Pesticidal compositions and related methods

A process of applying a pesticidal composition to an area to control a pest, wherein the pesticidal composition comprises at least one compound selected from a compound of formula I, or any agriculturally acceptable salt thereof, wherein R1, R2, R3, R4, R5, R6, R7, R8, Q, Z, L, La, and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted) picolinates

... 4-Amino-3-chloro-5-fluoro-6-(substituted)picolinates are conveniently prepared from 3,4,5,6-tetrachloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange and hydrolysis, esterification and transition metal assisted coupling.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A1 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 132-. (canceled)35. A herbicidal composition claim 34 , comprising a herbicidally effective amount of at least one compound as claimed in .36. The herbicidal composition as claimed in claim 35 , in a mixture with at least one formulation auxiliary.37. The herbicidal composition as claimed in claim 35 , comprising at least one further pesticidally active compound selected from the group consisting of insecticides claim 35 , acaricides claim 35 , herbicides claim 35 , fungicides claim 35 , safeners and growth regulators.38. The herbicidal composition as claimed in claim 37 , comprising a safener.39. The herbicidal composition as claimed in claim 38 , comprising a further herbicide.40. A method for controlling an unwanted plant claim 34 , comprising applying an effective amount of at least one compound as claimed in claim 34 , to a plant and/or on a site of unwanted plant growth.41. A compound as claimed in claim 34 , wherein said compound is capable of being used for controlling an unwanted plant in a plant crop.42. A compound as claimed in claim 41 , wherein the plant crop is a transgenic plant crop.43. A method for controlling an unwanted plant claim 35 , comprising applying an effective amount of a herbicidal composition as claimed in claim 35 , to a plant and/or on a site of unwanted plant growth. The invention relates to herbicidal compounds and compositions and to methods for controlling undesirable vegetation.The occurrence of undesirable vegetation, e.g., weeds, is a constant problem facing farmers in crops, pasture, and other settings. Weeds compete with crops and negatively impact crop yield. The use of chemical herbicides is an important tool in controlling undesirable vegetation.There remains a need for new chemical herbicides that offer a broader spectrum of weed control, ...

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”):

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di-tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

Pesticidal Compositions and Processes Related Thereto

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

ARYLALKYL ESTERS OF 4-AMINO-6-(SUBSTITUTED PHENYL)-PICOLINATES AND 6-AMINO-2-(SUBSTITUTED PHENYL)-PYRIMIDINECARBOXYLATES AND THEIR USE AS SELECTIVE HERBICIDES FOR CROPS

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs. 2. The compound of in which Y represents substituted phenyl.3. The compound of in which Z represents Cl claim 1 , —CH═CHor OCH.4. The compound of in which Rand Rrepresent H.5. The compound of in which Rrepresents a benzyl.6. The compound of in which Rrepresents an unsubstituted or ortho- claim 1 , meta- or para-monosubstituted benzyl.8. The compount of in which X represents H.9. The compount of in which X represents F.10. The compound of in which Y represents substituted phenyl.11. The compound of in which Z represents Cl.12. The compound of in which Rand Rrepresent H.13. The compound of in which Rrepresents a benzyl.14. The compound of in which Rrepresents an unsubstituted or ortho- claim 7 , meta- or para-monosubstituted benzyl.15. An herbicidal composition comprising an herbicidally effective amount of a compound of Formula IA claim 7 , according to claim 7 , or a compound of Formula IB claim 7 , according to claim 7 , in a mixture with an agriculturally acceptable adjuvant or carrier.16. A method of controlling undesirable vegetation which comprises contacting the vegetation via foliar or water application or the locus thereof with or applying to the soil or water to prevent the emergence of vegetation an herbicidally effective amount of a compound of Formula IA claim 7 , according to claim 7 , or a compound of Formula IB claim 7 , according to .17. A method for the selective postemergent control of undesirable vegetation in the presence of rice claim 7 , wheat or forage which comprises applying to said undesirable vegetation icidally effective amount of a compound of Formula IA claim 7 , according to claim 7 , or a compound of Formula IB claim 7 , according to claim 7 , or an herbicidal composition thereof. This application claims the benefit of ...

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di- tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

PTERIDINES AND THEIR USE AS AGROCHEMICALS

The present disclosure relates to 1- or 2-(4-(aryloxy)-phenyl)ethylamino-, oxy- or sulfanyl)pteridines and 1- or 2-(4-(heteroaryloxy)-phenyl)ethylamino-, oxy- or sulfanyl)pteridines and their use as agrochemicals and animal health products. More specifically, the invention provides new compounds of the formula (I-A): This application is a divisional application and claims priority to U.S. patent application Ser. No. 12/551,008, filed on Aug. 31, 2009, which is incorporated herein by reference in its entirety.The present disclosure relates to 1- or 2-(4-(aryloxy)-phenyl)ethylamino-, oxy- or sulfanyl)pteridines and 1- or 2-(4-(heteroaryloxy)-phenyl)ethylamino-, oxy- or sulfanyl)pteridines and their use as agrochemicals and animal health products.The present disclosure provides novel organic compounds that may demonstrate activity as pesticides, meaning that they may control fungi, insects, mites, and/or animal parasites. The disclosure also provides novel pesticide methods and compositions utilizing the novel compounds.More specifically, the invention provides new compounds of the formula (I-A):wherein:R is H, CH, phenyl, or a heterocycle comprising a 5 or 6 membered single ring or a fused ring system comprising at least one 5 or 6 membered heterocycle optionally substituted with H, halo, lower alkyl, lower alkoxy, benzyloxy, lower alkenyl, lower alkynyl, haloalkyl, haloalkoxy, NO, CN, lower alkoxycarbonyl, lower alkylcarbonyl, lower alkyl-SO, and aldoximes and lower alkyloximes, optionally substituted on oxygen by lower alkyl.Z is H, a C—C single bond, CH, NH, O, S, CN, CHO, OCH, CHCHO, or OCHCH;m is 4;p is 0 or 1;q is an integer from 0 to 2;Ris independently H, halo, lower alkyl, lower alkenyl, lower alkynyl, hydroxy, lower alkoxy, haloalkyl, haloalkoxy, NO, CN, lower alkylcarbonyl, lower alkoxycarbonyl, mercapto, lower alkylthio, aldoximes and lower alkyloximes, optionally substituted on oxygen by lower alkyl;Y is a C—C single bond, C(R)O or C(R);n is 2; ...

