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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3067. Отображено 100.
24-05-2012 дата публикации

Photosensitive copolymer and photoresist composition

Номер: US20120129105A1
Автор: Emad Aqad, James W. Thackeray, Owendi Ongayi, Su Jin Kang
Принадлежит: Rohm and Haas Electronic Materials LLC

A copolymer has formula: wherein R 1 -R 5 are independently H, C 1-6 alkyl, or C 4-6 aryl, R 6 is a fluorinated or non-fluorinated C 5-30 acid decomposable group; each Ar is a monocyclic, polycyclic, or fused polycyclic C 6-20 aryl group; each R 7 and R 8 is —OR 11 or —C(CF 3 ) 2 OR 11 where each R 11 is H, a fluorinated or non-fluorinated C 5-30 acid decomposable group, or a combination; each R 9 is independently F, a C 1-10 alkyl, C 1-10 fluoroalkyl, C 1-10 alkoxy, or a C 1-10 fluoroalkoxy group; R 10 is a cation-bound C 10-40 photoacid generator-containing group, mole fractions a, b, and d are 0 to 0.80, c is 0.01 to 0.80, e is 0 to 0.50 provided where a, b, and d are 0, e is greater than 0, the sum a+b+c+d+e is 1, l and m are integers of 1 to 4, and n is an integer of 0 to 5. A photoresist and coated substrate, each include the copolymer.

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Номер записи: 1
13-09-2012 дата публикации

Hexafluoropropene-based fluorosulfonated elastomers with a low glass transition temperature, containing neither tetrafluoroethylene nor a siloxane group

Номер: US20120231369A1
Автор: Abdellatif Manseri, Bruno Michel Ameduri, Mario Boucher, Michel Armand
Принадлежит: HYDRO QUEBEC

The present invention describes the synthesis of new fluorinated elastomers with very low glass transition temperatures (T g ), a good resistance to bases, gasoline and other carburants and good workability properties, these elastomers contain hexafluoropropene (HFP), perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride (PFSO 2 F), vinylidene fluoride (VDF) and/or at least one fluorinated alkene and/or one vinyl perfluorinated ether. In a precise case, they are prepared by radical polymerisation of HFP and PFSO 2 F or by radical terpolymerisation HFP, PFSO 2 F and VDF in the presence of different organic initiator, such as peroxides, peresters or diazo compounds.

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Номер записи: 2
08-11-2012 дата публикации

Immersion upper layer film forming composition and method of forming photoresist pattern

Номер: US20120282553A1
Автор: Atsushi Nakamura, Hiroaki Nemoto, Hiroki Nakagawa, Takashi Chiba, Tomohiro Utaka, Toru Kimura, Yukio Nishimura
Принадлежит: JSR Corp

An immersion upper layer film composition includes a resin and a solvent. The resin forms a water-stable film during irradiation and is dissolved in a subsequent developer. The solvent contains a monovalent alcohol having 6 or less carbon atoms. The composition is to be applied to form a coat on a photoresist film in an immersion exposure process in which the photoresist film is irradiated through water provided between a lens and the photoresist film.

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Номер записи: 3
16-05-2013 дата публикации

CURABLE COMPOSITION AND PROCESS FOR PRODUCING CURED FILM

Номер: US20130123382A1
Автор: ABE Takefumi, ERIGUCHI Takeshi, Ito Masahiro, TSURUOKA Kaori
Принадлежит: Asahi Glass Company, Limited

