28-01-2016 дата публикации
Номер: US20160027560A1
A barium titanate based PTC thermistor ceramic composition without using Pb. Its Curie temperature is shifted to a temperature higher than 120° C. The PTC thermistor can readily turn semiconductive even if it is sintered in air. The resistivity at 25° C. is low and the variation rate of the resistivity at 25° C. with time is little. The PTC thermistor ceramic composition includes a sintered body having a barium titanate based compound represented by formula (1) as the main component, (BaBiARE)(TiTM)O(1), wherein, 1.02y≦x≦1.5y (2), 0.007≦y≦0.125 (3), 0≦(w+z)≦0.01 (4), 0.97≦α≦1.06 (5), and the sintered body contains Ca in a ratio of 0.01 mol or more and less than 0.05 mol relative to 1 mol of Ti site in terms of element. 1. A PTC thermistor ceramic composition , comprising {'br': None, 'sub': 1-x-y-w', 'x', 'y', 'w', 'α', '1-z', 'z', '3, '(BaBiARE)(TiTM)O\u2003\u2003(1),'}, 'a sintered body comprising a barium titanate based compound represented by the following formula (1) as the main component,'}wherein, in the formula (1), A represents at least one element selected from the group consisting of Na and K,RE represents at least one element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Gd, Dy and Er,TM represents at least one element selected from the group consisting of V, Nb and Ta, [{'br': None, 'i': y≦x≦', 'y, '1.021.5\u2003\u2003(2)'}, {'br': None, 'i': 'y≦', '0.007≦0.125\u2003\u2003(3)'}, {'br': None, 'i': 'w+z', '0≦()≦0.01\u2003\u2003(4)'}, {'br': None, '0.97≦α≦1.06\u2003\u2003(5)'}], 'w, x, y, z and a satisfy the following inequations (2) to (5), in which, the units of w, x, y and z are all mole, and a represents the molar ratio of Ba site to Ti site,'}Ca is further contained in a ratio of 0.01 mol or more and less than 0.05 mol relative to 1 mol of Ti site in terms of element.2. The PTC thermistor ceramic composition of claim 1 , wherein claim 1 ,Si is further contained in the PTC thermistor ceramic composition in a ratio of 0.035 mol or less ...
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