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 3. A composition according to further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).4. A composition according to wherein further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide claim 2 , 1 claim 2 ,2-dichloropropane claim 2 , 1 claim 2 ,3-dichloropropene claim 2 , 1-methylcyclopropene claim 2 , 1-naphthol claim 2 , 2-(octylthio)ethanol claim 2 , 2 claim 2 ,3 claim 2 ,5-tri-iodobenzoic acid claim 2 , 2 claim 2 ,3 claim 2 ,6-TBA claim 2 , 2 claim 2 ,3 claim 2 ,6-TBA-dimethylammonium claim 2 , 2 claim 2 ,3 claim 2 ,6-TBA-lithium claim 2 , 2 claim 2 ,3 claim 2 ,6-TBA-potassium claim 2 , 2 claim 2 ,3 claim 2 ,6-TBA-sodium claim 2 , 2 claim 2 ,4 claim 2 ,5-T claim 2 , 2 claim 2 ,4 claim 2 ,5-T-2-butoxypropyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-2-ethylhexyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-3-butoxypropyl claim 2 , 2 claim 2 ,4 claim 2 ,5-TB claim 2 , 2 claim 2 ,4 claim 2 ,5-T-butomethyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-butotyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-butyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-isobutyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-isoctyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-isopropyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-methyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-pentyl claim 2 , 2 claim 2 ,4 claim 2 ,5-T-sodium claim 2 , 2 claim 2 ,4 claim 2 ,5-T-triethylammonium claim 2 , 2 claim 2 ,4 claim 2 ,5-T-trolamine claim 2 , 2 claim 2 ,4-D claim 2 , 2 claim 2 ,4-D-2-butoxypropyl claim 2 , 2 claim 2 ,4-D-2-ethylhexyl claim 2 , 2 claim 2 ,4-D-3 ...

PROCESS FOR THE PREPARATION OF 4-AMINO-5-FLUORO-3-HALO-6-(SUBSTITUTED)PICOLINATES

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling. 2. The process of in which an amine-containing product or intermediate is purified by: a) protonating with an acid to form a salt claim 1 , b) isolating the salt in higher purity by crystallization claim 1 , precipitation or extraction claim 1 , and c) neutralizing the purified salt with a base to form the purified neutral amine-containing product or intermediate.4. The process of in which an amine-containing product or intermediate is purified by: a) protonating with an acid to form a salt claim 3 , b) isolating the salt in higher purity by crystallization claim 3 , precipitation or extraction claim 3 , and c) neutralizing the purified salt with a base to form the purified neutral amine-containing product or intermediate.6. The process of in which an amine-containing product or intermediate is purified by: a) protonating with an acid to form a salt claim 5 , b) isolating the salt in higher purity by crystallization claim 5 , precipitation or extraction claim 5 , and c) neutralizing the purified salt with a base to form the purified neutral amine-containing product or intermediate. This application is a divisional of U.S. patent application Ser. No. 13/356,691 claims the benefit of U.S. Provisional Patent Application Ser. No. 61/435,958 filed Jan. 25, 2011.The present invention concerns a process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates. More particularly, the present invention concerns a process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates in which the 5-fluoro substituent is introduced by a halogen exchange early in the process scheme.U.S. Pat. No. 6,297,197 B1 describes inter alia certain 6-(alkoxy or aryloxy)-4-amino-3-chloro-5-fluoropicolinate compounds and their ...

ARYLALKYL ESTERS OF 4-AMINO-6-(SUBSTITUTED PHENYL)-PICOLINATES AND 6-AMINO-2-(SUBSTITUTED PHENYL)-PYRIMIDINECARBOXYLATES AND THEIR USE AS SELECTIVE HERBICIDES FOR CROPS

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs. 2. The compound of in which Y represents substituted phenyl.3. The compound of in which Z represents Cl claim 1 , —CH═CHor OCH.4. The compound of in which Rand Rrepresent H.5. The compound of in which Rrepresents a benzyl.6. The compound of in which Rrepresents an unsubstituted or ortho- claim 1 , meta- or para-monosubstituted benzyl. This application is a divisional of U.S. Non-Provisional application Ser. No. 13/356,668 filed Jan. 24, 2012 which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/435,925 filed Jan. 25, 2011.This invention relates to certain novel esters of 4-amino-6-(substituted phenyl)-picolinic acids and 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylic acids and to the use of these compounds as herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.A number of picolinic acids and their pesticidal properties have been described in the art. U.S. Pat. No. 6,784,137 B2 and U.S. Pat. No. 7,314,849 B2 disclose a genus of 4-amino-6-arylpicolinic acids and their derivatives and their use as selective herbicides, particularly for rice and cereals such as wheat and barley. WO 2005/063721 A1, WO 2007/082076 A1, U.S. Pat. No. 7,863,220 B2, U.S. Pat. No. 7,300,907 B2, U.S. Pat. No. 7,642,220 B2, and U.S. Pat. No. 7,786,044 B2 disclose certain 6-amino-2-substituted-4-pyrimidinecarboxylic acids and their derivatives and their use as herbicides. It has now been discovered that certain esters of 4-amino-6-(substituted phenyl)picolinic acids and of 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylic acids can provide superior weed control especially in rice and wheat cropping systems and in pasture management programs.Certain arylalkyl esters of ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Br or Cl.16. A ...

