25-07-2023 дата публикации
Номер: CN116478082A
Принадлежит:
The invention relates to a synthesis method of carbazolyl-containing Schiff base in a deep eutectic solvent, which comprises the following steps: adding choline chloride and methanesulfonic acid into a dry three-neck flask, and stirring at 80 DEG C to obtain a colorless transparent solution, namely the deep eutectic solvent; the preparation method comprises the following steps: cooling to room temperature, sequentially adding 3-formyl-9-alkyl carbazole and methyl (benzyl) hydrazinodithioformate, slowly heating, carrying out TLC (Thin Layer Chromatography) monitoring, after the reaction is finished, adding a small amount of water into a reaction container, separating out solids, carrying out suction filtration, washing a filter cake with water, and recrystallizing to obtain a pure product, and the yield can reach 90% or more. The catalyst can be reused for more than five times after being recovered. The method has the characteristics of low cost, high yield, high efficiency, environmental ...
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