ZWEIFACH HETEROCYCLISCH SUBSTITUIERTE SULFONYLAMINO(THIO)CARBONYLVERBINDUNGEN

MITTEL ZUR REGULIERUNG DES PFLANZENWACHSTUMS

BENZO (B>-1,4,5,7-DITHIADIAZEPIN-1,1,4,4TETRAOXYDDERIVATE.

HERBICIDES 5-CHLORDIFLUORMETHYL-1, 3, 4-THIADIAZOL-2-YL-OXYACETANILIDE

HERBICIDAL GUANIDINO-PYRIMIDINES AND -S-TRIAZINES

Substituted sulphonylaminocarbonyltriazolinones and their use as herbicides

PYRIMIDINYL(THIONO)(THIOL)-PHOSPHORIC(PHOSPHONIC)ACID ESTERS

Herbicidal or fungicidal sulphonylaminocarbonyltriazolinones with halogenated alk(en)oxy substituents

AMINOBENZOIC ACID DERIVATIVES

Utilization of substituted o-alkyl-carbamates for combating animal pests

SUBSTITUTED ARYLSULPHONYLGUANIDINES

SULPHONYLGUANIDINOTRIAZINE DERIVATIVES

Substituted 1-aryl-cyclopropylmethylamino-1,3,5-triazines

GUANIDINE DERIVATIVES

... 23189-5695 Guanidine derivatives of the formula in which R2 represents a six-membered aromatic hetero cyclic structure which contains at least one nitrogen atom and is substituted by halogen, amino, cyano or formyl and/or by optionally substituted radicals from the series comprising alkyl, alkoxy, alkylamino, dialkylamino, alkylcarbonyl and alkoxycarbonyl, and/or is optionally fused, R3 represents hydrogen, an optionally substituted radical from the series comprising alkyl, cycloalkyl, alkenyl, alkinyl and aralkyl, or the radical -S(O)n-R6, the other radicals can have varied meanings, and acid adducts and salts thereof, which possess herbicidal and plant growth regulating activity. Le A 22 435-CA ...

SUBSTITUTED PYRIDYL-PHENYL ETHERS

Substituted Pyridyl-phenyl Ethers Novel substituted pyridyl-phenyl ethers of the formula (I) in which X represents trifluoromethyl or chlorine, Y represents hydrogen or chlorine, R1 represents hydrogen or methyl and R2 represents formyl or the radicals of the formulae or in which R3 represents alkyl with 1 to 4 carbon atoms, or the two radicals R3 together represent an alkylene chain with 2 or 3 carbon atoms, R4, R5, R6 and R7 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms, m represents 1 or 2, n represents 0 or 1 and Z represents trimethylsilyl, optionally substituted azolyl which is bonded via nitrogen or the radicals of the formulae in which R8 represents alkyl with 1 to 4 carbon atoms, or the two radicals R8 together represent an alkylene chain with 2 or 3 carbon atoms, R9 represents alkyl with 1 to 4 carbon atoms, X1 represents oxygen or sulphur and R10 and R11 independently of one another represent hydrogen or alkyl with 1 ...

N-DICHLOROACETYL-1,2,3,4-TETRAHYDRO-QUINALDINE, A PROCESS FOR ITS PREPARATION AND ITS USE FOR PREVENTING DAMAGE TO CROP PLANTS BY HERBICIDES

The new compound N-dichloro-acetyl-1,2,3,4-tetrahydro-quinaldine of the formula (I) is outstandingly suitable for protecting crop plants against herbicidal damage by thiolcarbamates and/or acetanilides. The compound of the formula (I) is prepared by reacting 1,2,3,4-tetrahydro-quinaldine of the formula (II) with dichloroacetyl chloride.

TERT.-BUTYL-SUBSTITUTED PYRAZOLYL (THIONO) (THIOL)- PHOSPHORIC(PHOSPHONIC) ACID ESTERS AND ESTER-AMIDES AND THEIR USE AS INSECTICIDES, ACARICIDES AND NEMATICIDES

The present invention now provides, as new compounds, the tert.-bityl-substituted pyrazolyl(thiono)(thiol)phosphoric(phosphonic) acid esters and ester-amides of the general formula (I), in which R represents hydrogen, alkyl, cyanoalkyl or phenyl, the phenyl ring optionally carrying one or more substituents selected independently from halogen, halogenoalkyl, alkyl and alkylthio, R1 represents hydrogen, halogen, alkyl or alkylthio, R2 represents alkoxy, alkyl or phenyl, R3 represents alkoxy, alkylthio or monoalkylamino and X represents oxygen or sulphur. The compounds of the formula (I) have been found to possess an excellent insecticidal, acaricidal and nematicidal action.

OPTICALLY ACTIVE PHENOXYPROPIONIC ACID DERIVATIVES

New dextrorotatory enantiomers of phenoxy propionic acid derivatives of the formula (I) < IMG > in which R1 represents a radical of the formula < IMG > wherein X1 represents hydrogen or halogen, x2 represents halogen or trifluoromethyl, X3 represents halogen or trifluoromethyl, X4 represents hydrogen or halogen and X5 represents hydrogen or halogen, Y represents oxygen or the radical SOm, wherein m represents 0, 1 or 2, R2 represents hydrogen or methyl, n represents 1 or 2 and R3 and R4 independently of one another represent hydrogen, halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 to 4 carbon atoms, nitro, cyano or alkoxycarbonyl with 1 to 4 carbon atoms in the alkoxy group, processes for the preparation of the novel compound and their use as herbicides.

SUBSTITUTED 4-SULPHONYLAMINO-2-AZINYL-1,2,4-TRIAZOL-3-ONES, PROCESSES AND INTERMEDIATES FOR THEIR PREPARATION, AND THEIR USE AS HERBICIDES

Herbicidal substituted sulphonylaminotriazolinones of the formula (I) in which R1 represents an optionally substituted radical from the group consisting of alkyl, aralkyl, aryl and heteroaryl, R2 represents hydrogen or the group -SO2-R1 where R1 has the abovementioned meaning, R3 represents hydrogen, halogen, hydroxyl, mercapto, amino or an optionally substituted radical from the group consisting of alkyl, cycloalkyl, aralkyl, aryl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenylthio, alkinylthio, aralkoxy, aralkylthio, alkylamino and dialkylamino, R4 represents hydrogen, halogen, hydroxyl, amino or an optionally substituted radical from the group consisting of alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino and dialkylamino, X represents nitrogen or a CH group, Y represents nitrogen or a CR5 group where R5 represents hydrogen, halogen, cyano, alkyl, formyl, alkylcarbonyl or alkoxycarbonyl, and Z represents nitrogen or a CR6 ...

SELECTIVE HERBICIDES BASED ON HETEROARYLOXY-ACETAMIDES

Novel herbicidal active compound combinations consisting of (a) a heteroaryloxy-acetamide of the formula (I) (I) in which Het represents thiadiazolyl which is substituted by halogen or by C1-C4-alkyl or phenyl, each of which is optionally substituted by halogen, and Ar represents phenyl which is optionally substituted by halogen, C1-C4-alkyl or C1-C4-halogenoalkyl, and (b) one or more compounds from a second group of herbicides (according to the description) and/or a compound which improves the tolerance by crop plants (according to the description) exhibit, at certain weight ratios, synergistic effects and/or particularly good tolerance by crop plants with high herbicidal activity.

HERBICIDAL OR FUNGICIDAL SULPHONYLAMINOCARBONYLTRIAZOLINONES WITH HALOGENATED ALK(EN)YLTHIO SUBSTITUENTS

New sulphonylaminocarbonyltriazolinones have the formula (I), in which R1 stands for hydrogen, hydroxy, amino, alkylidene amino or for an optionally substituted residue from the series of alkyl, alkenyl, alkinyl, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl, arylalkyl; R2 stands for halogen-substituted alkyl or alkenyl; and R3 stands for an optionally substituted residue from the series of alkyl, aralkyl, aryl, heteroaryl. Also disclosed are salts of the compounds having the formula (I), a process and new intermediate products for preparing the compounds (I) and their use as herbicides and/or fungicides.

SUBSTITUTED SULPHONYLAMINO (THIO)CARBONYL COMPOUNDS AS HERBICIDES

... -101- The invention relates to novel substituted sulphonylamino(thio)carbonyl compounds of the formula (I) in which A represents oxygen, sulphur, NH, N-alkyl, N-aryl, -CH=N-, or -N=CH- or -CH=CH-, Q represents oxygen or sulphur, R1 represents respectively optionally substituted alkyl, alkenyl, alkiny l, cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, heterocyclyl or heterocyclylalkyl, R2 represents cyano, nitro, halogen or represents respectively optional ly substituted alkyl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulphinyl, alkylsulphonyl, alkenyl, alkinyl, alkenyloxy or alkinyloxy, and R3 represents respectively optionally substituted heterocyclyl having 5 ri ng members of which at least one represents oxygen, sulphur or nitrogen and a further one to three may represent nitrogen, (except for certain individual prior art compounds), furthermore to salts of novel compounds of the formula (I), to various processes and novel intermediates f or preparing the novel compounds and to their ...

PROCEDURE FOR THE PRODUCTION OF NEW ONES VINYLTHIONOPHOSPHORSAEUREESTERN AS WELL AS YOUR USE IN INSECTICIDES AND AKARIZIDEN.

PROCEDURE FOR THE PRODUCTION OF NEW ONES O-PYRAZOLOPYRIMIDINTHIONOTHIOLPHOSPHORSAEUREESTERN AS WELL AS YOUR USE AS ACTIVE SUBSTANCE COMPONENT IN INSECTICIDES, AKARIZIDEN AND NEMATIZIDEN MEANS.

PROCEDURE FOR THE PRODUCTION OF NEW ONES O-PHENYLTHIONOPHOSPHONSAEUREESTERN AS WELL AS THEIR USE AS ACTIVE SUBSTANCE COMPONENT IN INSECTICIDES, AKARIZIDEN AND NEMATIZIDEN MEANS.

PROCEDURE FOR THE PRODUCTION OF NEW ONES O-PHENYLDITHIOPHOSPHONSAEUREESTERN AND YOUR USE AS INSECTICIDES, AKARIZIDE AND NEMATIZIDE.

O-MORE PHENYLDITHIOPHOSPHONSAEUREESTER, PROCEDURES FOR YOUR PRODUCTION AND YOUR USE THAN INSECTICIDES, AKARIZIDE AND NEMATIZIDE.

