Method and kit for adsorbent performance evaluation

The present invention generally relates to methods and kits for measuring and analyzing degradation of adsorbent materials, particularly for adsorbent materials used in gas separation processes. The present invention can assess the damage to adsorbent due to contamination including moisture contamination and it can assess damage that is not contaminant-related. The advantage to the present invention is that it can detect degradation of adsorbent directly at the plant site before the degradation affects production. Another advantage is that it can conclusively determine whether the adsorbent is damaged. Because it is so inexpensive to run, the test of the present invention can be conducted to determine adsorbent damage and to confirm whether the damage continues to be an issue. The present invention can test adsorbents in any form, including, but not limited to, bead, pellet or powder form.

Adsorbent compositions

Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N 2 adsorption rates and capacities when used in air separation processes.

METHOD AND KIT FOR ADSORBENT PERFORMANCE EVALUATION

The present invention generally relates to methods and kits for measuring and analyzing degradation of adsorbent materials, particularly for adsorbent materials used in gas separation processes. The present invention can assess the damage to adsorbent due to contamination including moisture contamination and it can assess damage that is not contaminant-related. The advantage to the present invention is that it can detect degradation of adsorbent directly at the plant site before the degradation affects production. Another advantage is that it can conclusively determine whether the adsorbent is damaged. Because it is so inexpensive to run, the test of the present invention can be conducted to determine adsorbent damage and to confirm whether the damage continues to be an issue. The present invention can test adsorbents in any form, including, but not limited to, bead, pellet or powder form.

Method and kit for adsorbent performance evaluation

The present invention generally relates to methods and kits for measuring and analyzing degradation of adsorbent materials, particularly for adsorbent materials used in gas separation processes. The present invention can assess the damage to adsorbent due to moisture contamination and it can assess damage that is not moisture-related. The advantage to the present invention is that it can detect degradation of adsorbent before the degradation affects production. Another advantage is that it can conclusively determine whether the sieve is damaged. Because it is so inexpensive to run, the test of the present invention can be conducted to determine adsorbent damage and to confirm whether the damage continues to be an issue. The present invention can test adsorbents in any form, including, but not limited to, bead, pellet or powder form.

GAS SEPARATION ADSORBENTS AND MANUFACTURING METHOD

The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.

METHOD AND KIT FOR ADSORBENT PERFORMANCE EVALUATION

The present invention generally relates to methods and kits for measuring and analyzing degradation of adsorbent materials, particularly for adsorbent materials used in gas separation processes. The present invention can assess the damage to adsorbent due to moisture contamination and it can assess damage that is not moisture-related. The advantage to the present invention is that it can detect degradation of adsorbent before the degradation affects production. Another advantage is that it can conclusively determine whether the sieve is damaged. Because it is so inexpensive to run, the test of the present invention can be conducted to determine adsorbent damage and to confirm whether the damage continues to be an issue. The present invention can test adsorbents in any form, including, but not limited to, bead, pellet or powder form.

NOVEL ADSORBENT COMPOSITIONS

Gas separation adsorbents and manufacturing method

The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.

Stabilization of molecular sieves by salt addition

The low stability of some molecular sieves can be overcome during calcination by a solid state reaction between the molecular sieve and a salt. Molecular sieves including zeolites, metal substituted aluminosilicates, and metallosilicates can be stabilized by this method. The inventive process comprises mixing such molecular sieve with a salt, either directly or as a slurry; and then heating the resulting mixture to remove water, organics and adsorbed species. ...

Process for making microporous membranes having selected gas-selective sites and the membranes so made

A process for making microporous membranes that incorporate selected gas selective species as surface sites in a controlled spacing and orientation manner and such membranes so formed being suitable for separating and purifying the selected gas from selected gas containing gas mixtures. An example is the use of oxygen selective transition element complexes (TECs) as surface sites for separating and purifying oxygen from oxygen-containing gas mixtures.

