein said crystalline inorganic adsorbent is a zeolite claim 1 , alumino phosphate claim 1 , titanosilicate claim 1 , or zinc silicate or combinations thereof.4. The method of wherein said zeolite is an A-type zeolite.5. The method of wherein said A-type zeolite is exchanged with one or more cations selected from Li claim 4 , Na claim 4 , K claim 4 , Mg claim 4 , Ca claim 4 , Sr claim 4 , Ba claim 4 , Ag claim 4 , Cu claim 4 , or Zn.6. The method of wherein R is selected from H claim 1 , straight claim 1 , branched or cyclic claim 1 , substituted or unsubstituted claim 1 , Cto Calkyl claim 1 , alkenyl claim 1 , alkynyl claim 1 , alkoxy and aryl.7. The method of wherein each R is the same or different and are selected from linear claim 1 , branched and cyclic compounds Cto Corganic compounds.8. The method of wherein the silicone precursor is polymeric or oligomeric and wherein each R substituent is independently terminated by hydroxy claim 1 , methoxy claim 1 , ethoxy or combinations thereof.9. The method of ...

TUNABLE ADSORBENTS

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products. 115-. (canceled)16. A surface modified A type zeolite adsorbent having a effective pore size of less than or equal to 4.1 Å wherein the pore size of of said zeolite is reduced by 0.1 up to about 1.2 Å with a coating comprised of a silicone derived species , wherein said species is derived from a silicone precursor of formula I:{'br': None, 'sub': '2', 'i': 'n', '[(R)SiO]'}{'br': None, 'or of formula II{'br': None, 'sub': '1.5', 'RSiO'}wherein each R substituent is the same or different and it selected from a substituted or unsubstituted organic compound.17. The adsorbent of wherein prior to calcining claim 16 , the mixture is shaped into agglomerates claim 16 , beads claim 16 , extrudates claim 16 , or pellets.18. The adsorbent of wherein said zeolite is an A-type zeolite.19. The adsorbent of wherein said A-type zeolite is exchanged with one or more cations selected from Li claim 18 , Na claim 18 , K claim 18 , Mg claim 18 , Ca claim 18 , Sr claim 18 , Ba claim 18 , Ag claim 18 , Cu claim 18 , or Zn.20. The adsorbent of wherein each R is the same or different and is selected from H claim 16 , straight claim 16 , branched or cyclic claim 16 , substituted or unsubstituted claim 16 , ...

PROCESS FOR GENERATING HIGHER VPSA PRODUCT PRESSURE

The invention relates to a process for modifying the VPSA/VSA/PSA cycle to allow for maximum product pressure without the need for a base load oxygen compressor (BLOC) or base load oxygen blower (BLOB), thus supplying low pressure oxygen (3 to 7 Psig) to the end user while at the same time lowering product costs 10 to 30%. The system of this invention preferably employs larger piping runs from the VPSA to the oxy-fuel control skids, larger piping for the oxy-fuel control skid, larger piping for the VPSA, low pressure drop flow measurements, and low pressure drop check valves. 1. A pressure swing adsorption method for the separation of components of a feed gas mixture into at least a first component and a second component by selective adsorption of said first component into a bed of adsorbent , said method comprising the following steps on a cyclic basis:{'sub': '2', 'sup': −6', '2, 'a) raising the pressure of said feed gas to said bed during adsorption steps of the cycle to an adsorption pressure so as to enable adsorption of said first component by said adsorbent, said adsorbent exhibiting a mass transfer coefficient of >=12/s and an intrinsic Ndiffusivity of 3.5×10m/s at 1.5 bar and 300k,'}b) depressurizing said bed during the desorption steps of said cycle to a desorption pressure so as to desorb said first component from said adsorbent, a ratio of pressures of said adsorption pressure to said desorption pressure in a range of less than about 5.0;wherein said bed is pressurized to said adsorption pressure by pressurized feed gas and with no product pressurization.2. The pressure swing adsorption method of claim 1 , wherein said ratio of pressures ranges from about 3.5 to 5.3. The pressure swing adsorption method of claim 1 , wherein said intrinsic diffusivity of said adsorbent for said first component is equal to or greater than 4.0 ×10m/sec and said ratio of pressures falls in a range of from about 1.5 to 3.5.4. The pressure swing adsorption method of claim 3 , ...