PROCEDURE FOR THE PRODUCTION OF NEW ONES O-PHENYLDITHIOPHOSPHONSAEUREESTERN AND YOUR USE AS INSECTICIDES, AKARIZIDE AND NEMATIZIDE.

Production of 1-aralkyl biguanide derivatives useful as herbicide intermediates comprises reacting aralkylamine compounds with dicyanodiamide at high temperature in temperature controlling diluent

Production of 1-aralkyl biguanide derivatives (I) comprises reacting aralkylamine derivatives (II) with dicyanodiamide at 120-150 deg C in the presence of an inert diluent with a boiling point that allows the temperature to be controlled at 120-150 deg C and optionally in the presence of an additional diluent. Production of 1-aralkyl biguanide derivatives of formula (I) or their acid addition salts comprises reacting aralkylamine derivatives of formula (II) or their acid addition salts with dicyanodiamide at 120-150 deg C in the presence of an inert diluent with a boiling point that allows the temperature to be controlled at 120-150 deg C and optionally in the presence of an additional diluent. A = a single bond, alkanediyl, oxaalkanediyl or thiaalkanediyl; R = alkyl and Z = optionally substituted aryl or heteroaryl.

New thienylcycloalkylamino-1,3,5-triazine and thienylcycloalkenylamino-1,3,5-triazine derivatives are herbicides useful as desiccants and defoliants and especially for weed control

New thienylcycloalk(en)ylamino-1,3,5-triazine derivatives are claimed, and are prepared via new thienylcycloalk(en)yl-biguanidine derivatives. The thienylcycloalk(en)ylamino-1,3,5-triazine derivatives are of formula (I). Z = group of formula (i) or (ii); R<1> = H or optionally substituted alkyl; R<2> = H, CHO, or alkyl, alkyl-CO-, alkoxy-CO- or alkyl-NH-CO- (each optionally substituted), or NR<1>R<2> forms dialkylaminoalkylideneamino; R<3> = H, halo, or alkyl, alkyl-CO-, alkoxy-CO-, alkoxy, alkylthio, alkyl-SO-, alkyl-SO2-, alkenyl, alkynyl or cycloalkyl (each optionally substituted); R<4> = NH2, CN, CONH2, CSNH2, CHO, halo, or alkyl, alkyl-CO-, alkoxy, alkoxy-CO-, alkylthio, alkyl-SO-, alkyl-SO2-, alkyl-NH-, (alkyl)2N-, alkyl-CO-NH-, alkoxy-CO-NH-, alkyl-SO2-NH-, alkenyl, alkynyl, alkenyl-CO-, alkynyl-CO-, aryl, aryl-CO- or aralkyl (each optionally substituted); R<5> = any group R<4> or NO2; A<1>, A<2> and A<3> = O, S, CO, CS, or alkanediyl, provided at least 1 is alkanediyl and 2 S or ...

VERFAHREN ZUR HERSTELLUNG VON 1,1-DICHLORALKENEN

Novel triazines useful as herbicides suitable for the selective control of monocotyledonous and dicotyledonous weeds

Herbicidal substituted cyclohexylalkylamino-1,3,5-triazines (I), are new. Substituted 1,3,5-triazines of formula (I) are new. A = CHR3R4, 1C-haloalkyl-substituted 3-6C cycloalkyl, 3-6C alkynyl or 1-4C cyanoalkyl; R3, R4 = CN, halo, 1-4C alkoxy-substituted 1-6C alkyl, 1-4C haloalkyl or 3-7C cycloalkyl (both optionally substituted by NO2, CN, OH or halo); in each case optionally CN, halo or 1-4C alkoxy-substituted alkyl, alkoxy, alkylthio, alkyl-sulfinyl or alkyl sulfonyl (all having 1-6C) or optionally CN-, halo- or 1-4C alkyl substituted 3-6C cycloalkyl (sic); provided that the total number of carbon atoms of R3 + R4 is more than 3; R1 = amino, formylamino, dialkylaminoalkylidene amino, having up to 6C; optionally CN-, halo- or 1-4C alkoxy substituted alkyl carbonyl amino; alkoxy-carbonylamino or alkylaminocarbonylamino; R2 = alkyl, alkoxy, alkyl carbonyl, alkoxy-carbonyl, alkylthio, alkylsulfinyl or alkylsulfonyl (all optionally substituted by OH, CN, halo or 1-4C alkoxy), CN, halo or ...

IMIDE AMIDE DERIVATIVES

THIENOCYCLOALK (EN) YLAMINO-1,3,5-TRIAZINE SUBSTITUTED HERBICIDES

Herbicide implants for plants

CHLORINE-SUBSTITUTED VINYLAMINOBENZOIC ACID DERIVATIVES

SUBSTITUTED PYRIDYL-PHENYL ETHERS

SUBSTITUTED DITHIO-PHOSPHONIC ACID ESTER-AMIDES

GUANIDINE DERIVATIVES OF 6-MEMBERED AROMATIC N-HETEROCYCLICS

PYRIMIDINE %4,6<DIYL-BIS-%THIONO<%THIOL<-PHOSPHORIC %PHOSPHONACID ESTERS

THIONOTHIOLPHOSPHORIC ACID ESTER

Herbicidal 5-chlorodifluoramethyl-1,3,4-thiadiazol-2-yl-oxyacetanilides

N' -(4,6-DIMETHYL-PYRIMIDIN-2-YL)-N'' -(DI)SUBSTITUTED-N'''-(FLUOROALKOXYPHENYL-SULFONYL)- GUANIDINES

Novel herbicidally active fluoroalkoxyphenylsulphonylguanidines of the formula < IMG > in which M is hydrogen or one equivalent of a metal, R1 is fluorine-substituted alkyl, and R2, R3 and R4 each independently is hydrogen or various organic radicals, or 1:1 adducts thereof with strong acids.

MICROBICIDAL AGENTS CONTAINING 4-NITROSO-PYRAZOLES

Microbicidal agents which are used for protecting industrial materials and contain 4-nitroso-pyrazoles of the formula < IMG > wherein R1 represents cyanoalkyl with up to 6 carbon atoms, C3 to C8-cycloalkyl which is optionally interrupted by -S-, -SO- or SO2-, phenyl which is substituted by nitro, C1 to C4-alkoxy and/or phenylsulphonyl, benzyl which is optionally substituted by halogen, nitro, C1 to C4- alkyl and/or C1 to C4-alkoxy, or a 5-membered or 6-membered heterocyclic ring which contains 1 or 2 nitrogen atoms and optionally contains a sulphur atom and which is optionally benzofused. Certain new 4-nitroso-pyrazoles are disclosed wherein R1 is cyano-ethyl, phenyl which is nitro, methoxy and/or phenylsulphonyl substituted, pyrimidinyl, benzothiazolyl or the radical < IMG > ...

N'(4,6-DIMETHYLPYRIMIDIN-2-YL)-N"-SUBSTITUTED HYDROXY-N"'-(1-SUBSTITUTED-BENZENESULPHONYL)- GUANIDINE COMPOUNDS

ABSTRACT Herbicidally active oxyguanidine derivatives of the formula in which M represents hydrogen or one equivalent of a metal, R1 represents halogen, C1-C4-alkyl, C1-C2-halogeno-alkyl, C1-C4-alkoxy, phenyl or C1-C2-alkoxy-carbonyl, R2 represents hydrogen or the radical , and R3 represents C4-C12-alkyl, isopropyl or -if M represents one equivalent of a metal - also propyl, or represents C2-C12-halogenoalkyl, C1-C4-alkoxycarbonyl-C1-C2-alkyl, amino-carbonylmethyl, C1-C4-alkylaminocarbonylmethyl, di-C1-C4-alkylaminocarbonylmethyl, C3-C12-alkenyl, C3-C12-alkinyl, benzyl which is sub stituted by halogen, nitro, cyano, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or phenyl, benzhydryl, or phenethyl, all optionally substituted by halogen, nitro, cyano, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or carboxy-C1-C2-alkyl. or adducts thereof with strong acids. Le A 23 187

PYRIMIDINYLTHIONOPHOSPHONIC ACID ESTERS, PROCESS FOR THEIR PREPARATION AND THEIR USE AS INSECTICIDES, ACARICIDES AND NEMATOCIDES

... . The present invention relates to compositions of matter based on certain new pyrimidinylthionophosphonic acid esters, to a process for their preparation and to their use as insecticides, acaricides and nematocides. It is already known that pyrimidinylthionophosphonic acid esters, for example, O,O-dimethyl- and O,O-diethyl-O-pyrimidin(2)yl-thionophosphoric acid ester or O,O-diethyl-O-¢2-isopropyl-4-methyl-pyrimidin(6)yl!-thiono-phosphoric acid ester, have insecticidal and acaricidal properties (compare United States Patent Specification 3,741,968 and German Patent Specification 947,206). The present invention provides a composition of matter which comprises one or more pyrimidinylthionophosphonic acid esters of the general formula: (I) in which R represents alkyl with 1 to 6 carbon atoms, R' represents alkyl with 1 to 6 carbon atoms or phenyl, R" and RIV, which can be the same or different, represent alkyl with 1 to 4 carbon atoms or hydrogen, and R"' represents halogen or hydrogen alone ...

SUBSTITUTED ARYL SULPHONYL(THIO)UREAS USED AS HERBICIDES

The invention relates to novel substituted arylsulphonyl(thio)ureas (see formula I) in which A ~represents nitrogen or a CH grouping, Q ~represents oxygen or sulphur, R1 ~represents hydrogen, halogen or respectively optionally substituted alky l, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or hetero- cyclyloxy, R2 ~represents hydrogen, halogen or respectively optionally substituted alky l, alkoxy, alkylthio, alkylamino, dialkylamino, cycloalkyl, cycloalkyloxy or hetero- cyclyloxy, R3 ~represents hydrogen or optionally substituted alkyl, R4 ~represents respectively optionally substituted alkyl, alkoxy, alkenyl, alkinyl, alkenyloxy, alkinyloxy, cycloalkyl, cycloalkyloxy or cycloalkylalkyl, and R5 ~represents hydrogen, formyl or respectively optionally substituted alkyl , alkyl- carbonyl, alkoxycarbonyl, alkylsulphonyl, alkenyl, alkinyl, cycloalkyl, cycl o- alkylcarbonyl, cycloalkylsulphonyl or heterocyclyl, and to salts of compounds of the formula (I), except for ...