To provide a curable composition which is sufficiently cured even without a heating step at high temperature and from which a low dielectric constant cured film excellent in the solvent resistance is obtained. 1. A curable composition comprising a fluorinated polyarylene prepolymer (A) having a crosslinkable functional group , a compound (B) having a number average molecular weight of from 140 to 5 ,000 , having at least two crosslinkable functional groups and having no fluorine atoms , a copolymer (C) having the following units (c1) and (c2) and a radical polymerization initiator (D):unit (c1): a unit having a fluoroalkyl group having at most 20 carbon atoms, which may have an etheric oxygen atom between carbon atoms, and having no crosslinkable functional group;unit (c2): a unit having a crosslinkable functional group.2. The curable composition according to claim 1 , wherein each of the crosslinkable functional groups in the prepolymer (A) claim 1 , the compound (B) and the compound (C) which are independent of one another claim 1 , is a crosslinkable functional group selected from the group consisting of a vinyl group claim 1 , an allyl group claim 1 , an ethynyl group claim 1 , a vinyloxy group claim 1 , an allyloxy group claim 1 , an acryloyl group claim 1 , an acryloyloxy group claim 1 , a methacryloyl group and a methacryloyloxy group.3. The curable composition according to claim 1 , which contains from 10 to 80 parts by mass of the compound (B) based on the total amount (100 parts by mass) of the prepolymer (A) and the compound (B).4. The curable composition according to claim 1 , wherein the radical polymerization initiator (D) is a thermal initiator or a photoinitiator.5. The curable composition according to claim 1 , which contains from 0.1 to 20 parts by mass of the copolymer (C) based on the total amount (100 parts by mass) of the prepolymer (A) and the compound (B).6. The curable composition according to claim 1 , wherein the unit (c1) is a unit formed ...

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Номер записи: 4
23-05-2013 дата публикации

Process for producing carboxyl-containing polymer composition, and carboxyl-containing poylmer compostion

Номер: US20130131299A1
Автор: Masahiro Suzuki, Ryousuke Murakami, Shinichi Takemori, Yuichiro Morimitsu
Принадлежит: Sumitomo Seika Chemicals Co Ltd

A process is disclosed for producing a carboxyl-containing polymer composition that allows the possibility of obtaining a carboxyl-containing polymer composition which exhibits excellent dispersibility in water or the like, has a viscosity increasing to a lower degree compared to the viscosity of a neutralized viscous liquid using an additive-free carboxyl-containing polymer, and has a high degree of transparency in a neutralized viscous liquid thereof. A carboxyl-containing polymer composition is obtained by polymerizing a monomer containing an α,β-unsaturated carboxylic acid as a main component in a presence of a polyol (iso)stearic acid ester. A polyol in the polyol (iso)stearic acid ester is a polyol selected from a specific group, and the polyol (iso)stearic acid ester is used in the polymerization in an amount of 0.2 to 7 parts by mass based on 100 parts by mass of the α,β-unsaturated carboxylic acid.

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Номер записи: 5
06-06-2013 дата публикации

RESIST-PROTECTIVE FILM-FORMING COMPOSITION AND PATTERNING PROCESS

Номер: US20130143163A1
Автор: Hatakeyama Jun
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A pattern is printed by forming a photoresist layer on a wafer, forming a protective film thereon, exposure, and development. The protective film is formed from a composition comprising a copolymer of hydroxystyrene with acenaphthylene and/or vinylnaphthalene and a mixture of an alcohol solvent and an ether or aromatic solvent. 2. The protective film-forming composition of claim 1 , wherein the copolymer has further copolymerized therein one or more monomers selected from the group consisting of styrene claim 1 , vinylbiphenyl claim 1 , vinylbenzoic acid claim 1 , styrenesulfonic acid claim 1 , vinylanthracene claim 1 , hydroxyvinylanthracene claim 1 , vinylcarbazole claim 1 , vinylpyrene claim 1 , indene claim 1 , hydroxyindene claim 1 , and p-phenylstyrene.3. The protective film-forming composition of which is soluble in an alkaline developer.4. The protective film-forming composition of claim 1 , further comprising an organic solvent mixture of at least one alcohol solvent and at least one other solvent claim 1 ,the alcohol solvent being selected from the group consisting of 1-butyl alcohol, 2-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, 1-pentanol, 2-pentanol, 3-pentanol, tert-amyl alcohol, neopentyl alcohol, 2-methyl-1-butanol, 3-methyl-1-butanol, 3-methyl-3-pentanol, cyclopentanol, 1-hexanol, 2-hexanol, 3-hexanol, 2,3-dimethyl-2-butanol, 3,3-dimethyl-1-butanol, 3,3-dimethyl-2-butanol, 2-ethyl-1-butanol, 2-methyl-1-pentanol, 2-methyl-2-pentanol, 2-methyl-3-pentanol, 3-methyl-1-pentanol, 3-methyl-2-pentanol, 3-methyl-3-pentanol, 4-methyl-1-pentanol, 4-methyl-2-pentanol, 4-methyl-3-pentanol, cyclopentanol, and cyclohexanol,the other solvent being selected from an ether solvent selected from the group consisting of diisopropyl ether, diisobutyl ether, diisopentyl ether, di-n-pentyl ether, methyl cyclopentyl ether, methyl cyclohexyl ether, di-n-butyl ether, di-sec-butyl ether, diisopentyl ether, di-sec-pentyl ether, di-tert-amyl ether, and di-n-hexyl ether, ...

