HIGH GLOSS ABS SHEET WITH IMPROVED SURFACE ROUGHNESS AND MANUFACTURING METHOD THEREOF
ABS processed by a hydrophilic treatment is the present invention refers to the surface of the substrate, a water-soluble polymer (3,4-ethylenedioxythiophene)-polystyrene [...] intermediate layer of poly (vinylidene fluoride-trifluoro ethylene) provided with a fluorine-based resin layer by efficiency can be significantly improved surface roughness and of the plate has a glossiness of improved ABS sheet of relates to manufacturing method. Consumer indoor as well as improved performance of the motor vehicle desired until original track interior of wet liquid to flow down. Intermittent aeration, deoderization, agitating and an indoor interior original track plays the role is crucial to make. Make use of in particular provides a high-gloss fixed plate decorations is provided to no temperature gradients occur inside the indoor controls the whole operation of the consumer satisfaction level can be construction work and team. An exemplary a message of a typical acrylonitrile butadiene styrene (ABS) material of interior material injection predetermined size in a rough-surfaced. away of the plate has a glossiness of due to. Of brightening agent for ABS to overcome problem of, polyurethane material ABS for double-coating paint gloss family of (2coat) embodiment of a method of wet liquid to flow down. Furthermore, Korean opening patent 2010-0106714 call (patent document 1) ABS on one surface of the decorative films formed sheet metal layers, said ABS sheet on top fluorine-containing acrylate copolymer hard including the application of the coating composition and curing the method is the gloss for producing panels is disclosure. Said patent document 1 used in a fluorine-based acrylate copolymer 3 functional group or more acrylate resin framework fluorine (backbone) substituted compounds is introduced into the copolymers. As an error signal occurred, method conventional ABS material is applied in a polish in at components to increase softness further provided with a fluorine-based resin or urethane resin coating method been is applied. Provided with a fluorine-based resin coating a general method [...] artworking method powder coating at coating solution. Said powder coating the fluorine-containing resin powder onto subjects for a water high temperature heat treatment a form coating films by sintering a through. However it will be noted that we have polymer generally including ABS melting point body since point lower than room temperature, is thermally treated, it will be noted that we have polymer the powder coating mainly it will be noted that we have a metal than are used coating method. Said provided with a fluorine-based resin coating solution onto subjects oral admisnistration a solvent is coated on a carrier film to provide a coating film method in, lower temperature conditions power device is unit is off. However, to a point where the solvent is provided with a fluorine-based resin dissolving resistant to polarity, it will be noted that we have polymer generally including ABS direct overlap of an object beam and a n applying a coating method solution. limit. It will be noted that we have a polar solvent to the ABS by head side grooveless segment 21 dissolution body and which do not dissolve in a polar solvent to hydrophilic middle or intermediate ply is. required. I.e., hydrophobic indicative of ABS on the surface body it will be noted that we have hydrophilic thin film formation is desired to the driving direction and speed of, . material is used mainly UV ozone treatment. However, scratches on the surface substrate ABS UV ozone processing to get a gloss the photodiode to control more surface roughness suited to the coating do not go for. In the present invention the diffusion of P increased of the plate has a glossiness of at high gloss ABS sheet, intended for. Furthermore, series of coating process in the present invention ABS substrate of the surface roughness increase the gloss data and gate lines, each with a different provides method, intended. The for additional bus cycles besides for said, in the present invention ABS substrate, the polysilicon layer is (3,4-ethylenedioxythiophene)-polystyrene [...] and intermediate film is formed, said intermediate film, the polysilicon layer is of (vinylidene fluoride-trifluoro ethylene) provided with a fluorine-based resin layer is formed by coating a provides characterized by gloss ABS sheet. In addition said for for additional bus cycles besides, in the present invention ABS substrate surfactant solution of a hydrophilizing surface of the substrate number 1 process; a surfactant coating and drying washed with distilled ABS substrate number 2 process; ABS substrate, the polysilicon layer is dried (3,4-ethylenedioxythiophene)-styrene sulfonate (PEDOT-PSS) intermediate layer coated on the number 3 process ;, the polysilicon layer is film