SUBSTITUTED 2,4-DIAMINO-1,3,5-TRIAZINE AS HERBICIDE

The invention relates to a novel substituted 2,4-diamino-1,3,5-triazine of the general formula (I), in which R1 stands for hydrogen or for optionally substituting alkyl, R2 stands for formyl or for optionally substituting alkylcarbonyl, alkoxycarbonyl, alkylsulfonyl, arylcarbonyl or arysulfonyl respectively, R3 for optionally substituting alkyl or cycloalkyl respectively, R4 for hydrogen or alkyl, A for oxygen or methylene, Ar for optionally substituting aryl or heterocyclyl respectively and Z for hydrogen, hydroxy, cyano, nitro, halogen or for optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl or alkinyl respectively (in which three previously known combinations are excluded). The disclosure also relates to a method and to new intermediate products for producing the new compounds and their use as herbicides.

Substituted 2,4-diamino-1,3,5-triazine and their use as herbicides

The invention relates to novel substituted 2,4-diamino-1,3,5-triazines of the formula (I) in which R 1 represents, for exampe, H or C 1 -C 6 -alkyl, R 2 represents, for example, H, C 1 -C 6 -alkyl or —CO—R 6 , R 3 represents, for example, H, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkinyl or C 3 -C 6 -cycloalkyl, R 4 represents, for example, H, C 1 -C 6 -alkyl or C 3 -C 6 -cycloalkyl, R 5 represents one of the groupings below, where R 6 represents, for example, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy or C 2 -C 6 -alkenyl, R 7 to R 12 represents, for example, H or certain organic radicals and Q represents O or S, to processes and novel intermediates for their preparation and to their use as herbicides.

Substituierte Heterocyclylakylamino-1,3,5-triazine

The invention relates to substituted heterocyclyl alkylamino-1,3,5-triazines of general formula (I), in which R<1>, R<2>, R<3>, R<4> and R<5> have the meanings cited in the description. The invention also relates to the use of the inventive compounds as selective herbicides, and to methods and intermediate products for the production thereof.

SUBSTITUTED 1,3,5-TRIAZINE AS HERBICIDES

Substituted arylalkylamino-1,3,5-triazines

Substituted 2,4-diamino-1,3,5-triazines as herbicides

Substituted 1,3,5-triazines

Substituted triazoloazine sulphonamides

Substituted thienylalkylamino-1,3,5-triazines for use as herbicides

NOVEL TERT.-BUTYL-SUBSTITITED PYRAZOLYL(THIONO)(THIOL)- PHOSPHORIC(PHOSPHONIC) ACID ESTERS AND ESTER-AMIDES

N-DICHLOROACETYL-1,2,3,4-TETRAHYDRO-QUINALDINE

Substituted n-aryl-o-alkyl-carbamates

SULPHONYLOXYPYRIMIDINYL (THIONO) (THIOL-PHOSPORIC (PHOSPHONICACID ESTERS AND AMIDES

Substituted imide derivatives

Heterocyclically bisubstituted sulphonyl amino(thio)carbonyl compounds

SUBSTITUTED PYRIDYL-PHENYL ETHERS

FLUOROALKYLOXYPHENYL - SULPHONYLGUANIDINE

OPTICALLY ACTIVE ARALIPHATIC 2-(4(SUBST.PH/PYR)OXYPHENOXY)PROPRIONATES

Substituted 1,3,5-triazines

PROCESS FOR THE PREPARATION OF SULPHONYLISO(THIO)UREAS

A process for the preparation of a sulphonyliso(thio)urea of the formula < IMG > in which R1 represents an optionally substituted radical from the group consisting of alkyl, aralkyl, aryl and heteroaryl, R2 represents an optionally substituted and/or optionally fused, six-membered aromatic heterocycle containing at least one nitrogen atom, R3 represents an optionally substituted radical from the group consisting of alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkyl-alkyl and aralkyl, and Q represents oxygen or sulphur, comprising reacting a sulphonylguanidine of the formula < IMG > in which R4 represents an optionally substituted hydrocarbon radical, with a compound or the formula H-Q-R3 at a temperature between 0.degree.C and 150.degree.C. The products are known herbicides.

1-(2-OXYAMINOSULPHONYLPHENYLSULPHONYL)-3-HETEROARYL- UREAS

... 1-(2-Oxyaminosulphonylphenylsulphonyl)-3-heteroaryl-ureas The invention relates to new 1-(2-oxyaminosulphonyl-phenylsulphonyl)-3-heteroaryl-ureas of the general formula (I) < IMG > (I) in which R1 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl and aralkyl and R3 represents an optionally substituted and/or optionally fused six-membered aromatic heterocyclic radical containing at least one nitrogen atom, the following compounds being excluded: 1-(2-methoxy-aminosulphonylphenylsulphonyl)-, 1-(2-ethoxy-aminosulphonylphenylsulphonyl)-, 1-(2-propoxy-amino-sulphonylphenylsulphonyl)-, 1-(2-isopropoxyaminosulphonylphenyl-sulphonyl)- and 1-(2-butoxyaminosulphonylphenylsulphonyl)-3-(4,6-dimethyl-pyrimidin-2-yl)-urea, -3-(4,6-diethyl-pyrimidin-2-yl)-urea, -3-(4,6-dipropyl-pyrimidin-2-yl)-urea, ...

1-(2-OXYAMINOSULPHONYLPHENYLSULPHONYL)-3-TRIAZINYL- UREAS

Herbicidally active novel 1-(2-oxyaminosulphonylphenyl-sulphonyl)-3-triazinyl ureas of the formula in which R1 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 represents fluorine, chlorine, bromine, hydroxyl, cyclopropyl or C1-C4-alkyl (which is optionally substituted by fluorine and/or chlorine), or represents C1-C4-alkoxy (which is optionally substituted by fluorine and/or chlorine), or represents C1-C4-alkylthio (which is optionally substituted by fluorine and/or chlorine) or amino, or represents C1-C4-alkyl- or di-(C1-C4-alkyl)-amino (which are optionally substituted by fluorine) and R3 represents fluorine, chlorine, bromine, hydroxyl, cyclopropyl or C1-C4-alkyl (which is optionally substituted by Fluorine and/or chlorine), or represents C1-C4-alkoxy (which is optionally substituted by fluorine and/or chlorine), or represents C1-C4-alkylthio (which is optionally substituted by fluorine ...

(THIONO)(THIOL) PYRIDAZINONE-ALKANEPHOSPHONIC ACID ESTERS, THEIR USE AS INSECTICIDES AND ACARICIDES

The present invention relates to certain new (thiono) (thiol)pyridazinone-alkanephosphonic acid esters, to a process for their preparation and to their use as insecticides and acaricides. It is already known that (thiono)pyridazinephosphoric (phosphonic) acid esters, for example 0,0-diethyl-0¢1,6-dihydro-1-phenyl-, 1-methyl-, 1-carbethoxymethyl-, 1-(2'-cyanoethyl)- and 1-(2'-methyl-carbonylethyl)-6-pyridazinon- (3)yl!-thionophosphoric acid esters, 0,0-diethyl-0-¢1,6-dihydro-1-phenyl-6-pyridazinon(3)yl!-phosphoric acid ester and 0-ethyl-0-¢1,6-dihydro-6-pyridazinon(3)yl!-thionoethane-phosphonic acid ester, possess insecticidal and acaricidal properties (see U.S.Patent Specifications 2,759,937 and 3,310,560 and Netherlands Published Patent Application 6,904,664).

CYANOALKYLPHOSPHORIC ACID ESTER CHLORIDES AND A PROCESS FOR THEIR PREPARATION

New cyanoalkylphosphoric acid ester chlorides of the general formula in which R represents a hydrogen atom, an optionally substituted radical selected from alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical, R1 represents an optionally substituted radical selected from alkyl, alkenyl, alkinyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, alkenylthio, alkinylthio, arylthio, aralkylthio, alkylamino (monoalkylamino or dialkylamino), arylamino or aralkylamino and X represents oxygen or sulphur are obtained by the reaction of a phosphoric acid dichloride of the general formula (II) in which R1 and X have the meaning given above, with an aldehyde of the general formula R-CHO (III) in which R has the meaning given above, in the presence of an approximately equimolar quantity of a water-soluble cyanide. The compounds of the formula (I) can be used as intermediate products for the preparation of insecticides ...

O-ETHYL-S-N-PROPYL-O-(PYRAZOLO(1,5-A)-PYRIMIDIN-(2)YL)-THIONOTHIOLPHOSPHORIC ACID RS

O-ETHYL-S-n-PROPYL-O-¢PYRAZOLO(1,5-a)-PYRIMIDIN-(2)YL!-THIONOTHIOLPHOSPHORIC ACID ESTERS O-Ethyl-S-n-propyl-O-¢pyrazolo(1,5a)-pyrimidin(2)-yl!-thionothiolphosphoric acid esters of the formula (I) in which R is hydrogen or halogen, R1 is alkyl with 1 to 5 carbon atoms or hydrogen, R2 is hydrogen, halogen or acetyl, and R3 is hydrogen, alkyl with 1 to 4 carbon atoms or carbalkoxy with 1 to 4 carbon atoms in the alkyl radical, which possess arthropodicidal and nematicidal properties.

SELECTIVE HERBICIDES BASED ON N-AZINYL-N'-(2-ETHYLTHIO- PHENYLSULPHONYL)-UREAS

Selective herbicides based on N-azinyl-N'-(2-ethylthio- phenylsulphonyl)-ureas A b s t r a c t The invention relates to selective herbicides based on N-azinyl-N'-(2-ethylthio-phenylsulphonyl)-ureas of the general formula (I) (I) in which X represents hydrogen, halogen, C1-C3-alkyl (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkoxy (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkylthio, C1-C3-alkylamino or di-(C1-C2-alkyl)-amino, Y represents halogen, C1-C3-alkyl (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkoxy (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkylthio, C1-C3-alkylamino or di-(C1-C2-alkyl)-amino, and Z represents nitrogen or the grouping C-Z1, where Z1 represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, methoxy or ethoxy, and new compounds of the formula (I), and processes for their preparation.

SULPHONYL AMINO CARBONYL TRIAZOLINONES

The invention relates to new sulphonylaminocarbonyltriazolinones of the formula (I) (See formula I) in which Q represents oxygen, sulphur or one of the following groups (See formula II, III, IV) (in which the radicals R1, R2, R3 and R4 have the meanings given in the description), as well as to salts of compounds of the formula (I), to processes and novel inter-mediates for the preparation of the novel compounds, and to their use as herbicides.

SULPHONYL AMINO CARBONYL TRIAZOLINONES

The invention relates to new sulphonylaminocarbonyltriazolinones of the formula (I) (See formula I) in which Q represents oxygen, sulphur or one of the following groups (See formula II, III, IV) (in which the radicals R1, R2, R3 and R4 have the meanings given in the description), as well as to salts of compounds of the formula (I), to processes and novel inter- mediates for the preparation of the novel compounds, and to their use as herbicides.