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Номер записи: 6
04-07-2013 дата публикации

Process for superabsorbent polymer and crosslinker composition

Номер: US20130172180A1
Автор: Christoph Loick, Frank Schubert, Matthias Naumann, Stanley A. McIntosh
Принадлежит: Evonik Stockhausen LLC

The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.

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Номер записи: 7
11-07-2013 дата публикации

Led curable compositions

Номер: US20130176370A1
Автор: Johan Loccufier
Принадлежит: Agfa Gevaert NV

A radiation curable composition includes a) at least one monomer comprising at least one vinyl ether group and at least one (meth)acrylate group; and b) at least one diffusion hindered photoinitiator selected from the group consisting of a polymeric photoinitiator, a multifunctional photoinitiator and a polymerizable photoinitiator characterized in that the diffusion hindered photoinitiator includes at least one structural moiety according to Formula (I): wherein: R1 and R2 are independently selected from the group consisting of a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aryl or heteroaryl group, a halogen, an ether, a thioether, an aldehyde, a ketone, an ester, an amide, an amine and a nitro group; R1 and R2 may represent the necessary atoms to form a five to eight membered ring; and the dotted line represents the covalent bond of the structural moiety according to Formula (I) to the diffusion hindered photoinitiator.

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Номер записи: 8
18-07-2013 дата публикации

Vinyl ether functional oligomers and methods for making and using same

Номер: US20130184371A1
Автор: James V. Crivello
Принадлежит: RENSSELAER POLYTECHNIC INSTITUTE

The present invention includes vinyl ether functional oligomers and methods for their preparation, the method including alternating free radical copolymerization of a dialkyl maleate or dialkyl fumerate monomer with a multifunctional vinyl ether monomer in the presence of a solvent with a high chain transfer constant. Also within the scope of the invention are uses for the vinyl ether functional oligomers compositions of this invention, including radiation curable coatings, adhesives, printing inks and composites.

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Номер записи: 9
18-07-2013 дата публикации

Monomer composition containing unsaturated polyalkylene glycol ether-based monomer, method for producing composition thereof, polymer obtained using composition thereof, and method for producing polymer thereof

Номер: US20130184420A1
Автор: Hiroshi Kawabata
Принадлежит: NIPPON SHOKUBAI CO LTD

To provide a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer and having excellent stability. Provided is a monomer composition containing an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1): YO(R 1 O) n R 2   (1) [in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R 1 O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R 2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

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Номер записи: 10
22-08-2013 дата публикации

AQUEOUS POLYMERIZATION OF FLUORINATED MONOMER USING A MIXTURE OF FLUOROPOLYETHER ACIDS OR SALTS

Номер: US20130217849A1
Автор: BROTHERS PAUL DOUGLAS, Chapman Gregory Allen, Gangal Subhash Vishnu, Howell Jon Lee, Smith Adam Paul
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

A composition comprising a mixture of fluoropolyether acids or salts having a number average value of about 800 to about 2500 g/mol. The amount of fluoropolyether acids or salt in the mixture having a molecular weight of not more than 500 g/mol is not more than 50 ppm by weight of the total amount of fluoropolyether acids or salts in the mixture. The amount of fluoropolyether acids or salts in the mixture having a molecular weight of 2500 g/mol or greater is not more than 40% by weight of the total amount of fluoropolyether acids or salts in the mixture. Preferably the fluoropolyether acids or salts comprise an anionic group selected from the group consisting of carboxylate, sulfonate, sulfonamide anion and phosphonate. Also disclosed is an aqueous dispersion polymerization process for fluoropolymer manufacture employing polymerization agent comprising the specified mixture of fluoropolyether acids or salts. 1. A composition comprising a mixture of fluoropolyether acids or salts having a number average molecular weight of about 800 to about 2500 g/mol; wherein the amount of fluoropolyether acids or salt in said mixture having a molecular weight of not more than 500 g/mol is not more than 50 ppm by weight of the total amount of fluoropolyether acids or salts in said mixture; wherein the amount of fluoropolyether acids or salts in said mixture having a molecular weight of 2500 g/mol or greater is not more than 40% by weight of the total amount of fluoropolyether acids or salts in said mixture; and wherein the amount of fluoropolyether acids or salts in said mixture having a molecular weight of 3000 g/mol or greater is not more than 10% by weight of the total amount of fluoropolyether acids or salts in said mixture.2. The composition of wherein said fluoropolyether acids or salts comprise an anionic group selected from the group consisting of carboxylate claim 1 , sulfonate claim 1 , sulfonamide anion and phosphonate.3. The composition of wherein at least about 50% by ...

