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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 8565. Отображено 100.
01-03-2012 дата публикации

Polymer blend containing intermediate transfer members

Номер: US20120049121A1
Автор: JIN Wu
Принадлежит: Xerox Corp

An intermediate transfer media, such as a belt, that includes a polymer blend of a polymethacrylimide and a polysulfone, a polymethacrylimide and a polyphenylsulfone, or a polymethacrylimide and a polyethersulfone and optionally a conductive component.

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15-03-2012 дата публикации

Poly(Arylene Sulfide) and Production Process Thereof

Номер: US20120065361A1
Принадлежит: Kureha Corp

The invention provides a production process of a poly(arylene sulfide), comprising a polymerization step of subjecting at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound to a polymerization reaction in an organic amide solvent; a reaction step of adding a hydroxyl group-containing organic compound containing no bonded halogen atom in a proportion of 0.001 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system containing the organic amide solvent and a formed polymer after the polymerization step to cause the formed polymer to react with the hydroxyl group-containing organic compound; and a collecting step of collecting a polymer from the polymerization reaction system after the reaction step, and the poly(arylene sulfide).

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12-04-2012 дата публикации

Solvent resistance of epoxy resins toughened with polyethersulfone

Номер: US20120088864A1
Автор: Yen-Seine Wang
Принадлежит: Hexcel Corp

The solvent resistance of epoxy resins toughened with polyethersulfone is improved by using low molecular weight polyethersulfone. The resulting thermoplastic toughened epoxy resins are useful for making prepreg for aerospace applications.

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26-04-2012 дата публикации

Polyimide polyphenylsulfone blends with improved flame resistance

Номер: US20120100324A1

The present disclosure relates to a composition with improved flame resistance, to articles made from the composition, and to methods that include processing the composition. The composition can include from 15 to 85 percent by weight of a polyetherimide (PEI), from 15 to 85 percent by weight of a polyphenylsulfone (PPSU), a polyetherimide-siloxane copolymer in an amount up to 12 percent by weight, and from 0 to 0.30 percent by weight of a stabilizer.

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03-05-2012 дата публикации

Segmented polyarylene ether block copolymers

Номер: US20120108693A1
Принадлежит: BASF SE

The present invention relates to polyarylene ether block copolymers according to the general formula A-K-X-K-A, where —X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, and A— is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, and there is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar3 is an aromatic group having from 6 to 18 carbon atoms. The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.

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14-06-2012 дата публикации

Thermally stable biuret and isocyanurate based surface modifying macromolecules and uses thereof

Номер: US20120148774A1
Принадлежит: Interface Biologics Inc

The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties.

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05-07-2012 дата публикации

Flame retardant system

Номер: US20120172467A1
Принадлежит: BASF SE

The invention relates to a flame retardant comprising a) at least one sulfur compound of the formula (I) b) at least one halogen-free organophosphorus compound with phosphorus content in the range from 0.5 to 40% by weight, based on the phosphorus compound.

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12-07-2012 дата публикации

Polyarylene sulfide and method for producing the same

Номер: US20120178898A1
Принадлежит: TORAY INDUSTRIES INC

A method is provided for producing a polyarylene sulfide by reacting a sulfidizing agent with a dihalogenated aromatic compound in an organic polar solvent in the presence of an alkali metal hydroxide, the method includes <Step 1>: carrying out the reaction in such a manner that the polymerization time in a temperature range of 230° C. to less than 245° C. (T1a) is not less than 30 minutes and less than 3.5 hours and that the conversion ratio of the dihalogenated aromatic compound at the end of the step is 70 to 98 mol. % and <Step 2>: carrying out the reaction in such a manner that the polymerization time in a temperature range of 245° C. to less than 280° C. (T2) is not less than 5 minutes and less than 1 hour.

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13-09-2012 дата публикации

Fiber, fiber aggregate and adhesive having the same

Номер: US20120231260A1

Provided is a functional fiber and a fiber aggregate for realizing various functions, an adhesive for easily bonding electronic components, and a method for manufacturing the same. Particularly, a fiber extended in a length direction includes a carrier polymer and a plurality of functional particles, wherein the plurality of functional particles are embedded in the carrier polymer and physically fixed to the carrier polymer to be integrated.

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13-09-2012 дата публикации

Fiber, fiber aggregate and adhesive having the same

Номер: US20120231689A1

Provided is a functional fiber and a fiber aggregate for realizing various functions, an adhesive for easily bonding electronic components, and a method for manufacturing the same. Particularly, a fiber extended in a length direction includes a carrier polymer and a plurality of functional particles, wherein the plurality of functional particles are embedded in the carrier polymer and physically fixed to the carrier polymer to be integrated.

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04-10-2012 дата публикации

Blends of polyarylene ethers and polyarylene sulfides

Номер: US20120252962A1
Принадлежит: BASF SE

The present invention relates to thermoplastic molding materials comprising the following components: (A) at least one polyarylene ether, (B) at least one polyarylene sulfide, (C) at least one functionalized polyarylene ether comprising carboxyl groups having a viscosity number according to DIN EN ISO 1628-1 of 45 to 65 ml/g measured in 1% strength by weight solution in N-methyl-2-pyrrolidone at 25° C., (D) at least one fibrous or particulate filler and (E) optionally further additives and/or processing assistants. In addition, the present invention relates to a process for the preparation of the thermoplastic molding materials according to the invention, the use thereof for the production of shaped articles and the use of functionalized polyarylene ethers comprising carboxyl groups having a viscosity number according to DIN EN ISO 1628-1 of 45 to 65 ml/g measured in 1% strength by weight solution in N-methyl-2-pyrrolidone at 25° C. for increasing the elongation at break and for improving the impact strength.

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25-10-2012 дата публикации

Die attach film

Номер: US20120270381A1
Принадлежит: LG Chem Ltd

Provided are a die attach film, a semiconductor wafer, and a semiconductor packaging method. The die attach film can prevent generation of burrs or scattering of chips in a dicing process, and exhibits excellent expandability and pick-up characteristics in a die pressure-sensitive adhesive process. Further, the die attach film can prevent release, shifting, or deflection of a chip in a wire pressure-sensitive adhesive or molding process. Thus, it is possible to improve embeddability, inhibit warpage of a wafer or wiring substrate, and enhance productivity in a semiconductor packaging process.

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22-11-2012 дата публикации

Blends of polyarylene ethers and polyarylene sulfides

Номер: US20120296031A1
Принадлежит: BASF SE

The present invention relates to thermoplastic molding materials comprising the following components: (A) at least one polyarylene ether, (B) at least one polyarylene sulfide, (C) optionally at least one functionalized polyarylene ether comprising carboxyl groups, (D) at least one fibrous or particulate filler and (E) optionally further additives and/or processing assistants, the ratio of the apparent viscosity of the component (A) to that of the component (B), determined at 350° C. and a shear rate of 1150 s −1 , being from 2.5 to 3.7.

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03-01-2013 дата публикации

Polyetherimide resins with very low levels of residual contamination

Номер: US20130003227A1
Принадлежит: SABIC INNOVATIVE PLASTICS IP BV

Compositions and methods for producing compositions comprising a monoamine-endcapped polyimide component. Based on a gas chromatography mass spectroscopy analysis of a surface rinse of the composition performed at room temperature, the composition can have at least one surface with less than or equal to 5 ppb releasable phosphorous residuals, and less than or equal to 5 ppb releasable volatile organic compound residuals. The composition can also comprise less than or equal to 10 ppb combined releasable residuals. Because of the very low levels of residual contamination, the compositions can be used to produce a variety of articles, including a disk drive.

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14-03-2013 дата публикации

Fluorine-Containing Sulfonate, Fluorine-Containing Sulfonate Resin, Resist Composition and Pattern Formation Method

Номер: US20130065182A1
Принадлежит: Central Glass Co Ltd

According to the present invention, there is provided a fluorine-containing sulfonate resin having a repeating unit of the following general formula (3). In order to prevent deficiency such as roughness after pattern formation or failure in pattern formation, the fluorine-containing sulfonate resin incorporates therein a photoacid generating function and serves as a resist resin in which “a moiety capable of changing its developer solubility by the action of an acid” and “a moiety having a photoacid generating function” are arranged with regularity.

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28-03-2013 дата публикации

SULFONATED POLY(ARYLENES), POLYMER COMPOUNDS AND METHODS OF PRODUCING THE SAME

Номер: US20130079469A1

A copolymer containing, in addition to recurring elements of a sulfonated poly(arylene) containing exclusively recurring structural element(s) of the general formulas —[—Ar(SOM)-X—]— and —[—Ar(SOM)-Y—]—, wherein X and Y, which are identical or different from each other, each represent an electron-acceptor group, Arand Ar, which are either identical or different from each other, represent an aromatic or heteroaromatic ring system with 5-18 ring atoms; wherein the aromatic or heteroaromatic ring system, in addition to the SOM and the substituents X and Y, optionally comprises additional substituents which are not electron-donor groups; M represents monovalent cation and n is an integral number between 1 and 4; and wherein X, Y, Ar, Ar, M and n can be identical or different in various structural elements, independently of each other, one or several additional elements of at least one additional monomer or macromonomer. 1. A copolymer containing , in addition to recurring elements of a sulfonated poly(arylene) containing exclusively recurring structural element(s) of the general formulas —[—Ar(SOM)-X—]— and —[—Ar(SOM)-Y—]— , wherein X and Y , which are identical or different from each other , each represent an electron-acceptor group , Arand Ar , which are either identical or different from each other , represent an aromatic or heteroaromatic ring system with 5-18 ring atoms; wherein the aromatic or heteroaromatic ring system , in addition to the SOM and the substituents X and Y , optionally comprises additional substituents which are not electron-donor groups; M represents monovalent cation and n is an integral number between 1 and 4; and wherein X , Y , Ar , Ar , M and n can be identical or different in various structural elements , independently of each other , one or several additional elements of at least one additional monomer or macromonomer.2. The copolymer according to claim 1 , wherein the (at least) one additional monomer or macromonomer is a α claim 1 ,ω- ...

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04-04-2013 дата публикации

High-strength blends based on polyarylene ethers

Номер: US20130085224A1
Принадлежит: BASF SE

The present invention relates to molding compositions comprising (A) from 29 to 89% by weight of at least one polyarylene ether sulfone having an average number of phenolic end groups per chain of from 0 to 0.2, (B) from 0.5 to 20% by weight of a thermotropic polymer, (C) from 0.5 to 10% by weight of a polyarylene ether having predominantly OH end groups, (D) from 10 to 70% by weight of at least one fibrous or particulate filler, (E) from 0 to 40% by weight of additives or processing aids, where the total of the proportions by weight is 100% by weight, based on the thermoplastic molding composition.

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11-04-2013 дата публикации

High temperature polymer alloy containing stabilizers

Номер: US20130090416A1
Автор: Ke Feng, Xinyu Zhao
Принадлежит: Ticona LLC

The present disclosure is generally directed to a resin composition containing a mixture of high temperature polymers and at least one stabilizer. The stabilizer serves to prevent the polymers from adversely interfering with each other during melt processing. In one embodiment, the high temperature polymers present in the composition may comprise a mixture of an aromatic polyester polymer and a polyarylene sulfide polymer. The stabilizer comprises a phosphite stabilizer. The composition produces molded articles having better thermal stability and reduced mold deposits.

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16-05-2013 дата публикации

Compositions and Methods for Removing Organic Substances

Номер: US20130123411A1
Принадлежит: EASTMAN CHEMICAL COMPANY

Compositions and methods useful for the removal of organic substances from substrates, for example, electronic device substrates such as microelectronic wafers or flat panel displays, are provided. A method is presented which applies a minimum volume of the composition as a coating to the inorganic substrate whereby sufficient heat is added and immediately rinsed with water to achieve complete removal. These compositions and methods are particularly suitable for removing and completely dissolving photoresists of the positive and negative varieties as well as thermoset polymers from electronic devices. 1. A composition for cleaning organic resin from inorganic substrates comprising:a solvent or mixture of solvents; andat least one sulfonated polyester at a weight % of greater than 10.0%,wherein the solvent is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, diethylene glycol ethyl ether, diethylene glycol methyl ether, diethylene glycol butyl ether, diethylene glycol propyl ether, ethylene glycol propyl ether, ethylene glycol butyl ether and mixtures thereof.2. The composition according to claim 1 , wherein the solvent is at a weight % of from about 40% to about 97%.3. The composition according to claim 2 , wherein the solvent is at a weight % of from about 60% to about 90%. This application is a continuation of U.S. patent application Ser. No. 13/346,877 filed Jan. 10, 2012, which was a Divisional of U.S. patent application Ser. No. 12/413,085 filed Mar. 27, 2009, which are hereby incorporated herein by reference.The present invention relates generally to the removal of organic substances from a substrate. In particular, the present invention relates to a universal method with a range of compositions, which applies to the removal of both amorphous and thermoset polymers from electronic devices such as semiconductor wafers and flat panel displays (FPD), and other microelectronic substrates.Various polymers are used in the ...

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30-05-2013 дата публикации

Graft copolymers

Номер: US20130137784A1
Принадлежит: GAMBRO LUNDIA AB

Graft copolymers of hydrophobic polymers and hydrophilic polymers, a method for their preparation, and their use in membranes for medical treatments such as hemodialysis, hemodiafiltration and hemofiltration, in membranes for water purification, and in membranes for bioprocessing.

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20-06-2013 дата публикации

Molded Part for a Portable Electronic Device

Номер: US20130155597A1
Автор: Luo Rong, Zhao Xinyu
Принадлежит: Ticona LLC

A molded part that has a relatively small thickness so that it can be readily employed in portable electronic devices is provided. The molded part is formed from a thermoplastic composition that contains a polyarylene sulfide and an aromatic amide oligomer. Due to the improved crystallization rate, the thermoplastic composition can be molded at lower temperatures to still achieve the same degree of crystallization. In addition to minimizing the energy requirements of the molding operating, the use of lower temperatures can also decrease the production of “flash” normally associated with high temperature molding operations. The composition may also possess good viscosity properties that allow it to be readily molded into parts of a variety of different shapes and sizes. 2. The molded part of claim 1 , wherein the aromatic amide oligomer has a molecular weight of about 3 claim 1 ,000 grams per mole or less.3. The molded part of claim 1 , wherein ring B is phenyl.4. The molded part of claim 1 , wherein ring B is naphthyl.6. The molded part of claim 5 , wherein m claim 5 , n claim 5 , and p are 0.7. The molded part of claim 5 , wherein Rand Rare phenyl substituted with —C(O)HN— or —NHC(O)—.9. The molded part of claim 8 , wherein m is 0.11. The molded part of claim 1 , wherein the oligomer is N1 claim 1 ,N4-diphenylterephthalamide.12. The molded part of claim 1 , wherein aromatic amide oligomers constitute from about 0.1 wt. % to about 8 wt. % of the composition.13. The molded part of claim 1 , wherein the composition further comprises boron nitride claim 1 , an impact modifier claim 1 , mineral filler claim 1 , fibrous filler claim 1 , organosilane coupling agent claim 1 , lubricant claim 1 , disulfide claim 1 , or a combination thereof.14. The molded part of claim 1 , wherein the composition has a crystallization potential of about 55% or more claim 1 , as determined by differential scanning calorimetry in accordance with ISO 10350.15. The molded part of claim 1 , ...

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20-06-2013 дата публикации

Nucleating System for Polyarylene Sulfide Compositions

Номер: US20130157033A1
Принадлежит: Ticona LLC

A nucleating system for a thermoplastic composition that contains a polyarylene sulfide is provided. The nucleating system includes a combination of an inorganic crystalline compound and an aromatic amide oligomer. The present inventors have discovered that the combination of these different types of nucleating agents result in excellent crystallization properties (e.g., rate of crystallization). Due to the improved crystallization rate, the thermoplastic composition can be molded at lower temperatures to still achieve the same degree of crystallization. In addition to minimizing the energy requirements of the molding operating, the use of lower temperatures can also decrease the production of “flash” normally associated with high temperature molding operations. The composition may also possess good viscosity properties that allow it to be readily molded into parts of a variety of different shapes and sizes.

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04-07-2013 дата публикации

Polyphenylene Sulfide Resin Composition with Improved Thermal Conductivity and Surface Appearance and Articles Thereof

Номер: US20130172466A1
Принадлежит: CHEIL INDUSTRIES INC.