N-AZINYL-N-(2-ETHYLSULPHINYL- PHENYLSULPHONYL)-UREAS

N-Azinyl-N'-(2-ethylsulphinyl-phenylsulphonyl)-ureas A b s t r a c t The invention relates to new N-azinyl-N'-(2-ethyl-sulphinyl-phenylsulphonyl)-ureas of the formula (I) (I) in which A represents nitrogen or a CH group, X represents hydrogen, halogen or alkyl, alkoxy or alkylthio, each of which has 1 to 3 carbon atoms and each of which is optionally substituted by halogen and Y represents alkyl or alkoxy, each of which has 1 to 3 carbon atoms and each of which is optionally substituted by halogen, and salts of compounds of the formula (I), processes for the preparation of these compounds and their salts, and their use as herbicides. Le A 28 897-Foreign Countries ...

SUBSTITUTED SULPHONYLAMIDINOHYDRAZONES

ABSTRACT OF THE DISCLOSURE Herbicidal substituted sulphonylamidinohydrazones of the formula

MITTEL ZUR BEEINFLUSSUNG DES PFLANZENWACHSTUMS

SUBSTITUTED 2,4-DIAMINO-1,3,5-TRIAZINE

Substituted N-cyano amidines

Substituted sulphonyl amino(thio)carbonyl compounds and their use as herbicides

N-(1-isopropyl-2-methyl-1-propenyl)heteroaryloxyacetamides and the use thereof as herbicides

Substituted sulphonylamino (thio)carbonyl compounds as herbicides

Substituted aryl sulphonyl amino(thio)carbonyl-triazolin(thi)ones as herbicides

VINYL(THIONO)(THIOL) PHOSPHORIC(PHOSPHONIC) ACID ESTERS

Process for producing n-phosphonomethyl glycine

CARBONYL PHENYL-SULPHONYLGUANIDINES

OXYGUANIDINE DERIVATIVES

Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides

PYRAZOLOPYRIMIDINYL(THIONO)(THIOL)- PHOSPHORIC(PHOSPHONIC) ACID ESTERS AND THEIR USE AS INSECTICIDES AND ACARICIDES

Abstract of the Disclosure O-Alkyl-O-[5-carbalkoxy-7-alkyl-pyrazolo (1,5-.alpha.)-pyrimidin-2-yl]-(thiono)(thiol)-phosphoric (phosphonic) acid esters of the formula

BENZODISULTAMS

Benzodisultams The invention relates to new benzodisultams of the general formula (I) in which R1 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkemyl, alkinyl and aralkyl, and R3 represents an optionally substituted and/or optionally fused six-membered aromatic heterocyclic radical which contains at least one nitrogen atom, a process for their preparation and their use as herbicides.

PROCESSES FOR THE PREPARATION OF 4-ALKOXY-6-ALKYL-2- CYANAMINO-1,3,5-TRIAZINES

... (IV) (V) (II) (III) (I) in which R1 is alkyl, R2 is alkoxy, R3 is H, or one equivalent of an alkali metal or alkaline earth metal ion, and R4 is one equivalent of an alkali metal or alkaline earth metal. The process is new and intermediate II is new. If R3 is an alkali or alkaline earth metal it can be converted to hydrogen by acid. The products are known intermediates for herbicides and plant growth regulators.

SUBSTITUTED PYRIDYL-PHENYL ETHERS

Substituted Pyridyl-phenyl Ethers Abstract of the Disclosure Novel substituted pyridyl-phenyl ethers of the formula (I) in which X represents trifluoromethyl or chlorine, Y represents hydrogen or chlorine, R1 represents hydrogen or methyl and R2 represents formyl or the radicals of the formulae or in which R3 represents alkyl with 1 to 4 carbon atoms, or the two radicals R3 together represent an alkylene chain with 2 or 3 carbon atoms, R4, R5, R6 and R7 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms, m represents 1 or 2, n represents 0 or 1 and Z represents trimethylsilyl or a radical of the formula:

HETEROCYCLICALLY DISUBSTITUTED SULPHONYLAMINO(THIO)CARBONYL COMPOUNDS

The invention relates to new heterocyclically disubstituted sulphonylamino(thio)carbonyl compounds of the formula (I) in which Q represents oxygen or sulphur, R1 and R2 axe identical or different and independently of one another represent a radical from the series comprising heterocyclyl, heterocyclylamino and heterocyclylimino, in each case optionally substituted and bonded via N, with the exception of optionally substituted pyrazolylamino in the meaning of R1, and salts of the compounds of the formula (T), furthermore to processes for their preparation, and to their use as herbicides.

SUBSTITUTED ARYL SULPHONYL AMINO (THIO) CARBONYL TRIAZOLIN(THI)ONES

The invention relates to novel substituted aryl sulphonyl amino (thio) carbonyl triazolin(thi)ones of formula (I) in which Ar is possibly substituted arylene or heteroarylene; Q1 is oxygen or sulphur; Q2 is oxygen or sulphur; R1 is hydrogen, hydroxy, amino, alkylidene amino or a possibly substitued radical from the series alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkyl alkyl, aryl, arylalkyl; R2 is hydrogen, hydroxy, mercapto, amino, halogen or a possibly substituted radical from the series alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, alkylthio, alkenylthio, alkinylthio, alkylamino, alkenylamino, alkinylamino, dialkylamino, alkanoylamino, aziridino, pyrrolidino, piperidino, morpholino, cycloalkyl, cycloalkenyl, cycloalkoxy, cycloalkylthio, cycloalkylamino, cycloalkyl alkyl, cycloalkyl alkoxy, cycloalkyl alkylthio, cycloalkyl alkylamino, aryl, aryloxy, arylthio, arylamino, arylalkyl, arylalkoxy, arylalkylthio, arylalkylamino ...

HERBICIDAL OR FUNGICIDAL SULPHONYLAMINOCARBONYLTRIAZOLINONESWITH HALOGENATED ALK(EN)OXY SUBSTITUENTS

The invention relates to novel sulphonylaminocarbonyltriazolinones havi ng halogenoalkoxy substituents of the formula (I) (see formula I) in which R1 represents hydrogen, hydroxyl, amino, alkylideneamino or a respective ly optionally substituted radical from the group consisting of alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl and arylalkyl, R2 represents respectively halogen-substituted alkyl or alkenyl, and R3 represents a respectively optionally substituted radical from the gro up consisting of alkyl, aralkyl, aryl and heteroaryl, and salts of compounds of the formula (I), and to processes and novel intermediates for preparing the compounds (I), and to their use as herbicide s and/or fungicides.

SELECTIVE HERBICIDES BASED ON METRIBUZIN AND SUBSTITUTED IMIDAZO[1,2-A]PYRIDIN-3-YL-SULFONYL COMPOUNDS

The novel herbicidally active compound combinations comprising (a) metribuzi n of the formula (I) and (b) an active compound from the group of the substituted imidazo[1,2-a]pyridin-3-yl-sulfonyl compounds of the formula (II) (see formula I) where Z ~~represents N or CH and R, X and Y ~are each as defined in the description, exhibit synergistic activities at certain weight ratios and can be used as selective herbicides in a variety of crop plants (for example maize, wheat and barley) .

2,4-diamino-pyrimidine derivatives and their use as microbicides and herbicides

The invention relates to novel 2,4-diamino-pyrimidine derivatives of the formula (I), in which R?1, R2, R3, R4, R5 and R6¿ have the meanings defined in the description. The invention also relates to their acid addition salts and metal salt complexes and to several methods for producing said novel substances and to their use as microbicides and herbicides. Also disclosed are novel intermediates of the formulae (IIa) and (IIb), wherein R?1, R5, R6¿, X and Z have the meanings defined in the description, and to methods for producing them.

New 2,4-diamino-pyrimidine derivatives useful as microbicides in protection of plants and materials and as herbicides

2,4-Diamino-pyrimidine derivatives (I) are new. 2,4-Diamino-pyrimidine derivatives of formula (I) and their addition salts and metal salt complexes are new. R<1> = CF3; CHF2; CClF2; CH3; OCH3; OCF3; SCH3; SCF3; CH3SO; CH3SO2; CN; Cl; Br; COOH; CONH2 or alkoxycarbonyl; R<2> = halo; CN or NO2; R<3> = H; alkyl; OH; alkoxy; NH2; NH(alkyl); N(alkyl)2; CH3SO2; COCH3; COOH; alkoxycarbonyl; CONH2; alkyl-NH-CO or CF3CO; R<4> = cycloalkyl, aryl, aralkyl, aryloxyalkyl, heteroaryl or heteroarylalkyl (each optionally substituted); R<5>, R<6> = H; alkyl; CH3SO2; COCH3; COOH; alkoxycarbonyl; CONH2; alkyl-NH-CO or CF3CO or R<5> + R<6> = 4-6C alkylene or (CH2)2-O-(CH2)2 or R<1> = CF3; CHF2; CClF2; CH3; OCH3; OCF3; SCH3; SCF3; CH3SO2; CN; Cl; Br; COOH; CONH2; or alkoxycarbonyl; R<2> = H; R<3> = H; alkyl; OH; alkoxy; NH2; NH(alkyl); N(alkyl)2; CH3SO2; COCH3; COOH; alkoxycarbonyl; CONH2; alkyl-NH-CO or CF3CO; R<4> = cycloalkyl, aryl, aralkyl, aryloxyalkyl, heteroaryl or heteroarylalkyl (each optionally substituted); R<5> = H and R<6> = CH3SO2 or CF3CO. Independent claims are also included for the following: (1) preparation of (I); (2) new 4-halo-2-amino-pyrimidine compounds of formula (II); (3) new 4-hydroxy-pyrimidine compounds of formula (VIII); (4) preparation of compounds (II) and (5) preparation of compounds (VIII). X, Z = Cl or Br.

Dichlorpyridylmethylcyanamidine

Neue Dichlorpyridylmethylcyanamidine der Formel DOLLAR F1 in welcher DOLLAR A R·1· für Wasserstoff, Alkyl oder gegebenenfalls substituiertes Aralkyl steht und DOLLAR A R·2· für Wasserstoff, gegebenenfalls substituiertes Alkyl, gegebenenfalls substituiertes Alkoxy, gegebenenfalls substituiertes Alkylthio, gegebenenfalls substituiertes Aryl, gegebenenfalls substituiertes Aryloxy oder gegebenenfalls substituiertes Arylthio steht, DOLLAR A ein Verfahren zur Herstellung der neuen Stoffe und deren Verwendung zur Bekämpfung von unerwünschten Mikroorganismen.