PROCESS FOR THE PREPARATION OF 4-AMINO-3-CHLORO-5-FLUORO-6-(SUBSTITUTED) PICOLINATES

4-Amino-3-chloro-5-fluoro-6-(substituted)picolinates are conveniently prepared from 3,4,5,6-tetrachloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange and hydrolysis, esterification and transition metal assisted coupling. This application is a continuation of U.S. Ser. No. 13/356,669, filed Jan. 24, 2012, which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/435,966 filed Jan. 25, 2011.The present invention concerns a process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates. More particularly, the present invention concerns a process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates in which the 5-fluoro substituent is introduced by a halogen exchange early in the process scheme.U.S. Pat. No. 6,297,197 B1 describes inter alia certain 4-amino-3-chloro-5-fluoro-6-(alkoxy or aryloxy)picolinate compounds and their use as herbicides. U.S. Pat. Nos. 6,784,137 B2 and 7,314,849 B2 describe inter alia certain 4-amino-3-chloro-5-fluoro-6-(aryl)picolinate compounds and their use as herbicides. U.S. Pat. No. 7,432,227 B2 describes inter alia certain 4-amino-3-chloro-5-fluoro-6-(alkyl)picolinate compounds and their use as herbicides. Each of these patents describes the manufacture of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinate starting materials by fluorination of the corresponding 5-(unsubstituted)picolinates with 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate). It would be advantageous to produce 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates without having to rely on direct fluorination of the 5-position of the picolinate with an expensive fluorinating agent like 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate).The present invention concerns a process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates from 3,4,5,6-tetrachloropicolinonitrile. More ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 132-. (canceled)34. The compound of claim 33 , whereinX is N or CY, wherein Y is hydrogen or halogen;{'sup': 1', '1′', '1′, 'sub': 1', '8', '7', '10, 'Ris OR, wherein R is hydrogen, C-Calkyl, or C-Carylalkyl;'}{'sup': '2', 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '4', '1', '4', '1', '4', '1', '4, 'Ris halogen, C-Calkyl, C-Chaloalkyl, C-C-alkenyl, C-Chaloalkenyl, C-Calkynyl, C-C-alkoxy, C-Chaloalkoxy, C-Calkylthio, or C-Chaloalkylthio.'}{'sup': 3', '4', '3', '4', '3′', '4′', '3′', '4′, 'sub': 1', '6', '1', '6', '3', '6', '3', '6', '3', '6', '1', '3', '1', '3', '1', '6', '3', '6', '3', '6', '1', '6', '1', '6, 'Rand Rare hydrogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, or Rand Rtaken together represent ═CR(R), wherein R and R are independently hydrogen, C-Calkyl, C-Calkenyl, C-Calkynyl, C-Calkoxy or C-Calkylamino;'}{'sup': '5', 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '3', '1', '3', '1', '3', '1', '3', '1', '4', '2', '4, 'Ris hydrogen, halogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, C-Chaloalkylthio, amino, C-Calkylamino, or C-Chaloalkylamino;'}{'sup': 6', '6′', '6″, 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '3', '1', '3', '2, 'R, R, and R are independently hydrogen, halogen, C-Calkyl, C-Chaloalkyl, cyclopropyl, halocyclopropyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, CN, or NO;'}{'sup': 7', '7′, 'sub': 1', '4', '1', '4', '1', '3', '1', '3', '1', '3', '1', '4, 'Rand R are independently hydrogen, halogen, C-Calkyl, C-Chaloalkyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, cyclopropyl, amino or C-Calkylamino;'}{'sup': '8', 'sub': 1', '6', '1', '4', '3', '6', '3', '6', '1', '3', ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

PESTICIDAL COMPOSITIONS AND RELATED METHODS

A pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof, wherein R, R, R, R, R, R, Z, Q, and Y are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests, or to an area to control pests. 2. The composition of claim 1 , wherein R claim 1 , R claim 1 , and Rare hydrogen.3. The composition of claim 1 , wherein Ris hydrogen claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , or I4. The composition of claim 1 , wherein Ris hydrogen or F.5. The composition of claim 1 , wherein Ris selected from F claim 1 , Cl claim 1 , Br claim 1 , I claim 1 , or unsubstituted C-Calkyl.6. The composition of claim 1 , wherein Ris Cl or CH.7. The composition of claim 1 , wherein Y—C≡C—Ris CHC≡CH or CH(CH)C≡CH.8. The composition of claim 1 , wherein Ris (C-C)alkyl-S(O)—(C-C)alkyl claim 1 , (C-C)alkyl-S(O)—(C-C)haloalkyl claim 1 , or (C-C)alkyl-S(O)—(C-C)alkyl-(C-C)halocycloalkyl.9. The composition claim 1 , wherein Q and Xare independently oxygen (O).10. The composition claim 1 , wherein n is 0 or 1.11. The composition claim 1 , wherein Z is C—R.12. The composition of claim 1 , further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).13frontalis. The composition of claim 1 , further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide claim 1 , 1 claim 1 ,2-dichloropropane claim 1 , 1 claim 1 ,3-dichloropropene claim 1 , 1-methylcyclopropene claim 1 , 1-naphthol claim 1 , 2-(octylthio)ethanol claim 1 , 2 claim 1 ,3 claim 1 ,5-tri-iodobenzoic acid ...

PESTICIDAL COMPOSITIONS AND RELATED METHODS

A pesticidal composition comprises at least one compounds selected from a compound of formula, or any agriculturally acceptable salt thereof, wherein R, R, R, R, R, RR, R, Q, Z, L, L, and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests. 3. The composition of claim 1 , further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).4. The composition of claim 1 , further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide claim 1 , 1 claim 1 ,2-dichloropropane claim 1 , 1 claim 1 ,3-dichloropropene claim 1 , 1-methylcyclopropene claim 1 , 1-naphthol claim 1 , 2-(octylthio)ethanol claim 1 , 2 claim 1 ,3 claim 1 ,5-tri-iodobenzoic acid claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-dimethylammonium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-lithium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-potassium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-sodium claim 1 , 2 claim 1 ,4 claim 1 ,5-T claim 1 , 2 claim 1 ,4 claim 1 ,5-T-2-butoxypropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-2-ethylhexyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-3-butoxypropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-TB claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butometyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butotyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isobutyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isoctyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isopropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-methyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-pentyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T- ...

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 132-. (canceled)34. The compound of claim 33 , wherein R is hydrogen or C-Calkyl.35. The compound of claim 34 , wherein R is hydrogen.37. The compound of claim 34 , wherein R is C-Calkyl.38. The compound of claim 37 , wherein R is methyl.40. The compound of claim 33 , wherein R is a substituted or unsubstituted Carylalkyl group.41. The compound of claim 40 , wherein R is a benzyl group.42. A herbicidal composition comprising a compound of and an agriculturally acceptable adjuvant or carrier.43. The composition of claim 42 , further comprising an additional herbicidal compound.44. The composition of claim 42 , further comprising a safener.46. A method of controlling undesirable vegetation comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or growth of vegetation a herbicidally effective amount of a compound of .47. A method of controlling undesirable vegetation comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or growth of vegetation a herbicidally effective amount of a compound of .48. A method of controlling undesirable vegetation comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or growth of vegetation a herbicidally effective amount of a compound of .49. A method of controlling undesirable vegetation comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or growth of vegetation a herbicidally effective amount of a compound of .50. A method of controlling undesirable vegetation comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or ...