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Номер записи: 11
03-10-2013 дата публикации

Low viscosity fluoroelastomers

Номер: US20130261249A1
Автор: Apostolo Marco, Comino Giovanni, Cristini Marco
Принадлежит: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

The invention pertains to a low viscosity curable (per)fluoroelastomer [fluoroelastomer (A)] having a number-averaged molecular weight of 3 000 to 45 000, said (per)fluoroelastomer comprising at least 1% moles, with respect to the total moles of recurring units, of recurring units derived from at least one (per)fluoromethoxyalkylvinylether of formula (I): 3. The fluoroelastomer of claim 2 , wherein said monomer (M) is selected from the group consisting of:{'br': None, 'sub': 2', '2', '3, 'CF═CFOCFO—CF;\u2003\u2003(M1)'}{'br': None, 'sub': 2', '2', '2', '3, 'CF═CFOCFO—CFCF; and\u2003\u2003(M2)'}{'br': None, 'sub': 2', '2', '2', '2', '3, 'CF═CFOCFO—CFCFOCF.\u2003\u2003(M3)'}4. The fluoroelastomer (A) of claim 1 , wherein said fluoroelastomer (A) is selected from the group consisting of:(1) VDF-based copolymers, comprising recurring units derived from VDF, from the monomer (M) and optionally from at least one additional (per)fluorinated monomer different from said monomer (M) and said VDF [comonomer (C)];(2) TFE-based copolymers, comprising recurring units derived from TFE, from the monomer (M) and optionally from at least one additional (per)fluorinated monomer different from said monomer (M) and said TFE [comonomer (C)].6. The fluoroelastomer (A) of claim 4 , comprising at least 3% moles with respect to the total moles of recurring units claim 4 , of recurring units derived from said monomer (M).7. The fluoroelastomer (A) of claim 4 , wherein the sum of recurring units derived from said monomer (M) and said comonomer (C) represents at least 10% moles claim 4 , with respect to the total amount of recurring units of said fluoroelastomer (A).9. The fluoroelastomer (A) of claim 1 , having a number-averaged molecular weight of at least 7 000.10. The fluoroelastomer (A) of claim 1 , having a number-averaged molecular weight of at most 40 000.11. The fluoroelastomer (A) of comprising cure sites as pendant groups bonded to certain recurring units.13. The fluoroelastomer (A) ...

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Номер записи: 12
20-02-2014 дата публикации

Polymer of maleic acid, allyl ether and (meth)acrylic acid compounds, and preparation and use thereof

Номер: US20140051801A1
Автор: Joerg Zimmermann, Lukas Frunz, Ueli Sulser
Принадлежит: SIKA TECHNOLOGY AG

The invention relates to comb polymers of maleic acid or derivatives thereof, allyl ethers and (meth)acrylic acid or derivatives thereof, and to the preparation thereof by free radical polymerization at a reaction temperature of 10° C. to 50° C. The invention further relates to the use of such comb polymers for improving the processability of hydraulically setting compositions.

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Номер записи: 13
06-03-2014 дата публикации

Laundry detergents and cleaning compositions comprising carboxyl group-containing polymers

Номер: US20140066352A1
Автор: Atsuro Yoneda, Brian Joseph Loughnane, Daisuke Michitaka, Jeffrey Scott Dupont, Xiaoli Wang, Xiaoyan Liu
Принадлежит: Procter and Gamble Co

The present invention relates to a laundry detergent or a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the laundry detergent or cleaning composition are also encompassed by the present invention.