A polyphenylene sulfide resin composition comprises (A) about 30 to about 50% by weight of a polyphenylene sulfide resin; (B) about 1 to about 5% by weight of an amorphous polyamide resin; and (C) about 45 to about 69% by weight thermally conductive insulating fillers. 1. A polyphenylene sulfide resin composition comprising:(A) about 30 to about 50 wt % of a polyphenylene sulfide resin;(B) about 1 to about 5 wt % of an amorphous polyamide resin; and(C) about 45 to about 69 wt % of thermally conductive insulating fillers.2. The polyphenylene sulfide resin composition of claim 1 , wherein the polyphenylene sulfide resin (A) has a weight average molecular weight of about 3 claim 1 ,000 to about 50 claim 1 ,000 g/mol.3. The polyphenylene sulfide resin composition of claim 1 , wherein the amorphous polyamide resin (B) has a glass transition temperature (Tg) about 110 to about 200° C.5. The polyphenylene sulfide resin composition of claim 1 , wherein the amorphous polyamide resin (B) includes polyamide prepared from terephthalic acid and 2 claim 1 ,2 claim 1 ,4-trimethyl hexamethylene diamine or 2 claim 1 ,4 claim 1 ,4-trimethyl hexamethylene diamine; polyamide prepared from isophthalic acid and 1 claim 1 ,6-hexamethylene diamine; a copolyamide prepared from a combination of terephthalic acid/isophthalic acid and 1 claim 1 ,6-hexamethylene diamine; a copolyamide prepared from isophthalic acid claim 1 , 3 claim 1 ,3′-dimethyl-4 claim 1 ,4′-diamino dicyclohexylmethane claim 1 , and laurolactam or lactam; copolyamide prepared from a combination of terephthalic acid/isophthalic acid claim 1 , 3 claim 1 ,3′-dimethyl-4 claim 1 ,4′-diamino dicyclo hexylmethane and laurolactam claim 1 , or a combination thereof.6. The polyphenylene sulfide resin composition of claim 1 , wherein the thermally conductive insulating fillers (C) include spherical thermally conductive insulating fillers (c1) claim 1 , plate-shaped thermally conductive insulating fillers (c2) or a combination thereof.7 ...

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01-08-2013 дата публикации

METHOD FOR PRODUCING THERMOPLASTIC RESIN COMPOSITION, THERMOPLASTIC RESIN COMPOSITION, AND MOLDED ARTICLE

Номер: US20130196104A1
Принадлежит: Toray Industries, Inc.

The present invention provides a thermoplastic resin composition, which is excellent in low-temperature toughness and high-temperature creep characteristics, by a method for producing a thermoplastic resin composition by melt-kneading: 1. A method for producing a thermoplastic resin composition by melt-kneading:(a) a polyphenylene sulfide resin, with{'sup': '2', '(b) a polyetherimide resin or a polyethersulfone resin, wherein the thermoplastic resin composition contains 99 to 1% by weight of the component (a) and 1 to 99% by weight of the component (b) based on 100% by weight of the total amount of the component (a) and the component (b); the melt-kneading step is the step of melt-kneading by an extruder provided with an elongational flow zone which is a zone in which melt-kneading is performed while being allowed to undergo elongational flow; and a flow effect pressure drop before and after the elongational flow zone is from 50 to 1,000 kg/cm.'}2. The method for producing a thermoplastic resin composition according to claim 1 , wherein a ratio of the total length of the elongational flow zone to the full length of a screw of the extruder is from 5 to 60%.3. The method for producing a thermoplastic resin composition according to claim 1 , which satisfies the equation Lk/D=0.2 to 10 claim 1 , where Lk denotes the length of one elongational flow zone in a screw of the extruder claim 1 , and D denotes a screw diameter.4. A thermoplastic resin composition comprising:(a) a polyphenylene sulfide resin, and(b) a polyetherimide resin or a polyethersulfone resin, wherein the thermoplastic resin composition contains 99 to 1% by weight of the component (a) and 1 to 99% by weight of the component (b) based on 100% by weight of the total amount of the component (a) and the component (b), and also satisfies the following conditions:(i) tensile elongation, measured in accordance with ASTM-D638 under the conditions of a tension speed of 10 mm/minute and an ambient temperature of − ...

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05-09-2013 дата публикации

COMPOSITION FOR OPTICAL MATERIAL

Номер: US20130231425A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

The present invention relates to a composition for an optical material capable of suppressing generation of inhomogeneity called “stria” in polymerization, in particular, generation of striae in a lens having high optical power or a surface with high radius of curvature, and more specifically relates to a composition for an optical material, comprising: a stabilizer having a mass ratio of dibutyltin dichloride to monobutyltin trichloride of 97.0/3.0 to 100.0/0.0; an episulfide compound; a polythiol compound; and a polymerization catalyst for the episulfide compound. 1. A composition for an optical material , comprising:a stabilizer having a mass ratio of dibutyltin dichloride to monobutyltin trichloride of 97.0/3.0 to 100.0/0.0;an episulfide compound;a polythiol compound; anda polymerization catalyst for the episulfide compound.2. A composition for an optical material according to claim 1 , wherein the stabilizer contains dibutyltin dichloride by at least 97.0 mass % and monobutyltin trichloride by 3.0 mass % or less.3. A composition for an optical material according to claim 1 , further comprising a polyisocyanate compound.4. A composition for an optical material according to claim 1 , further comprising sulfur.5. A composition for an optical material according to claim 2 , further comprising a polyisocyanate compound.6. A composition for an optical material according to claim 2 , further comprising sulfur7. A composition for an optical material according to claim 3 , further comprising sulfur8. A composition for an optical material according to claim 5 , further comprising sulfur The present invention relates to a composition for an optical material and especially to a composition for an optical material, suitably used for optical materials such as plastic lens, prism, optical fiber, information recording substrate, filter and the like (plastic lens, in particular).A plastic material has been increasingly used for various types of optical materials, in particular, ...

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12-09-2013 дата публикации

FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITION, REINFORCING FIBER BUNDLE, AND PROCESS FOR PRODUCTION OF FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITION

Номер: US20130234361A1
Принадлежит: Toray Industries, Inc.

The present invention relates to fiber-reinforced thermoplastic resin composition comprising 0.1 to 10 mass % of a (meth)acrylic-based polymer, 1 to 70 mass % of reinforcing fiber, and 20 to 98.9 mass % of thermoplastic resin, wherein the (meth)acrylic-based polymer has, in a side chain, at least one functional group selected from a hydroxyl group, a carboxyl group, an amide group, and an urea group, and has a cohesive energy density (CED) of 385 to 550 MPa. The present invention provides, particularly in the case of using a polyolefin-based resin as matrix resin, a fiber-reinforced thermoplastic resin composition and a reinforcing fiber bundle which have high adhesiveness and good mechanical characteristics. 115.-. (canceled)17. The fiber-reinforced thermoplastic resin composition according to claim 16 , wherein the (meth)acrylic-based polymer contains one or more (meth)acrylic-based monomer units selected from 2-hydroxyethyl methacrylate unit claim 16 , N-(2-hydroxyethyl)acrylic amide unit claim 16 , and N-(2-methacryloyl oxyethyl)ethylene urea unit.18. The fiber-reinforced thermoplastic resin composition according to claim 16 , wherein the (meth)acrylic-based polymer contains 0 to 5 mass % of a (meth)acrylic-based monomer unit having a carboxyl group claim 16 , 3 to 25 mass % of a (meth)acrylic-based monomer unit having a hydroxyl group claim 16 , and 70 to 97 mass % of (meth)acrylic acid alkyl ester unit having an alkyl group with 1 to 4 carbon atoms.19. The fiber-reinforced thermoplastic resin composition according to claim 16 , wherein of all the (meth)acrylic-based monomer units in the (meth)acrylic-based polymer claim 16 , (meth)acrylic-based monomer units in which an acryloyloxy group or a methacryloyloxy group is bonded to a hydrogen and/or a primary carbon atom account for 60 mass % or more claim 16 ,20. The fiber-reinforced thermoplastic resin composition according to claim 16 , wherein the (meth)acrylic-based polymer has a hydroxyl group in a side chain ...

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19-09-2013 дата публикации

REINFORCED THERMOPLASTIC ARTICLES, COMPOSITIONS FOR THE MANUFACTURE OF THE ARTICLES, METHODS OF MANUFACTURE, AND ARTICLES FORMED THEREFROM

Номер: US20130244528A1
Автор: Lowery Daniel F.
Принадлежит: SABIC INNOVATIVE PLASTICS IP B.V.

A composition for the manufacture of a porous, compressible article, the composition comprising a combination of: a plurality of reinforcing fibers; a plurality of polysulfone fibers; and a plurality of polymeric binder fibers; wherein the polymeric binder fibers have a melting point lower than the polysulfone fibers; methods for forming the porous, compressible article; and articles containing the porous, compressible article. An article comprising a thermoformed dual matrix composite is also disclosed, wherein the composite exhibits a time to peak release, as measured by FAR 25.853 (OSU test), a 2 minute total heat release, as measured by FAR 25.853 (OSU test), and an NBS optical smoke density of less than 200 at 4 minutes, determined in accordance with ASTM E-662 (FAR/JAR 25.853). 1. A composition for the manufacture of a porous , compressible article , the composition comprising a combination of:a plurality of reinforcing fibers;a plurality of polysulfone fibers; anda plurality of polymeric binder fibers;wherein the polymeric binder fibers have a melting point lower than the polysulfone fibers.2. The composition of claim 1 , further comprising an aqueous solvent.3. The composition of claim 1 , whereinthe average fiber length of the reinforcing fibers is from 5 to 75 millimeters and the average fiber diameter of the reinforcing fibers is from 5 to 125 micrometers;the average fiber length of the polysulfone fibers is from 5 to 75 millimeters, and the average fiber diameter of the polysulfone fibers is from 5 to 125 micrometers; andthe average fiber length of the polymeric binder fibers is from 2 millimeters to 25 millimeters, and the average fiber diameter of the polymeric binder fibers is from 5 to 50 micrometers.4. A method for forming a porous article claim 1 , the method comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'forming a layer comprising a suspension of the composition of in a liquid;'}at least partially removing the liquid from the ...

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03-10-2013 дата публикации

PIPES AND CONNECTORS MADE OF POLYBIPHENYL ETHER SULFONE POLYMERS FOR CONVEYING GASES

Номер: US20130255785A1
Принадлежит: BASF SE

The invention relates to the use of a thermoplastic molding composition which comprises at least one polybiphenyl ether sulfone polymer, to produce moldings for conveying gas. 114-. (canceled)15. A process to produce a self-supporting molding for conveying a gas which comprises utilizing the thermoplastic molding composition which comprises at least one polybiphenyl ether sulfone polymer.16. The process according to claim 15 , wherein the polybiphenyl ether sulfone polymer is produced through polycondensation comprising in step (a) the reaction of a component (a1) which comprises at least one aromatic dihydroxy compound with a component (a2) which comprises at least one aromatic sulfone compound having two halogen substituents claim 15 , wherein component (a1) comprises 4 claim 15 ,4′-dihydroxybiphenyl.17. The process according to claim 16 , wherein the polycondensation in step (a) is carried out in the presence of an organic solvent which comprises N-methylpyrrolidone.18. The process according to claim 16 , wherein the molar ratio (a1):(a2) of the components is from 1.005 to 1.1.19. The process according to claim 16 , wherein component (a1) comprises at least 50% by weight of 4 claim 16 ,4′-dihydroxybiphenyl.20. The process according to claim 16 , wherein component (a2) is 4 claim 16 ,4′-dihalo sulfone.21. The process according to claim 16 , wherein component (a2) is 4 claim 16 ,4′-dichlorodiphenyl sulfone or 4 claim 16 ,4′-difluorodiphenyl sulfone.22. The process according to claim 16 , wherein component (a1) is 4 claim 16 ,4′-dihydroxybiphenyl and component (a2) is 4 claim 16 ,4′-dichlorodiphenyl sulfone.23. The process according to claim 15 , wherein the molding composition further comprises at least one further polymer selected from the group consisting of polyether sulfone (PESU) claim 15 , polysulfone (PSU) claim 15 , polyetherimides claim 15 , polyphenylene sulfides claim 15 , polyether ether ketones claim 15 , polyimides claim 15 , and poly-p-phenylenes.24. ...

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03-10-2013 дата публикации

RESIN COMPOSITION, COMPOSITE CURED PRODUCT USING SAME, AND METHOD FOR PRODUCING THE COMPOSITE CURED PRODUCT

Номер: US20130261229A1
Принадлежит: Toray Industries, Inc.

A resin composition including 10 to 90% by mass of (A) a component to be polymerized containing a compound represented by Formula (1), and 90 to 10% by mass of (B) a thermosetting resin, the (A) and (B) each being capable of undergoing a reaction to increase molecular weight by itself when heated: 2. The resin composition according to claim 1 , wherein said compound represented by Formula (1) is one selected from the group consisting of a cyclic polyphenylene sulfide claim 1 , a cyclic polyphenylene ether ether ketone claim 1 , a cyclic polyphenylene ether ketone and a cyclic polyphenylene ether sulfone.3. The resin composition according to claim 1 , wherein said (B) is one selected from the group consisting of an epoxy resin claim 1 , a bismaleimide resin and a polyimide resin.4. The resin composition according to claim 1 , further comprising a zero-valent transition metal compound.5. The resin composition according to claim 4 , wherein said zero-valent transition metal compound comprises a metal belonging to Groups 8 to 11 and Periods 4 to 6 of the periodic table.6. The resin composition according to claim 1 , further comprising an alkali metal salt.7. The resin composition according to claim 1 , further comprising (C) a reinforcement fiber.8. The resin composition according to claim 7 , wherein said (C) reinforcement fiber is a carbon fiber.9. A method of producing a composite cured product comprising allowing the resin composition according to to react by heating to obtain a composite cured product.10. A method of producing a composite cured product comprising impregnating the resin composition according to into a reinforcement fiber and then allowing said resin composition to react by heating to obtain a composite cured product.12. The composite cured product according to claim 11 , further comprising (C) a reinforcement fiber.13. The resin composition according to claim 2 , wherein said (B) is one selected from the group consisting of an epoxy resin claim 2 , ...

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17-10-2013 дата публикации

Polyarylene Sulfide Composition Including a Functionalized Siloxane Polymer and a Non-Aromatic Impact Modifier

Номер: US20130269977A1
Автор: Rong LUO, Xinyu Zhao
Принадлежит: Ticona LLC

Polyarylene sulfide compositions are described as are methods of forming the polyarylene sulfide compositions. The polyarylene sulfide compositions are formed by melt processing polyarylene sulfide, a reactively functionalized siloxane polymer and a non-aromatic impact modifier. The non-aromatic impact modifier is, e.g., an ethylene-based copolymer or terpolymer or a silicone elastomer. The compositions exhibit good strength and heat resistance characteristics and can be utilized in forming a variety of products such as automotive components and electrical components.

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17-10-2013 дата публикации

Polyarylene Sulfide Composition Including a Silane Coupling Agent and a Silicone Elastomer

Номер: US20130273281A1
Автор: Luo Rong, Zhao Xinyu
Принадлежит:

Polyarylene sulfide compositions are described as are methods of forming the polyarylene sulfide compositions. The polyarylene sulfide compositions are formed by melt processing polyarylene sulfide, a silane coupling agent and a silicone elastomer. The silane coupling agent is, e.g., an amino silane coupling agent and the silicone elastomer can be a poly(dimethyl siloxane). The compositions exhibit good strength and heat resistance characteristics and can be utilized in forming a variety of products such as pipes and houses, automotive components and electrical components. 1. A polyarylene sulfide composition comprising:a polyarylene sulfide;a silane coupling agent; anda silicone elastomer, wherein the polyarylene sulfide composition exhibits a tensile modulus of greater than about 3000 MPa as measured according to ISO Test No. 527 and meets the V-0 flammability standard at a thickness of 0.2 millimeters.2. The polyarylene sulfide composition according to claim 1 , wherein the composition exhibits a tensile break strain of less than about 3% as measured according to ISO Test No claim 1 , 527 or exhibits an unnotched Izod impact strength of less than about 1.7 kJ/mas measured according to ISO Test No. 180/1 A.3. The polyarylene sulfide composition according to claim 1 , wherein the polyarylene sulfide is a polyphenylene sulfide or is a reactively functionalized polyarylene sulfide.4. The polyarylene sulfide composition according to claim 1 , wherein the silane coupling agent is an amino silane coupling agent.5. The polyarylene sulfide composition according to claim 4 , wherein the amino silane coupling agent is an amino propyl triethoxy silane.6. The polyarylene sulfide composition according to claim 1 , wherein the silicone elastomer is a poly(diorganosiloxane).7. The polyarylene sulfide composition according to claim 6 , wherein the poly(diorganosiloxane) is poly(dimethylsiloxane).8. The polyarylene sulfide composition according to claim 1 , wherein the silicone ...

