12-09-2013 дата публикации
Номер: US20130233788A1
A filtering membrane has a supporting structure comprising filaments and is coated with a dope to produce a polymeric membrane layer. Some or all of the filaments comprise a second polymer that is soluble or swellable in a solvent of the dope. The supporting structure may be braided with yarns. One or more yarns may comprise filaments comprising the second polymer. In one example, a braided tubular support is coated with a dope based on PVDF in NMP. Some or all of the yarns of the braid are made of bi-component core-sheath PET-PVDF filaments. With as few as 4% of the yarns in the braid made of the bicomponent filaments, peel strength and pull force of the membrane is improved relative to a braid made entirely of PET yarns. In experimental examples, unpeelable composite membranes were produced. The membrane may be used, for example, for water or wastewater filtration applications. 1. A method of forming a membrane comprising the steps of ,a) braiding a plurality of yarns into a supporting structure;b) coating the supporting structure with a dope comprising a film forming polymer and a solvent; and,c) coagulating the dope to form a membrane layer on the supporting structure, wherein,d) the supporting structure comprises a first polymer; ande) one or more of the yarns comprises filaments comprising a second polymer that is soluble or swellable in the solvent.2. The method of wherein the second polymer is the same polymer as the film forming polymer.3. The method of wherein 50% or more of the filaments in one or more of the yarns comprise the second polymer.4. The method of wherein essentially all of the filaments in one or more of the yarns comprise the second polymer.5. The method of wherein 50% or more of the supporting structure is made up of the first polymer or the first polymer and a third polymer.6. The method of wherein between 1% and 100% of the yarns comprise filaments comprising the second polymer.7. The method of wherein the filaments comprising the second ...
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