and intermediates (vinylidene fluoride-trifluoro ethylene) of fluorine-based polymeric solution coating process number 4 ; characterized by including a gloss ABS sheet to provides manufacturing method. According to the present invention, polyurethane coating of to instead of performing a carrier for painting vehicle body, provided with a fluorine-based resin coating high gloss are formed on plastic ABS down. High gloss ABS sheet producing intermittent aeration, deoderization, agitating and in the present invention, is useful as a material. Figure 1 ABS substrate to come in contact with the of before coating surfactant film on the surface of the negative is electrophotographic for comparing a voltage obtained. Figure 2 shows a embodiment of then surfactant coating also according to whether, compares of brightening agent for substrate surface ABS is of graph. According to P (VDF-TrFE) also Figure 3 shows a concentration of solution is of graph compares change gloss. Made in Figure 4 in the embodiment 1 of 1 bear ABS ABS sheet compared e.g. with respect to the substrate 60 is of graph compares change gloss [...]. Made in Figure 5 in the embodiment 1 of 1 bear ABS ABS sheet compared e.g. with respect to the substrate is of graph compares change surface roughness. Made in Figure 6 in the embodiment 1 of 1 bear ABS ABS sheet compared e.g. with respect to the substrate is electrophotographic comparing the signal-to-contact angle droplets. The present invention refers to surface roughness increased of the plate has a glossiness of data and gate lines high gloss ABS sheet of relates to manufacturing method. The present invention according to sheet gloss ABS, ABS substrate, the polysilicon layer is (3,4-ethylenedioxythiophene)-styrene sulfonate (hereinafter, 'PEDOT-PSS' by) and intermediate film is formed, said intermediate film, the polysilicon layer is (vinylidene fluoride-trifluoro ethylene) (hereinafter, by' P (VDF-Tree) ') of formed layer provided with a fluorine-based resin I.e., provided with a fluorine-based resin directly onto the substrate in the present invention ABS instead coating layer, a polymer layer is hydrophilic PEDOT-PSS by intermediate film one of the at least two, low surface roughness and compared to ABS substrate simultaneously improving their brightness is the. Manufacturing method of the present invention according to course included in gloss ABS plastic sheet such as non-contact resistance, easy to equal. Number 1 process, on the substrate at a ABS ABS substrate is coated with surfactant solution surface characteristics of skin through hydrophobic from hydrophilic into the stuffing box and acts is process to change a. Understructure identified from the picture of of Figure 1, the coating surfactant solution substrate ABS ABS processed substrate droplets-adsorbers method of contact angle between, thereby been hydrophilizing medium is ABS can be viewed. General hydrophilization treatment method is compared for high strength wire and plate and even a UV, coated with surfactant ABS substrate is hydrophilic more maintains line is set up. ABS substrate surfactant solution results in processing performance to the surface of glass method specifically for, ABS substrate which solution of surfactant, the surfactant include sodium use of Saccharomyces cerevisiae [...] specific gravity of 0.50 to 1.29 g, distilled water paste has better mouth feeling and 0.5-3 weight % mixing 30 minute or more preparation of a solution of a surfactant at a level, the third to eo. In the present invention embodiment a coating used to monitor the field on winter embodiment have been performed by a method, for example spin coater using 3000 rpm from 500 rpm until sequentially speed up while surfactant solution coated. Number 2 process, a surfactant coating ABS in distilled water having substrate having a selected drying which washes the.. I.e., the roughened due to surfactant coating in order to improve the substrate surface ABS, . having a selected cleaning in distilled water having flowing. Said cleaning intensity of distilled, but approximately there is a difference or the like 20 seconds to 1. suitable minutes. Thus washed with distilled water, at a temperature in the range 40-60 °C ABS substrate drying to 10-60 minutes. Also 2 the surfactant coating according to whether embodiment of then, the comparing the ABS showed of brightening agent for substrate surface. Also according to 2, further the cleaning procedure distilled ABS substrate embodiment a low surface roughness and of the plate has a glossiness of the implant is also more can be the output insurance document. Number 3 by coating the lens polymer solution PEDOT-PSS process, is intermediate layer. I.e., ABS on the surface of a substrate a surfactant coating PEDOT: PSS coating is water-soluble polymer. ABS substrate with a surfactant coating pre-process the stuffing box and acts as a hydrophilizing in the body, PEDOT: PSS of water-soluble polymer a polymer layer is water-soluble dispersed into a polar can be formed may be screen. The coating used to monitor the field on winter PEDOT-PSS embodiment have been performed by a method, for example spin coater using 3000 rpm from 500 rpm until sequentially speed up while surfactant solution coated. Number 4 fluorine-based process is coating polymeric solution. Said fluorine-based polymer include weight average molecular weight of 10,000 or more, preferably weight average molecular weight of 50,000-1,000,000 the first voice portion out of an P (VDF-TrFE) range. P (VDF-TrFE) a polarity as the solvent 2-butanone nitride, which in turn are dissolved in rice field point, viscosity index, oxidation stability, preferably at a temperature 80-90 °C 1 temporal extent 400 rpm at a speed of predetermined chemical the agitated nitride, which in turn are dissolved, the third to eo. The concentration of said fluorine-containing polymer solution within a range from 1-8 weight % on, preferably within a range from 2-7% weight concentration use an. ABS said P (VDF-TrFE) on a substrate the speed at which the solution of 1500-4500 rpm, preferably holds the 3000-4500 rpm. Generally coating speed is increased though the-adsorbers visible a tendency for the increased gloss, coating speed 3000 rpm or more at least 90% of the plate has a glossiness of a mean water level in made of a extremely improved showed. Also according to the concentration of solution P (VDF-TrFE) 3 gloss change is compared of graph. I.e., 3500 rpm coating rate ABS on a substrate when solution of P (VDF-TrFE), each weight fluorine-based polymer solution concentration of 1%, 3% weight, coating metal to 7.5 weight % and compared their brightness. Also 3 P (VDF-TrFE) solution according to 3 weight % concentration of at least 95% gloss when best. to have undergone an aspect. The present invention refers to such as taught or more of the following in the embodiment and comparison it should bar described pulsating current is based aspect, the present invention the limited not. In the embodiment 1. 1) surfactant coating process ABS of 5 cm x 5 cm shown substrate. Sodium use of Saccharomyces cerevisiae [...] (sigma- [...] yarn product) distilled a 30 minute or more mixing paste has better mouth feeling and 3 weight % concentration of surfactant solution results manufacturing processes and the cost of production. Said ABS is solution of surfactant substrate, spin coater using → 3000 rpm 500 rpm → 1000 rpm sequentially speed up while surfactant solution coated. 2) distilled water washing and drying process Surface roughened by surfactant coating in order to improve the, 30 seconds in distilled water having flowing ABS was for cleaning substrates. Distilled water washed with ABS substrate 10 minutes in 50 °C using hot plate was chemical. 3), the duration of the process of intermediate film soluble polymer PEDOT: PSS polymer (Heraeus yarn product of Germany) a 0.45 micro m standard syringes is filtered in a filter (a communication network and downloads one: advantec), the third to eo the coating solution. Said ABS on the substrate at a PEDOT: PSS is solution of coating, spin coater using → 3000 rpm 500 rpm → 1000 rpm sequentially speed up while PEDOT: PSS laminated silicate coated. 4) provided with a fluorine-based resin film, the duration of the process of Fluorine-based polymer P (VDF-TrFE) in 200,000 weight average molecular weight (of French piezotech yarn product) the first voice portion out of an. A P (VDF-TrFE) 2-butanone (sigma-aldrich yarn product 99.7% purity) dissolving in out 3 weight % concentration solutions. ABS said P (VDF-TrFE) on a substrate using spin coater solution coated the coatings speed 3500 rpm. Alcohol to the glycolide monomer at said ABS sheet gloss, surface roughness, contact angle is greater than a predetermined to table 1 showed the clip to. Compared example 1. Compares e.g. ABS substrate 1 to 5 cm x 5 cm of corresponding advertisement based on the shown list, the bear ABS was 1 table a-time. Bear ABS of gloss, surface roughness, contact angle is greater than a predetermined to table 1 showed the clip to. Compared e.g. 2-4. Said in the embodiment 1 according to ABS sheet may be carried out at an, after the surfactant coating fender of a the cleaning procedure distilled. example. And, compared e.g. ABS coated intermediate film soluble polymer in 2-4 on the substrate at a concentration of 3 weight % provided with a fluorine-based resin solution of the, coating (compared e.g. 2) 3000 rpm each speed, 3500 rpm (compared e.g. 3), 5000 rpm (compared e.g. 4) change, coated. Compared e.g. 2-4 alcohol to the glycolide monomer at said ABS sheet gloss, surface roughness, contact angle is greater than a predetermined to table 1 showed the clip to. Compared e.g. 5-7. Said in the embodiment 1 according to ABS sheet may be carried out at an, provided with a fluorine-based resin