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 132-. (canceled)34. The compound of claim 33 , wherein{'sub': 1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3, 'X is CY, wherein Y is C-Calkyl, C-Chaloalkyl, C-Calkoxy, C-Chaloalkoxy, C-Calkoxy, C-Calkylthio, or C-Chaloalkylthio;'}{'sup': 1', '1′', '1″', '1″′', '1′', '1″', '1″′, 'sub': 1', '8', '7', '10', '1', '12', '3', '12', '3', '12, 'Ris OR or NRR, wherein R is hydrogen, C-Calkyl, or C-Carylalkyl, and R and R are independently hydrogen, C-Calkyl, C-Calkenyl, or C-Calkynyl;'}{'sup': 2', '17', '18', '19', '20', '21', '17', '18', '19', '20', '21, 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '2', '4', '1', '3', '1', '3', '1', '4', '1', '4', '1', '10', '3', '6', '1', '10, 'Ris halogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, C-Chaloalkylthio, amino, C-Calkylamino, C-Chaloalkylamino, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, cyano, or a group of the formula —CR═CR—SiRRR, wherein Ris hydrogen, F, or Cl; Ris hydrogen, F, Cl, C-Calkyl, or C-Chaloalkyl; and R, R, and Rare independently C-Calkyl, C-Ccycloalkyl, phenyl, substituted phenyl, C-Calkoxy, or OH;'}{'sup': 3', '4', '3', '4', '3', '4', '3′', '4′', '3′', '4′', '3′', '4′, 'sub': 1', '6', '1', '6', '3', '6', '3', '6', '3', '6', '1', '3', '1', '3', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '3', '6', '3', '6', '1', '6', '1', '6, 'Rand Rare independently hydrogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, C-Calkoxycarbonyl, C-Calkylcarbamyl, C-Calkylsulfonyl, C-Ctrialkylsilyl, C-Cdialkylphosphonyl, or Rand Rtaken together with N is a 5- or 6-membered saturated ring, or Rand Rtaken together represent ═CR(R), ...

3-ALKOXY, THIOALKYL AND AMINO-4-AMINO-6-(SUBSTITUTED)PICOLINATES AND THEIR USE AS HERBICIDES

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di-tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control. 2. The compound of claim 1 , wherein Q is C-Calkoxy or C-Chaloalkoxy.3. The compound of claim 1 , wherein Q is SRor NRR4. The compound of claim 1 , wherein Q is C-Calkoxy.5. The compound of claim 1 , wherein Q is methoxy.6. The compound of claim 1 , wherein X is H or F.7. The compound of claim 1 , wherein Y is Ar.8. The compound of claim 1 , wherein Ar is para-substituted phenyl with or without other substituents.9. The compound of claim 8 , wherein the para-substituted phenyl has no other substitutents.10. The compound of claim 8 , wherein the para-substituted phenyl has one or two other substitutents.11. The compound of claim 8 , wherein the para-substituted phenyl has three or four other substitutents.12. The compound of claim 8 , wherein the other substituents is each independently halogen or Calkoxy.13. The compound of claim 1 , wherein:a. Q is methoxy,b. X is H or F,c. Y is para-substituted phenyl with or without other substituents, and{'sup': 1', '2, 'd. Rand Rindependently represent H.'}14. The compound of claim 1 , wherein the compound is the compound of formula A or claim 1 , with respect to the carboxylic acid moiety of Formula A claim 1 , a C-Calkyl ester or benzyl ester thereof.16. A herbicidal composition comprising an herbicidally effective amount of a compound of and an agriculturally acceptable adjuvant or carrier.17. A method of controlling undesirable vegetation comprising contacting the vegetation or the locus thereof with claim 1 , or applying to soil or water to prevent the emergence of vegetation claim 1 , an herbicidally effective amount of a compound of .20. The compound of claim 18 , wherein the compound is a compound of Formula II or a C-Calkyl ester or benzyl ester thereof. This ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): and processes related thereto. 2Bemisia. A process according to wherein said pest is spp.3Bemisia tabaci.. A process according to wherein said pest is65. A process according to through further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).75. A process composition according to through further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide claims 1 , 1 claims 1 ,2-dichloropropane claims 1 , 1 claims 1 ,3-dichloropropene claims 1 , 1-methylcyclopropene claims 1 , 1-naphthol claims 1 , 2-(octylthio)ethanol claims 1 , 2 claims 1 ,3 claims 1 ,5-tri-iodobenzoic acid claims 1 , 2 claims 1 ,3 claims 1 ,6-TBA claims 1 , 2 claims 1 ,3 claims 1 ,6-TBA-dimethylammonium claims 1 , 2 claims 1 ,3 claims 1 ,6-TBA-lithium claims 1 , 2 claims 1 ,3 claims 1 ,6-TBA-potassium claims 1 , 2 claims 1 ,3 claims 1 ,6-TBA-sodium claims 1 , 2 claims 1 ,4 claims 1 ,5-T claims 1 , 2 claims 1 ,4 claims 1 ,5-T-2-butoxypropyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-2-ethylhexyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-3-butoxypropyl claims 1 , 2 claims 1 ,4 claims 1 ,5-TB claims 1 , 2 claims 1 ,4 claims 1 ,5-T-butomethyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-butotyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-butyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-isobutyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-isoctyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-isopropyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-methyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T-pentyl claims 1 , 2 claims 1 ,4 claims 1 ,5-T- ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Br or Cl.16. A ...