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17-10-2013 дата публикации

Polyarylene Sulfide Components for Heavy Duty Trucks

Номер: US20130273286A1
Автор: Luo Rong, Zhao Xinyu
Принадлежит: Ticona LLC

Components for heavy duty trucks are described that exhibit high strength and flexibility. The components are formed from a polyarylene sulfide that exhibits high strength and flexibility characteristics. Methods for forming the components are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The heavy duty truck components can include tubular member such as pipes and hoses that can be utilized in exhaust systems, charge air systems, urea tanks, fuel systems, and so forth. 1. A heavy duty truck component comprising a polyarylene sulfide composition , the polyarylene sulfide composition of the heavy duty truck component including a polyarylene sulfide and a crosslinked impact modifier.2. The heavy duty truck component of claim 1 , wherein the polyarylene sulfide composition has one or more of the following characteristics:{'sup': '2', 'a notched Charpy impact strength of greater than about 3 kJ/mas measured according to ISO Test No. 179-1 at a temperature of 23° C.;'}{'sup': '2', 'a notched Charpy impact strength of greater than about 8 kJ/mas measured according to ISO Test No. 179-1 at a temperature of −30° C.;'}an elongation at yield of greater than about 4.5% as measured according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min;a tensile strength at break of greater than about 30 MPa as measured according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min;a tensile modulus of less than about 3000 MPa as measured according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min;exhibits a loss in Charpy notched impact strength as determined according to ISO Test no. 179-1 at 23° C. of less than about 17% following ...

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17-10-2013 дата публикации

Blow Molded Thermoplastic Composition

Номер: US20130273287A1
Принадлежит: Ticona LLC

Components formed of blow molded thermoplastic compositions are described. The blow molded thermoplastic compositions exhibit high strength and flexibility. Methods for forming the thermoplastic compositions are also described. Formation methods include dynamic vulcanization of a composition that includes an impact modifier dispersed throughout a polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers. 1. A component comprising a blow molded thermoplastic composition , the thermoplastic composition including a polyarylene sulfide and a crosslinked impact modifier.2. The component of claim 1 , wherein the blow molded thermoplastic composition has a notched Charpy impact strength of greater than about 3 kJ/mas determined according to ISO Test No. 197-1 at 23° C. and a tensile modulus of less than about 3000 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min.3. The component of claim 1 , wherein the component is an automotive component.4. The component of claim 3 , wherein the automotive component is a component of the fuel system claim 3 , an exterior structure or a support structure for an automobile claim 3 , or a component of an automotive exhaust system.5. The component of claim 4 , wherein the automotive component is a fuel filler neck claim 4 , or a fuel tank.6. The component of claim 1 , wherein the component is a single layer or a multi-layer tubular component.7. The component of claim 6 , wherein the single layer or multi-layer tubular component is a flow line claim 6 , a riser claim 6 , or an air duct.8. The component of ...

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17-10-2013 дата публикации

Polyarylene Sulfide for Oil and Gas Flowlines

Номер: US20130273288A1
Автор: Luo Rong, Zhao Xinyu
Принадлежит: Ticona LLC

Flowlines for use in oil and gas applications are described. The flowlines include a barrier layer that includes polyarylene sulfide composition that exhibits high strength and flexibility characteristics. Methods for forming the flowlines are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The flowlines can include production fluid flowlines, supporting fluid flowlines, bundled flowlines, etc. and can be utilized as risers, pipelines, jumpers, and the like. 1. A flowline for an oil and/or gas production application , the flowline comprising a polyarylene sulfide composition , the polyarylene sulfide composition of the flowline including a polyarylene sulfide and a crosslinked impact modifier.2. The flowline of claim 1 , the polyarylene sulfide composition has one or more of the following characteristics:an elongation at yield of greater than about 4.5% as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min;a tensile modulus of less than about 3000 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min;an elongation at yield of greater than about 7% as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min;a tensile modulus of less than about 2300 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min;a deflection temperature under load of greater than about 90° C. as measured according to ISO Test No. 75 at 1.8MPa;{'sup': '2', 'a notched Charpy impact strength of greater than about 3 kJ/mas measured according to ISO Test No. 179-1 at a temperature of 23° C.;'}{'sup': '2', 'a notched Charpy impact strength of greater than about ...

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17-10-2013 дата публикации

Dynamically Vulcanized Polyarylene Sulfide Composition

Номер: US20130273290A1
Принадлежит:

Polyarylene sulfide compositions are described that exhibit high strength and flexibility. Methods for forming the polyarylene sulfide compositions are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers. 1. A polyarylene sulfide composition including a polyarylene sulfide and a crosslinked impact modifier , wherein the polyarylene sulfide composition has a notched Charpy impact strength of greater than about 3 kJ/mas measured according to ISO Test No. 179-1 at a temperature of 23° C. and a notched Charpy impact strength of greater than about 8 kJ/mas measured according to ISO Test No. 179-1 at a temperature of −30° C.2. The polyarylene sulfide composition according to claim 1 , wherein the composition has at least one of the following characteristics:an elongation at yield of greater than about 4.5% as determined according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min;{'sup': '2', 'a notched Charpy impact strength of greater than about 30 kJ/mas measured according to ISO Test No. 179-1 at a temperature of 23° C.;'}{'sup': '2', 'a notched Charpy impact strength of greater than about 10 kJ/mas measured according to ISO Test No. 179-1 at a temperature of −30° C.;'}a ratio of the notched Charpy impact strength as determined according to ISO Test no. 179-1 at 23° C. to that at −30° C. greater than about 3.5;a tensile break stress of greater than about 30 MPa as measured ...

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24-10-2013 дата публикации

Dual-Cure Polymer Systems

Номер: US20130277890A1

The present invention includes compositions that are useful to prepare dual-cure shape memory polymer systems. The present invention further provides methods of generating a shape memory polymer, optical device, polymer pad with an imprint, or suture anchor system. 1. A method of generating a given polymer , comprising the steps of: wherein said first polymerizable composition undergoes polymerization when submitted to a first polymerization reaction condition,', 'wherein said second polymerizable composition undergoes polymerization when submitted to a second polymerization reaction condition, and', 'wherein said first and second polymerization reaction conditions are orthogonal to each other;, 'providing an initial composition comprising a first polymerizable composition and a second polymerizable composition,'}submitting said initial composition to said first polymerization reaction condition to promote polymerization of said first polymerizable composition, thereby forming an intermediate composition; and,submitting said intermediate composition to said second polymerization reaction condition to promote polymerization of said second polymerizable composition, thereby forming said given polymer.2. The method of claim 1 , wherein said given polymer is used to prepare at least one material selected from the group consisting of a shape memory polymer claim 1 , optical material claim 1 , impression material claim 1 , and combinations thereof.3. The method of claim 1 , wherein said initial composition comprises [ 'wherein the ratio of the thiol equivalent concentration of said at least one thiol monomer in said initial composition and the acrylate equivalent concentration of said at least one acrylate monomer in said initial composition ranges from about 0.05 to about 0.95; and,', '(a) at least one thiol monomer,'}, wherein the ratio of the nucleophile equivalent concentration of said at least one nucleophilic monomer in said initial composition and the isocyanate ...

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31-10-2013 дата публикации

POLYMER PARTICLE, AQUEOUS DISPERSION INCLUDING THE SAME, AND FLUORORESIN COATING COMPOSITION USING THE SAME

Номер: US20130289175A1
Автор: LIU YUQING
Принадлежит:

The present invention provides a polymer particle comprising a polymer and a filler contained therein, wherein the polymer is soluble in an organic solvent and is also water insoluble, and wherein the polymer particle contains from 5 to 500 parts by weight of filler per 100 parts by weight of polymer, and a mean particle size of 75 μm or less. The invention also provides an aqueous dispersion including this particle; an aqueous fluororesin coating composition that uses this aqueous dispersion; and a fluororesin laminate or layered coating having a layer obtained from this fluororesin coating composition. 1. A polymer particle comprising a polymer and a filler contained therein , wherein the polymer is soluble in an organic solvent and is also water insoluble , and wherein the polymer particle contains from 5 to 500 parts by weight of filler per 100 parts by weight of polymer , and a mean particle size of 75 μm or less.2. The polymer particle according to claim 1 , wherein the polymer is at least one selected from polyimides claim 1 , polyamide imides claim 1 , polyamides claim 1 , polyesters claim 1 , polyethylene terephthalate claim 1 , polyphenylene sulfide claim 1 , polysulfones claim 1 , polyetherimides claim 1 , and polyethersulfones.3. The polymer particle according to or claim 1 , wherein the filler is an organic particle or inorganic particle.4. The polymer particle according to claim 3 , wherein the inorganic particle is at least one selected from silicon carbide claim 3 , silicon oxide claim 3 , aluminum oxide claim 3 , zinc oxide claim 3 , tin oxide claim 3 , titanium dioxide claim 3 , barium sulfate claim 3 , and carbon black.5. The polymer particle according to claim 3 , wherein the organic particle is at least one selected from polyphenylene sulfide claim 3 , polyetheretherketone claim 3 , and aramid.6. A polymer particle aqueous dispersion comprising a polymer particle according to and an organic solvent in which the polymer of said polymer particle ...

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07-11-2013 дата публикации

MOLDING MATERIAL, PREPREG, FIBER-REINFORCED COMPOSITE MATERIAL, FIBER-REINFORCED COMPOSITE MATERIAL LAMINATE, AND PROCESS FOR PRODUCTION OF FIBER-REINFORCED MOLDING BASE MATERIAL

Номер: US20130295806A1
Принадлежит:

A molding material is provided including a composite having 1 to 50 wt % of (A) a bundle of continuous reinforcing fibers and 0.1 to 40 wt % of (B) a polyarylene sulfide prepolymer or (B′) a polyarylene sulfide; and 10 to 98.9 wt % of (C) a thermoplastic resin adhered to the composite; wherein the composite further has (D) a zero-valent transition metal compound or (E) a low-valent iron compound in an amount of 0.001 to 20 mol % based on the amount of sulfur atoms contained in the component (B) or (B′). A prepreg and a method of producing a fiber-reinforced molding base material is also provided. By using the molding material according to the present invention which exhibits excellent economic efficiency and productivity, a molded article having excellent mechanical characteristics can be easily produced. 1. A molding material comprising:a composite comprising 1 to 50 wt % of (A) a bundle of continuous reinforcing fibers and 0.1 to 40 wt % of (B) a polyarylene sulfide prepolymer or (B′) a polyarylene sulfide; and10 to 98.9 wt % of (C) a thermoplastic resin adhered to said composite;wherein said composite further comprises (D) a zero-valent transition metal compound in an amount of 0.001 to 20 mol % based on the amount of sulfur atoms contained in said component (B) or (B′).2. The molding material according to claim 1 , wherein said component (D) is a compound which comprises a metal belonging to one of Groups 8 to 11 and one of Periods 4 to 6 of periodic table.3. The molding material according to claim 1 , wherein said component (D) is a compound containing palladium and/or nickel.4. A molding material comprising:a composite comprising 1 to 50 wt % of (A) a bundle of continuous reinforcing fibers and 0.1 to 40 wt % of (B) a polyarylene sulfide prepolymer or (B′) a polyarylene sulfide; and10 to 98.9 wt % of (C) a thermoplastic resin adhered to said composite;wherein said composite further comprises (E) a low-valent iron compound in an amount of 0.001 to 20 mol % ...

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07-11-2013 дата публикации

FIRE RESISTANT, HIGH FLOW POLY(ARYL ETHER SULFONE) COMPOSITION

Номер: US20130296474A1
Автор: WEINBERG Shari A.
Принадлежит:

Polymer composition (C) containing (i) a poly(aryl ether sulfone) material (M12) composed of a poly(biphenyl ether sulfone) (P1) and, optionally in addition, a poly(aryl ether sulfone) (P2) containing recurring units with arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and (ii) a per(halo)fluoropolymer material (M34), composed of a per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are derived from a per(halo)fluoromonomer other than tetrafluoroethylene, and a polytetrafluoroethylene (P4). 1. (canceled)2. A polymer composition (C) comprising: from 55 to 100 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(biphenyl ether sulfone) (P1), and', {'sub': '2', 'from 45 to 0 wt. %, based on the total weight of the poly(aryl ether sulfone) material (M12), of at least one poly(aryl ether sulfone) (P2) of which more than 50 wt. % of the recurring units are recurring units (R2) containing at least one ether group (—O—), at least one sulfone group (—SO—) and at least two arylene groups linked to each other via a secondary, ternary or quaternary carbon atom, and'}], '50 wt. % or more and below 98 wt. %, based on the total weight of the polymer composition (C), of a poly(aryl ether sulfone) material (M12) which comprises'} from 5 to 95 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one per(halo)fluoropolymer (P3) of which at least 2.0 wt. % of the recurring units are recurring units (R3) derived from at least one per(halo)fluoromonomer other than tetrafluoroethylene, and', 'from 95 to 5 wt. %, based on the total weight of the per(halo)fluoropolymer material (M34), of at least one polytetrafluoroethylene (P4)., '1-25 wt. %, based on the total weight of the polymer composition (C), of a per(halo)fluoropolymer material (M34) which comprises'}3. The polymer composition according to claim 2 , wherein the weight of the poly( ...

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05-12-2013 дата публикации

Fiber Reinforced Shaped Articles and Process for Making Same

Номер: US20130323447A1
Принадлежит: Ticona LLC

Blow molded articles are made from a polymeric composition containing a mixture of polyphenylene sulfide resins. For instance, the polymeric composition may contain a linear polyphenylene sulfide resin combined with a branched polyphenylene sulfide resin. The composition can further contain a reinforcing agent, such as glass fibers, a polytetrafluoroethylene polymer, a polyphenylene oxide polymer, a silane coupling agent, and/or an impact modifier. Compositions made according to the present disclosure can have relatively high near zero shear rate melt strengths while also having high shear rate melt viscosities and high engineering stresses at a high percent elongations, making the compositions amenable to extrusion and molding processes. Compositions made according to the present disclosure are particularly well suited to molding articles with a complex shape. When producing blow molded articles, for instance, the composition provides better control over wall thickness while having improved interior surface smoothness at higher throughput and extrusion rates. 1. A shaped polymer article comprising:a blow molded hollow member including an interior surface and an exterior surface and having a wall thickness between the interior surface and the exterior surface, the hollow member being made from a fiber reinforced polymeric composition comprising on a weight percent basis:a) a linear polyphenylene sulfide having a melt viscosity of from about 20 Pa·s to about 500 Pa·s;b) a branched polyphenylene sulfide, the weight ratio of the branched polyphenylene sulfide to the linear polyphenylene sulfide being from about 1:5 to about 1:60, the linear polyphenylene sulfide and the branched polyphenylene sulfide being present in the composition in an amount of at least about 35% by weight;c) reinforcing fibers present in the composition in an amount from about 10% to about 50% by weight; andd) a compatibilizer;{'sup': '−1', 'wherein the composition has a melt viscosity of at least ...

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19-12-2013 дата публикации

Method for producing polymer fine particle

Номер: US20130337263A1
Принадлежит: TORAY INDUSTRIES INC

A fine polymer particle production method includes producing an emulsion in a liquid prepared by dissolving and mixing a polymer A and a polymer B in organic solvents in which a solution phase composed primarily of the polymer A and a solution phase composed primarily of the polymer B are formed as separate phases, and bringing it into contact with a poor solvent for the polymer A to precipitate the polymer A. This method serves for easy synthesis of fine polymer particles with a narrow particle size distribution and the method can be effectively applied to production of highly heat-resistant polymers that have been difficult to produce with the conventional methods.

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19-12-2013 дата публикации

Performance Enhancing Additives For Fiber Formation And Polysulfone Fibers

Номер: US20130338297A1
Принадлежит: Individual

The present invention relates to the use of additives in processes to form polymeric fibers. These fibers can be formed into membranes with improved middle and/or higher molecular weight solute removal.

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26-12-2013 дата публикации

Benzoxazine Resins

Номер: US20130345352A1
Принадлежит: CYTEC TECHNOLOGY CORP

A curable polymer composition containing: (A) a thermoset benzoxazine resin precursor component; (B) optionally, an arylsulphone-containing benzoxazine component, and (C) a polyarylsulphone thermoplastic toughening agent, wherein in the absence of component (B), component (C) contains one or more benzoxazine pendant-and/or end-groups.

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16-01-2014 дата публикации

Polyetherimide resins with very low levels of residual contamination

Номер: US20140016450A1
Принадлежит: SABIC INNOVATIVE PLASTICS IP BV

Compositions and methods for producing compositions comprising a monoamine-endcapped polyimide component. Based on a gas chromatography mass spectroscopy analysis of a surface rinse of the composition performed at room temperature, the composition can have at least one surface with less than or equal to 5 ppb releasable phosphorous residuals, and less than or equal to 5 ppb releasable volatile organic compound residuals. The composition can also comprise less than or equal to 10 ppb combined releasable residuals. Because of the very low levels of residual contamination, the compositions can be used to produce a variety of articles including a disk drive.

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06-02-2014 дата публикации

Polymer blend compositions

Номер: US20140039099A1
Принадлежит: SABIC INNOVATIVE PLASTICS IP BV

Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.

