21-01-2015 дата публикации
Номер: CN104292079A
Принадлежит:
The invention relates to a preparation method of bisphenol TMC. The preparation method of the bisphenol TMC comprises the following steps: (a) sequentially putting phenol, 3,3,5-trimethyl cyclohexanone and a composite catalyst into a reaction vessel, uniformly mixing, reacting for 8-15 hours at the temperature of 30-40 DEG C, then warming to 55-65 DEG C, and filtering while hot to obtain filtrate and filter residue; (b) evaporating the filtrate at the pressure of 200-700Pa and the temperature of 75-90 DEG C for removing phenol, so as to obtain a crude product; and (c) dissolving the crude product in an alcohol solvent and crystallizing, wherein the composite catalyst is formed by compounding a main catalyst and a secondary catalyst, mass ratio of the main catalyst to the secondary catalyst is 7:3, the main catalyst comprises ferric chloride, copper chloride and aluminium trioxide, and the secondary catalyst is macrorecticular styrene strongly acidic cation resin. The preparation method ...
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