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-amino-2-(HETEROCYCLIC)pyrimidine-4-carboxylates AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 3. The compound of whereinX is CH, CF, or N;{'sup': 1', '1′', '1′, 'sub': 1', '8', '7', '10, 'Ris OR, wherein R is hydrogen, C-Calkyl, or C-Carylalkyl;'}{'sup': '2', 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '4', '1', '4', '1', '4', '1', '4, 'Ris halogen, C-Calkyl, C-Chaloalkyl, C-C-alkenyl, C-Chaloalkenyl, C-Calkynyl, C-C-alkoxy, C-Chaloalkoxy, C-Calkylthio, or C-Chaloalkylthio.'}{'sup': 3', '4', '3', '4', '3′', '4′', '3′', '4′, 'sub': 1', '6', '1', '6', '3', '6', '3', '6', '3', '6', '1', '3', '1', '3', '1', '6', '3', '6', '3', '6', '1', '6', '1', '6, 'Rand Rare hydrogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calknyl, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, or Rand Rtaken together represent ═CR(R), wherein Rand R are independently hydrogen, C-Calkyl, C-Calkenyl, C-Calknyl, C-Calkoxy or C-Calkylamino;'}A is A1, A2, A3, A7, A8, A9, A10, A11, A12, A13, A14, A15, A21, A22, A23, A24, A27, A28, A29, A30, A31, or A32;{'sup': '5', 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '3', '1', '3', '1', '3', '1', '3', '1', '4', '2', '4, 'Ris hydrogen, halogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, C-Chaloalkylthio, amino, C-Calkylamino, or C-Chaloalkylamino;'}{'sup': 6', '6′', '6″, 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '3', '1', '3', '2, 'R, R, and R are independently hydrogen, halogen, C-Calkyl, C-Chaloalkyl, cyclopropyl, halocyclopropyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, CN, or NO;'}{'sup': 7', '7′, 'sub': 1', '4', '1', '4', '1', '3', '1', '3', '1', '3', '1', '4, 'Rand R are independently hydrogen, halogen, C-Calkyl, C-Chaloalkyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, cyclopropyl, amino or C-Calkylamino;'}{'sup': '8', 'sub ...

4-AMINO-6-(4-SUBSTITUTED-PHENYL)-PICOLINATES AND 6-AMINO-2-(4-SUBSTITUTED-PHENYL)-PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides. 2. The compound of claim 1 , wherein Ar is Ar1.3. The compound of claim 1 , wherein Ar is Ar2.4. The compound of claim 1 , wherein Ar is Ar3.5. The compound of claim 1 , wherein Ar is Ar4.6. The compound of claim 1 , wherein Ar is Ar5.7. The compound of claim 1 , wherein Ar is Ar6.8. The compound of claim 1 , wherein Ris OR.9. The compound of claim 8 , wherein Ris H or C-Calkyl.10. The compound of claim 9 , wherein R is H or methyl.11. The compound of claim 1 , wherein X is N.12. The compound of claim 1 , wherein X is CY.13. The compound of claim 12 , wherein Y is hydrogen claim 12 , halogen claim 12 , C-Calkyl claim 12 , C-Chaloalkyl claim 12 , C-Calkoxy claim 12 , C-Chaloalkoxy claim 12 , C-Calkoxy claim 12 , C-Calkylthio claim 12 , or C-Chaloalkylthio.14. The compound of claim 13 , wherein Y is H claim 13 , F claim 13 , Cl claim 13 , or CH.15. The compound of claim 1 , wherein Ris halogen claim 1 , C-Calkenyl claim 1 , C-Chaloalkenyl claim 1 , C-Calkoxy claim 1 , C-Chaloalkoxy claim 1 , C-Calkylthio claim 1 , or C-Chaloalkylthio.16. The compound of claim 15 , wherein Ris halogen claim 15 , C-Calkenyl claim 15 , C-Chaloalkenyl claim 15 , or C-Calkoxy.17. The compound of claim 16 , wherein Ris Cl claim 16 , OCH claim 16 , or vinyl.18. The compound of claim 1 , wherein Rand Rare each independently hydrogen claim 1 , C-Calkyl claim 1 , C-Chaloalkyl claim 1 , C-Calkenyl claim 1 , C-Chaloalkenyl claim 1 , C-Calkynyl claim 1 , formyl claim 1 , (C-Calkyl)carbonyl claim 1 , (C-Chaloalkyl)carbonyl claim 1 , (C-Calkoxy)carbonyl claim 1 , (C-Calkyl)carbamyl claim 1 , tri(C-Calkyl)silyl claim 1 , or Rand Rtaken together represent ═CRR claim 1 , wherein R and R are each independently hydrogen claim 1 ...

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

Novel 4-amino-6-(heterocyclic)picolinic acids and their derivatives and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives are useful to control undesirable vegetation. 2. The compound of wherein Ris halogen claim 1 , C-C-alkenyl claim 1 , C-Chaloalkenyl claim 1 , or C-C-alkoxy.3. The compound of wherein Ris Cl claim 2 , methoxy claim 2 , vinyl claim 2 , or 1-propenyl.4. The compound of wherein Rand Rare both hydrogen.5. The compound of wherein X is N claim 1 , CH claim 1 , or CF.6. The compound of wherein Ris hydrogen or halogen.7. The compound of wherein Ris hydrogen or F.8. The compound of wherein Ris hydrogen or F.9. The compound of wherein R is hydrogen.10. The compound of wherein:{'sup': '2', 'sub': 2', '4', '2', '4', '1', '4, 'Ris halogen, C-C-alkenyl, C-Chaloalkenyl, or C-C-alkoxy;'}{'sup': 3', '4, 'Rand Rare both hydrogen; and'}X is N, CH, or CF.11. The compound of wherein:{'sup': '2', 'sub': 2', '4', '1', '4, 'Ris halogen, C-C-alkenyl, or C-C-alkoxy;'}{'sup': 3', '4, 'Rand Rare hydrogen; and'}X is N, CH, or CF;Ar is Ar1, Ar3, Ar7, Ar9, Ar10, Ar13, Ar15, Ar16, Ar19, Ar21, or Ar22;{'sup': '5', 'Ris hydrogen or F;'}{'sup': '6', 'Ris hydrogen or F;'}{'sup': '6′', 'R is hydrogen;'}{'sup': 7', '7′', '8', '8′', '9', '9′', '9″', '9′″, 'R, R, R, R, R, R, R, and R, if applicable to the relevant Ar group, are independently hydrogen or fluorine.'}12. The compound of wherein:{'sup': '2', 'Ris chlorine, methoxy, vinyl, or 1-propenyl.'}{'sup': 3', '4, 'Rand Rare hydrogen; and'}X is N, CH, or CF.13. The compound of wherein:{'sup': '2', 'Ris chlorine;'}{'sup': 3', '4, 'Rand Rare hydrogen; and'}X is N, CH, or CF.14. The compound of wherein:{'sup': '2', 'Ris methoxy;'}{'sup': 3', '4, 'Rand Rare hydrogen; and'}X is N, CH, or CF.15. The compound of wherein:{'sup': '2', 'Ris vinyl or 1-propenyl;'}{'sup': 3', '4, 'Rand Rare hydrogen; and'}X is N, CH, or CF.16. A herbicidal composition comprising the compound of and an agriculturally acceptable adjuvant or ...

