08-07-2021 дата публикации
Номер: US20210206638A1
Принадлежит:
Inorganic compounds having the formula LiMPQ, where M is Ga, In, Bi, Sb, As, Al, or a combination thereof, and Q is S and/or Se, ar provided. Methods and devices for detecting incident neutrons and alpha-particles using the compounds are also provided. For thermal neutron detection applications, the compounds can be enriched with lithium-6 isotope (Li) to enhance their neutron detecting capabilities. 1. A lithium-containing chalcophosphate compound having the formula LiMPQ , where M is Ga , In , Bi , Sb , As , Al , or a combination thereof , and Q is S , Se , or a combination thereof.2. The compound of claim 1 , wherein the Li comprises Li.3. The compound of claim 1 , wherein the compound is a quaternary compound.4. The compound of claim 3 , wherein the compound is doped with an external dopant.5. The compound of claim 4 , wherein the external dopant is selected from Cd claim 4 , Hg claim 4 , Pb claim 4 , Sn claim 4 , and combinations of two or more thereof.6. The compound of having the formula LiInPSe.7. The compound of claim 3 , wherein the compound has the formula LiInMPSe claim 3 , where M is the external dopant and x has a value in the range from 0.00001 to 0.05.8. The compound of claim 7 , wherein the compound is LiInCdPSe claim 7 , where Cd is the external dopant and x has a value in the range from 0.00001 to 0.05.9. The compound of claim 6 , wherein the Li comprises Li.10. The compound of claim 1 , wherein the compound is in the form of a single-crystal having a length of at least 0.5 cm.11. The compound of claim 6 , wherein the compound is in the form of a single-crystal having a length of at least 0.5 cm.12. A method for detecting thermal neutrons or alpha particles claim 6 , the method comprising:{'sub': 2', '6, 'applying an electric field across a single-crystal of a lithium-containing chalcophosphate compound having the formula LiMPQ, where M is Ga, In, Bi, Sb, As, Al, or a combination thereof, and Q is S, Se, or a combination thereof,'}exposing the ...
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