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06-02-2014 дата публикации

BLENDS OF POLYPHENYLENE ETHER SULFONE AND SILICONE POLYESTER CARBONATE

Номер: US20140039103A1
Принадлежит:

Disclosed herein is a composition comprising a polyphenylene ether sulfone and a resorcinol based silicone aryl polyester carbonate copolymer wherein greater than or equal to 50 mol % of copolymer repeating units are ester units derived from resorcinol, based on the total molar amount of all repeating units in the polymer and wherein the blend has less than 1 weight percent polycarbonate, based on the total weight of the composition, has FAR 25.853 peak heat release of less than 60 KW/mand time to peak heat release of greater than or equal to 120 seconds. 1. An article comprising a thermoplastic composition , wherein the article is a rail car interior article or an airplane interior article and the thermoplastic composition comprises 70 to 99 wt % of a polyphenylene ether sulfone and 1 to 30 wt % of a resorcinol based silicone aryl polyester carbonate copolymer , based on the total weight of the composition , wherein greater than or equal to 50 mol % of resorcinol based silicone aryl polyester carbonate copolymer repeating units are ester units derived from resorcinol , based on the total molar amount of all repeating units in the polymer and wherein the blend comprises less than 1 weight percent polycarbonate , based on the total weight of the composition , and the composition has a FAR 25.853 peak heat release of less than 50 KW/m , a time to peak heat release of greater than or equal to 120 seconds , and a melt volume viscosity rate (MVR) at 300° C. using a six minute equilibration time , with 6.7 Kg , as measured by ASTM D1238 , of greater than or equal to 2.0 cc/10 minutes.2. The article of claim 1 , wherein the composition has a multiaxial impact strength claim 1 , as measured by ASTM D3763 claim 1 , of greater than or equal to 70 Joules.3. The article of claim 1 , wherein greater than or equal to 80 mol % of copolymer repeating units are ester units derived from resorcinol claim 1 , based on the total molar amount of all repeating units in the polymer and ...

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10-04-2014 дата публикации

Polyphenylene sulfide resin composition and molding comprising same (as amended)

Номер: US20140100306A1
Принадлежит: TORAY INDUSTRIES INC

The invention provides a polyphenylene sulfide resin composition including: 1 to 100 parts by weight of an olefin elastomer (B); and 0.01 to 10 parts by weight of a carboxylic acid amide wax mixture (C), relative to 100 parts by weight of a polyphenylene sulfide resin (A), wherein the carboxylic acid amide wax mixture (C) is obtained by adding 0.01 to 5 parts by weight of an antioxidant to 100 parts by weight of a carboxylic acid amide wax produced by reaction of a higher aliphatic monocarboxylic acid, a polybasic acid and a diamine.

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03-01-2019 дата публикации

DEVICE FOR A FISHING REEL AND DRAG DEVICE FOR A FISHING REEL USING THE SAME

Номер: US20190000057A1
Принадлежит:

A device for a fishing reel comprising a resin composition includes a polyarylene sulfide resin composition (component A), a glass fibers (component B) contains 10 to 300 parts by weight of the component B based on 100 parts by weight of the component A, an aramid fibers (component C) contains 1 to 100 parts by weight of the component C based on 100 parts by weight of the component A, and a fluoric resin (component D) contains 5 to 100 parts by weight of the component D based on 100 parts by weight of the component A. 1. A device for a fishing reel comprising:a resin composition includinga polyarylene sulfide resin composition (component A),a glass fibers (component B) containing 10 to 300 parts by weight of the component B based on 100 parts by weight of the component A,an aramid fibers (component C) containing 1 to 100 parts by weight of the component C based on 100 parts by weight of the component A, anda fluoric resin (component D) containing 5 to 100 parts by weight of the component D based on 100 parts by weight of the component A.2. The device for the fishing reel according to claim 1 , whereinthe fiber diameter of the component B is 3 to 12 μm.3. The device for the fishing reel according to claim 1 , whereinthe fiber length of the component C is 0.7 to 1.5 mm.4. The device for the fishing reel according to claim 2 , whereinthe fiber length of the component C is 0.7 to 1.5 mm.5. A drag device for a fishing reel for regulating relative rotation between a drive gear configured to interlock with a spool and a drive shaft claim 2 , the drag device comprising:a sound-generating mechanism comprisinga sound generating device configured to be integrally rotated with one of the drive gear or the drive shaft and having a sound-generating portion, anda sound unit that configured to integrally rotated with an other of the drive gear and the drive shaft and configured to interfere with the sound-generating portion by the relative rotation between the drive gear and the ...

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02-01-2020 дата публикации

BLOCK COPOLYMERS AND USES THEREOF

Номер: US20200000936A1
Принадлежит:

An encoding/decoding apparatus and method using a low-density parity-check code (LDPC code) is disclosed. Basic column group information, serving as a set of information regarding positions of rows with weight 1, is extracted from a reference column in each column group of a predetermined parity-check matrix. Column group information transforms the positions of rows with weight 1 into positions whose lengths are within a required parity length. A parity-check matrix is generated according to the generated column group information. Data is enclosed or decoded based on the generated parity-check matrix. 146-. (canceled)47. A supramolecular structure comprising a (i) a block copolymer comprising a positively charged block , and (ii) a nucleic acid , wherein said supramolecular structure has a maximal diameter of 60 nm or less.48. The supramolecular structure of claim 47 , wherein said supramolecular structure is a molecule or a vesicle.49. The supramolecular structure of claim 47 , wherein said block copolymer further comprises a hydrophilic block or a hydrophobic block.50. The supramolecular structure of claim 49 , wherein said block copolymer further comprises a hydrophilic block and a hydrophobic block.51. The supramolecular structure of claim 47 , wherein said maximal diameter is 40 nm or less.52. The supramolecular structure of claim 47 , wherein said block copolymer comprises PEG-PPS-PEI.53. The supramolecular structure of claim 47 , wherein said nucleic acid comprises a single-stranded oligonucleotide claim 47 , a short interfering RNA claim 47 , an aptamer claim 47 , or plasmid DNA.54. A method of transfecting a cell with a nucleic acid comprising contacting said cell with the supramolecular structure of .55. A block copolymer comprising PEG-PPS-PEI.56. The block copolymer of claim 55 , wherein the PPS block and the PEI block are attached via a bond that is labile in an endosome.57. The block copolymer of claim 56 , wherein said bond comprises a disulfide bond ...

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07-01-2021 дата публикации

POLYTHIOETHER PREPOLYMERS AND THEIR USE IN CURABLE COMPOSITIONS IN PARTICULAR IN MASTICS

Номер: US20210002429A1
Принадлежит: SOCOMORE

A polythioether prepolymer including functional groups capable of being obtained by the reaction: of at least one compound T having a number f of thiol functional group number selected from 2, 3, 4 and 6, with at least one compound E having a number g of epoxy functional groups number selected from 2 and 3. Also, a method of preparation for this prepolymer, a composition including this prepolymer and an oligomer as well as its use as a mastic and a polythioether polymer obtained from this polythioether prepolymer with an oligomer. 1. A polythioether prepolymer comprising thiol functional groups , wherein the polythioether polymer is capable of being obtained by the reaction: of at least one compound T having a number f of thiol functional groups selected from 2 , 3 , 4 and 6 , with at least one compound E having a number g of epoxy functional groups selected from 2 and 3.2. The polythioether prepolymer according to claim 1 , wherein during the reaction of at least one compound T and at least one compound E claim 1 , the compounds T comprising thiol groups and the compounds E comprising the epoxy groups react according to a ratio number of thiol groups:number of epoxy groups from 3:1 to 4:1.3. The polythioether prepolymer according to wherein the polythioether polymer comprises pendant hydroxyl functional groups.4. The polythioether prepolymer according to claim 1 , wherein the polythioether prepolymer is capable of being obtained from at least one compound T comprising at least two groups selected from the group consisting of:{'sub': 2', 'nb, 'b) —(CH)—SH;'}{'sub': 2', 'nc', '2', 'mc, 'c) —(CH)—O—(CH)—SH;'}{'sub': 2', 'nd', '2', 'md, 'd) —(CH)—O—(CO)—(CH)—SH;'}{'sub': 2', 'ne', '2', 'me, 'e) —(CH)—(CO)—O—(CH)—SH;'}{'sub': 2', 'nf', '2', '2', 'lf', '2', 'mf, 'f) —(CH)—O—(CHCHO)—(CH)—SH;'}{'sub': 2', 'ng', '2', '2', 'lg', '2', 'mg, 'g) —(CH)—(CO)—O—(CHCHO)—(CH)—SH;'}{'sub': 2', 'nh', '2', '2', 'lh', '2', 'mh, 'h) —(CH)—O—(CO)—(CHCHO)—(CH)—SH;'}{'sub': 2', 'ni', '2', ' ...

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03-01-2019 дата публикации

POLYARYLENE SULFIDE RESIN COMPOSITION AND INSERT MOLDED ARTICLE

Номер: US20190002693A1
Принадлежит: Polyplastics Co., Ltd.

A polyarylene sulfide resin composition characterized by comprising a polyarylene sulfide resin, and an olefinic copolymer comprising an α-olefin-derived structural unit and an α,β-unsaturated acid glycidyl ester-derived structural unit, wherein the olefinic copolymer content is at least 1.0 parts by mass and less than 5.0 parts by mass with respect to 100 parts by mass of the polyarylene sulfide resin, a melt viscosity of the polyarylene sulfide resin measured at 310° C. and a shear rate of 1216 secis at least 70 Pa·s and at most 300 Pa·s, and a flow length for a width of 20 mm and a thickness of 1 mm, at a cylinder temperature of 320° C., an injection pressure of 100 MPa and a mold temperature of 150° C., is at least 80 mm and at most 200 mm. 1. A polyarylene sulfide resin composition comprising a polyarylene sulfide resin , and an olefinic copolymer comprising an α-olefin-derived structural unit and an α ,β-unsaturated acid glycidyl ester-derived structural unit , whereinthe olefinic copolymer content is at least 1.0 parts by mass and less than 5.0 parts by mass with respect to 100 parts by mass of the polyarylene sulfide resin;{'sup': '−1', 'a melt viscosity of the polyarylene sulfide resin, measured at 310° C. and a shear rate of 1216 sec, is at least 70 Pa·s and at most 250 Pa·s; and'}a flow length for a width of 20 mm and a thickness of 1 mm, at a cylinder temperature of 320° C., an injection pressure of 100 MPa and a mold temperature of 150° C., is at least 80 mm and at most 200 mm.2. The polyarylene sulfide resin composition according to claim 1 , wherein the olefinic copolymer further comprises a (meth)acrylic acid ester-derived structural unit.3. The polyarylene sulfide resin composition according to claim 1 , comprising an inorganic filler.4. The polyarylene sulfide resin composition according to claim 3 , wherein the inorganic filler is fibrous.5. The polyarylene sulfide resin composition according to claim 3 , wherein the inorganic filler content is at ...

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13-01-2022 дата публикации

Polyphenylene sulfide resin composition and molded article

Номер: US20220010073A1
Принадлежит: TORAY INDUSTRIES INC

A polyphenylene sulfide resin composition includes a blend of the following: 100 parts by weight of a polyphenylene sulfide resin (A); 100 to 250 parts by weight of a modified cross-section glass fiber (B); and 25 to 150 parts by weight of a non-fibrous inorganic filler (C) satisfying the following (C-a) and (C-b): (C-a) having a Mohs hardness of more than 2 and less than 4, and (C-b) having a melting point or softening point of 380° C. or more; wherein the ratio X/Y of the mass X of the modified cross-section glass fiber (B) to the mass Y of the non-fibrous inorganic filler (C) is more than 1 and less than 7.

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07-01-2021 дата публикации

CELLULOSE-TEMPLATED CONDUCTIVE POLYMER CONTAINING BINDER FOR ACTIVE MATERIAL COMPOSITIONS AND LITHIUM ION BATTERIES PREPARED THEREFROM

Номер: US20210005893A1
Принадлежит:

The present invention relates to an electrode active-material composition including, as a binder material for an electrode active material, a conductive polymer synthesized using a cellulose-based compound and/or a weakly acidic compound alone or in combination as a template, and a lithium-ion battery manufactured using the same, and particularly to PEDOT:CMC synthesized as a preferred active-material composition, and a lithium-ion battery manufactured using the same as a binder. The technique of the present invention is capable of improving the cycle characteristics, that is, the lifetime, of the lithium-ion battery including an anode active material made of a graphite component and/or a silicon component alone or in combination, along with various cathode active materials including a nickel-cobalt-manganese (NCM)-based active material, a nickel-cobalt-aluminum (NCA)-based active material, a lithium-cobalt oxide (LCO) active material, and other lithium containing materials. 1. A lithium-ion battery ,wherein an active-material composition of either or both of an anode and a cathode for the lithium-ion battery comprises:a cellulose-based conductive polymer binder synthesized using a cellulose-based compound as a template, ora mixed conductive polymer binder obtained by mixing the cellulose-based conductive polymer binder with at least one conductive polymer synthesized using a different type of compound as a template.2. The lithium-ion battery of claim 1 , wherein the cellulose-based compound is configured such that a portion of an —R component of an —OR group of a cellulose molecule is substituted with a component that enables dissolution in water claim 1 , in which a degree of substitution is 0.5 or more; andthe cellulose-based compound is configured such that an —R component of an —OR group of a cellulose molecule is alkylcarboxylic acid or a salt compound thereof or a hydroxyl group.3. The lithium-ion battery of claim 2 , wherein a length of an alkyl group of the ...

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03-01-2019 дата публикации

METHOD FOR PRODUCING PLATED COMPONENT, PLATED COMPONENT, CATALYTIC ACTIVITY INHIBITOR AND COMPOSITE MATERIAL FOR ELECTROLESS PLATING

Номер: US20190008051A1
Принадлежит: Maxell Holdings, Ltd.

A method for producing a plated part, includes: forming, on a surface of a base member, a catalyst activity inhibiting layer containing a polymer which has at least one of an amide group and an amino group; irradiating with light or heating a part of the surface of the base member on which the catalyst activity inhibiting layer is formed; applying an electroless plating catalyst to the surface of the base member heated or irradiated with the light; and bringing an electroless plating solution into contact with the surface of the base member to which the electroless plating catalyst is applied, to form an electroless plating film at a light-irradiated portion or a heated portion of the surface. 1. A method for producing a plated part , comprising:forming, on a surface of a base member, a catalyst activity inhibiting layer containing a polymer which has at least one of an amide group and an amino group;irradiating with light or heating a part of the surface of the base member on which the catalyst activity inhibiting layer is formed;applying an electroless plating catalyst to the surface of the base member heated or irradiated with the light; andbringing an electroless plating solution into contact with the surface of the base member to which the electroless plating catalyst is applied, to form an electroless plating film at a light-irradiated portion or a heated portion of the surface.2. The method for producing the plated part according to claim 1 , further comprising washing the surface of the base member after the part of the surface of the base member is heated or irradiated with the light and before the electroless plating solution is brought into contact with the surface of the base member.3. The method for producing the plated part according to claim 1 , wherein the polymer is a branched polymer having a side chain.4. The method for producing the plated part according to claim 3 , wherein the branched polymer is a dendritic polymer.5. The method for producing ...

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14-01-2016 дата публикации

Photochemical preparation of hydroxyl-terminated polyisobutylenes and related methods and uses

Номер: US20160009850A1
Принадлежит: UNIVERSITY OF AKRON

The present invention relates to novel hydroxyl-terminated polyisobutylenes and methods of making and using them. The hydroxyl-terminated polyisobutylenes contain a sulfur unit, —S—, within each terminal end group. The well-defined, sulfur containing, primary hydroxyl-terminated polyisobutylenes of the present invention can be simply, rapidly, and essentially quantitatively obtained by subjecting the unsaturated telechelic PIBs and mercapto alcohols to UV light-activated thiol-ene reactions. The resultant sulfur containing, primary hydroxyl-terminated polyisobutylenes can then be used in the production of polyurethanes and like materials.

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10-01-2019 дата публикации

Hydraulic fluid and fuel resistant sealants

Номер: US20190010370A1
Автор: Renhe Lin, Weibin Cui
Принадлежит: PRC Desoto International Inc

Compositions that are resistant to hydraulic fluid and aviation fuel contain sulfur-containing prepolymers and solvent-resistant organic fillers. The compositions are useful in aerospace sealant applications.