PESTICIDAL COMPOSITIONS AND RELATED METHODS

A process of applying a pesticidal composition to an area to control a pest, wherein the pesticidal composition comprises at least one compound selected from a compound of formula I, or any agriculturally acceptable salt thereof, wherein R, R, R, R, R, R, R, R, Q, Z, L, L, and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (Formula One) 2. A composition according to wherein said molecule said X is CR8.3. A composition according to wherein said molecule said R1 is H.4. A composition according to wherein said molecule said R2 is H.5. A composition according to wherein said molecule said R3 is H.6. A composition according to wherein said molecule said R4 is halo or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R4 is F claim 1 , Cl claim 1 , or unsubstituted C-Calkyl.8. A composition according to wherein said molecule said R4 is Cl claim 1 , or CH.9. A composition according to wherein said molecule said R5 is substituted or unsubstituted C-CalkylC═CR12.10. A composition according to wherein said molecule said R5 is unsubstituted C-CalkylC═CR12.11. A composition according to wherein said molecule said R5 is CHC≡CH.12. A composition according to wherein said molecule said R6 is O.13. A composition according to wherein said molecule said R7 is substituted or unsubstituted C-Calkyl claim 1 , OR9 claim 1 , or R9S(O)R9.14. A composition according to wherein said molecule said R7 is a substituted C-Calkyl wherein said substituent is one or more halos.15. A composition according to wherein said molecule said R7 is a substituted C-Calkyl wherein said substituent is one or more F or Cl or a combination thereof.16. A composition according to wherein said molecule said R7 is a substituted C-Calkyl wherein said substituent is one or more F.17. A composition according to wherein said molecule said R7 is CHCF.18. A composition according to wherein said molecule said R7 is an unsubstituted C-Calkyl.19. A composition according to wherein said molecule said R7 is CH(CH) claim 1 , CH claim 1 , C(CH) claim 1 , or CHCHCHCH.20. A composition according to wherein said molecule said R7 is OR9.21. A composition according to wherein said molecule said R7 is O(unsubstituted C-Calkyl).22. A composition according to ...

PROCESS FOR THE PREPARATION OF 4-AMINO-3-CHLORO-5-FLUORO-6-(SUBSTITUTED) PICOLINATES

4-Amino-3-chloro-5-fluoro-6-(substituted)picolinates are conveniently prepared from 3,4,5,6-tetrachloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange and hydrolysis, esterification and transition metal assisted coupling. 1. A compound of the formula:wherein X and Y independently represent F or Cl;wherein X and Y independently represent F or Cl with the proviso that at least one of X and Y are F;{'sup': '1', 'wherein Wrepresents F, C1, Br or I; or'}{'sup': '2', 'wherein Wrepresents Cl, Br or I.'} This application is a divisional of U.S. Continuation patent application Ser. No. 14/171,791, filed Feb. 4, 2014, which claims the benefit of U.S. Utility patent application Ser. No. 13/356,669, filed Jan. 24, 2012, which claims the benefit of U.S. Provisional Patent Application Ser. No. 61/435,966 filed Jan. 25, 2011.The present invention concerns a process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates. More particularly, the present invention concerns a process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinates in which the 5-fluoro substituent is introduced by a halogen exchange early in the process scheme.U.S. Pat. No. 6,297,197 B1 describes inter alia certain 4-amino-3-chloro-5-fluoro-6-(alkoxy or aryloxy)picolinate compounds and their use as herbicides. U.S. Pat. No. 6,784,137 B2 and 7,314,849 B2 describe inter alia certain 4-amino-3-chloro-5-fluoro-6-(aryl)picolinate compounds and their use as herbicides. U.S. Pat. No. 7,432,227 B2 describes inter alia certain 4-amino-3-chloro-5-fluoro-6-(alkyl)picolinate compounds and their use as herbicides. Each of these patents describes the manufacture of 4-amino-3-chloro-5-fluoro-6-(substituted)picolinate starting materials by fluorination of the corresponding 5-(unsubstituted)picolinates with 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate). It would be advantageous to produce 4-amino-3-chloro-5 ...