Substituting 2-amino-4-alkylamino-1,3,5-triazine as herbicide

The invention relates to a novel substituted 2-amino-4-alkylamino-1,3,5-triazine of the general formula (I), in which R1 stands for optionally substituted methyl, R2 stands for hydrogen or alkyl, Y for substituted benzyl, naphthylmethyl, heterocyclymethyl or heterocyclyoxy respectively, and Z for hydrogen, halogen, or for optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl or alkinyl respectively. Disclosed is also a method and new intermediate products for producing the new compounds and their use as herbicides.

Amide derivs. for use as herbicidal antidote(s)

Amides of formula (I) are used to improve tolerance of crops towards herbicidal acetamide derivs. of formula (II). R = H, halo or (all opt. substd.) alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, tricycloalkyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, aryloxy, carbamoyl, alkoxycarbonyl or dithiobanyl; R1 and R2 = H, HCO, ClSO2 or (all opt. susbtd.) alkyl, alkenyl, alkadienyl, alkynyl, cycloalkyl, cycloalkenyl, alkoxy, alkylthio, alkylcarbonyl, alkoxycarbonyl, Ph, PhO, PhSO2 or heterocyclyl; or they are NH2, alkylideneimino or opt. substd. alkylcarbonylamino or di(alkylcarbonyl)amino; R1 and R2 may together complete opt. substd. alkylideneimino; pyrrolidinyl; piperidinyl; piperidonyl; perhydroazepinyl, perhydroazocinyl; dihydropyrazolyl; di- or tetra-hydropyridinyl; azabicyclononyl; morpholinyl; perhydro-1,3-oxazinyl; 1,3-oxazolidinyl; 1,4-piperazinyl; perhydro-1,4-diazepinyl; di-, tetra- or per-hydroquinolyl or -isoquinolyl; indoly or di- or per-hydroindilyl; Het = opt. substd. 5-membered heterocylyl, opt. fused to a benzo ring; R3 and R4 = H, alkyl (opt. substd.), alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkoxy, alkenyloxy, alkoxyalkoxy, heterocyclyl or opt. substd. aryl, or R3 and R4 together complete an opt. substd., satd. or unsatd. heterocycle which may contain further hetero atoms.

Substituted 1,3,5-triazines

The invention relates to novel substituted 1,3,5-triazines of general formul a (I), in which A represents CHR3R4 or represents C1-halogenoalkyl-substituted C3-C6-cycloalkyl, C3-C6-alkinyl or C1-C4- cyanoalkyl, where R1, R2, R3 and R4 are each as defined in the description, and to processes for their preparation, to novel intermediates, including their preparation, and to the use of the compounds of general formula (I) as herbicides.

Substituting 2-amino-4-alkylamino-1,3,5-triazine as herbicide

The invention relates to a novel substituted 2-amino-4-alkylamino-1,3,5-triazine of the general formula (I), in which R1 stands for optionally substituted methyl, R2 stands for hydrogen or alkyl, Y for substituted benzyl, naphthylmethyl, heterocyclymethyl or heterocyclyoxy respectively, and Z for hydrogen, halogen, or for optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl or alkinyl respectively. Disclosed is also a method and new intermediate products for producing the new compounds and their use as herbicides.

SUBSTITUTED 1,3,5-TRIAZINES AS HERBICIDES

Sulfonyl-guanidinotriazine derivatives

Novel sulphonylguanidinotriazine derivatives of the formula I <IMAGE> (in which the radicals M, R<1>, R<2>, R<3>, R<4> and R<5> are as defined in the description> and 1:1-adducts of compounds of the formula (I) with strong acids, their preparation and their use as herbicides.

O-ethyl-o-pyridazinyl thiono benzene phosphonic acid esters

Substituted arylsulfonyl guanidines

Novel substituted arylsulphonylguanidines of the formula (I) <IMAGE> (where the radicals M, R<1>, R<2>, R<3> and the indices m and n are as defined in the description), and 1:1-adducts of compounds of the formula (I) with strong acids, their preparation, and their use as herbicides.

5-Aryl-3-(1'-halogen-1'-methyl)ethyl-pent-4-en-carboxylic acid esters, process for their preparation, and their use for the preparation of 3-(2-arylvinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid esters

A process for the preparation of 3-(2-arylvinyl)-2,2-dimethyl- cyclopropane-1-carboxylic acid esters of the general formula (I) <IMAGE> in which Ar, R and R<1> have the meaning indicated in the description, which is characterised in that compounds of the general formula (II) <IMAGE> are reacted with a base, and novel intermediates for their preparation and processes for the preparation of these intermediates.

ENDOPARASICICIDAL AGENTS

Process for the preparation of styryl-cyclopropane carboxylates, intermediates therefor and their production

Derivatives of Phosphoryloxypyrazole

The present invention relates to the use of novel and of known phosphoryloxypyrazole derivatives of the general formula (I) <IMAGE> in which Q represents oxygen or sulphur, R<1> represents in each case optionally substituted alkyl or aryl, R<2> and R<3> are identical or different and independently of one another represent hydrogen, cyano, nitro, carbamoyl, carboxyl, halogen or in each case optionally substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkoxycarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl or aryl, R<4> represents alkyl and R<5> represents alkylthio, alkylamino, aralkylamino or dialkylamino, as herbicides and to novel substances of the formula (IA1) <IMAGE> in which Q, A<1>, A<2>, A<3>, A<4> and A<5> have the meanings given in the description, and to their use as pesticides.

Substituted sulphonyl amino azoles

The invention relates to novel substituted sulphonylaminoazoles of the general formula (I) <IMAGE> to a process for their preparation, and to their use as herbicides. The general formula (I) represents the possible isomers of the formulae (1A), (1B) and (1C), <IMAGE> and mixtures of these isomers. <??>(In the above formulae, the variable radicals R<1>, R<2>, R<3>, R<4>, A or A', D, E, X, Y and Z have the meanings given in the description).

Substituted 1,3,5-triazines as herbicides

The invention relates to novel substituted 1,3,5-triazines of general formula (I), in which A represents CHR3R4 or represents C¿1?-halogenoalkyl-substituted C3-C6-cycloalkyl, C3-C6-alkinyl or C1-C4-cyanoalkyl, where R?1, R2, R3 and R4¿ are each as defined in the description, and to processes for their preparation, to novel intermediates, including their preparation, and to the use of the compounds of general formula (I) as herbicides.

METHOD FOR PRODUCING SULVONYLISO (THIO) UREA

Substituted N-aryl-O-alkyl-carbamates

The invention relates to novel substituted N-Aryl-O-alkyl-carbamates of general formula (I), in which: m represents the numbers 0, 1 or 2; n represents the numbers 0 or 1; Ar represents an optionally substituted, monocyclic or bicyclic, if needed, partially saturated, carbocyclic or heterocyclic grouping; Q represents O (oxygen), S (sulfur), SO, SO2 or CH2 (carbene); R<1> represents optionally substituted alkyl; R<2> represents halogen or optionally substituted alkyl or alkoxy; R<3> represents hydrogen or alkyl, and; R<4> represents alkyl or cycloalkyl. The invention also relates to methods for producing the novel substituted N-Aryl-O-alkyl-carbamates, and to their use as herbicides.

Process for the preparation of 3,3-dimethyl-cyclopropane-1,2-dicarboxylic acid esters

A novel process for the preparation of known 3,3-dimethylcyclopropane-1,2-dicarboxylic acid esters of the formula I <IMAGE> in which R' and R have the meaning indicated in the description, which is characterised in that 1,3-dibromo-2,2-dimethylpropane-1,3-dicarboxylic acid esters of the formula II <IMAGE> are reacted at temperatures between 20 and 200 DEG C with zinc, if appropriate in the presence of a diluent.

Substituted alxoxycarbonyl compounds

The invention relates to novel substituted alkoxycarbonyl compounds of formula (I), wherein n stands for 0 or 1; Ar stands for an optionally substituted monocyclic or bicyclic saturated or optionally partially- unsaturated carbocyclic or heterocyclic group; Q represents O (oxygen), S (sulfur), SO, SO2, NH, N(Alkyl) or CH2 (methylene); R1 stands for alkyl or cycloalkyl; R2 stands for hydrogen or alkyl; Y stands for NH or N(alkyl) and Z stands for optionally substituted monocyclic or bicyclic, saturated or partially unsaturated heterocyclyl bonded by N or it also stands for optionally substituted cycloalkylamino or arylamino in case n stands for 1 and Ar stands for a bicyclic group. The invention also relates to the production of said compounds and to their use as agents in the treatment of plants, more particularly as a herbicide, fungicide and insecticide.

Substituted guanidine derivatives

A plant growth regulating compound of the formula ##STR1## in which R 2 is an optionally substituted nitrogen heterocyclic radical, R 3 is hydrogen, alkyl, cycloalkyl, alkenyl, alkinyl or aralkyl, and R 4 is hydrogen, or if R 3 is not hydrogen R 4 may be hydroxyl or a variety of radicals, or R 3 and R 4 together may form a ring, or an acid adduct thereof.

N'-(4,5,6-trisubstituted-pyrimidin-2-yl)-n''(di) substituted-n''-(di)substituted-n'''-(substituted- benzenesulphonyl)-guanidines

Sulphonylguanidinopyrimidine derivatives Abstract The invention relates to new sulphony(guanidino-pyrimidine derivatives of the general formula (I) (I) (wherein the radicals M, R1, R2, R3, R4, R5 and R6 have the meanings given in the description) and 1:1 adducts of compounds of the formula (I) with strong acids, processes for their preparation, and their use as herbicides. Le A 23 307 - Foreign countries

4-fluoro-3-phenoxy-benzyl ethers, process for their preparation, intermediate products therefor and process for their preparation

METHOD FOR PRODUCING OXYGUANIDINES

Herbicidal 5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacetanilides

The invention relates to novel 5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacet-anilides of the general formula (I) (see formula I) in which n represents the number 0, 1, 2 or 3, R represents straight-chain or branched alkyl having 1 to 4 carbon atoms, and X represents nitro, cyano, halogen or represents in each case optionally cyano-, halogen- or C1-C4-alkoxy-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl or alkylsulphonyl having in each case 1 to 4 carbon atoms, - except for the compounds N-methyl-5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacetanilide, N-ethyl-5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacetanilide, 4-chloro-N-methyl-(5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl)-oxyacetanilide and 3-trifluoromethyl-N-methyl-(5-chlorodifluorometh-yl-1,3,4-thiadiazol-2-yl)-oxyacetanilide, N-i-propyl-5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl-oxyacetanilide, and 4-fluoro-N-methyl-(5-chlorodi-fluoromethyl-1,3,4-thiadiazol-2-yl)-oxyacetanilide and 4-fluoro-N-ethyl-(5-chlorodifluoromethyl-1,3,4-thiadiazol-2-yl)-oxyacetanilide, and to a process for their preparation and to their use as herbicides.

