01-02-2018 дата публикации
Номер: US20180030173A1
Принадлежит:
LG CHEM, LTD.
The present invention provides a catalyst composition including a functionalizing agent of the following Formula 1 together with a rare earth metal compound, an alkylating agent, and a halogen compound, having good catalytic activity and polymerization reactivity and useful for the preparation of a conjugated diene-based polymer having high linearity and excellent processability, and a conjugated diene-based polymer prepared using the catalyst composition. 1. A catalyst composition for preparing a conjugated diene-based polymer , the catalyst composition comprising:a functionalizing agent of the following Formula 1;a rare earth metal compound;an alkylating agent; and {'br': None, 'sub': 1', 'a', '1', '2', '2', 'n-1', 'm-a, '(X)-M-([Y-M-(X)]).\u2003\u2003[Formula 1]'}, 'a halogen compoundin Formula 1,{'sub': 1', '2, 'm is an atomic valence of M, n is an atomic valence of M,'}a satisfies a relation of 0≦a≦m−1,{'sub': 1', '2, 'Mand Mare each independently selected from the group consisting of elements in group 14 and elements in group 15,'}{'sub': 1', '2', '1-20', 'a', 'b', 'c', 'd', 'e', 'f', 'a', 'b', 'c', 'd', 'e', 'f', '1-20', '3-20', '6-20', '7-20', '7-20', '1-20', '3-20', '6-20', '7-20', '7-20, 'Xand Xare each independently selected from the group consisting of a hydrogen atom, monovalent Chydrocarbon, —OR, —NRR, —SiRRRand a covalent bonding functional group, where R, R, R, R, Rand Rare each independently selected from the group consisting of a hydrogen atom, Calkyl, Ccycloalkyl, Caryl, Calkylaryl, Carylalkyl, —NR′R″ and a covalent bonding functional group, where R′ and R″ are each independently selected from the group consisting of a hydrogen atom, Calkyl, Ccycloalkyl, Caryl, Calkylaryl, Carylalkyl, and a covalent bonding functional group,'}{'sub': 1', '2, 'Y is a divalent hydrocarbon group substituted or unsubstituted with at least one covalent bonding functional group, where at least one of X, Xand Y includes a covalent bonding functional group, and'}the ...
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