4-AMINO-6-(HETEROCYCLIC)PICOLINATES AND 6-AMINO-2-(HETEROCYCLIC)PYRIMIDINE-4-CARBOXYLATES AND THEIR USE AS HERBICIDES

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides. 132-. (canceled)34. The compound of claim 33 , wherein{'sub': 1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3', '1', '3, 'X is CY, wherein Y is C-Calkyl, C-Chaloalkyl, C-Calkoxy, C-Chaloalkoxy, C-Calkoxy, C-Calkylthio, or C-Chaloalkylthio;'}{'sup': 1', '1′', '1″', '1′″', '1′', '1″', '1′″, 'sub': 1', '8', '7', '10', '1', '12', '3', '12', '3', '12, 'Ris OR or NRR, wherein R is hydrogen, C-Calkyl, or C-Carylalkyl, and R and R are independently hydrogen, C-Calkyl, C-Calkenyl, or C-Calkynyl;'}{'sup': 2', '17', '18', '19', '20', '21', '17', '18', '19', '20', '21, 'sub': 1', '4', '1', '4', '2', '4', '2', '4', '2', '4', '1', '4', '1', '4', '1', '4', '1', '4', '1', '4', '2', '4', '1', '3', '1', '3', '1', '4', '1', '4', '1', '10', '3', '6', '1', '10, 'Ris halogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, C-Calkoxy, C-Chaloalkoxy, C-Calkylthio, C-Chaloalkylthio, amino, C-Calkylamino, C-Chaloalkylamino, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, cyano, or a group of the formula —CR═CR—SiRRR, wherein Ris hydrogen, F, or Cl; Ris hydrogen, F, Cl, C-Calkyl, or C-Chaloalkyl; and R, R, and Rare independently C-Calkyl, C-Ccycloalkyl, phenyl, substituted phenyl, C-Calkoxy, or OH;'}{'sup': 3', '4', '3', '4', '3', '4', '3′', '4′', '3′', '4′', '3′', '4′, 'sub': 1', '6', '1', '6', '3', '6', '3', '6', '3', '6', '1', '3', '1', '3', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '1', '6', '3', '6', '3', '6', '1', '6', '1', '6, 'Rand Rare independently hydrogen, C-Calkyl, C-Chaloalkyl, C-Calkenyl, C-Chaloalkenyl, C-Calkynyl, formyl, C-Calkylcarbonyl, C-Chaloalkylcarbonyl, C-Calkoxycarbonyl, C-Calkylcarbamyl, C-Calkylsulfonyl, C-Ctrialkylsilyl, C-Cdialkylphosphonyl, or Rand Rtaken together with N is a 5- or 6-membered saturated ring, or Rand Rtaken together represent ═CR(R), ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 75. A composition according to any one of , , or , further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).8. A composition according to further comprising a seed.95. A process comprising applying a composition according to one of claim 7 , claim 7 , or . This application is a continuation of, and claims the benefit of, U.S. patent application Ser. No. 13/788,736, which was filed on Mar. 7, 2013, and which claims priority from, and benefit of, U.S. provisional application Ser. No. 61/639,274, which was filed on Apr. 27, 2012. The entire content of these applications are hereby incorporated by reference into this application.This disclosure is related to the field of processes to produce molecules that are useful as pesticides (e.g., acaricides, insecticides, molluscicides, and nematicides), such molecules, and processes of using such molecules to control pests.Pests cause millions of human deaths around the world each year. Furthermore, there are more than ten thousand species of pests that cause losses in agriculture. The world-wide agricultural losses amount to billions of U.S. dollars each year.Termites cause damage to all kinds of private and public structures. The world-wide termite damage losses amount to billions of U.S. dollars each year.Stored food pests eat and adulterate stored food. The world-wide stored food losses amount to billions of U.S. dollars each year, but more importantly, deprive people of needed food.There is an acute need for new pesticides. Certain pests are ...

Pesticidal compositions and processes related thereto

This document discloses molecules having the formula (I) and processes related thereto.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula ("Formula One"): and processes related thereto.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (1) and processes related thereto.

PESTICIDE MOLECULES

MOLÉCULAS PESTICIDAS. A presente invenção se refere a moléculas pesticidas apresentando a seguinte fórmula (I): sendo que A, R6, R7 e R8 são como definidos ao longo do relatório descritivo. PESTICIDE MOLECULES. The present invention relates to pesticidal molecules having the following formula (I): wherein A, R6, R7 and R8 are as defined throughout the specification.

Pesticidal compositions and processes related thereto

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Pesticidal compositions and processes related thereto

This disclosure is related to the field of molecules that are useful as pesticides (e.g. acaricides, insecticides, molluscicides, and nematicides). Such molecules are generally those according to the following Formula:

Pesticidal compositions and related methods

A pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof, wherein R1, R2, R4, R5, R6, R7, Z, Q, and Y are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests, or to an area to control pests.

Pesticidal compositions and related methods

A pesticidal composition comprises at least one compounds selected from a compound of formula (I), or any agriculturally acceptable salt thereof, wherein R1, R2, R3, R4, R5, R6, R7,R8, Q, Z, L, La, and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests.

Arylalkyl esters of 4-amino-6-(substituted phenyl)picolinates and 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylates and their use as herbicides

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di- tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic)picolinic acids and their derivatives; 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives; and methods of using the same as herbicides.

Arylalkyl esters of 4-amino-6-(substituted phenyl)-picolinates and 6-amino-2-(substituted phenyl)-pyrimidinecarboxylates and their use as selective herbicides for crops

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

Arylalkyl esters of 4-aminopicolinates and their use as herbicides

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

Arylalkyl esters of 4-amino-6-(substituted phenyl)picolinates and 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylates and their use as herbicides

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

Arylalkyl esters of 4-amino-6-(substituted phenyl)-picolinates and 6-amino-2-(substituted phenyl)-pyrimidinecarboxylates and their use as selective herbicides for crops

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

Arylalkyl esters of 4-amino-6-(substituted phenyl)picolinates and 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylates and their use as herbicides

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

Novel 4-amino-6-(heterocyclic)picolinic acids and their derivatives and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives are useful to control undesirable vegetation.

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinic acids having a halogen, alkyl or mono-, di- tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their 5 derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

Pyridine and pyrimidine carboxylate herbicides and methods of use thereof

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

Arylalkyl esters of 4-amino-6-(substituted phenyl)picolinates and 6-amino-2-(substituted phenyl)-4-pyrimidinecarboxylates and their use as herbicides

Arylalkyl esters of 4-aminopicolinic acids and 6-amino-4-pyrimidinecarboxylates are herbicides for control of weeds especially those species common to rice and wheat cropping systems and in pasture management programs.

3-alkoxy, thioalkyl and amino-4-amino-6-(substituted)picolinates and their use as herbicides

3-halo-(arly)-4-iminotetrahydropicolinates and their use as herbicides

3-Halo-6-(aryl)-4-iminotetrahydropicolinic acids having mono-, di- tri- and tetra-substituted aryl substituents in the 6-position, and their acid derivatives, are herbicides demonstrating a broad spectrum of weed control.

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

Novel 4-amino-6-(heterocyclic)picolinic acids and their derivatives and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their derivatives are useful to control undesirable vegetation.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic)picolinic acids, 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates, and derivatives thereof are provided. Also provided are herbicidal compositions including these compounds, as well as methods of using thereof as herbicides.

4-amino-6-(4-substituted-phenyl)-picolinates and their use as herbicides

Provided herein are 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives, compositions comprising the acids and their derivatives, and methods of use thereof as herbicides.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-2(heterocyclic) pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic )picolinic acids, 6-amino-2-(heterocyclic )pyrimidine-4-carboxylates, and derivatives thereof are provided. Also provided are herbicidal compositions including these compounds, as well as methods of using thereof as herbicides. The occurrence of undesirable vegetation, e.g., weeds, is a constant problem facing famers in crops, pasture, and other settings. Weeds compete with crops and negatively impact crop yield. The use of chemical herbicides is an important tool in controlling undesirable vegetation.