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09-01-2020 дата публикации

POLYARYLENE ETHER SULFONE COMPRISING NAPHTHALIC ACID ANHYDRIDE ENDGROUPS

Номер: US20200010680A1
Принадлежит: BASF SE

A polyarylene ether sulfone comprising endgroups of formula (I), a process for its manufacture, a molding composition comprising the polyarylene ether sulfone, use of the molding composition and fiber, film or shaped article produced using the molding composition. 2: The polyarylene ether sulfone of claim 1 , comprising at least 15% of the endgroups.3: The polyarylene ether sulfone of claim 1 , comprising from 25% to 90% of the endgroups.8. (canceled)9: A molding composition comprising the polyarylene ether sulfone of .10: The molding composition of comprising(A) from 5 to 95% by weight of the polyarylene ether sulfone comprising endgroups of formula I,(B) from 5 to 95% by weight of a polyamide, andoptionally a further component,wherein total proportions of all components by weight is 100%, based on a thermoplastic molding composition.11: The molding composition of comprising(A) from 30 to 75% by weight of the polyarylene ether sulfone, and(B) from 25 to 70% by weight of the polyamide,12: The molding composition of claim 9 , comprising(B) polyamide PA 9T, PA 9T-co-8.1T, PA 6T6I, PA 6T66, PA 66T or a mixture thereof.13: The molding composition of claim 9 , further comprising(C) from 10 to 70% by weight of a polyarylene ether sulfone having no endgroups of formula I.14: The molding composition of claim 9 , further comprising(D) from 10 to 62.5% by weight of a fibrous or particulate filler.15. (canceled)16: A fiber claim 9 , film or shaped article comprising the molding composition of . The present invention relates to polyarylene ether sulfones having anhydride endgroups.Polyarylene ethers are classified as high-performance thermoplastics. Polyarylene ethers may have—depending on how they are produced—for instance hydroxy, halogen, amino, epoxy or anhydride endgroups. EP 840 758 A discloses polyarylene ethers with phthalic acid anhydride endgroups. These are obtained by reacting a hydroxy endgroup containing polyarylene ether with halogen substituted phthalic acid ...

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03-02-2022 дата публикации

MULTI-COMPONENT SYSTEMS FOR PREPARING FOAMED PRODUCTS

Номер: US20220033606A1
Принадлежит:

Foamed products are produced using multi-component systems which are advantageously free of isocyanate. The components of the systems are combined, with the resulting mixture then undergoing curing and foaming to provide a foamed product, wherein the characteristics of the foamed product may be varied by selecting particular reactants to be present in the multi-component system. The systems employ at least one (meth)acrylate compound having two or more (meth)acrylate functional groups per molecule, at least one thiol compound having two or more thiol functional groups per molecule, at least one free radical initiator, at least one blowing agent, at least one surfactant, and optionally at least one promoter for the free radical initiator. 1. A multi-component system for preparing a foamed product , comprising:a) a first component comprised of at least one (meth)acrylate compound having two or more (meth)acrylate functional groups per molecule; andb) a second component comprised of at least one thiol compound having two or more thiol functional groups per molecule;wherein at least one free radical initiator is present in at least one of the first component or the second component, at least one surfactant is present in at least one of the first component or the second component, and at least one blowing agent is present in at least one of the first component or the second component;wherein in the event the multi-component system has a molar ratio of thiol functional groups to (meth)acrylate functional groups of 0.5:1 or greater and the at least one free radical initiator includes at least one organic peroxide, the multi-component system additionally comprises at least one promoter for the at least one organic peroxide, wherein the at least one free radical initiator and the at least one promoter for the at least one free radical initiator are present in different components.2. The multi-component system of claim 1 , wherein the multi-component system has a molar ratio ...

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03-02-2022 дата публикации

EPOXY RESIN COMPOSITIONS, PREPREG, AND FIBER-REINFORCED COMPOSITE MATERIALS

Номер: US20220033640A1
Принадлежит: Toray Industries, Inc.

An epoxy resin composition is provided which includes a poly-naphthalene-based epoxy resin having two or more epoxy groups per molecule combined with a non-linear multi-phenyl epoxy resin and an additional epoxy resin having an epoxy functionality of 3 or more, as well as a prepreg, and a fiber-reinforced composite material prepared using the epoxy resin composition. More specifically, an epoxy resin composition is provided which contains a combination of particular types of epoxy resins and curatives that, when cured, provides high flexural modulus and that is suitable for preparing a fiber-reinforced composite material capable of withstanding extreme use environments such as low-temperature environments and high-temperature moisture-absorbing environments. In addition, epoxy resin systems are provided which are capable of achieving a high Tg along with good thermal stability for long periods of time at elevated temperatures (e.g., 180° C. or more) when cured at 210° C. for 2 hours. 1. An epoxy resin composition for a fiber-reinforced composite material comprising component (A) , component (B) , component (C) , and component (D) , wherein the epoxy resin composition when cured has a weight loss of less than 1.0% when thermally soaked at 180° C. for 1000 hours , and wherein:component (A) comprises at least one poly-naphthalene-based epoxy resin;component (B) comprises at least one non-linear multi-phenyl epoxy resin in a total amount of from 10 to 35 PHR per 100 PHR of total epoxy resin;component (C) comprises at least one epoxy resin having an epoxy functionality of at least three which is neither a poly-naphthalene-based epoxy resin nor a non-linear multi-phenyl epoxy resin; andcomponent (D) comprises at least one amine curing agent.3. The epoxy resin composition according to claim 1 , wherein component (B) comprises at least one non-linear multi-phenyl epoxy resin having a structure corresponding to Formula (II):{'br': None, 'sup': 1', '2, 'X—C(Y)(Z)—X\u2003\ ...

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19-01-2017 дата публикации

ELECTROSTATIC DISSIPATIVE POLYESTER TPU AND COMPOSITIONS THEREOF

Номер: US20170015815A1
Принадлежит:

The present invention relates to an electrostatic dissipative thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender. The polyester polyol intermediate, may be derived from at least one dialkylene glycol and at least one dicarboxylic acid, or an ester or anhydride thereof. The invention further provides for methods of making said thermoplastic polyurethane composition, polymer blends containing said thermoplastic and polymer articles made from said thermoplastic. 131-. (canceled)32. An electrostatic dissipative thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender; and wherein the composition further comprises tri-n-butylmethylammonium bis-(trifluoroethanesulfonyl)imide.331. The composition of claim wherein (a) , the polyester polyol component , is substantially free of polyether polyols.34. The composition of further comprising at least one base polymer.35. The composition of wherein the base polymer comprises: a polyolefin; a styrenic; a thermoplastic polyurethane claim 34 , a polyamide; an acrylic polymer; a polyvinylchloride claim 34 , a chlorinated polyvinylchloride; a polyoxymethylene; a polyester; a polycarbonate; a polyphenylene oxide; polyphenylene sulfide; or combinations thereof.36. A shaped polymeric article comprising the electrostatic dissipative thermoplastic polyurethane composition of .37. The polymeric article of claim 36 , wherein the article comprises: packaging materials for ESD sensitive semiconductor and electronic parts; durable or consumable parts for clean room equipment and applications; construction materials for clean rooms and datacenters; fibers; laminated sheets; conveyor belts; pharmaceutical products;medical devices; electronic components; separators for use in the construction of lithium-ion ...

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21-01-2016 дата публикации

PROCESS AND COMPOSITION FOR WELL DISPERSED, HIGHLY LOADED COLOR MASTERBATCH

Номер: US20160017144A1
Принадлежит:

A highly loaded and well-dispersed masterbatch composition and process for making thereof from a split stream process. The masterbatch composition includes a colorant, a thermoplastic carrier, a metallocene polymer processing aid, and optionally an additive. The split stream may be formed of a primary feed and a secondary feed. The primary and second feeds are combined by at least one of the following: supplying the secondary feed in either the same feed port as the primary feed, in a stream located upstream the primary feed, in a stream located downstream the primary feed, or a combination thereof.

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21-01-2016 дата публикации

POLY (ARYLENE ETHER) FLAME RETARDANT RESIN COMPOSITION AND NON-CROSSLINKED FLAME RETARDANT CABLE

Номер: US20160017146A1
Принадлежит:

Disclosed are a flame retardant poly(arylene ether) resin composition and a flame retardant non-crosslinked cable. According to the present invention, provided are a flame retardant poly(arylene ether) resin composition to provide flexibility, flame retardancy, productivity, extrusion processability, etc. while maintaining heat resistance, and a flame retardant non-crosslinked cable manufactured using the composition.

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21-01-2016 дата публикации

Liquid-crystal film

Номер: US20160017228A1
Принадлежит: National Taiwan University NTU

A liquid-crystal film includes a liquid crystal mixture with the gel state. The liquid crystal mixture is formed of at least one π-conjugated polymer gelator and a liquid-crystal unit. The concentration of the at least one π-conjugated polymer gelator is 0.05-5 wt %. The concentration of the liquid-crystal unit is 95-99.95 wt %. The at least one π-conjugated polymer gelator is aligned through the liquid-crystal unit and combined together to form a plurality of fibers. The fibers include at least 60% arranged regularly in direction and some of the fibers are linked with one another to form a network structure.

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18-01-2018 дата публикации

Preparation of silica reinforced rubber containing styrene/butadiene elastomer, rubber composition and tire with component

Номер: US20180016422A1
Принадлежит: Goodyear Tire and Rubber Co

The invention relates to preparation of a precipitated silica reinforced rubber composition which contains styrene/butadiene elastomer modified with a combination of bis(3-triethoxysilylpropyl) polysulfide silica coupler and mercaptoorganoalkoxysilane, a rubber composition thereof and a tire with a component of such rubber composition.

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15-01-2015 дата публикации

Multifunctional sulfur-containing polymers, compositions thereof and methods of use

Номер: US20150018550A1
Принадлежит: PRC Desoto International Inc

Disclosed are multifunctional sulfur-containing polymers that are the reaction products of a sulfur-containing diol, a polyol containing at least three hydroxyl groups per polyol molecule, and an aldehyde, a ketone, or a combination thereof. Sealant compositions comprising the multifunctional sulfur-containing polymers are also disclosed.

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17-01-2019 дата публикации

Method For Providing Surface Modifying Composition With Improved Byproduct Removal

Номер: US20190016845A1
Принадлежит: Fresenius Medical Care Holdings, Inc.

A method forming a surface modifying composition with reduced need for organic solvent and evaporation thereof for removal of insoluble reaction byproducts from the composition. The purified composition can be used in the formation of articles having improved biocompatibility, such as medical articles (e.g., spun hollow fiber). 1. A method comprising:forming a first solution by phase transitioning at least a portion of a surface modifying composition to a liquid state, the surface modifying composition comprising:a) at least one polymer or oligomer, andb) an insoluble reaction byproduct of i) a fluorotelomer alcohol and ii) an isocyanate, wherein said insoluble reaction byproduct is substantially insoluble in said polymer or oligomer; andremoving from the first solution at least a portion of said insoluble reaction byproduct present in the first solution to obtain a second solution;wherein said polymer or oligomer comprises a polymer or oligomer backbone covalently attached to at least one surface active group.2. The method of claim 1 , wherein said first solution is formed by dissolving at least a portion of said surface modifying composition in at least one solvent.3. The method of claim 1 , wherein said first solution is formed by melting said polymer or oligomer of said surface modifying composition.4. The method of claim 1 , wherein the insoluble reaction byproduct is fluorotelomer alcohol end capped di-isocyanate.5. The method of claim 1 , wherein the fluorotelomer alcohol (FTOH) is 4:2 FTOH claim 1 , 5:2 FTOH claim 1 , 6:2 FTOH claim 1 , 7:2 FTOH claim 1 , 8:2 FTOH claim 1 , 9:2 FTOH claim 1 , 10:2 FTOH claim 1 , or a combination thereof.6. The method of claim 1 , wherein the fluorotelomer alcohol is 6:2 fluorotelomer alcohol.7. The method of claim 1 , wherein the isocyanate has two or more isocyanate functional groups.8. The method of claim 1 , wherein the isocyanate is di-isocyanate claim 1 , tri-isocyanate claim 1 , or a combination thereof.9. The method ...

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21-01-2021 дата публикации

Polysulfone-Urethane Copolymer, Membranes And Products Incorporating Same, And Methods For Making And Using Same

Номер: US20210017340A1
Принадлежит: Fresenius Medical Care Holdings, Inc.

A polysulfone-urethane copolymer is disclosed, which can be used as a membrane polymer, e.g., a matrix polymer, a pore forming agent, or both, while enhancing a membrane's blood compatibility. Methods are disclosed for forming the copolymer and incorporating the copolymer in membranes (e.g., spun hollow fibers, flat membranes) and other products. 120-. (canceled)21. A method for preparing a polysulfone-urethane copolymer , comprising1) reacting an aromatic diol and a dihalodiphenyl sulfone to form a polysulfone block, and control the stoichiometry so that the polysulfone block has dihalodiphenyl end groups,2) reacting at least one oligo- or polyurethane block with an aromatic dihydroxyl compound which end caps the at least one oligo- or polyurethane block to form an encapped oligo- or polyurethane block, and3) reacting the polysulfone block and the end-capped oligo- or polyurethane block to form the polysulfone-urethane copolymer.22. The method of claim 21 , wherein said step 1) and said step 2) are conducted in the presence of at least one metal carbonate and at least one solvent.23. The method of claim 22 , wherein said metal carbonate is dipotassium carbonate and said solvent is a polar aprotic solvent.24. The method of claim 21 , wherein said polysulfone block having said dihalodiphenyl end groups comprises repeating units of an aromatic dihydroxyl compound and a dihalodiphenyl sulfone and a dihalodiphenyl sulfone end groups.25. The method of claim 21 , wherein said reacting in said step 1) is in the presence of a metal carbonate as a catalyst at a reaction temperature of from about 145° C. to about 185° C. for about 2 hours to about 12 hours in a reaction vessel setup with a fractionation column.26. The method of claim 21 , wherein said step 2) is maintained at a reaction temperature of 65° C.±5° C. at atmospheric pressure for at least 2 hours or until no change is seen in the amount of NCO end groups.27. The method of claim 21 , wherein in said step 3) claim ...

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21-01-2021 дата публикации

THERMOPLASTIC COMPOSITION AND METHOD OF PREPARING THE SAME

Номер: US20210017382A1
Принадлежит: TAIWAN TEXTILE RESEARCH INSTITUTE

A method of preparing a thermoplastic composition is provided. The method includes the following steps. A polyetherimide or a polyphenylene sulfide is provided. A polyimide is provided, wherein the glass transition temperature of the polyimide is between 128° C. and 169° C., the 10% thermogravimetric loss temperature of the polyimide is between 490° C. and 534° C., and when the polyimide is dissolved in N-methyl-2-pyrrolidone and the solid content of the polyimide is 30 wt %, the viscosity of the polyimide is between 100 cP and 250 cP. A melt process is performed to mix the polyetherimide and the polyimide or mix the polyphenylene sulfide and the polyimide to form a thermoplastic composition. Further, a thermoplastic composition is also provided. 1. A method of preparing a thermoplastic composition , comprising:providing a polyetherimide;providing a polyimide, wherein a glass transition temperature of the polyimide is between 128° C. and 169° C., a 10% thermogravimetric loss temperature of the polyimide is between 490° C. and 534° C., and when the polyimide is dissolved in N-methyl-2-pyrrolidone (NMP) and a solid content of the polyimide is 30 wt %, a viscosity of the polyimide is between 100 cP and 250 cP; andperforming a melt process to mix the polyetherimide and the polyimide to form the thermoplastic composition.2. The method of preparing the thermoplastic composition according to claim 1 , wherein the polyimide is used in an amount of from 1 part by weight to 10 parts by weight based on a use amount of 100 parts by weight of the polyetherimide.3. The method of preparing the thermoplastic composition according to claim 1 , wherein a process temperature of the melt process is between 300° C. and 350° C.4. The method of preparing the thermoplastic composition according to claim 1 , wherein a melt index (MI) of the thermoplastic composition is from 7 g/10 min to 15 g/10 min at 320° C.5. A thermoplastic composition claim 1 , comprising:a polyetherimide; anda ...

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10-02-2022 дата публикации

POROUS MEMBRANES FOR HIGH PRESSURE FILTRATION

Номер: US20220040647A1
Автор: Di Nicolo Emanuele
Принадлежит:

The present invention relates to a porous membrane suitable for use in high pressure filtration method. 115-. (canceled)16. A method for purifying a fluid containing at least one contaminant , said method comprising the steps of(I) providing a fluid containing at least one contaminant;(II) providing a membrane [membrane (PSP)] comprising at least one porous layer [layer (PSP)] comprising at least one aromatic sulfone polymer [polymer (SP)] and at least one polyphenylene polymer [polymer (PP)];(III) contacting said fluid containing at least one contaminant and said membrane (PSP) by applying a pressure higher than 1 bar to said fluid; and(IV) recovering the fluid free from said at least one contaminant.171. The method according to claim , wherein said membrane (PSP) comprises said layer (PSP) as the only layer or said membrane (PSP) is a multi-layered membrane.181. The method according to claim , wherein said polymer (SP) is a polymer comprising at least one group of formula —Ar—SO—Ar′— [recurring units (R)] , wherein Ar and Ar′ , equal to or different from each other , are aromatic groups , and wherein more than 50% by moles of the recurring units of said polymer (SP) are connected by ether linkages in the main chain.20. The method according to claim 18 , wherein said polymer (SP) is selected from poly(phenylene sulfone) polymers [polymers (PPSU)] claim 18 , poly(sulfone) polymers [polymers (PSU)] and poly(ether sulfone) polymers [polymers (PESU)].261. The method according to claim claim 18 , wherein said method is for purifying non-drinkable water claim 18 , said fluid is saline water or brackish water claim 18 , said contaminant is the salts content dissolved into said fluid claim 18 , and said membrane (PSP) is a multi-layered membrane comprising (I) a substrate layer claim 18 , (II) an outer layer consisting of aromatic polyamides and (III) the layer (PSP) claim 18 , said layer (PSP) being interposed between said substrate layer and said outer layer.271. The ...