MID-RANGE PURITY OXYGEN BY ADSORPTION

The present invention relates to a process cycle that allows for the stable production of mid-range purity oxygen from air, using traditional system designs. Typical cycles have a limited production benefit when generating Oat lower than % purity, however they suffer a production loss at higher purity. The process cycles of the invention are capable of producing significantly more contained Oat a lower purity. In addition to enhanced production capacity, lower power consumed per mass of product and more stable product purity and flow are realized by the process of the invention compared to traditional alternatives. 2. The process of wherein the adsorber bed is pressurized to said adsorption pressure by pressurized feed gas and with no product pressurization.3. The process of wherein the equalization steps is the cycle are each less than or equal to 1.5 seconds.4. The process of wherein the equalization steps in the cycle ranges from about 0.5 to about 1.25 seconds.5. The process of wherein said mid-range oxygen has an average purity of from about 75% to less than about 90%.6. The process of wherein said mid-range oxygen has an average purity of from about 75% to about 85%.7. The process of wherein said nitrogen selective adsorbent is a high rate adsorbent or a low rate adsorbent and comprises at least one of LiX zeolite claim 1 , 5A claim 1 , 13X claim 1 , CaX claim 1 , and mixed cation zeolites.8. The process of wherein the highest adsorption pressure is in the range of about 100 kPa to about 2000 kPa claim 1 , and the lowest desorption pressure is in the range of from about 20 kPa to about 100 kPa.9. The process of which comprises two or more adsorbent beds wherein each bed contains at least one nitrogen selective adsorbent.10. An adsorption process for the production of mid-range purity oxygen from a feed gas containing at least oxygen and nitrogen which comprises continuously feeding the feed gas into a feed input end of an adsorber bed containing at least one ...

SUPERIOR CARBON ADSORBENTS

The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and COworking capacity for use in a HPSA process. 111-. (canceled)12. A core-shell carbon adsorbent for use in gas separation comprising an adsorbent shell and 10-90 vol % of inert core having a porosity less than or equal to 10% , wherein said adsorbent shell comprises from about 75-99 wt % of at least one carbon adsorbent and from about 1-25 wt % of at least one binder , wherein said adsorbent has a particle size of from about 0.5 and 5 mm and a sphericity >0.8.13. The core-shell adsorbent of wherein said inert core is selected from dense ceramics claim 12 , sand claim 12 , bauxite claim 12 , cordierite claim 12 , analcite claim 12 , hematite claim 12 , magnetite claim 12 , granite claim 12 , marble claim 12 , dolomitic limestone claim 12 , shale claim 12 , and combinations thereof.14. The core-shell adsorbent of wherein said core has a porosity of from 0 to 5%.15. The core-shell adsorbent of wherein said carbon is activated carbon derived from coal claim 12 , charcoal claim 12 , wood claim 12 , coconut shell claim 12 , polymer claim 12 , pitch and mixtures thereof.16. The core-shell adsorbent of wherein said carbon is a carbon molecular sieve17. (canceled)18. The core-shell adsorbent of wherein adsorbent shell comprises from about 2 to about ...

Process for handling variable flow rates and compositions in pressure swing adsorption systems

The present invention generally relates to a process for responding to feed flow variations by changing the process cycle and thereby increasing the productivity and capacity of the system significantly over constant process systems. This increases the flexibility a PSA system for customers that do not require a constant or uniform product flow rate and/or for processes and applications that experience feed streams that vary in flow, temperature, and/or composition.

Superior carbon adsorbents

The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and CO 2 working capacity for use in a H 2 PSA process.

Superior core-in-shell component composite adsorbents for vsa/vpsa/psa systems

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.

Superior core-in-shell component composite adsorbents for vsa/vpsa/psa systems

Energy efficient vpsa system with direct drive high speed centrifugal compressors.