3-SUBSTITUTED 1- (2-HALOGENALKOXY-BENZOLSULFONYL) -3-HETEROARYL- (THIO) UREA

METHOD FOR PRODUCING SULFONYL URINE SALTS, NEW SULFONYL URINE SALTS AND THEIR USE AS HERBICIDES

Substituted arylsulphonylaminoguanidinotriazines

(thiono) (thiol)phosphoric(phosphonic) acid esters and ester-amides and their use as insecticides and acaricides

Imidamide derivatives

The invention relates to novel imidamide derivatives of formula (I), wherein R, R1, R2 and R3 have the meaning mentioned in the description. The inventio n also relates to a method of production and to the use of said derivatives fo r combating animal pests such as insects, arachnids and especially nematodes.< /SDOAB>

Substituted n-aryl-o-alkyl-carbamates

Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides

Insecticide and acaricide means and method of making the active component

Preparation of sulphonylisothioureas

Disclosed is a process for the preparation of a sulphonylisothiourea of the formula ##STR1## wherein R 1 , R 2 , R 3 , X, Y and Z are as defined herein, which comprises reacting a sulphonic acid amide of the formula R.sup.1 --SO.sub.2 --NH.sub.2, (II) or a metal salt thereof, with an N-heteroaryl-iminodithiocarbonic acid, S,S-diester of the formula ##STR2## at a temperature between about 20° C. and 200° C. Intermediates and a process for their preparation are also disclosed.

Herbicidal or fungicidal sulphonylaminocarbonyltriazolinones with halogenated alk(en)oxy substituents

The invention relates to novel sulphonylaminocarbonyltriazolinones having halogenoalkoxy substituents of the formula (I) (see formula I) in which R1 represents hydrogen, hydroxyl, amino, alkylideneamino or a respectively optionally substituted radical from the group consisting of alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl and arylalkyl, R2 represents respectively halogen-substituted alkyl or alkenyl, and R3 represents a respectively optionally substituted radical from the group consisting of alkyl, aralkyl, aryl and heteroaryl, and salts of compounds of the formula (I), and to processes and novel intermediates for preparing the compounds (I), and to their use as herbicides and/or fungicides.

Use of amides for improving the tolerance by crop plants of herbicidally active heteroaryloxyacetamides

Heterocyclically bisubstituted sulphonyl amino(thio)carbonyl compounds

The invention relates to novel heterocyclically bisubstituted sulphonyl amino(thio)carbonyl compounds of formula (I) in which Q is oxygen or sulphur, R?1 and R2¿ are the same or different and mutually independently stand for a possibly substituted N-bonded radical from the series heterocyclyl, heterocyclylamino and heterocyclicylimino, substituted pyrazolylamino being excepted as the significance of R1, and salts of the compounds of formula (I), a process for their production and their use as herbicides.

Substituted arylsulfonyl-aminoguanidinoazine

Dithiophosphonic-acid esters

The invention relates to the novel dithiophosphonic acid esters of the general formula (I) <IMAGE> in which n stands for the numbers 0, 1 or 2 and R<1>, R<2> and R<3> are identical or different and stand for alkyl, which can be used as pesticides.

Sulfonylamino (thio) carbonyl compounds

The invention concerns novel sulphonylamino(thio)carbonyl compounds of formula (I) in which: A stands for a single bond, oxygen, sulphur or the N-R group, R standing for hydrogen, alkyl, alkenyl, alkinyl or cycloalkyl; Q stands for oxygen or sulphur; R<1> stands for hydrogen, formyl or for in each case optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkoxycarbonyl, alkylsulphonyl, cycloalkyl, cycloalkylcarbonyl or cycloalkylsulphonyl; R<2> stands for cyano, halogen or for in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy or alkinyloxy; and R<3> stands for in each case optionally substituted heterocyclyl with 5 ring members, of which at least one can be oxygen, sulphur or nitrogen, and between one and three further ring members can be nitrogen; as well as salts of compounds of formula (I), the previously known compounds 4,5-dimethoxy-2-(2,5-dimethoxy-phenyl-sulphonylaminocarbonyl)-2,4-dihy dro-3H-1,2,4-triazol-3-one, 4,5-diethoxy-2-(2,5-dimethoxy-phenylsulphonylaminocarbonyl)-2,4-dihydr o-3H-1,2,4-triazol-3-one and N-(2,5-dimethoxy-phenylsulphonyl)-1,5-dimethyl-1H-pyrazole-3-carboxamide being excluded by disclaimers. The invention further concerns processes and novel intermediate products for preparing the novel substances and their use as herbicides.

Sulphonyl-iso-thioureido-triazine derivatives and process therefor

ABSTRACT The invention relates to a sulphonylisothioureido-triazine derivative of the general formula (VIIA) (VIIA) in which R1A represents a substituted phenyl radical

0-alkyl-0-(6-substituted-pyridazin-(3)yl)-(thiono) (thiol)alkanephosphonic acid esters

Abstract of the Disclosure O-Alkyl-O-[6-substituted-pyridezin(3)yl]-(thiono) (thiol)alkanephosphonic acid ester of the formula

Herbicides containing as activ substance derivatives of sulphonil-guanidino-triazin and process for production of the activ substance

PROCESS FOR THE PREPARATION OF GUANIDINE DERIVATIVES

A plant growth regulating compound of the formula <IMAGE> in which R2 is an optionally substituted nitrogen heterocyclic radical, R3 is hydrogen, alkyl, cycloalkyl, alkenyl, alkinyl or aralkyl, and R4 is hydrogen, or if R3 is not hydrogen R4 may be hydroxyl or a variety of radicals, or R3 and R4together may form a ring, or an acid adduct thereof.

Preparation of oxyguanidines

A process for the preparation of an oxyguanidine of the formula ##STR1## in which R 1 is an organic radical, R 2 , R 3 and R 4 each is hydrogen or an organic or inorganic substituent, X is N or CH, Y is N or CR 3 , and Z is N or CR 4 , comprising reacting ##STR2## in which R 5 is optionally substituted alkyl or aralkyl, or its hydrogen halide, with a hydroxylamine derivative of the formula H.sub.2 N--O--R.sup.1 (III) at a temperature between about 0° C. and 150° C. New isothioureas of the formula ##STR3## are also shown.

PROCESS FOR THE PREPARATION OF REPLACED CARBONYLPHENYLSULPHONYL-GUANIDINES, HERBICIDIC COMPOSITIONS, APPLICATION, PROCESSES FOR PREPARING COMPOSITES AND FOR PREPARING COMPOUNDS

Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides

The invention relates to novel substituted 2-amino-4-alkylamino-1,3,5-triazines of formula (I), in which R1 stands for respectively optionally substituted alkyl with 2 to 6 carbon atoms or cycloalkyl with 3 to 6 carbon atoms, R2 stands for hydrogen or alkyl with 1 to 4 carbon atoms, A for oxygen or methylene, Ar for respectively optionally substituted phenyl, naphthyl or heterocycyl, and Z for hydrogen, for halogen or for respectively optionally substituted alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, alkenyl or alkinyl, methods and new intermediate products for their production and their use as herbicides.

PROCESS FOR THE PREPARATION OF SULPHONYLUREA SALTS, SULPHONYLUREA SALTS, HERBICIDIC COMPOSITIONS, APPLICATION AND PROCESS FOR THE PREPARATION OF COMPOSITIONS

Optically active phenozypropionic acid derivatives

Herricidal substituted sulphonylamidinohydrazones

Herbicidal substituted sulphonylamidinohydrazones of the formula ##STR1## in which R 1 represents in each case optionally substituted aryl, aralkyl or heteroaryl, R 2 represents hydrogen, or represents in each case optionally substituted alkyl, aryl or aralkyl, R 3 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkadienyl, alkinyl, (hetero)aryl, aralkyl, aralkenyl, alkoxy, alkoxycarbonyl or dialkylamino, or together with R 2 represents optionally substituted alkanediyl, R 4 represents hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxyalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio, amino, alkylamino or dialkylamino, X represents nitrogen or a --CH group, Y represents nitrogen or a --CR 5 group where R 5 represents hydrogen, halogen, cyano, alkyl, formyl, alkyl-carbonyl or alkoxy-carbonyl, and Z represents nitrogen or a --CR 6 group where R 6 represents hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxy, halogenoalkyl, alkylthio, alkylamino or dialkylamino.

Substituted 2-amino-4-alkylamino-1,3,5-triazines as herbicides

O-ethyl-S-n-propyl-0-2-cyanovinyl-thionothiol-phosphoric acid esters

O-ethyl-S-n-propyl-O-vinyl-thionothiolphosphoric acid esters of the formula IN WHICH R is lower alkyl, carbo-lower alkoxy, or phenyl or naphthyl optionally substituted by halogen, nitro, nitrile, lower alkyl, lower alkoxy or halo-lower alkyl and R'' is hydrogen or lower alkyl, WHICH POSSESS INSECTICIDAL AND ACARICIDAL PROPERTIES.

O-PHENYLTHIONOPHOSPHONIC ACID ESTERS, METHOD FOR THEIR MANUFACTURING AND USE AS INSECTICIDES, ACARICIDES AND NEMATICIDES

Vinyl (thiono) (thiol) phosphoric (phosphonic) acid esters, and their use as insecticides, acaricides and nematicides

ABSTRACT OF THE DISCLOSURE The present invention relates to certain new vinyl (thiono)(thiol) phosphoric (phosphonic) acid esters, to a process for their preparation and to their use as insecti-cides, acaricides and n???ticides. It is already known that 2-carboalkoxy-2-cyano-vinyl-phosphoric(phosphonic) acid esters, for example 0,0-diethyl-0-[1-methyl-2-cyano-2-carbethoxyvinyl]-phosphoric acid ester and 0-ethyl-0-[1-methyl-2-carbethoxy-2-cyanovinyl]-ethane-phosphonic acid ester (see Belgian Patent Specification 654,748) and 0,0-diethyl-0-(2-ethoxy-2-carbethoxyvinyl)-thionophosphoric acid ester (see Belgian Patent Specifi-cation 755,934), as well as 0,0-dimethyl- and 0,0-diethyl-S-(1-ethylthio-1-carbethoxymethyl)-thionothiolphosphoric acid esters (see German Ausl?g??chrift (German Published Specification) 1,068,699 and 0,0-dimethyl-S-(1,2-dicarbethoxy-ethyl)-thionothiolphosphoric acid ester (see U.S. Patent Specification 2,578,652), have insecticidal and acaricidal properties.