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22-01-2015 дата публикации

THERMALLY STABLE BIURET AND ISOCYANURATE BASED SURFACE MODIFYING MACROMOLECULES AND USES THEREOF

Номер: US20150025198A1
Принадлежит: Interface Biologics Inc.

The invention relates to surface modifying macromolecules (SMMs) having high degradation temperatures and their use in the manufacture of articles made from base polymers which require high temperature processing. The surface modifier is admixed with the base polymer to impart alcohol and water repellency properties. 29.-. (canceled)10. The surface modifier of claim 1 , wherein said surface active group is selected from the group consisting of radicals of the general formula CHF(CF)CHCH— and CHF(CF)(CHCHO)— claim 1 , whereinm is 0, 1, 2, or 3;χ is an integer between 1-10;r is an integer between 2-20; ands is an integer between 1-20.11. The surface modifier of claim 10 , wherein m is 0 or 1.12. (canceled)13. The surface modifier of claim 10 , wherein each surface active group is selected claim 10 , independently claim 10 , from (CF)(CF)CHCHO— claim 10 , (CF)(CF)CHCHO— claim 10 , (CF)(CF)CHCHO— claim 10 , CHF(CF)CHO— claim 10 , and (CF)(CF)CHO—.1460.-. (canceled)61. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is diethylene glycol-orthophthalic anhydride polyester claim 1 , and B is formed from isophorone diisocyanate (IPDI) trimer.62. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is polytetramethylene oxide claim 1 , and B is formed from hexamethylene diisocyanate (HDI) trimer.63. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is polytetramethylene oxide claim 1 , and B is formed from isophorone diisocyanate (IPDI) trimer.64. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is poly(diethylene glycol)adipate claim 1 , and B is formed from isophorone diisocyanate (IPDI) trimer.65. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is poly(hexamethylene carbonate) claim 1 , and B is formed from isophorone diisocyanate (IPDI) trimer.66. The surface modifier of claim 1 , wherein n is 0 claim 1 , A is poly(ethyleneglycol)-block-poly(propyleneglycol))-block-poly(ethylene glycol) claim 1 , and B is formed ...

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10-02-2022 дата публикации

FLUIDITY MODIFIER, COMPOSITION CONTAINING SAME, AND CURED PRODUCT OF SAID COMPOSITION

Номер: US20220041858A1
Принадлежит: DIC CORPORATION

A fluidity modifier for a coating material or the like contains an ester resin represented by the following general formula (I) or general formula (II) (Y represents a hydrogen atom or a monocarboxylic acid residue having 1 to 9 carbon atoms, G represents an aliphatic diol residue having 2 to 9 carbon atoms, A represents an aliphatic dicarboxylic acid residue having 2 to 10 carbon atoms, X represents a dicarboxylic acid residue having 1 to 8 carbon atoms, Z represents a monoalcohol residue having 2 to 10 carbon atoms, n represents the number of repeating units and is an integer of 0 to 30, and m represents the number of repeating units and is an integer of 0 to 30; G and A may be the same or different for each repeating unit, and a plurality of G may be the same as or different from each other). 2. The inorganic composition according to claim 1 , whereinin the general formula (I), Y is a hydrogen atom or a monocarboxylic acid residue having 1 to 6 carbon atoms, G is an aliphatic glycol residue having 3 to 5 carbon atoms, A is an aliphatic dicarboxylic acid residue having 2 to 6 carbon atoms, and X is a dicarboxylic acid residue having 2 to 6 carbon atoms.3. The inorganic composition according to claim 1 , whereinin the general formula (II), Z is a monoalcohol residue having 4 to 10 carbon atoms, A is an aliphatic dicarboxylic acid residue having 2 to 6 carbon atoms, G is an aliphatic glycol residue having 3 to 5 carbon atoms, and X is a dicarboxylic acid residue having 2 to 6 carbon atoms.4. The inorganic composition according to claim 1 , whereinthe acid value is in a range of 3 to 35.5. The inorganic composition according to claim 1 , whereinthe inorganic filler is one or more kinds selected from the group consisting of calcium carbonate, manganese dioxide, and talc.6. The inorganic composition according to claim 1 , wherein the inorganic composition is a curing agent for a polysulfide-based sealing material.7. (canceled)8. (canceled)9. (canceled)10. (canceled)11. ...

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28-01-2021 дата публикации

Porous membrane and filter cartridge

Номер: US20210023510A1
Принадлежит: Fujifilm Corp

A porous membrane includes a polymer which includes one or more structural units selected from the group consisting of a structural unit represented by Formula (I) and a structural unit represented by Formula (II), in which a content of the structural unit represented by Formula (II) is 1% by mass or more and less than 10% by mass with respect to a total mass of the structural unit represented by Formula (I) and the structural unit represented by Formula (II)

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23-01-2020 дата публикации

REACTOR

Номер: US20200024371A1
Принадлежит:

A polymerization device that includes: a reaction vessel that houses a polymerization solution and in which a polymerization reaction is performed; a stirring blade that stirs the polymerization solution housed in the reaction vessel; a plurality of heat transfer pipes that transfer heat to the polymerization solution in order to start the polymerization reaction and cause the polymerization reaction to proceed, and that remove, from the polymerization solution, heat generated by the polymerization reaction; and a baffle arranged between a vessel wall of the reaction vessel and the heat transfer pipes. 1. A reactor comprising:a reaction vessel that houses a polymerization solution and in which a polymerization reaction is performed;a stirring blade configured to stir the polymerization solution housed in the reaction vessel;a plurality of heat transfer pipes configured to transfer heat to the polymerization solution in order to start the polymerization reaction and cause the polymerization reaction to proceed, and to remove, from the polymerization solution, heat generated by the polymerization reaction; anda baffle arranged between a vessel wall of the reaction vessel and the heat transfer pipes; whereinthe plurality of heat transfer pipes are arranged in a circumferential shape around the stirring blade, include heat transfer pipes whose lower ends are arranged in a position higher than a bottom face of the reaction vessel, and restrict an amount of the polymerization solution circulated from an inner side to a vessel wall side of the reaction vessel, at a depth at which the heat transfer pipes are arranged, andthe baffle changes a flow direction of the polymerization solution that has flowed between the vessel wall of the reaction vessel and the heat transfer pipes arranged in the circumferential shape, and generates a flow of the polymerization solution to an inward direction of the reaction vessel.2. The reactor according to claim 1 , whereina plurality of the ...

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23-01-2020 дата публикации

OPTICAL MATERIAL COMPOSITION

Номер: US20200024450A1
Принадлежит: MITSUBISHI GAS CHEMICAL COMPANY, INC.

Provided is an optical material composition which makes it possible to design an optical material exhibiting a broad range of properties. This optical material composition contains a compound (A) represented by formula (1), 1,2,3,5,6-pentathiepane (b), and if necessary, a compound (B) represented by formula (2). The content of the compound (B) constitutes 0-30 mass % of the total mass of the composition: 2. The optical material composition according to claim 1 , wherein the content of the compound (A) is 20% to 80% by mass relative to the total mass of the composition.3. The composition according to claim 1 , which further comprises a polythiol (a).4. The composition according to claim 3 , wherein the polythiol (a) is at least one selected from 1 claim 3 ,2 claim 3 ,6 claim 3 ,7-tetramercapto-4-thiaheptane claim 3 , methanedithiol claim 3 , (sulfanylmethyldisulfanyl)methanethiol claim 3 , bis(2-mercaptoethyl)sulfide claim 3 , 2 claim 3 ,5-bis(mercaptomethyl)-1 claim 3 ,4-dithiane claim 3 , 1 claim 3 ,2-bis(2-mercaptoethylthio)-3-mercaptopropane claim 3 , 4 claim 3 ,8-dimercaptomethyl-1 claim 3 ,11-dimercapto-3 claim 3 ,6 claim 3 ,9-trithiaundecane claim 3 , 4 claim 3 ,7-dimercaptomethyl-1 claim 3 ,11-dimercapto-3 claim 3 ,6 claim 3 ,9-trithiaundecane claim 3 , 5 claim 3 ,7-dimercaptomethyl-1 claim 3 ,11-dimercapto-3 claim 3 ,6 claim 3 ,9-trithiaundecane claim 3 , 1 claim 3 ,1 claim 3 ,3 claim 3 ,3-tetrakis(mercaptomethylthio)propane claim 3 , tetramercaptopentaerythritol claim 3 , 1 claim 3 ,3-bis(mercaptomethyl)benzene claim 3 , 1 claim 3 ,4-bis(mercaptomethyl)benzene claim 3 , and thiiranemethanethiol.5. The composition according to claim 1 , which further comprises sulfur.6. The composition according to claim 1 , wherein the mass ratio of the compound (A) to the compound (B) is 45:55 to 100:0.7. The composition according to claim 1 , wherein the mass ratio of the compound (A) to 1 claim 1 ,2 claim 1 ,3 claim 1 ,5 claim 1 ,6-pentathiepane (b) is 25:75 to 95:5.8. ...

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23-01-2020 дата публикации

AROMATIC POLYSULFONE, AROMATIC POLYSULFONE COMPOSITION, AND METHOD FOR PRODUCING AROMATIC POLYSULFONE

Номер: US20200024451A1
Автор: Ito Kazuyuki
Принадлежит:

An aromatic polysulfone includes an amino group-containing aromatic polysulfone containing a repeating unit represented by the following general formula (A) and having an amino group at a polymer chain end. The aromatic polysulfone has a weight average absolute molecular weight (Mw) of 20,000 g/mol or more and a reduced viscosity (unit: dL/g) of 0.30 or more. 1. An aromatic polysulfone comprising an amino group-containing aromatic polysulfone substantially including a repeating unit represented by the following general formula (A) and having an amino group at least at one polymer chain end , and having a weight average absolute molecular weight (Mw) of 20 ,000 g/mol or more and a reduced viscosity (unit: dL/g) of 0.30 or more ,{'br': None, 'sub': '2', '-Ph1-SO-Ph2-O—\u2003\u2003(A)'}(Ph1 and Ph2 are each independently a phenylene group which may have a substituent.)2. The aromatic polysulfone according to claim 1 , which has a glass transition temperature (Tg) of 220° C. or higher.3. The aromatic polysulfone according to claim 1 , wherein the number of amino groups at said polymer chain end is 0.4 or more per 100 repeating units represented by said formula (A).4. An aromatic polysulfone composition comprising the aromatic polysulfone according to and another different aromatic polysulfone.5. A method for producing an aromatic polysulfone claim 1 , the method comprisingallowing a polycondensation reaction between a phenoxy end or phenolate end generated as a by-product and a halogen end by condensing an aromatic halogenosulfone compound with an amino compound, whereinsaid polycondensation reaction comprises:mixing said aromatic halogenosulfone compound and said amino compound such that a molar ratio of an amino group of said amino compound with respect to a halogen atom at an end of said aromatic halogenosulfone compound is less than 1.0; andreacting while heating at a temperature higher than 180° C. The present invention relates to an aromatic polysulfone, an ...

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29-01-2015 дата публикации

Structural adhesive and bonding application thereof

Номер: US20150030844A1
Принадлежит: CYTEC TECHNOLOGY CORP

A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler as a rheology/thixotropy modifying component. The weight ratio of part (A) to part (B) is within the range of 3:2 to 10:2. In another embodiment, the structural adhesive composition is based on a one-part system which includes the components of the resinous part (A) in the two-part system mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine. The one-part system is curable within the temperature range of 140-300° F. (60-150° C.). The paste adhesive disclosed herein has film-like properties and is particularly useful in rapid-assembly aerospace structure bonding applications.

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02-02-2017 дата публикации

Hydrosilyl-containing organopolysiloxane, making method, addition curable silicone composition, and semiconductor package

Номер: US20170029571A1
Принадлежит: Shin Etsu Chemical Co Ltd

An organopolysiloxane having at least 4 terminal hydrosilyl groups per molecule is novel. Also provided is an addition curable silicone composition comprising (A) a linear organopolysiloxane having at least two alkenyl groups per molecule, (B) an organopolysiloxane having at least 4 terminal hydrosilyl groups per molecule, and (C) a hydrosilylation catalyst.

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04-02-2016 дата публикации

POLYTHIOETHER SEALANTS

Номер: US20160032058A1
Принадлежит: 3M INNOVATIVE PROPERTIES COMPANY

Certain polythioether polymers are presented, as well as compositions which are radiation curable to polythioether polymers and seals and sealants comprising same. The compositions radiation curable to polythioether polymers include those comprising: a) at least one dithiol monomer; b) at least one diene monomer; c) at least one multifunctional monomer having at least three ethenyl groups; and d) at least one photoinitiator. In another aspect, the compositions radiation curable to polythioether polymers include those comprising: f) at least one dithiol monomer; g) at least one diene monomer; h) at least one multifunctional monomer having at least three thiol groups; and i) at least one photoinitiator. In another aspect, the compositions radiation curable to poly-thioether polymers include those comprising: k) at least one thiol terminated polythioether polymer; l) at least one multifunctional monomer having at least three ethenyl groups; and m) at least one photoinitiator. 1. A composition which is radiation curable to a polythioether polymer , comprising:a) at least one dithiol monomer;b) at least one diene monomer;c) at least one multifunctional monomer having at least three ethenyl groups; andd) at least one photoinitiator.2. The composition according to additionally comprising:e) at least one epoxy resin.3. The composition according to or wherein said at least one multifunctional monomer has three ethenyl groups.4. A composition which is radiation curable to a polythioether polymer claim 1 , comprising:f) at least one dithiol monomer;g) at least one diene monomer;h) at least one multifunctional monomer having at least three thiol groups; andi) at least one photoinitiator.5. The composition according to additionally comprising:j) at least one epoxy resin.6. The composition according to or wherein said at least one multifunctional monomer has three thiol groups.7. A composition which is radiation curable to a polythioether polymer claim 4 , comprising:k) at least ...

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04-02-2016 дата публикации

POLYPHENYLENE SULFIDE RESIN COMPOSITION, MOLDED PRODUCT OF POLYPHENYLENE SULFIDE RESIN COMPOSITION AND PRODUCTION METHOD OF POLYPHENYLENE SULFIDE RESIN COMPOSITION

Номер: US20160032100A1
Принадлежит: Toray Industries, Inc.

There is provided a polyphenylene sulfide resin composition, comprising 5 to 95% by weight of a component (B) which is a polyphenylene sulfide resin having a weight-average molecular weight of not less than 10,000 and a weight loss percentage ΔWr of not greater than 0.18% under heating, relative to 95 to 5% by weight of a component (A) which is a polyphenylene sulfide resin having the weight loss percentage ΔWr of greater than 0.18%, wherein a total of the component (A) and the component (B) is equal to 100% by weight. 1. A production method of a polyphenylene sulfide resin composition , comprising the steps of: {'br': None, 'i': Wr', 'W', 'W', 'W, 'Δ=(1−2)/1×100%\u2003\u2003(1)'}, 'providing a component (A) which is a polyphenylene sulfide resin having a weight loss percentage ΔWr expressed by Equation (1) of greater than 0.18% under heatingwherein ΔWr denotes weight loss percentage (%) and is a value determined from a sample in thermogravimetric analysis at a temperature rise rate of 20° C. per minute under ordinary-pressure and non-oxidizing-atmosphere ΔWr is determined from a sample weight (W1) at 100° C. and a sample weight (W2) at 330° C.;providing a component (B) which is a polyphenylene sulfide resin having a weight-average molecular weight of not less than 10,000 and having the weight loss percentage ΔWr expressed by the Equation (1) of not greater than 0.18% under heating;providing a component (C) that is a fibrous and/or non-fibrous filler and/or a component (E) that is a functional group-containing olefin copolymer; andmelt kneading 95 to 5% by weight of the component (A) with 5 to 95% by weight of the component (B) and additionally with 1 to 500 parts by weight of the component (C) and/or 1 to 70 parts by weight of the component (E), wherein total of the component (A) and the component (B) is equal to 100% by weight.2. The production method of a polyphenylene sulfide resin composition according to claim 1 , whereinthe melt kneading comprises melt ...

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01-02-2018 дата публикации

REVERSIBLE DERIVATIZATION OF POLY (ARYL ETHER KETONES)

Номер: US20180030227A1
Принадлежит: CYTEC TECHNOLOGY CORP.