Process for separation of oxygen from an oxygen containing gas using oxygen selective sorbents

The invention is directed to a process for the separation of oxygen from an oxygen containing gas using an oxygen selective material comprising a transition element complex comprising a first transition element ion and one or more chelating ligands, wherein: i) said first transition element ion is capable of accepting intermolecular donation; ii) said chelating ligand or ligands provides up to four intramolecular donor sites to said transition element ion; iii) said chelating ligand or ligands provides an intermolecular donor site to a second transition element ion which is contained in second discrete transition element complex; and iv) said chelating ligand or ligands contains at least one substituent that inhibits μ-peroxo dimer formation on said sorbent; wherein when said material is in deoxy form, the total number of donor sites to said first transition element ion is five.

HIGH RATE AND HIGH CRUSH-STRENGTH ADSORBENTS

High rate and high crush-strength adsorbent particles and collections of such particles, and particularly LiLSX particles, are provided. A binder is employed in the form of a colloidal solution during the method of manufacture. Suitable binders include various silica binders. The particles are made using the steps of mixing, agglomeration, calcination and in the case of certain adsorbents such as LiX and LiLSX, ion exchange and activation. When the adsorption rate is expressed in the form SCRR/p (mmol mm2/g s), desirable collections of adsorbent particles can have values of at least 4.0 for the highly-exchanged Li (at least 90% Li exchanged) form of the collection of particles and can further be characterized by particles having average crush strengths of at least 0.9 lbf for particles having an average diameter of at least about 1.0 mm.

High rate and high crush-strength adsorbents

High rate and high crush-strength adsorbent particles and collections of such particles, and particularly LiLSX particles, are provided. A binder is employed in the form of a colloidal solution during the method of manufacture. Suitable binders include various silica binders. The particles are made using the steps of mixing, agglomeration, calcination and in the case of certain adsorbents such as LiX and LiLSX, ion exchange and activation. When the adsorption rate is expressed in the form SCRR/p (mmol mm2/g s), desirable collections of adsorbent particles can have values of at least 4.0 for the highly-exchanged Li (at least 90% Li exchanged) form of the collection of particles and can further be characterized by particles having average crush strengths of at least 0.9 lbf for particles having an average diameter of at least about 1.0 mm.

High rate compositions

The present invention relates generally to compositions useful in adsorption and reactive processes comprising an adsorbent powder, such as a zeolite, and a binder mixed to form an agglomerate having a porosity of 0.30≦ε p ≦0.42 and a N 2 pore diffusivity D p ≧3.5×10 −6 m 2 /s and wherein the mean particle diameter of the crystalline zeolite powder is 10 μm or less; the mean particle diameter of the binder is 0.10 d A or less, and the binder concentration is 10% or less expressed on a dry weight basis.

Adsorbent compositions

Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.

PROCESS FOR SEPARATING GASES AND ADSORBENT COMPOSITIONS USED THEREIN

The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO 2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-° K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.

NOVEL ADSORBENT COMPOSITIONS

Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced Nadsorption rates and capacities when used in air separation processes. 1. An adsorption process for separating Nfrom a gas mixture containing Nand at least one less strongly adsorbable component comprising contacting the mixture with an adsorbent composition which selectively adsorbs the Nand the at least one less strongly adsorbable component is recovered as product; the adsorbent composition comprising free-flowing agglomerated particles of a type X zeolite bound together by a silicone-derived binding agent and wherein the Ncapacity of the composition is equal to or greater than 26 ml/g at 1 atm and 27° C.2. The adsorption process of wherein the process comprises a cyclic adsorption process for the separation of gases.3. The adsorption process of wherein the process is selected from the group consisting of a VSA claim 2 , TSA claim 2 , PSA claim 2 , VPSA process and combinations thereof.4. The adsorption process of wherein the adsorbent composition exhibits a N/OHenry's Law selectivity of greater than 15.8.5. The adsorption process of wherein the adsorbent compositions further comprises a clay binder in concentrations of not more than 1 part clay binder to 5 parts silicone-derived binding agent.6. The adsorption process of wherein the one or more zeolites comprise a zeolite having a SiO/AlOratio of less than or equal to 2.5.7. The adsorption process of wherein the one or more zeolites ...

Process for separating gases and adsorbent compositions used therein

The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO 2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-° K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.