La presente invención se relaciona con un método y sistema para mejorar la eficiencia energética y de capital de la planta de VPSA a través de la optimización de los compresores de alimentación, vacío, y/o productos centrífugos de velocidad variable de accionamiento directo para lograr un menor costo de producción de productos de gas unitarios. Más específicamente, la presente invención se relaciona con un nuevo proceso y sistema de VPSA eficiente energético que usa compresores centrífugos de accionamiento directo de alta velocidad para lograr un rango de producción más amplio. Puede lograrse un consumo de energía significativamente menor durante la vida útil de la operación de la planta mediante el uso de compresores dimensionados con la demanda ambiental y producción promedio, usando un rango operativo y velocidad de los compresores centrífugos de alta velocidad variable de accionamiento directo para satisfacer la demanda de producción deseada. Dado que la mayoría de las plantas tienden a funcionar por debajo del pico de producción, la mayor parte de la vida útil de la planta. Además, la máquina de menor tamaño ofrece ahorros de capital de la planta a partir de la inversión inicial. The present invention relates to a method and system for improving the energy and capital efficiency of the VPSA plant through the optimization of the direct drive variable speed centrifugal, vacuum, and/or feed compressors to achieve better performance. lower cost of production of unit gas products. More specifically, the present invention relates to a new energy efficient VPSA process and system using high speed direct drive centrifugal compressors to achieve a broader production range. Significantly lower energy consumption can be achieved over the lifetime of the plant operation by using compressors sized with ambient demand and average production, using an operating range and speed of direct drive variable speed high speed centrifugal compressors for meet the desired production ...

Process for generating higher vpsa product pressure

The invention relates to a process for modifying the VPSA/VSA/PSA cycle to allow for maximum product pressure without the need for a base load oxygen compressor (BLOC) or base load oxygen blower (BLOB), thus supplying low pressure oxygen (3 to 7 Psig) to the end user while at the same time lowering product costs 10 to 30%. The system of this invention preferably employs larger piping runs from the VPSA to the oxy-fuel control skids, larger piping for the oxy-fuel control skid, larger piping for the VPSA, low pressure drop flow measurements, and low pressure drop check valves.

Cryogenic adsorption process for xenon recovery

An adsorption process for xenon recovery from a cryogenic liquid or gas stream is described wherein a bed of adsorbent is contacted with the aforementioned xenon containing liquid or gas stream and adsorbs the xenon selectively from this fluid stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. Operating the adsorption bed to near full breakthrough with xenon, prior to regeneration, enables production of a high purity product from the adsorption bed and further enables oxygen to be used safely as a purge gas, even in cases where hydrocarbons are co-present in the feed stream.

Energy efficient vpsa process with direct drive high speed centrifugal compressors

The invention relates to a method and system for improving PSA/VPSA plant energy efficiency during times of reduced production demand and capital efficiency through optimizing feed, vacuum, and centrifugal product compressors to achieve lower energy consumption and lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient PSA/VPSA turn down process and system which employs high speed direct drive centrifugal product compressor to achieve desired production. Significant lower energy consumption can be achieved by employing lower flow, and lower adsorption top pressure in the lower production range.

Process for handling variable flow rates and compositions in pressure swing adsorption systems

The present invention generally relates to a process for responding to feed flow variations by changing the process cycle and thereby increasing the productivity and capacity of the system significantly over constant process systems. This increases the flexibility a PSA system for customers that do not require a constant or uniform product flow rate and/or for processes and applications that experience feed streams that vary in flow, temperature, and/or composition.

Superior core-in-shell component composite adsorbents for vsa/vpsa/psa systems

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.

Characteristics of tunable adsorbents for rate selective separation of nitrogen from methane

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: An isosteric heat of adsorption of from about 5kJ/mol to about 30kJ /mol, as determined by the LRC method, for the adsorbate, and an equivalent 65kJ/mol or less isosteric heat of adsorption for the product, wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least 10 times greater than the rate of adsorption for the product gas as determined by the TGA method and recovering said product gas with a reduced a level of said adsorbate impurity. The invention also related to an adsorbent useful in PSA separations, particularly separating N2 from methane, CO2 from methane O2 from N2 and the like.

