10-01-2019 дата публикации
Номер: US20190009252A1
The present invention relates to catalyst compositions containing a mixed oxide catalyst of formula (I) or formula (II) as described herein, their preparation, and their use in a process for ammoxidation of various organic compounds to their corresponding nitriles and to the selective catalytic oxidation of excess NHpresent in effluent gas streams to Nand/or NO. 1. A catalyst composition comprising a mixed oxide catalyst of formula (I) or (II):{'br': None, 'sub': 12', 'a', 'b', 'c', 'd', 'e', 'f', 'h, 'sup': 1', '2', '3', '4', '5', '6, 'MoXXXXXXO\u2003\u2003(I)'}{'br': None, 'sub': i', 'j', 'k', 'm', 'n', 'q', 'x', 'y', 'r, 'FeMoCrBiMNQXYO\u2003\u2003(II)'} [{'sup': '1', 'Xis Cr and/or W;'}, {'sup': '2', 'Xis Bi, Sb, As, P, and/or a rare earth metal;'}, {'sup': '3', 'Xis Fe, Ru, and/or Os;'}, {'sup': '4', 'Xis Ti, Zr, Hf, B, Al, Ga, In, TI, Si, Ge, Sn, and/or Pb;'}, {'sup': '5', 'Xis Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Mn, Re, V, Nb, Ta, Se, and/or Te;'}, {'sup': '6', 'Xis an alkaline earth metal and/or an alkali metal;'}, '0≤a≤5;', '0.03≤b≤25;', '0≤c≤20;', '0≤d≤200;', '0≤e≤8;', '0≤f≤3; and', 'h is the number of oxygen atoms required to satisfy the valence requirements of the component elements other than oxygen present in formula (I), where', '1≤c+d+e+f≤200;', '0≤e+f≤8; and, 'wherein in the formula (I) M is Ce and/or Sb;', 'N is La, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, B, Al, Ga, In, TI, Si, Ge, Sn, Pb, P, and/or As;', 'Q is W, Ru, and/or Os;', 'X is Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Mn, Re, V, Nb, Ta, Se, and/or Te;', 'Y is an alkaline earth metal and/or an alkali metal;', '0.2≤i≤100;', '0≤j≤2;', '0≤k≤2;', '0.05≤m≤10;', '0≤n≤200;', '0≤q≤8;', '0≤x≤30;', '0≤y≤8;', 'j and kj; and', 'r is the number of oxygen atoms required to satisfy the valence requirements of the component elements other than oxygen present in formula (II),, 'wherein in the formula (II) 4≤m+n+q+x+y≤200;', '0≤q+x+y≤30; and, 'wherein{'sup ...
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