N,n-dimethyl-0-pyrazolyl-carbamic acid esters and their use as insecticides

ABSTRACT OF THE DISCLOSURE The present invention provides the N,N-dimethyl-O-pyrazolyl-carbamic acid esters of the general formula (I) in which R represents hydrogen, alkyl, cyanoalkyl or phenyl and R1 represents alkoxy or alkylthio. The compound of the formula (I) have been found to possess an excellent insecticidal action. The invention also provides a process for their preparation in which a 5-hydroxypyrozole is reacted, either as such in the presence of an acid acceptor or in the form of an alkali metal salt, alkaline earth Metal salt or ammonium salt, with N,N-dimethylcarbamic acid chloride in the presence of a solvent or diluent.

Substituted n-aryl-o-alkyl-carbamates

The invention relates to novel substituted N-Aryl-O-alkyl-carbamates of general formula (I), in which: m represents the numbers 0, 1 or 2; n represents the numbers 0 or 1; Ar represents an optionally substituted, monocyclic or bicyclic, if needed, partially saturated, carbocyclic or heterocyclic grouping; Q represents O (oxygen), S (sulfur), SO, SO2 or CH2 (carbene); R1 represents optionally substituted alkyl; R2 represents halogen or optionally substituted alkyl or alkoxy; R3 represents hydrogen or alkyl, and; R4 represents alkyl or cycloalkyl. The invention also relates to methods for producing the novel substituted N-Aryl-O-alkyl-carbamates, and to their use as herbicides.

BENZODISULTAME

Herbicidally active novel benzodisultams of the formula <IMAGE> in which R1 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 represents hydrogen, fluorine, chlorine, bromine, hydroxyl, cyclopropyl, C1-C4-alkyl (which is optionally substituted by fluorine and/or chlorine), C1-C4-alkoxy [which is optionally substituted by fluorine and/or chlorine], C1-C4-alkylthio (which is optionally substituted by fluorine and/or chlorine), amino, or C1-C4-alkyl- or di-(C1-C4-alkyl)-amino (which is optionally substituted by fluorine) and R3 represents hydrogen, fluorine, chlorine, bromine, hydroxyl, cyclopropyl, C1-C4-alkyl (which is optionally substituted by fluorine and/or chlorine), C1-C4-alkoxy (which is optionally substituted by fluorine and/or chlorine), C1-C4-alkylthio (which is optionally substituted by fluorine and/or chlorine), amino or C1-C4-alkyl- or di-(C1-C4-alkyl)-amino (which is optionally substituted by fluorine).

Substituted cyclopropylcarbonylphenylaminosulfonylureas

Use of n-phosphonomethylglycine esters in aqueous solution as herbicides, and new n-phosphonomethylglycine esters

The invention concerns the new use of N-phosphonomethylglycine esters, some of them prior art, of formula (I): (HO)2P(O)-CH2-NH-CH2-CO-O-R, in which R is alkyl substituted with one or more hydroxy, carboxylic, halogen, alkoxy, hydroxyalkoxy, alkoxyalkoxy, hydroxyalkoxyalkoxy, alkoxyalkoxyalkoxy, alkylcarbonyl, hydroxyalkylcarbonyl or alkoxycarbonyl groups; alkenyl or alkinyl optionally substituted with one or more hydroxy, carboxylic, halogen or alkoxycarbonyl groups; cycloalkyl or cycloalkylalkyl optionally substituted with one or more hydroxy, carboxylic, halogen, alkyl, hydroxyalkyl, alkoxyalkyl, alkoxy or alkoxycarbonyl groups; or oxacycloalkyl, dioxacycloalkyl, oxacycloalkylalkyl or dioxacycloalkylalkyl optionally substituted with alkyl; or acid adducts thereof, alone in aqueous solution, i.e. without additives, as herbicides, as well as a sub-group of new N-phosphonomethylglycine esters, of the formula (IA): (HO)2P(O)-CH2-NH-CH2-CO-O-A, in which A is as defined in the description. The invention also concerns a method of producing such compounds and their use as herbicides.

Substituted aryloxyalkylaminotriazines

The invention relates to novel substituted aryloxy alkyl amino triazines of formula (I) wherein R1 stands, for example, for H or C1-C6 alkyl; R2 stands, for example, for H, C1-C6-alkyl or C1-C6 alkyl carbonyl; R3 stands, for example, for C2-C6 alkyl, R4 stands for example for H or C1-C4 alkyl; AR stands, for example, for substituted or unsubstituted phenyl and Z stands, for example, halogen, C1-C6 alkyl, C1-C6 hydroxy alkyl, C1-C6 halogen alkyl or C3C6 cyclo alkyl. The invention also relates to a method for the production and use thereof as herbicides.

Process for preparing sulphonylurea salts, new sulphonylurea salts, and their use as herbicides

New 2,4-di:amino-1,3,5-triazine derivatives

2,4-Diamino-1,3,5-triazine derivatives of formula (I) are new. R1 = H or optionally substituted alkyl, alkanoyl, alkoxycarbonyl, alkenoyl or alkynoyl; R2 = H or optionally substituted alkenyl or alkynyl; R3 = -A-Z; A = optionally substituted alkanediyl optionally terminated or interrupted by O, S, NH or alkylimino; and Z = optionally substituted cyclopentyl, cyclohexyl, phenyl, naphthyl, tetralinyl, decalinyl, indanyl, indenyl, furyl, benzofuryl, dihydrobenzofuryl, thienyl, benzothienyl, dihydrobenzothienyl, isobenzofuryl, dihydroisobenzofuryl, isobenzothienyl, dihydroisobenzothienyl, pyrrolyl, indolyl, isoindolyl, indolinyl, isoindolinyl, benzdioxolyl, oxazolyl, benzoxazolyl, thiazolyl, benzothiazolyl, benzimidazoly, indazolyl, oxadiazolyl, thiadiazolyl, pyrazolyl, pyridinyl, pyrimidinyl, pyrazinyl, pyridazinyl, quinolyl, isoquinolyl. quinoxalinyl, cinnolinyl and phthalazinyl. Also claimed are intermediates of formula (IV) (see 'Preparation').

Substituted n-aryl-o-aryloxyalkyl carbamates and their use as herbicides

S- (TRIFLUORCHLORAETHYLMERCAPTO) - AETHYL (THIONO) - (DI) THIOLPHOSPHORUS (PHOSPHONE) - ACID ESTER OR. -ESTERAMIDE, THE PROCESS FOR THEIR MANUFACTURING AND THEIR USE AS INSECTICIDE, ACARICIDE AND NEMATICIDE

Arylaminosulfonylureas

Sulphonylaminoguanidinoazines

Substituted pyridyl-phenyl ethers

Novel substituted pyridyl-phenyl ethers of the formula ##STR1## in which X represents trifluoromethyl or chlorine, Y represents hydrogen or chlorine, R 1 represents hydrogen or methyl and R 2 represents formyl or the radicals of the formulae ##STR2## in which R 3 represents alkyl with 1 to 4 carbon atoms, or the two radicals R 3 together represent an alkylene chain with 2 or 3 carbon atoms, R 4 , R 5 , R 6 and R 7 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms, m represents 1 or 2, n represents 0 or 1 and Z represents trimethylsilyl, optionally substituted azolyl which is bonded via nitrogen or the radicals of the formulae ##STR3## in which R 8 represents alkyl with 1 to 4 carbon atoms, or the two radicals R 8 together represent an alkylene chain with 2 or 3 carbon atoms, R 9 represents alkyl with 1 to 4 carbon atoms, X 1 represents oxygen or sulphur and R 10 and R 11 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms, and their use as herbicides.

Use of N-phosphonomethyl-glycine esters in aqueous solution as herbicides and new N-phosphonomethyl-glycine esters

The invention concerns the new use of N-phosphonomethylglycine esters, some of them prior art, of formula (I): (HO)2P(O)-CH2-NH-CH2-CO-O-R, in which R is alkyl substituted with one or more hydroxy, carboxylic, halogen, alkoxy, hydroxyalkoxy, alkoxyalkoxy, hydroxyalkoxyalkoxy, alkoxyalkoxyalkoxy, alkylcarbonyl, hydroxyalkylcarbonyl or alkoxycarbonyl groups; alkenyl or alkinyl optionally substituted with one or more hydroxy, carboxylic, halogen or alkoxycarbonyl groups; cycloalkyl or cycloalkylalkyl optionally substituted with one or more hydroxy, carboxylic, halogen, alkyl, hydroxyalkyl, alkoxyalkyl, alkoxy or alkoxycarbonyl groups; or oxacycloalkyl, dioxacycloalkyl, oxacycloalkylalkyl or dioxacycloalkylalkyl optionally substituted with alkyl; or acid adducts thereof, alone in aqueous solution, i.e. without additives, as herbicides, as well as a sub-group of new N-phosphonomethylglycine esters, of the formula (IA): (HO)2P(O)-CH2-NH-CH2-CO-O-A, in which A is as defined in the description. The invention also concerns a method of producing such compounds and their use as herbicides.

INSECTICIDES AND ACARICIDE AGENTS

Phenoxypropionic-acid derivatives, processes for their preparation and their use as herbicides

Phenoxy propionic acid derivs. of formula (I) are new (where R is OH, Cl, alkoxy, haloalkoxy, alkoxy-alkoxy, alkenoxy, alkinoxy, aralkoxy, alkylthio or alkylthioalkoxy; X is H or halogen). Diphenylether derivs. of formula (II) are also new (where X1 is H, F or Br). (I) are herbicides and can also be used as defoliants, desiccants. (I) can be used as selective herbicides in dicotyledon crops, and in cereals, and rice.

ACYLED SULPHONYLQUANIDINES, PREPARATION AND USE THEREOF, AND INTERMEDIATES FOR THEIR PREPARATION AND PREPARATION OF THESE

OPTICALLY ACTIVE PROPIONIC ACID DERIVATIVES

Use of n-substituted heterocyclylalkylamines as herbicides and novel n-substituted thienylalkylamines

The invention relates to the use of N-substituted heterocyclylalkylamines of general formula (I), wherein A represents a single bond or alkanediyl, R1 represents optionally substituted alkyl, R2 represents hydrogen, amino or optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, respectively, Y represents cyano or nitro and Z represents optionally substituted heterocyclyl, as herbicides. The invention also relates to novel N-substituted thienylalkylamines and to methods for producing the same.