solution anti-in coating and varies the speed and coating concentration the coated. I.e., compared e.g. the 5% weight 3 provided with a fluorine-based resin concentration of the preparation of a solution of → 3500 rpm 500 rpm → 1000 rpm → 2000 rpm while increasing speed coated step 4 of coating is an example for producing sheets of ABS. The 6% weight 1 compared e.g. provided with a fluorine-based resin concentration of the preparation of a solution of 3500 rpm while maintaining the coating speed for producing sheets of ABS by coating is an example. The 7.5 weight % compared e.g. 7 provided with a fluorine-based resin concentration of the preparation of a solution of 3500 rpm while maintaining the coating speed for producing sheets of ABS by coating is an example. Alcohol to the glycolide monomer at 5-7 e.g. compared said ABS sheet gloss, surface roughness, contact angle is greater than a predetermined to table 1 showed the clip to. Furthermore, also 4,5 and also in Figure 6 1 e.g. comparison in the embodiment 1 of a produced in substrate and Bear ABS ABS against the seat 60 [...] gloss change, surface roughness change, and water drop contact angle is greater than a predetermined and compared results. As a result of the comparing the gloss also Figure 4 shows a, of light emitted from at least the ABS on the surface of a substrate in the embodiment 1 a produced in ABS forward 13% average of the plate has a glossiness of sheet. been improved. Figure 5 shows a 30x30 using AFM also to obtain an Image from the surface of the surface roughness value of the adaptation seams 5 also calculates a root mean square (rms). A surface roughness average 59% .been improved. Figure 6 as of the result of comparison between the contact angle droplets, surface hydrophobic. been improved. The present invention relates to an ABS sheet with improved surface roughness and gloss, by laminating an intermediate film of poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate and a fluorine-based resin film of poly(vinylidene fluoride-trifluoroethylene) in order, on a hydrophilic-treated ABS substrate surface; and to a manufacturing method thereof. The ABS sheet of the present invention is useful as an interior component material of a vehicle required for high gloss. COPYRIGHT KIPO 2016 ABS substrate, the polysilicon layer is (3,4-ethylenedioxythiophene)-polystyrene [...] and intermediate film is formed, said intermediate film, the polysilicon layer is of (vinylidene fluoride-trifluoro ethylene) provided with a fluorine-based resin layer is formed by coating a gloss characterized by ABS sheet. According to Claim 1, said ABS substrate characterized by hydrophilizing treatment with the use of gloss ABS sheet. According to Claim 1, said ABS substrate further coating the coated surfactant solution results in, distilled water to the cleaning and drying a gloss characterized by hydrophilizing treatment with the use of ABS sheet. ABS substrate surfactant solution of a hydrophilizing surface of the substrate number 1 process; a surfactant coating and drying washed with distilled ABS substrate number 2 process; ABS substrate, the polysilicon layer is dried (3,4-ethylenedioxythiophene)-styrene sulfonate (PEDOT-PSS) intermediate layer coated on the number 3 process ;, the polysilicon layer is film and intermediates (vinylidene fluoride-trifluoro ethylene) of fluorine-based polymeric solution coating process number 4 ; to gloss ABS sheet manufacturing method characterized by including a. According to Claim 4, said surfactant solution to an aqueous solution having a sodium use of Saccharomyces cerevisiae [...] manufacturing method characterized by gloss ABS sheet. According to Claim 4, the drying said performing, at a temperature in the range 40-60 °C characterized by gloss ABS sheet manufacturing method. According to Claim 4, said fluorine-based polymer solution concentration is 1-8 weight % and, characterized by a coated 1500-4500 rpm speed coating gloss ABS sheet manufacturing method. According to Claim 7, said fluorine-based polymer solution concentration is 2-5 weight % and, characterized by a coated 3000-4500 rpm speed coating gloss ABS sheet manufacturing method. Number 1 anti to number 3 anti more absorbents selected from the gloss terms using ABS for car interior. Opening ingredient In the embodiment 1 Compared e.g. 1 2 3 4 5 6 7 Provided with a fluorine-based resin Concentration (wt %) 3 Bare ABS 3 3 3 3 1 7.5 Coating speed (rpm) 3500 3000 3500 5000 3500 (4step) 3500 3500 Whether embodiment the cleaning procedure The embodiment is not embodiment is not embodiment is not embodiment The embodiment The embodiment The embodiment Gloss 96 85.4 58.8 55 71.0 65.6 62.3 72.9 Roughness (nm) 12.5 31.0 10.8 15.8 19.7 Not Not Out Average roughness (nm) 9.9 24.0 8.6 19.6 15.4 Not Not Out Contact angle (°) 85.6 78.3 - - - - - - Not: Out does not measure negative: measuring unavailability rms 300 nm or more
