25-03-2021 дата публикации
Номер: US20210086312A1
The present invention relates to an article comprising a ceramic substrate () comprising a source of zirconium oxide; a metallic substrate (); and a braze joint disposed between the ceramic substrate and the metallic substrate. The braze joint comprises (i) a gold rich phase () interfacing against a surface of the ceramic substrate. The gold rich phase comprises a refractory metal selected from the group consisting of molybdenum, tungsten, niobium, tantalum and combinations thereof; and (ii) a second metallic phase () comprising a metal selected form the group consisting of nickel, iron, vanadium, cobalt, chromium, osmium, tantalum or combinations thereof. 1. An article comprising:{'b': '310', 'a. a ceramic substrate () comprising a source of zirconium oxide;'}{'b': '320', 'b. a metallic substrate (); and'}c. a braze joint disposed between the ceramic substrate and the metallic substrate, [{'b': '330', '(iii) a gold rich phase () interfacing against a surface of the ceramic substrate, said gold rich phase comprises a refractory metal selected from the group consisting of molybdenum, tungsten, niobium, tantalum and combinations thereof; and'}, {'b': '340', '(iv) a second metallic phase () comprising a metal selected form the group consisting of nickel, iron, vanadium, cobalt,'}], 'wherein the braze joint compriseschromium, osmium, tantalum or combinations thereof.2. The article according to claim 1 , wherein the source of zirconium oxide has the formula:{'br': None, 'sub': '2-x', 'ZrOwhere x is greater than 0.'}3. The article according to claim 1 , wherein the source of zirconium oxide further comprises yttria claim 1 , magnesia claim 1 , scandia claim 1 , alumina claim 1 , calcia or ceria.4. The article according to claim 1 , wherein the source of zirconium oxide is selected from the group consisting of zirconia claim 1 , yttria stabilised zirconia claim 1 , magnesia stabilised zirconia claim 1 , scandia stabilized zirconia claim 1 , calcia stabilised zirconia claim ...
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