Process for the preparation of 6-(aryl)-4-aminopicolinates

3-Halo-6-(aryl)-4-iminotetrahydropicolinic acid esters are heated with polar solvents to prepare 6-(aryl)-4-aminopicolinates.

Arylalkyl esters of 4-aminopicolinates and their use as herbicides

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

Novel 4-amino-6-(heterocyclic)picolinic acids and their derivatives and 6-amino-2 (heterocyclic )pyrimidine-4-carboxylates and their derivatives are useful to control undesirable vegetation. The occurrence of undesirable vegetation, e.g., weeds, is a constant problem fadng famers in crops, pasture, and other settings. Weeds compete with crops and negatively impact crop yield. The use of chemical herbicides is an important tool in controlling undesirable vegetation.

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-amino-6-(heterocyclic)picolinates and their use as herbicides

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

Process for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates

4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.

Improved synthesis of 4-amino-6-(heterocyclic)picolinates

The present disclosure relates to improved processes for preparing 4-amino-6-(heterocyclic)picolinates.

Process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted) picolinates

Pyridine and pyrimidine carboxylate herbicides and methods of use thereof

Provided herein are pyridine and pyrimidine carboxylates and their derivatives, and compositions and methods of use thereof as herbicides.

Pesticidal compositions and processes related thereto

本文件係揭露具有下列化學式(“化學式1”)之分子：□及其相關之方法。

Arylalkyl esters of 4-aminopicolinates and their use as herbicides 4-

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula ("Formula One"): and processes related thereto.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides

4-Amino-6-(heterocyclic )picolinic acids, 6-amino-2-(heterocyclic )pyrimidine-4-carboxylates, and derivatives thereof are provided. Also provided are herbicidal compositions including these compounds, as well as methods of using thereof as herbicides. The occurrence of undesirable vegetation, e.g., weeds, is a constant problem facing famers in crops, pasture, and other settings. Weeds compete with crops and negatively impact crop yield. The use of chemical herbicides is an important tool in controlling undesirable vegetation.

Process for the preparation of 4-amino-5-fluoro-3-halo-6-picolinates (substituted)

Se preparan convenientemente 4-Amino-5-fluoro-3-halo-6-picolinatos (sustituidos) a partir de 4, 5, 6-tricloropicolinatos por medio de una serie de etapas que incluyen intercambio de flúor, aminación, halógeno, halogenación y acoplamiento asistido por metal de transición. 4-Amino-5-fluoro-3-halo-6-picolinates (substituted) are conveniently prepared from 4, 5, 6-trichloropicolinates by means of a series of steps including fluorine exchange, amination, halogen, halogenation and transition assisted metal coupling.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are compounds of Formula (I), including compositions comprising said compounds, and methods of use thereof as herbicides. The compounds of Formula (I) include 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives.

Pesticidal compositions and related methods

A pesticidal composition comprises a compound of formula I or any agriculturally acceptable salt thereof, wherein R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , Z, Q, and Y are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests, or to an area to control pests.

4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides

Provided herein are compounds of Formula (I), including compositions comprising said compounds, and methods of use thereof as herbicides. The compounds of Formula (I) include 4-amino-6-(4-substituted-phenyl)-picolinic acids and their derivatives, and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylic acids and their derivatives.

Pesticidal compositions and related methods

A pesticidal composition comprises at least one compounds selected from a compound of formula (I), or any agriculturally acceptable salt thereof, wherein R1, R2, R3, R4, R5, R6, R7,R8, Q, Z, L, La, and x are as described herein. A method of controlling pests comprises applying the pesticidal composition near a population of pests.

Arylalkyl esters of 4-amino-6-(substituted phenyl)picolinates and its use as herbicides

The invention relates to a compound of Formula (IA): (see formula (IA) wherein: Y represents C1-C8 alkyl, C3-C6 cycloalkyl, or phenyl substituted with 1-4 substituents independently selected from the group consisting of halo, C1-C3 alkyl, C3-C6 cycloalkyl, C1-C3 alkoxy, C1-C3 haloalkyl, C1-C3 haloalkoxy, cyano, nitro and NR1R2, or where two adjacent substituents are taken together as ~O(CH2)n O~ or ~O(CH2)n~, wherein n=1 or 2; Z represents halo, C1-C3 alkoxy, or C2-C4 alkenyl; R1 and R2 independently represent H, C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkynyl, hydroxy, C1-C6 alkoxy, amino, or C1-C6 acyl; and R3 represents unsubstituted or substituted C7-C11 arylalkyl.

Process for the preparation of 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates

processo para o preparo de 4-amino-3-cloro-5-fluoro-6-(substituído) picolinatos a presente invenção refere-se a 4-amino-3-cloro-5-fluro-6-(substituído)picolinatos que são convenientemente preparados a partir de 3,4,5,6-tetracloropicolinonitrilo por meio de uma série de etapas envolvendo permuta de flúor, aminação, permuta de halogênio e hidrólise, esterificação e acoplamento auxiliado por metal de transição. Process for the preparation of 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates The present invention relates to 4-amino-3-chloro-5-fluoro-6- (substituted) picolinates which are conveniently prepared from 3,4,5,6-tetrachloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange and hydrolysis, esterification and transition metal-assisted coupling.

Pesticidal compositions and processes related thereto

81778840 . = Abstract There is a need for new pesticides due to pesticide resistance in pests. The present invention relates to molecules useful as pesticides having the following formula (1), to processes to produce these molecules, to compositions comprising these moelcules and to processes of using these molecules to control pests. R7 A*'NAR8 (1) R6 CA 2852688 2020-02-24

? 4-AMINO-6- (HETEROCYCLIC) PICOLINATES AND 6-AMINO-2- (HETEROCYCLIC) PYRIMIDINE-4-CARBOXYLATES AND ITS USE AS HERBICIDES ?.

Novedosos ácidos 4-amino-6-(heterocíclico)picolínicos y sus derivados y 6-amino-2- (heterocíclico)pirimidina-4-carboxilatos y sus derivados son útiles para controlar vegetación no deseada.

Pesticide compositions and procedures related thereto

Una molécula que tiene una de las siguientes estructuras **(Tabla)** A molecule that has one of the following structures **(Table)**