Intermolecularly bound transition element complexes for oxygen-selective adsorption

A process and composition for selectively adsorbing oxygen from a gaseous mixture. The chemisorption is carried out by a porous three-dimensional transition element complex comprised of intermolecularly bound TEC units, said units further comprised of at least one multidentate ligand forming at least one five- or six-membered chelate ring on each unit.

High Rate Compositions

The present invention relates generally to compositions useful in adsorption and reactive processes comprising an adsorbent powder, such as a zeolite, and a binder mixed to form an agglomerate having a porosity of 0.30≦ε≦0.42 and a Npore diffusivity D≧3.5×10m/s and wherein the mean particle diameter of the crystalline zeolite powder is 10 μm or less; the mean particle diameter of the binder is 0.10 dor less, and the binder concentration is 10% or less expressed on a dry weight basis. 1. A composition useful in adsorption and reactive processes comprising an adsorbent powder and a binder mixed to form an agglomerate having a porosity of 0.30≦ε≦0.42 and a Npore diffusivity D≧3.5×10m/s and wherein the mean particle diameter of the adsorbent powder is 10 μm or less; the mean particle diameter of the binder is 0.10 dor less , and the binder concentration is 10% or less expressed on a dry weight basis.2. The composition of wherein the average diameter (d) of the adsorbent powder particles is 2 μm≦d≦8 μm.3. The composition of wherein the binder is a non clay type binding agent.4. The composition of wherein the binder is present in an amount of 7% or less expressed on a dry weight basis.5. The composition of wherein the binder is a silicone derived binding agent.6. The composition of wherein the silicone derived binding agent is present in an amount of 7% or less expressed on a dry weight basis.7. The composition of wherein the mean diameter of the binder is 0.01 dA or less.8. The composition of wherein the Cof the adsorbent powder particle size distribution is ≦0.5.9. The composition of wherein the Cof the adsorbent powder particle size distribution is ≦0.25.10. The composition of wherein porosity is 0.35≦ε≦0.40.11. The composition of wherein the Npore diffusivity is D≧5.5×10m/s.12. The composition of wherein the adsorbent powder is a zeolite with a SiO/Al2O≦15.13. The composition of wherein the zeolite has SiO/Al2O≦3.5.14. The composition of wherein the adsorbent powder ...

NOVEL ADSORBENT COMPOSITIONS

Adsorbent compositions useful in adsorption, separation and purification processes are made using silicone-derived binding agents. The adsorbent compositions having enhanced adsorption rate and crush strength properties are made from agglomerated crystallite particles bound with silicone-derived binding agents. The silicone binder precursors are calcined during the manufacturing process to produce the silicone-derived binding agents. The adsorbent compositions are preferably used in air separation processes. 1. An adsorbent composition prepared by the heat treatment of a mixture comprising at least one active material and a silicone-derived binding agent to form agglomerated particles containing 90% or more of the at least one active material calculated on a dry weight final product basis and having a crush strength value of greater than that obtained from the value determined by the relationship y=1.2x−0.2 where y is the mean crush strength in lbF and x is the mean particle size in mm.2. The composition of wherein the at least one active component is one or more aluminosilicates claim 1 , aluminas claim 1 , and silicas.3. The composition of wherein the at least one active material is one or more zeolites.4. The composition of wherein the one or more zeolites includes a zeolite having a silica to alumina ratio of less than or equal to 2.5.5. The composition of wherein the zeolite is a LiX zeolite.6. The composition of wherein the silicone-derived binding agent is derived from a silicone binder precursor of the general formula [R2SiO]n claim 1 , where R is one or more organic side groups selected from C1 to C8 organic compounds claim 1 , including linear claim 1 , branched and cyclic compounds or mixtures thereof and wherein the polymeric or oligomeric silicones are terminated by hydroxy claim 1 , methoxy claim 1 , ethoxy groups or mixtures thereof.7. The composition of wherein the silicone binder precursor is selected from an hydroxy claim 6 , methoxy claim 6 , or ...

