01-08-2013 дата публикации
Номер: US20130192976A1
Disclosed herein are titania photocatalysts, titania photocatalytic compositions, and methods of making the same. The photocatalysts may, for example, be represented by the formula of (TiM)(OCN), where M, r, x, are y defined in the specification. The photocatalysts may, in some embodiments, provide superior photocatalytic activity relative to titania. Also disclosed are methods making the photocatalysts. The method may provide economical techniques for obtaining the titania photocatalysts. 1. A titanium-oxide based photocatalyst represented by the formula of (TiM)(OCN) , wherein:M is selected from the group consisting of Sn, Ni, Sr, Ba, Fe, Bi, V, Mo, W, Zn, Cu, and combinations thereof;r is in the range of about 0.0001 to about 0.25;x is in the range of about 0.001 to about 0.1; andy is in the range of about 0.001 to about 0.1.2. The photocatalyst of claim 1 , wherein r is no more than about 0.05.3. The photocatalyst of claim 1 , wherein M is selected from the group consisting of Sn claim 1 , Ni claim 1 , Sr claim 1 , Ba claim 1 , Fe claim 1 , Bi claim 1 , and combinations thereof.4. The photocatalyst of claim 3 , wherein r is in the range of about 0.0001 to about 0.15.5. The photocatalyst of claim 1 , wherein M is selected from the group consisting of Mo claim 1 , W claim 1 , and combinations thereof.6. The photocatalyst of claim 5 , wherein r is in the range of about 0.0001 to about 0.10.7. The photocatalyst of claim 1 , wherein M is V.8. The photocatalyst of claim 7 , wherein r is in the range of about 0.0001 to about 0.05.9. The photocatalyst of claim 1 , wherein M is Sn.10. The photocatalyst of claim 1 , wherein x is in the range of about 0.001 to about 0.07.11. The photocatalyst of claim 1 , wherein y is in the range of about 0.001 to about 0.05.12. The photocatalyst of claim 1 , wherein the photocatalyst is selected from the group consisting of (TiSn)(OCN) claim 1 , (TiSn)(OCN) claim 1 , (TiSn)(OCN) claim 1 , (TiSn)(OCN) claim 1 , (TiSn)(OCN) claim 1 , (TiNi ...
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