Characteristics of tunable adsorbents for rate selective separation of nitrogen from methane

The invention relates to an adsorbent useful in PSA separations, separating N2 or CO2 from methane, 02 from N2 and the like, and to a PSA process for separating an adsorbate impurity from a feed stream comprising product gas, comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to about 2000 psig, said adsorbent bed comprises adsorbent having: an isosteric heat of adsorption of from about 5kJ/mol to about 30kJ /mol, as determined by a LRC method, for the adsorbate, and an equivalent 65kJ/mol or less isosteric heat of adsorption for the product, wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least times greater than the rate of adsorption for the product gas as determined by a TGA method and recovering said product gas with a reduced a level of said adsorbate impurity.

Characteristics of tunable adsorbents for rate selective separation of nitrogen from methane

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: An isosteric heat of adsorption of from about 5kJ/mol to about 30kJ /mol, as determined by the LRC method, for the adsorbate, and an equivalent 65kJ/mol or less isosteric heat of adsorption for the product, wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least 10 times greater than the rate of adsorption for the product gas as determined by the TGA method and recovering said product gas with a reduced a level of said adsorbate impurity. The invention also related to an adsorbent useful in PSA separations, particularly separating N2 from methane, CO2 from methane O2 from N2 and the like.

Mid-range purity oxygen by pressure swing adsorption

The present invention relates to a process cycle that allows for the stable production of mid-range purity oxygen from air, using traditional system designs. Typical cycles have a limited production benefit when generating O2 at lower than 90% purity, however they suffer a production loss at higher purity. The process cycles of the invention are capable of producing significantly more contained O2 at a lower purity. In addition to enhanced production capacity, lower power consumed per mass of product and more stable product purity and flow are realized by the process of the invention compared to traditional alternatives. The most suitable drawing: Figure 2.

Rate/kinetic selective multiple bed adsorption process cycle

The present invention is directed to an intensified process cycle that utilizes the adsorption beds present to a substantially greater degree allowing the processing of significantly more gas and/or the generation of significantly more product. The elimination of purge steps, reduction in equalization step times, and introduction of overlapping feed and equalization steps which normally cause a degradation in performance for equilibrium-based cycles, frees extra step for other actions to be taken, such as additional equalization steps, etc.

Energy efficient VPSA system with direct drive high speed centrifugal compressors

The present invention relates to a method and system for improving VPSA plant energy and capital efficiency through optimizing direct drive variable speed centrifugal feed, vacuum, and/or product compressors to achieve lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient VPSA process and system which employs high speed direct drive centrifugal compressors to achieve wider production range. Significant lower energy consumption can be achieved over the plant operation life by employing compressors sized with average ambient and production demand, utilizing direct drive variable high speed centrifugal compressors' speed and operating range to meet the desired production demand. Since majority of the plants tend to run at below peak production most of operating life of the plant. In addition, the smaller size machine offers plant capital savings from the initial investment.

Energy efficient VPSA process with direct drive high speed centrifugal compressors

The invention relates to a method and system for improving PSA/VPSA plant energy efficiency during times of reduced production demand and capital efficiency through optimizing feed, vacuum, and centrifugal product compressors to achieve lower energy consumption and lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient PSA/VPSA turn down process and system which employs high speed direct drive centrifugal product compressor to achieve desired production. Significant lower energy consumption can be achieved by employing lower flow, and lower adsorption top pressure in the lower production range.

Tunable adsorbents

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 A for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.

METHODS TO IMPROVE THE ENERGY EFFICIENCY OF AN ADSORTIVE GAS SEPARATION SYSTEM AND TO OPERATE AN ADSORPTION SYSTEM

MÉTODOS PARA APRIMORAR A EFICIÊNCIA ENERGÉTICA DE UM SISTEMA DE SEPARAÇÃO DE GÁS ADSORTIVO E PARA OPERAR UM SISTEMA DE ADSORÇÃO. A invenção se refere a um método e a um sistema para aprimorar a eficiência energética de usinas de PSA/VPSA durante tempos de demanda de produção e eficiência de capital reduzidos através da otimização dos compressores de produto, de alimentação, a vácuo e centrífugos para alcançar menor consumo de energia e menor custo de produção do produto de gás unitário. Mais especificamente, a presente invenção se refere a um novo processo e sistema de redução de PSA/VPSA eficiente energeticamente que emprega um compressor de produto centrífugo de acionamento direto e de alta velocidade para obter a produção desejada. Um consumo de energia significativamente mais baixo pode ser obtido empregando-se fluxo mais baixo, e menor pressão de topo de adsorção na faixa de produção mais baixa. METHODS FOR IMPROVING THE ENERGY EFFICIENCY OF AN ADSORTIVE GAS SEPARATION SYSTEM AND FOR OPERATING AN ADSORPTION SYSTEM. The invention relates to a method and a system for improving the energy efficiency of PSA/VPSA plants during times of reduced production demand and capital efficiency by optimizing product, feed, vacuum and centrifugal compressors to achieve lower energy consumption and lower production cost of the unit gas product. More specifically, the present invention relates to a new energy efficient PSA/VPSA reduction process and system that employs a high speed, direct drive centrifugal product compressor to achieve the desired output. Significantly lower energy consumption can be obtained by employing lower flow, and lower adsorption top pressure in the lower production range.

