10-04-2014 дата публикации
Номер: US20140097141A1
Принадлежит:
Methods for the synthesis of compounds of the formula AMSnS, where x has a value in the range from 0.5 to 1; A is Li, Na, K, or Rb; and M is Mg, Mn, Zn, or Fe, are provided. Also provided are methods of remediating fluid samples using the compounds. 1. A method for the synthesis of a compound of the formula AMSnS , where x has a value in the range from 0.5 to 1; A is Li , Na , Rb , or Cs; and M is Mg , Ca , Mn , Zn , or Fe , wherein the method is a solid state method comprising heating a reaction mixture of ACO , M , S and Sn to a temperature and for a time sufficient to produce the compound of the formula AMSnS , via a solid state reaction.2. The method of claim 1 , wherein the reaction mixture consists of ACO claim 1 , M claim 1 , S and Sn.3. The method of claim 1 , wherein heating the reaction mixture comprises heating the mixture to a temperature of no greater than about 1000° C. for a time of no greater than about 15 hours and further wherein the method provides a yield of the compound having the formula AMSnSof at least about 50% claim 1 , based on total mass.4. The method of claim 1 , further comprising ball milling the reaction mixture prior to heating.5. The method of claim 1 , wherein A is K and M is Mg.6. A method for the synthesis of a compound of the formula AMSnS claim 1 , where x has a value in the range from 0.5 to 1; A is Li claim 1 , Na claim 1 , Rb claim 1 , or Cs; and M is Mg claim 1 , Ca claim 1 , Mn claim 1 , Zn claim 1 , or Fe claim 1 , wherein the method is a hydrothermal method comprising heating a reaction mixture of ACO claim 1 , M claim 1 , S claim 1 , Sn and water to a temperature and for a time sufficient to produce the compound of the formula AMSnS claim 1 , via a hydrothermal reaction claim 1 , and further wherein heating the reaction mixture comprises heating the mixture to a temperature of no greater than about 250° C. for a time of no greater than about 10 hours and further wherein the method provides a yield of the compound having ...
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