NOVEL ADSORBENT COMPOSITIONS

Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced Nadsorption rates and capacities when used in air separation processes. 1. A heat treated adsorbent composition comprising a mixture of at least one active material and a silicone-derived binding agent formed as agglomerated particles comprised of 90% or more of the at least one active material calculated on a dry weight final product basis and having:a median pore diameter of equal to or greater than 0.45 μm,10% or less of the macropores and mesopores are of less than or equal to 0.1 μm,a hysteresis factor of equal to or greater than 0.6, anda crush strength value of equal to or greater than that obtained from the value determined by the relationship y=1.2x−0.3 where y is the mean crush strength in lbF and x is the mean particle size in mm.2. The composition of wherein the at least one active material has an average particle size of greater than 1 micron.3. The composition of wherein the one or more zeolites includes a zeolite having a SiO/AlOratio of less than 15.4. The composition of wherein the one or more zeolites includes a zeolite having a SiO/AlOratio of less than or equal to 2.5.5. The composition of wherein the zeolite is LiLSX or LiX.6. The composition of wherein the silicone-derived binding agent is derived from a silicone binder precursor of the general formula [RSiO] claim 1 , where R is one or more organic side groups selected from C1 to C8 organic compounds claim 1 , including ...

Gas separation adsorbents and manufacturing method

The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.

Process for separating gases and adsorbent compositions used therein

The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-°K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.

Oxygen selective sorbents

Intermolecularly bound transition element complexes for oxygen-selective adsorption

A process and composition for selectively adsorbing oxygen from a gaseous mixture. The chemisorption is carried out by a porous three-dimensional transition element complex comprised of intermolecularly bound TEC units, said units further comprised of at least one multidentate ligand forming at least one five- or six-membered chelate ring on each unit.

Oxygen selection sorbents

Oxygen selective sorbents

The invention is directed to an oxygen selective material for separating oxygen from oxygen-containing gas mixtures, the material comprising a transition element complex comprising a first transition element ion and one or more chelating ligands, wherein: i) the chelating ligand or ligands provides up to four electron donor sites to the transition element ion; ii) the chelating ligand or ligands provides an intermolecular electron donor site to the second transition element ion which is contained in the second discrete transition element complex; and iii) the chelating ligand or ligands contains at least one substituent that inhibits µ-peroxo dimer formation on the complex; wherein when the complex is in deoxy form, the total number of electron donor sites to the first transition element ion is five.

Method and kit for adsorbent performance evaluation

The present invention generally relates to methods and kits for measuring and analyzing degradation of adsorbent materials, particularly for adsorbent materials used in gas separation processes. The present invention can assess the damage to adsorbent due to contamination including moisture contamination and it can assess damage that is not contaminant-related. The advantage to the present invention is that it can detect degradation of adsorbent directly at the plant site before the degradation affects production. Another advantage is that it can conclusively determine whether the adsorbent is damaged. Because it is so inexpensive to run, the test of the present invention can be conducted to determine adsorbent damage and to confirm whether the damage continues to be an issue. The present invention can test adsorbents in any form, including, but not limited to, bead, pellet or powder form.

Stabilization of molecular sieves by salt addition

The low stability of some molecular sieves can be overcome during calcination by a solid state reaction between the molecular sieve and a salt. Molecular sieves including zeolites, metal substituted aluminosilicates, and metallosilicates can be stabilized by this method. The inventive process comprises mixing such molecular sieve with a salt, either directly or as a slurry; and then heating the resulting mixture to remove water, organics and adsorbed species.

Oxygen-selective sorbents

塩添加によるモレキュラーシーブの安定化

(57)【要約】 【課題】 不安定なモレキュラーシーブを熱安定化する 方法及び熱安定性モレキュラーシーブを提供する。 【解決手段】 ａ）不安定なモレキュラーシーブを塩 と、直接にか又はスラリーとしてのいずれかで混合する 工程；並びにｂ）工程ａ）から生じる混合物を加熱して 水、有機物、及び吸着された種の内の一種又はそれ以上 を除く工程を含む方法。含浸された塩に会合される電荷 調整性カチオン、及び含浸された塩に会合されるアニオ ンを含むモレキュラーシーブを含む熱安定性モレキュラ ーシーブ吸着剤。

High rate and high crush-strength adsorbents