Método e sistema de adsorção por modulação de pressão

a presente invenção se refere a um processo para modificar o ciclo de vpsa/vsa/psa a fim de possibilitar uma pressão de produto máxima sem a necessidade de um compressor de oxigênio de carga de base (bloc) ou um soprador de oxigênio de carga de base (blob), fornecendo, dessa forma, oxigênio de baixa pressão (de 3 a 7 psig) para o usuário final, reduzindo, ao mesmo tempo, os custos do produto em 10 a 30%. o sistema da presente invenção usa, de preferência, uma tubulação maior de vpsa até os suportes de controle de oxicombustível, uma tubulação maior para os suportes de controle de oxicombustível, uma tubulação maior para vpsa, medições de fluxo de baixa queda de pressão e válvulas de verificação de baixa queda de pressão.

Energy efficient vesa process with direct drive high speed centrifugal compressors

The invention relates to a method and system for improving PSANPSA plant energy efficiency during times of reduced production demand and capital efficiency through optimizing feed, vacuum, and centrifugal product cornpressors to achieve lower energy consurnption and lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient PSANPSA turn down process and system which employs high speed direct drive centrifugal product cornpressor to achieve desired production. Significant lower energy consumption can be achieved by employing lower flow, and lower adsorption top pressure in the lower production range.

Adsorvente compósito de núcleo-cápsula para uso na separação de gases de batelada, e processo de separação de gás cíclico

ADSORVENTE COMPÓSITO DE NÚCLEO-CÁPSULA PARA USO NA SEPARAÇÃO DE GASES DE BATELADA, E PROCESSO DE SEPARAÇÃO DE GÁS CÍCLICO. A presente invenção se refere a um adsorvente de núcleo em cápsula superior que compreende adsorvente, e um núcleo inerte, em que o dito núcleo tem uma porosidade menor que 10%, e tem uma capacidade térmica volumétrica maior que 1 J/K*cc. Os adsorventes da invenção têm boa força física, e permitem um tempo de ciclo maior, reduzindo, assim, as perdas de despressurização (respiro) em comparação com adsorventes conhecidos. A invenção se refere a um projeto de adsorvedor para um processo de adsorção de oscilação de pressão/vácuo (VSA, VPSA, PSA) projetado para obter produto de oxigênio a partir de ar utilizando os adsorventes da invenção.

Processo de adsorção para a recuperação de xenônio

um processo de adsorção para a recuperação de xenônio a partir de um líquido criogênico ou fluxo de gás é descrito, em que um leito de adsorvente é colocado em contato com o fluxo de gás ou líquido contendo xenônio anteriormente mencionado, e adsorve o xenônio, seletivamente, do fluxo de fluido. o leito de adsorção é operado até ao menos quase o total avanço com xenônio para possibilitar a ampla rejeição de outros componentes do fluxo, antes da regeneração usando o método de oscilação de temperatura. operar o leito de adsorção até quase o total avanço com xenônio, antes da regeneração, possibilita a produção de um produto de alto grau de pureza do leito de adsorção e permite, ainda, que o oxigênio seja usado com segurança como um gás de purga, mesmo nos casos em que os hidrocarbonetos estão copresentes no fluxo de alimentação.