Process for producing 4-fluoro-3-phenoxy-thoulene

Process for the preparation of phosphoric acid cyanohydrin esters, phosphoric acid cyanohydrin esters, pesticides containing them, and their use

Phosphoric acid cyanohydrin esters of the formula I <IMAGE> in which R represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl or an optionally substituted heterocyclic radical, R<1> and R<2> are identical or different and individually represent optionally substituted radicals from the series comprising alkyl, alkenyl, alkynyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, arylthio, aralkylthio, alkylamino (mono- and dialkylamino), arylamino, aralkylamino, or together represent alkanediyl, alkanedioxy, aminoalkyloxy or alkanediamino, and X represents oxygen or sulphur, are obtained by reacting phosphoryl chlorides of the formula II <IMAGE> in which X, R<1> and R<2> have the abovementioned meanings, with aldehydes of the formula III R-CHO (III> in which R has the abovementioned meaning, in the presence of approximately equimolar amounts of water-soluble cyanides. Some of the compounds of the formula I are novel. They can be used as insecticides and acaricides.

4-fluoro-3-bromo benzaldehyde acetals

The new compound ##STR1## is prepared and converted to the new acetal ##STR2## which is reacted with an alkali phenolate or alkaline earth metal phenolate in the presence of copper or a copper compound as a catalyst and in the presence of a diluent at a temperature between about 100° and 200° C. to produce the new acetal ##STR3## which can be hydrolyzed to the corresponding aldehyde which is a known intermediate for pyrethroid-like insecticides.

PROCESS FOR THE PREPARATION OF OXYGUANIDINE DERIVATIVES, HERBICIDAL COMPOSITIONS, APPLICATION, PROCESS FOR THE PREPARATION OF COMPOSITIONS AND PROCESS FOR THE PREPARATION OF 4,6-DIMETHYL-2-OXYGUANIDINOPIRIMIDINE DERIVATIVES

PROCESS FOR THE PRODUCTION OF 4-FLUORO-3-PHENOXY-TOLUENE

Substituted 2,4-diamino-1,3,5-triazines

The invention relaters to compounds of the formula:and their use as herbicides.

Selective herbicides on basis of N-azinyl-N'-(2-ethylthiophenylsulfonyl)-ureas

The invention relates to selective herbicides based on N-azinyl-N'-(2-ethylthiophenylsulphonyl)ureas of the general formula (I) <IMAGE> in which X represents hydrogen, halogen, C1-C3-alkyl (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkoxy (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkylthio, C1-C3-alkylamino or di(C1-C2-alkyl)amino, Y represents halogen, C1-C3-alkyl (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkoxy (which is optionally substituted by fluorine, chlorine, methoxy or ethoxy), C1-C3-alkylthio, C1-C3-alkylamino or di(C1-C2-alkyl)amino, and Z represents nitrogen or the group C-Z<1> in which Z<1> represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, methoxy or ethoxy, and to novel compounds of the formula (I) and processes for their preparation.

Sulphonylisothioureidopyrimidine derivative

ABSTRACT OF THE DISCLOSURE A sulphonylisothioureidopyrimidine derivative of the general formula (VII A) (VII A) in which R1 represents a substituted phenyl radical

TIENOCICLOALQU (EN) ILAMINO-1,3,5-SUBSTITUTED TRIAZINS.

Tienocicloalqu(en)ilamino-1, 3, 5-triazinas substituidas. La invención se refiere a nuevas tienocicloalqu(en)ilamino-1, 3, 5-triazinas substituidas, a procedimientos para su obtención con inclusión de los nuevos productos intermedios y su empleo como herbicidas. Tienocycloalkyl (en) ilamino-1, 3, 5-substituted triazines. The invention relates to new thienocycloalkyl (en) ilamino-1, 3, 5-substituted triazines, to methods for obtaining them including new intermediate products and their use as herbicides.

Process for the preparation of styryl-cyclopropanecarboxylic acid esters and new intermediate products for this process

A process for the preparation of a styryl-cyclopropane-carboxylic acid ester of the formula ##STR1## in which R is C 1-4 -alkyl or an alcohol radical customary in pyrethroids, R 1 is alkoxy or alkylthio, either of which may be optionally substituted by halogen, R 2 is hydrogen or alkoxy, or R 1 and R 2 together are optionally halogen-substituted alkylenedioxy, and R 3 is hydrogen or chlorine, comprising reacting a compound of the formula ##STR2## with, respectively, one, two or three equivalents of a base at a temperature below 60° C. The products are insecticidally active when R is the residue of a pyrethroid-type alcohol. Various syntheses are given for the starting materials which are new.

O-alkyl-O-[1,6-dihydro-1-substituted-6-thioxopyridazin(3)yl]-(thiono) (thiol) phosphoric (phosphonic) acid ester and esteramides

O-Alkyl-O-[1,6-dihydro-1-substituted-6-thioxopyridazin(3)yl]-(thiono) (thiol) phosphoric (phosphonic) acid esters and ester-amides of the formula ##STR1## in which R is alkyl with 1 to 6 carbon atoms, R' is alkyl, alkoxy, alkylmercapto or alkylamino with 1 to 6 carbon atoms per alkyl chain, or phenyl, R" is alkyl, cyanoalkyl, carbalkoxyalkyl or alkylcarbonylalkyl with 1 to 4 carbon atoms per alkyl chain, phenyl or phenyl carrying at least one substituent selected from the group consisting of halogen, nitro, alkyl with 1 to 4 carbon atoms and halogenoalkyl with 1 to 4 carbon atoms, and X is oxygen or sulfur, Which possess arthropodicidal properties.

Substituted n-aryl-o-alkyl-carbamates

The invention concerns novel substituted N-aryl-O-alkyl-carbamates having general formula (I), wherein m, n, Q, R<1>, R<2>, R<3> and R<4> have the meanings cited in the description. The invention also relates to a method for the production of said carbamates and to their use as herbicides.

2,4-DIAMINO-1,3,5-SUBSTITUTED TRIAZINS.

2, 4-Diamino-1, 3, 5-triazinas substituidas de la fórmula general (I) en la que Q significa O (oxígeno), S (azufre), SO, SO2, NH o N(alquilo con 1 a 4 átomos de carbono), R1 significa hidrógeno o significa alquilo con 1 a 6 átomos de carbono, substituido en caso dado por hidroxi, por ciano, por halógeno o por alcoxi con 1 a 4 átomos de carbono, R2 significa hidrógeno, significa formilo o significa alquilo, alquilcarbonilo, alcoxicarbonilo o alquilaminocarbonilo, con respectivamente 1 a 6 átomos de carbono en los grupos alquilo substituidos respectivamente en caso dado por ciano, por halógeno o por alcoxi con 1 a 4 átomos de carbono, R3 significa alquilo con 1 a 6 átomos de carbono substituido en caso dado por hidroxi, por ciano, por halógeno o por alcoxi con 1 a 4 átomos de carbono, o significa cicloalquilo con 3 a 6 átomos de carbono substituido en caso dado por ciano, por halógeno o por alquilo con 1 a 4 átomos de carbono, R4 significa hidrógeno o alquilo con 1 a 4 átomos de carbono,R5 significa hidrógeno o alquilo con 1 a 4 átomos de carbono. 2, 4-Diamino-1, 3, 5-substituted triazines of the general formula (I) in which Q means O (oxygen), S (sulfur), SO, SO2, NH or N (alkyl with 1 to 4 atoms carbon), R1 means hydrogen or means alkyl with 1 to 6 carbon atoms, substituted if necessary by hydroxy, cyano, halogen or alkoxy with 1 to 4 carbon atoms, R2 means hydrogen, means formyl or means alkyl , alkylcarbonyl, alkoxycarbonyl or alkylaminocarbonyl, with respectively 1 to 6 carbon atoms in the alkyl groups substituted respectively in case of cyano, halogen or alkoxy with 1 to 4 carbon atoms, R3 means alkyl with 1 to 6 carbon atoms substituted if necessary by hydroxy, by cyano, by halogen or by alkoxy with 1 to 4 carbon atoms, or means cycloalkyl with 3 to 6 carbon atoms substituted if necessary by cyano, by halogen or by alkyl with 1 to 4 atoms carbon, R4 means hydrogen or alkyl with 1 to 4 carbon atoms, R5 means hydrogen or alkyl with 1 to 4 carbon atoms.

1-(2-trifluoromethoxy-phenylsulphonyl)-3-heteroaryl- (thio)ureas

ABSTRACT 1-(2-Trifluoromethoxy-phenylsulphonyl)-3-heteroaryl-(thio)urea herbicides of the formula

Herbicidal novel 1-(2-trifluoromethoxy-phenylsulphonyl)-3-heteroaryl-(thio)ureas

1-(2-Trifluoromethoxy-phenylsulphonyl)-3-heteroaryl-(thio)urea herbicides of the formula ##STR1## in which Q represents oxygen or sulphur, R 1 represents hydrogen, C 1 -C 4 -alkyl or benzyl, R 2 represents hydrogen, halogen, hydroxyl, C 1 -C 4 -alkyl, C 1 -C 4 -halogenoalkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -halogenoalkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -halogenoalkylthio, amino, C 1 -C 4 -alkylamino or di-(C 1 -C 4 -alkyl)-amino, X represents nitrogen or a --CH-- grouping, Y represents nitrogen or a --CR 3 -- grouping, wherein R 3 represents hydrogen, halogen, C 1 -C 4 -alkyl, (C 1 -C 2 -alkyl)-carbonyl or (C 1 -C 2 -alkoxy)-carbonyl, and Z represents nitrogen or a --CR 4 -- grouping, wherein R 4 represents hydrogen, halogen, hydroxyl, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -alkylamino or di-(C 1 -C 4 -alkyl)-amino.

Dichloropyridyl methyl cyanamidines

The invention relates to novel dichloropyridyl methyl cyanamidines of formula (I), in which R1 represents hydrogen, alkyl or optionally substituted aralkyl and R2 represents hydrogen, optionally substituted alkyl, optionally substituted alkoxy, optionally substituted alkylthio, optionally substituted aryl, optionally substituted aryloxy or optionally substituted arylthio. The invention also relates to a method for producing said novel substances and to the use thereof for combating undesirable micro-organisms.

OPTICALLY ACTIVE PROPIONIC ACID ESTER DERIVATIVES