The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs, such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution. 1. A method of forming a soluble derivative of a poly (aryl ether ketone) (“PAEK”) , comprising:mixing a starting poly (aryl ether ketone) (PAEK) polymer with a solvent and an acid, said solvent being selected from a group consisting of diethylether, tetrahydrofuran (THF), dioxin, and chlorinated solvents; andreacting the PAEK mixture with a Lewis acid and a thiol compound in amounts effective to form a poly (aryl ether thioacetal) compound which comprises at least one thioacetal group;{'sub': 3', '2, 'wherein the Lewis acid is boron trifluoride diethyl etherate (BFEtO), the thiol compound is 1,2 ethanedithiol or 1,3-propanedithiol, and the starting PAEK is selected from: poly (ether ketone) (“PEK”), poly (ether ether ketone) (“PEEK”), poly (ether ketone ketone) (“PEKK”), and poly (ether ketone ether ketone ketone) (“PEKEKK”).'}2. The method of claim 1 , wherein the chlorinated solvent is selected from at least one of dichloromethane (DCM) claim 1 , trichloromethane (chloroform) claim 1 , dichloroethane ...

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31-01-2019 дата публикации

Composite Structure

Номер: US20190030771A1
Принадлежит:

A composite structure comprising a resinous component that is adhered to a surface of a metal component is provided. The resinous component is formed from a polymer composition that comprises a polyarylene sulfide, inorganic fibers, and an impact modifier. The inorganic fibers have an aspect ratio of from about 1.5 to about 10. 1. A composite structure comprising a resinous component that is adhered to a surface of a metal component , wherein the resinous component is formed from a polymer composition that comprises a polyarylene sulfide , inorganic fibers , and an impact modifier , wherein the inorganic fibers having an aspect ratio of from about 1.5 to about 10 , the aspect ratio being defined as the cross-sectional width of the fibers divided by the cross-sectional thickness of the fibers.2. The composite structure of claim 1 , wherein the inorganic fibers constitute from about 1 wt. % to about 50 wt. % of the polymer composition claim 1 , the impact modifier constitutes from about 1 wt. % to about 40 wt. % of the polymer composition and/or the polyarylene sulfide constitutes from about 35 wt. % to about 95 wt. % of the polymer composition.3. The composite structure of claim 1 , wherein the polyarylene sulfide is a linear polyphenylene sulfide.4. The composite structure of claim 1 , wherein the impact modifier includes an epoxy-functionalized olefin copolymer.5. The composite structure of claim 1 , wherein the epoxy-functionalized olefin copolymer contains an ethylene monomeric unit and an epoxy-functional (meth)acrylic monomeric component.6. The composite structure of claim 5 , wherein the epoxy-functional (meth)acrylic monomeric component is derived from glycidyl acrylate claim 5 , glycidyl methacrylate claim 5 , or a combination thereof.7. The composite structure of claim 5 , wherein the epoxy-functional (meth)acrylic monomeric unit constitutes from about 1 wt. % to about 20 wt. % of the copolymer.8. The composite structure of claim 5 , wherein the epoxy- ...

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31-01-2019 дата публикации

Pneumatic Tire

Номер: US20190030962A1
Автор: Shinzawa Tatsuro
Принадлежит:

In a pneumatic tire provided with a band-like sound absorbing member adhered on a tire inner surface of a tread portion in a tire circumferential direction, a rubber composition constituting the tread portion contains a particular cyclic polysulfide, a compounded amount thereof is in a particular range specified by an average thickness of the sound absorbing member in the tire circumferential direction or by a ratio of an average width of the sound absorbing member in the tire circumferential direction to a width of a belt layer. 4. The pneumatic tire according to claim 1 , wherein a volume of the band-like sound absorbing member is from 10% to 30% relative to a cavity volume of the tire.5. The pneumatic tire according to claim 1 , wherein the band-like sound absorbing member has a missing portion at at least one position in the tire circumferential direction.6. The pneumatic tire according to claim 1 , wherein the R moiety in Formula (1) is —CH—CH—O—CH—O—CH—CH—.7. The pneumatic tire according to claim 2 , wherein a volume of the band-like sound absorbing member is from 10% to 30% relative to a cavity volume of the tire.8. The pneumatic tire according to claim 2 , wherein the band-like sound absorbing member has a missing portion at at least one position in the tire circumferential direction.9. The pneumatic tire according to claim 2 , wherein the R moiety in Formula (1) is —CH—CH—O—CH—O—CH—CH—.10. The pneumatic tire according to claim 3 , wherein a volume of the band-like sound absorbing member is from 10% to 30% relative to a cavity volume of the tire.11. The pneumatic tire according to claim 3 , wherein the band-like sound absorbing member has a missing portion at at least one position in the tire circumferential direction.12. The pneumatic tire according to claim 3 , wherein the R moiety in Formula (1) is —CH—CH—O—CH—O—CH—CH—. The present technology relates to a pneumatic tire provided with a tire noise reduction device and particularly relates to a pneumatic ...

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17-02-2022 дата публикации

POLYARYLENE ETHER SULFONE COMPRISING NAPHTHALIC ACID ANHYDRIDE ENDGROUPS

Номер: US20220049096A1
Принадлежит: BASF SE

A polyarylene ether sulfone contains endgroups of formula (I), 116-. (canceled)18: The molding composition according to claim 17 , comprising:from 30 to 75% by weight of the at least one polyarylene ether sulfone, andfrom 25 to 70% by weight of the at least one polyamide.19: The molding composition according to claim 17 , wherein the at least one polyamide is selected from the group consisting of PA 9T claim 17 , PA 9T-co-8.1T claim 17 , PA 6T6I claim 17 , PA 6T66 claim 17 , PA 66T claim 17 , and a mixture thereof.20: The molding composition according to claim 17 , wherein the at least one further component is at least one polyarylene ether sulfone having no endgroups of formula (I) claim 17 ,wherein the molding composition comprises 10 to 70% by weight of the at least one polyarylene ether sulfone having no endgroups of formula (I).21: The molding composition according to claim 17 , wherein the at least one further component is at least one fibrous or particulate filler claim 17 , andwherein the molding composition comprises 10 to 62.5% by weight of the at least one fibrous or particulate filler.22: A fiber claim 17 , film claim 17 , or shaped article claim 17 , comprising the molding composition according to .23: The molding composition according to claim 17 , wherein the at least one polyarylene ether sulfone comprises at least 15% of the endgroups of formula (I).24: The molding composition according to claim 17 , wherein the at least one polyarylene ether sulfone comprises from 25% to 90% of the endgroups of formula (I). The present invention relates to polyarylene ether sulfones having anhydride endgroups.Polyarylene ethers are classified as high-performance thermoplastics. Polyarylene ethers may have—depending on how they are produced—for instance hydroxy, halogen, amino, epoxy or anhydride endgroups. EP 840 758 A discloses polyarlyene ethers with phthalic acid anhydride endgroups. These are obtained by reacting a hydroxy endgroup containing polyarylene ether ...

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31-01-2019 дата публикации

Polyarylene Sulfide Composition with Improved Adhesion to Metal Components

Номер: US20190031879A1
Принадлежит:

A polymer composition that comprises a polyarylene sulfide, inorganic fibers, an impact modifier that includes an epoxy-functionalized copolymer, and an epoxy resin having an epoxy equivalent weight of from about 250 to about 1,500 grams per gram equivalent is provided. The inorganic fibers having an aspect ratio of from about 1.5 to about 10, the aspect ratio being defined as the cross-sectional width of the fibers divided by the cross-sectional thickness of the fibers. 1. A polymer composition comprising a polyarylene sulfide , inorganic fibers , an impact modifier that includes an epoxy-functionalized copolymer , and an epoxy resin having an epoxy equivalent weight of from about 250 to about 1 ,500 grams per gram equivalent as determined in accordance with ASTM D1652-11e1 , wherein the inorganic fibers having an aspect ratio of from about 1.5 to about 10 , the aspect ratio being defined as the cross-sectional width of the fibers divided by the cross-sectional thickness of the fibers.2. The polymer composition of claim 1 , wherein the inorganic fibers constitute from about 1 wt. % to about 50 wt. % of the polymer composition claim 1 , the impact modifier constitutes from about 1 wt. % to about 40 wt. % of the polymer composition claim 1 , the epoxy resin constitutes from about 0.01 wt. % to about 3 wt. % of the polymer composition claim 1 , and/or the polyarylene sulfide constitutes from about 35 wt. % to about 95 wt. % of the polymer composition.3. The polymer composition of claim 1 , wherein the polyarylene sulfide is a linear polyphenylene sulfide.4. The polymer composition of claim 1 , wherein the epoxy-functionalized olefin copolymer contains an ethylene monomeric unit.5. The polymer composition of claim 1 , wherein the epoxy-functionalized olefin copolymer contains an epoxy-functional (meth)acrylic monomeric component.6. The polymer composition of claim 5 , wherein the epoxy-functional (meth)acrylic monomeric component is derived from glycidyl acrylate claim ...

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30-01-2020 дата публикации

BLENDS OF AROMATIC POLYMERS AND ADDUCTS OBTAINED THEREFROM

Номер: US20200032060A1
Принадлежит:

The present invention relates to polymers and blends of polymers comprising anthracene moieties able to undergo a cycloaddition reaction under certain stimuli, thereby forming polymer adducts endowed with improved or additional properties with respect to those of the starting polymers. 3. The blend of claim 2 , wherein T is selected from the group consisting of a bond claim 2 , —SO— and —C(CH)—.4. The blend of any one of - claim 2 , wherein at least one of the PAES polymers (P1) and/or (P2) comprises at least 50 mol. % (based on the total number of moles in the PAES polymer) of recurring units (R) of formula (L).6. The blend of claim 1 , comprising at least one polymer (P1) and at least one polymer (P2).8. A polymer adduct obtained by heating at a temperature ranging from 60° C. to 250° C. claim 1 , preferably from 65° C. to 200° C. claim 1 , the blend of any one of to .12. A method for recycling a coating or a formed article claim 7 , comprising the polymer adduct of claim 7 , by submitting the coating or formed article to heating at a temperature ranging from 100° C. to 500° C.13. A recycled material obtainable by the method of or . This application claims priority to U.S. provisional application No. 62/468,187—filed on Mar. 7, 2017, and to European application No. 17165733.1—filed on Apr. 10, 2017, the whole content of each of these applications being incorporated herein by reference for all purposes.The present invention relates to polymers and blends of polymers comprising anthracene moieties able to undergo a cycloaddition reaction under certain stimuli, thereby forming polymer adducts endowed with improved or additional properties with respect to those of the starting polymers.Stimuli-responsive polymers, also called smart polymers, are defined as polymers which can change their properties under specific conditions, for example humidity, pH, UV light or heat. Stimuli-responsive polymers are for example used in drug delivery. As an example, conformational ...

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30-01-2020 дата публикации

COMPOSITIONS CONTAINING HOLE CARRIER MATERIALS AND POLY(ARYL ETHER SULFONE)S, AND USES THEREOF

Номер: US20200032086A1
Принадлежит:

Described herein are compositions comprising hole carrier materials, typically conjugated polymers, and poly(aryl ether sulfones)s, ink compositions comprising hole carrier materials and poly(aryl ether sulfones)s, and uses thereof, for example, in organic electronic devices. 1. A composition comprising:(a) at least one hole carrier material, and(b) at least one poly(aryl ether sulfone).23.-. (canceled)4. The composition according to claim 1 , wherein the at least one hole carrier material is a polythiophene.6. The composition according to claim 5 ,{'sub': 1', '2, 'wherein Ris H and Ris other than H, or'}{'sub': 1', '2, 'wherein Rand Rare both other than H, or'}{'sub': 1', '2', 'a', 'b', 'c', 'd', 'p', 'e', 'f, 'wherein Ris H and Ris —O[C(RR)—C(RR)—O]—R, or —ORor'}{'sub': 1', '2', 'a', 'b', 'c', 'd', 'p', 'e', 'f, 'wherein Rand Rare each, independently, —O[C(RR)—C(RR)—O]—R, or —OR.'}78.-. (canceled)9. The composition according to claim 4 , wherein the polythiophene is regioregular.10. The composition according to claim 9 , wherein the degree of regioregularity is about 0 to 100% claim 9 , or about 25 to 99.9% claim 9 , or about 50 to 98%.1113.-. (canceled)14. The composition according to claim 5 , wherein Rand Rare each —O[CH—CH—O]—Ror —O[CH(CH)—CH—O]—R.1516.-. (canceled)17. The composition according to claim 5 , wherein Ris methyl claim 5 , propyl claim 5 , or butyl.1949.-. (canceled)50. An ink composition comprising the composition according to and a liquid carrier.51. A device comprising the composition according to claim 1 , wherein the device is an OLED claim 1 , OPV claim 1 , transistor claim 1 , capacitor claim 1 , sensor claim 1 , transducer claim 1 , drug release device claim 1 , electrochromic device claim 1 , or battery device. This application is a provisional application.The present invention relates to compositions comprising hole carrier materials, typically conjugated polymers, and poly(aryl ether sulfones)s, ink compositions comprising hole carrier ...

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04-02-2021 дата публикации

MULTIPHASE FERRITES AND COMPOSITES COMPRISING THE SAME

Номер: US20210032121A1
Автор: CHEN Yajie, Li Qifan
Принадлежит:

In an aspect, a multiphase ferrite comprises a CoW phase that is optionally doped with Ru; a CFO phase having the formula Me“CoFeO, wherein Me” is at least one of Ni, Zn, or Mg, r is 0 to 0.5, and z is −0.5 to 6 0.5; and a CoRu-BaM phase having the formula BaCoRuFeO, wherein x is 0 to 2, y is 0.01 to 2; and the Ba can be partially replaced by at least one of Sr or Ca. In another aspect, a composite can comprise a polymer and the multiphase ferrite. In yet another aspect, a method of making a multiphase ferrite can comprise mixing and grinding a CoRu-BaM phase ferrite and a CFO phase ferrite to form a mixture; and sintering the mixture in an oxygen atmosphere to form the multiphase ferrite. 1. A multiphase ferrite comprising:{'sub': '2', 'a CoW phase that optionally comprises Ru;'}{'sub': r', '1−r', '2+z', '4, 'a CFO phase having the formula Me“CoFeO, wherein Me” is at least one of Ni, Zn, or Mg, r is 0 to 0.5, and z is −0.5 to 0.5; and'}{'sub': x+y', 'y', '12−(2/3)x−2y', '19, 'a CoRu-BaM phase having the formula BaCoRuFeO, wherein x is 0 to 2, y is 0.01 to 2; and the Ba is optionally partially replaced by at least one of Sr or Ca.'}2. The multiphase ferrite of claim 1 , wherein the multiphase ferrite comprises:{'sub': '2', '50 to 95 volume percent of the CoW phase;'}1 to 20 volume percent of the CFO phase; and5 to 50 volume percent of the CoRu-BaM phase;all based on the total volume of the multiphase ferrite.3. The multiphase ferrite of claim 1 , wherein the CoW phase comprises Ru.4. A composite comprising:a multiphase ferrite; anda polymer; [{'sub': '2', 'CoW phase that is optionally doped with Ru;'}, {'sub': r', '1−r', '2+z', '4, 'a CFO phase having the formula Me“CoFeO, wherein Me” is at least one of Ni, Zn, or Mg, r is 0 to 0.5, and z is −0.5 to 0.5; and'}], 'wherein the multiphase ferrite has'}{'sub': x+y', 'y', '12−(2/3)x−2y', '19, 'a CoRu-BaM phase having the formula BaCoRuFeO, wherein x is 0 to 2, y is 0.01 to 2; and the Ba is optionally partially replaced ...

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09-02-2017 дата публикации

Membranes and method for the production thereof

Номер: US20170036173A1

The invention concerns the field of polymer chemistry and relates to membranes, such as those used as membranes for the preparation of aqueous solutions by means of reverse osmosis or microfiltration, ultrafiltration or nanofiltration, for example. The object of the present invention is the specification of membranes that exhibit a reduced fouling tendency with equally suitable or improved filtration properties, as well as the specification of a simple and cost-effective method for the production thereof. The object is attained with membranes comprising a substrate on which a porous supporting layer is arranged, on which supporting layer a separation-active layer is arranged, and on which separation-active layer a cover layer is also arranged, wherein the material of the separation-active layer comprises functional groups which primarily have carbon-carbon triple bonds and/or carbon-nitrogen triple bonds, and wherein the material of the cover layer has functional groups which are primarily at least azide groups, and the functional groups having at least carbon-carbon triple bonds and/or carbon-nitrogen triple bonds are chemically coupled covalently with the azide groups.