Rate/kinetic selective multiple bed adsorption process cycle

The present invention is directed to an intensified process cycle that utilizes the adsorption beds present to a substantially greater degree allowing the processing of significantly more gas and/or the generation of significantly more product. The elimination of purge steps, reduction in equalization step times, and introduction of overlapping feed and equalization steps which normally cause a degradation in performance for equilibrium-based cycles, frees extra step for other actions to be taken, such as additional equalization steps, etc.

Rate/kinetic selective multiple bed adsorption process cycle

The present invention is directed to an intensified process cycle that utilizes the adsorption beds present to a substantially greater degree allowing the processing of significantly more gas and/or the generation of significantly more product. The elimination of purge steps, reduction in equalization step times, and introduction of overlapping feed and equalization steps which normally cause a degradation in performance for equilibrium-based cycles, frees extra step for other actions to be taken, such as additional equalization steps, etc.

Caracteristicas de adsorbentes afinables para la separacion selectiva por tasa de nitrogeno a partir de metano.

La presente invención se relaciona, generalmente, con un proceso de adsorción por oscilación de presión para separar una impureza de adsorbato de una corriente de alimentación que comprende gas de producto; el proceso comprende alimentar la corriente de alimentación a un lecho adsorbente a una presión de aproximadamente 60 psig a 2000 psig, en donde el lecho adsorbente comprende el adsorbente que tiene: Un calor isostérico de adsorción de aproximadamente 5 kJ/mol a aproximadamente 30 kJ/mol, según lo determinado por el método de LRC para el adsorbato, y un calor isostérico equivalente de 65 kJ/mol o menos de adsorción para el producto, en donde el adsorbente tiene una tasa de adsorción para la impureza de adsorbato que es al menos 10 veces mayor que la tasa de adsorción para el gas de producto según lo determinado por el método de TGA y la recuperación del gas de producto con un nivel reducido de la impureza de adsorbato. La invención también se relaciona con un adsorbente útil en separaciones de PSA, particularmente que separa N2 del metano, CO2 del metano, O2 del N2 y lo similar.

Proceso de adsorcion por oscilacion de presion al vacio (vpsa) energeticamente eficiente con compresores centrifugos de alta velocidad de accionamiento directo.

La invención se relaciona con un método y sistema para mejorar la eficiencia energética de la planta de PSA/VPSA durante tiempos de demanda de producción reducida y eficiencia de capital mediante la optimización de compresores de productos de alimentación, vacío y centrífugos para lograr un menor consumo de energía y un menor costo de producción de productos gaseosos. Más específicamente, la presente invención se relaciona con un nuevo proceso y sistema de reducción de PSA/VPSA energéticamente eficiente que usa un compresor de producto centrífugo de accionamiento directo de alta velocidad para lograr la producción deseada. Puede lograrse un consumo de energía significativamente menor mediante el uso de un flujo menor y una presión superior de adsorción menor en el intervalo de producción menor.

Energy efficient vpsa system with direct drive high speed centrifugal compressors

The present invention relates to a method and system for improving VPSA plant energy and capital efficiency through optimizing direct drive variable speed centrifugal feed, vacuum, and/or product compressors to achieve lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient VPSA process and system which employs high speed direct drive centrifugal compressors to achieve wider production range. Significant lower energy consumption can be achieved over the plant operation life by employing compressors sized with average ambient and production demand, utilizing direct drive variable high speed centrifugal compressors' speed and operating range to meet the desired production demand. Since majority of the plants tend to run at below peak production most of operating life of the plant. In addition, the smaller size machine offers plant capital savings from the initial investment.

Superior Core-In-Shell Component Composite Adsorbents for VSA/VPSA/PSA Systems

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents. The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention. (Figure 1)

Energy efficient VPSA system with direct drive high speed centrifugal compressors

The invention relates to a method and system for improving PSA/VPSA plant energy efficiency during times of reduced production demand and capital efficiency through optimizing feed, vacuum, and centrifugal product compressors to achieve lower energy consumption and lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient PSA/VPSA turn down process and system which employs high speed direct drive centrifugal product compressor to achieve desired production. Significant lower energy consumption can be achieved by employing lower flow, and lower adsorption top pressure in the lower production range.

Superior carbon adsorbents

The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and CO 2 working capacity for use in a H 2 PSA process.

Superior core-in-shell component composite adsorbents for VSA/VPSA/PSA systems

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents.The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.