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31-01-2019 дата публикации

THIN FILM CAPACITORS

Номер: US20190035556A1
Принадлежит:

Dielectric capacitors including dielectric compositions with high dielectric constant, low dielectric loss, and high thermal stability are disclosed. The dielectric compositions can include a dipolar polymer having a high glass transition temperature (e.g., T>150° C.) in combination with either (i) another dipolar polymer having a high glass transition temperature (e.g., T≥150° C.) in the form of a blend, or (ii) the dipolar polymer with an inorganic interfacial agent volume content less than 2 vol % in the dielectric composition. 1. A dielectric capacitor comprising a dielectric composition comprising either (i) a blend of at least two dipolar polymers , each having a glass transition temperature (T) of at least 150° C. , and/or (ii) a dipolar polymer having a Tof at least 150° C. with an interfacial agent at less than 2 vol % , wherein dielectric composition has a dielectric constant higher than 25% of the constituent dipolar polymer and a dielectric loss less than 0.01 from −50° C. to temperatures below the Tof the dipolar polymer.2. The dielectric capacitor of claim 1 , comprising the blend and wherein the blend has a dielectric constant higher than 40% of any constituent dipolar polymer.3. The dielectric capacitor of claim 1 , wherein the dipolar polymer is one or more of: meta-phenylene polyurea (meta-PU) claim 1 , poly(arylene ether urea) (PEEU) claim 1 , aromatic polyurea (ArPU) claim 1 , aromatic polythiourea (ArPTU) claim 1 , Polycarbonate (PC) claim 1 , Polyetheretherketone (PEEK) claim 1 , Polyetherimide (PEI) claim 1 , Polyimide (PI) claim 1 , Polyether sulfone (PES) claim 1 , Polyphenylsulfone (PPSU) claim 1 , Polysulfone (PSU) claim 1 , Polybenzimidazole (PBI) claim 1 , Poly(phthalazinone ether ketone) (PPEK) claim 1 , or combinations thereof.4. The dielectric capacitor of claim 1 , wherein the blend of dipolar polymers include polymer A with polymer B and wherein polymer A is selected from meta-phenylene polyurea (meta-PU) claim 1 , poly(arylene ...

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12-02-2015 дата публикации

ORGANIC SEMICONDUCTING POLYMERS

Номер: US20150041727A1
Принадлежит: Merck Patent GmBH

The invention relates to novel organic semiconducting polymers containing one or more monomers derived from s-indacene fused symmetrically on each terminus with dithieno[3,2-b;2′,3′-d]thiophene (IDDTT), cyclopenta[2,1-b;3,4-b′]dithiophene (IDCDT), or derivatives thereof, to methods for their preparation and educts or intermediates used therein, to polymer blends, mixtures and formulations containing them, to the use of the polymers, polymer blends, mixtures and formulations as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these polymers, polymer blends, mixtures or formulations. 2. Polymer according to claim 1 , characterized in that in the units of formula I Xand Xdenote S.4. Polymer according to claim 1 , characterized in that in the units of formula I Rdenote straight-chain claim 1 , branched or cyclic alkyl with 1 to 30 C atoms which is unsubstituted or substituted by one or more F atoms claim 1 , or denote aryl or heteroaryl that is substituted by one or more straight-chain claim 1 , branched or cyclic alkyl groups with 1 to 30 C atoms claim 1 , in which one or more non-adjacent CHgroups are optionally replaced by one or more non-adjacent CHgroups are optionally replaced by —O— claim 1 , —S— claim 1 , —C(O)— claim 1 , —C(O)—O— claim 1 , —O—C(O)— claim 1 , —O—C(O)—O— claim 1 , —NR— claim 1 , —SiRR— claim 1 , —CF— claim 1 , —CHR═CR— claim 1 , —CY═CY— or —C≡C— in such a manner that O and/or S atoms are not linked directly to one another claim 1 , and in which one or more H atoms are optionally replaced by F claim 1 , Cl claim 1 , Br claim 1 , I or CN.8. Polymer according to claim 5 , characterized in that it is selected from the following formulae{'br': None, 'sup': 1', '2', '3, 'sub': x', 'y', 'n, '*—[(Ar—U—Ar)—(Ar)]—*\u2003\u2003IVa'}{'br': None, 'sup': 1', '2', '3', '3, 'sub': x', 'y', 'n, '*—[(Ar—U—Ar)—(Ar—Ar)]—*\u2003\u2003IVb'}{' ...

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07-02-2019 дата публикации

POLYPHENYLENE SULFIDE RESIN COMPOSITION AND MANUFACTURING METHOD OF THE SAME

Номер: US20190040256A1
Принадлежит:

A polyphenylene sulfide resin composition is obtained by mixing a polyphenylene sulfide resin (a), a fluororesin (b) and an organosilane compound (c). When a resin phase-separated structure of a molded product formed from the polyphenylene sulfide resin composition is observed by an electron microscope, the component (a) forms a continuous phase, the component (b) forms a primary dispersed phase having a number-average dispersion diameter of not greater than 1 μm, and a secondary dispersed phase of the component (a) is included in the primary dispersed phase of the component (b). 18-. (canceled)9. A polyphenylene sulfide resin composition obtained by mixing a polyphenylene sulfide resin (a) , a fluororesin (b) and an organosilane compound (c) , whereinwhen a resin phase-separated structure of a molded product formed from the polyphenylene sulfide resin composition is observed by an electron microscope, the component (a) forms a continuous phase, the component (b) forms a primary dispersed phase having a number-average dispersion diameter of not greater than 1 μm, and a secondary dispersed phase of the component (a) is included in the primary dispersed phase of the component (b).10. The polyphenylene sulfide resin composition according to claim 9 , wherein the component (b) is a reactive functional group-containing fluororesin.11. The polyphenylene sulfide resin composition according to claim 9 , wherein the component (b) is an ethylene tetrafluoroethylene copolymer.12. The polyphenylene sulfide resin composition according to claim 9 , wherein the component (a) is a carboxyl group-containing polyphenylene sulfide resin having a content of a carboxyl group not lower than 25 μmol/g and not higher than 400 μmol/g.13. The polyphenylene sulfide resin composition according to claim 9 , wherein the component (a) has a weight-average molecular weight not less than 30000 and not greater than 150000.14. The polyphenylene sulfide resin composition according to claim 9 , wherein ...

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06-02-2020 дата публикации

REACTOR

Номер: US20200040111A1
Принадлежит:

A polymerization device that includes: a reaction vessel that houses a polymerization solution and in which a polymerization reaction is performed; a stirring blade that stirs the polymerization solution housed in the reaction vessel; a plurality of heat transfer pipes that transfer heat to the polymerization solution in order to start the polymerization reaction and cause the polymerization reaction to proceed, and that remove, from the polymerization solution, heat generated by the polymerization reaction; and a baffle arranged between a vessel wall of the reaction vessel and the heat transfer pipes. 1. A manufacturing method for a reaction product comprising:housing a polymerization solution in a reaction vessel in which a polymerization reaction is performed;stirring the polymerization solution housed in the reaction vessel using a stirring blade;transferring heat to the polymerization solution in order to start the polymerization reaction and cause the polymerization reaction to proceed, and to remove, from the polymerization solution, heat generated by the polymerization reaction using a plurality of heat transfer pipes; whereinthe plurality of heat transfer pipes are arranged in a circumferential shape around the stirring blade, include a heat transfer pipe whose lower end is arranged in a position higher than a bottom face of the reaction vessel, and restrict an amount of the polymerization solution circulated from an inner side to a vessel wall side of the reaction vessel, at a depth at which the heat transfer pipes are arranged,the method further comprising changing a flow direction of the polymerization solution that has flowed between the vessel wall of the reaction vessel and the heat transfer pipes arranged in the circumferential shape using a baffle arranged between a vessel wall of the reaction vessel and the heat transfer pipes, thereby generating a flow of the polymerization solution to an inward direction of the reaction vessel, and whereinthe ...

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06-02-2020 дата публикации

Polymer composition

Номер: US20200040137A1
Принадлежит: Kyushu University NUC, Nissan Chemical Corp

wherein definition of the symbols are as described in the DESCRIPTION.

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06-02-2020 дата публикации

FLUORINATED COPOLYMER COMPOSITION

Номер: US20200040173A1
Принадлежит:

A fluorinated copolymer composition includes a thermoplastic resin A and a fluorinated elastomer B dispersed within thermoplastic resin A. Thermoplastic resin A has a shear stress (τ) of greater than 0.11 MPa when measured with a capillary rheometer at a shear rate of 243 secand at 360° C. in accordance with ASTM D3835. Fluorinated elastomer B dispersed within thermoplastic resin A has an average dispersed particle size of less than 50 μm. 1. A fluorinated copolymer composition comprising:{'sub': 'A', 'sup': '−1', 'a thermoplastic resin A having a shear stress (τ) of greater than 0.11 MPa when measured with a capillary rheometer at a shear rate of 243 secand at 360° C. in accordance with ASTM D3835; and'}a fluorinated elastomer B dispersed within thermoplastic resin A and having an average dispersed particle size of less than 50 μm.2. The fluorinated copolymer composition as set forth in wherein thermoplastic resin A is at least one melt-moldable claim 1 , heat-resistant thermoplastic resin selected from the group consisting of a polyarylate claim 1 , a polyether sulfone claim 1 , a polyaryl sulfone claim 1 , an aromatic polyamide claim 1 , an aromatic polyether amide claim 1 , an aromatic polyether imide claim 1 , a polyphenylene sulfide claim 1 , a polyaryl ether ketone claim 1 , a polyamideimide and a liquid crystal polyester.3. The fluorinated copolymer composition as set forth in wherein fluorinated elastomer B comprises units derived from at least one monomer selected from the group consisting of tetrafluoroethylene claim 2 , hexafluoropropylene claim 2 , vinylidene fluoride and chlorotrifluoroethylene.4. The fluorinated copolymer composition as set forth in having a flexural modulus of from 1 claim 1 ,000 to 3 claim 1 ,700 MPa.5. The fluorinated copolymer composition as set forth in wherein the ratio of the viscosity of thermoplastic resin A to fluorinated elastomer B is greater than 0.35 when the viscosity is measured with a capillary rheometer at a shear ...

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18-02-2021 дата публикации

Fast-cure resin formulations with consistent handling characteristics

Номер: US20210047460A1
Принадлежит: Cytec Industries Inc

The present invention relates to rapid-curing resin formulations as well as fiber-reinforced composite materials comprising the same and their use in the manufacture of molded articles, particularly where the manufacturing process requires high throughput and where resin formulations having consistent handling characteristics (e.g., tack and flexibility) would be preferable across normal to elevated laminating environments (as defined by temperatures between 20° C. and 60° C.). The present invention further relates to a manufacturing process for preparing an article, particularly a molded article, from a fiber-reinforced composite material comprising a rapid-curing resin formulation.

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18-02-2021 дата публикации

High Molecular Weight Polyphenylene Sulfide Resin, Preparation Method and Use Thereof

Номер: US20210047471A1

The disclosure relates to a high molecular weight polyphenylene sulfide resin and a preparation method and application thereof. The disclosure uses a sulfur-containing compound and a halogenated aromatic compound as raw materials, an alkaline compound and a fatty acid as polycondensation aids to carry out a polycondensation reaction. After purification treatment, a primary polyphenylene sulfide is obtained. Then, the primary polyphenylene sulfide reacts with a chain extender at a high temperature to form a high molecular weight polyphenylene sulfide resin. The preparation method of the disclosure has the advantages of high yield, low cost, and is capable of selectively and controllably preparing polyphenylene sulfide resins with different melt viscosities and molecular weights, and the obtained polyphenylene sulfide resins have excellent heat resistance. The linear high molecular weight polyphenylene sulfide resin with high thermal stability obtained by the disclosure can be used for producing plates, pipes and rods, can be mechanically processed like metals, such as cutting, grinding, polishing, drilling, and can be used to produce fibers, membranes, films, and especially are applicable to automotive parts, electronic/electrical equipment, chemical and machinery industry.

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15-02-2018 дата публикации

MISCIBLE POLYPHENYLENE ETHER SULFONE/POLYALKYLENE TEREPHTHALATE BLENDS

Номер: US20180044524A1
Принадлежит:

Described herein is a composition comprising a polymer blend. The polymer blend comprises 92 to 99 weight percent of a polyphenylene ether sulfone and 1 to 8 weight percent of a polyalkylene terephthalate, wherein weight percent is based on the combined weight of the polyphenylene ether sulfone and polyalkylene terephthalate. The polymer blend has a transmittance greater than or equal to 60% and a haze less than or equal to 10% at a thickness of 3.2 millimeters, as determined according to ASTM D1003. 2. The composition of claim 1 , wherein the polyphenylene ether sulfone comprises greater than or equal to 90 mol % of repeating units of formula (1).3. The composition of claim 1 , wherein the polyalkylene terephthalate comprises a polyethylene terephthalate claim 1 , a polycyclohexane dimethanol terephthalate claim 1 , a polycyclohexane dimethanol-ethylene glycol terephthalate copolymer or a combination comprising at least one of the foregoing.4. The composition of claim 1 , wherein the polyalkylene terephthalate is a polyethylene terephthalate having a diethylene glycol content of 0.1 to 4 weight percent based on the weight of the polyethylene terephthalate claim 1 , an intrinsic viscosity greater than 0.4 and less than 0.90 dl/g and 5 to 100 meq/kg of carboxylic acid end groups.5. The composition of claim 1 , wherein the polyphenylene ether sulfone has a weight average molecular weight of 10 claim 1 ,000 to 90 claim 1 ,000.6. The composition of claim 1 , wherein the polyphenylene ether sulfone is present in an amount of 95 to 99 weight percent and the polyalkylene terephthalate is present in an amount of 1 to 5 weight percent.7. The composition of claim 1 , wherein the polyphenylene ether sulfone is present in an amount of 95 to 97 weight percent and the polyalkylene terephthalate is present in an amount of 3 to 5 weight percent.8. The composition of claim 1 , wherein the polymer blend has a single glass transition temperature and no melting temperature as ...

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08-05-2014 дата публикации

Reinforcing material for solid polymer fuel cell, and cohesive/adhesive composition for use in same

Номер: US20140127608A1
Принадлежит: DAI NIPPON PRINTING CO LTD

There is provided a reinforcing material equipped with a cohesive/adhesive layer, having a proper initial adhesion force to an adherend, such as an electrolyte membrane, a catalyst layer and a gas diffusion layer, and which can be temporarily fixed readily. A reinforcing material produced by forming a cohesive/adhesive layer on a substrate. The cohesive/adhesive layer includes an aliphatic polyamide, an epoxy resin and a polythiol. When the reinforcing material is used, it becomes possible to correct the position of an adherend after the adhesion of the reinforcing material to the adherend. In addition, it can prevent the formation of wrinkles on the adherend or the like upon the adhesion of the reinforcing material. Therefore, a catalyst layer laminated membrane or the like which has a reinforcing material attached thereto can be produced readily without requiring the employment of any highly skilled technique.

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14-02-2019 дата публикации

Rubber Composition for Tires

Номер: US20190048174A1
Принадлежит:

Provided is a rubber composition containing from 1 to 50 parts by mass of an organic microparticle having an average particle size of 0.001 to 100 μm and having a crosslinked structure per 100 parts by mass of a diene rubber, the organic microparticle being a crosslinked microparticle of a copolymer formed from at least two types of segments having repeating units that are different each other, the at least two types of segments being formed from an oligomer or prepolymer having a functional group and having a molecular weight of 500 to 20000, and the functional group forming a crosslinked structure between the at least two types of segments. 1. A rubber composition for a tire , comprising from 1 to 100 parts by mass of an organic microparticle having an average particle size of 0.001 to 100 μm and having a crosslinked structure per 100 parts by mass of a diene rubber ,the organic microparticle being a crosslinked microparticle of a copolymer formed from at least two types of segments having repeating units that are different each other,the at least two types of segments being formed from an oligomer or prepolymer having a functional group and having a molecular weight of 500 to 20000, andthe functional group forming a crosslinked structure between the at least two types of segments.2. The rubber composition for a tire according to claim 1 , wherein at least one of the segments further has at least one selected from the group consisting of a sulfur atom claim 1 , a mercapto group claim 1 , a thioether bond claim 1 , and a polysulfide bond.3. The rubber composition for a tire according to claim 1 , further comprising from 1 to 100 parts by mass of carbon black and/or a white filler per 100 parts by mass of the diene rubber.4. The rubber composition for a tire according to claim 1 , wherein the crosslinked structure of the organic microparticle is a crosslinked structure formed by allowing the functional group to crosslink in between the at least two types of segments ...

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14-02-2019 дата публикации

Polymer composition containing a cycloalkyl alkyl dicarboxylic acid diester as a plasticizer

Номер: US20190048179A1
Принадлежит: BASF SE

The present invention relates to a polymer composition comprising a cycloalkyl alkyl dicarboxylic diester as plasticizer, to molding compositions and plastisols each comprising such a polymer composition, and to the use of these polymer compositions.

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