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Номер записи: 14
20-03-2014 дата публикации

Comb polymers as dispersants for alkaline activated binders

Номер: US20140080943A1
Автор: Arnd Eberhardt, Delphine Marchon, Robert Flatt, Ueli Sulser
Принадлежит: SIKA TECHNOLOGY AG

A comb polymer that is a dispersant in a binder composition includes an alkaline activating agent, wherein the activating agent is intended for activation of a latently hydraulic and/or puzzolanic binder, and wherein the comb polymer has a polymer backbone formed from a plurality of backbone monomers and a plurality of polymeric side chains each formed from a plurality of side chain monomers and bonded thereto, and wherein at least some of the backbone monomers have one or more ionizable groups, and features a structure constant K of the comb polymer, defined as K=[(N−1)z] 2 /nP 915 N 3/5 ×10 5 , at least equal to 70, where n is the average number of side chains per comb polymer molecule, N is the average number of backbone monomers per side chain, P is the average number of side chain monomers per side chain, and z is the average number of ionizable groups per side chain-free backbone monomer.

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Номер записи: 15
07-01-2016 дата публикации

MOLD RELEASING AGENT

Номер: US20160002377A1
Автор: Chang Jung-Wei, CHIOU REN-REN, HO JIH-HSIH
Принадлежит: TAIWAN FLUORO TECHNOLOGY CO., LTD.

A mold releasing agent is copolymerized with a fluorine-containing monomer, an acrylic ester monomer, and an acid monomer. Whereby, the mold releasing agent has comparable releasing performance and longevity to long-chain copolymers containing halothane. 1. A mold releasing agent , comprising:a fluorine-containing monomer;an acrylic ester monomer; andan acid monomer.2. The mold releasing agent of claim 1 , wherein the fluorine-containing monomer is represented by the general expression CH═C(—X)C(═O)—Y—Z—R claim 1 , where{'sub': 'f', 'X is hydrogen atom, monovalent organic group, halogen atoms, linear or branched perfluoroalkyl with 1 to 21 carbon atoms, or cyano; Y is oxygen atom, sulfur atom, or secondary amine; Z is straight chain alkane, divalent organic group, aromatics or Cycloaliphatic of which carbon-number is 6 to 18, or aliphatic groups of which carbon-number is 1 to 10; Ris linear or branched perfluoroalkyl of which carbon-number is 1 to 21.'}3. The mold releasing agent of claim 1 , wherein the acrylic ester monomer is represented by the general expression CH═CACOOA claim 1 , where{'sub': 1', '2', 'n', '2n+1, 'Ais hydrogen atom, methyl, or halogen atoms other than fluorine atom; Ais CHalkyl, wherein n is between 1 and 30.'}5. The mold releasing agent of claim 1 , further comprising silicon oil.6. The mold releasing agent of claim 5 , wherein the silicon oil is selected from the group consisting of dimethyl silicone oil claim 5 , methyl chloride silicon oil claim 5 , methylphenyl silicone oil claim 5 , and organic denatured silicone oil.8. The mold releasing agent of claim 1 , wherein the acid monomer is selected from at least one member of the group consisting of carboxylic acid claim 1 , phosphate group claim 1 , phosphonic acid group claim 1 , phosphinic acid group claim 1 , sulfate claim 1 , sulfo group claim 1 , and sulfino.9. The mold releasing agent of claim 1 , further comprising Azobisisobutyronitrile or azobisisobutyronitrile HEPTANITRILE.10. The ...

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Номер записи: 16
01-01-2015 дата публикации

METHOD FOR PRODUCING HOMOPOLYMER OR RANDOM COPOLYMER OF HYDROXYL GROUP-CONTAINING VINYL ETHER

Номер: US20150005467A1
Автор: MASUKAWA Tomohiro, Sugihara Shinji
Принадлежит: MARUZEN PETROCHEMICAL CO., LTD.

[Object] To provide a method of producing a homopolymer or random copolymer of hydroxyl group-containing vinyl ether simply and conveniently as well as efficiently. 1. A method of producing a homopolymer or a random copolymer of a hydroxyl group-containing vinyl ether , said method comprising the step of polymerizing , using an oil-soluble radical polymerization initiator in the absence or presence of a solvent , a monomer component comprising at least one hydroxyl group-containing vinyl ether represented by the following formula (1):{'br': None, 'sub': 2', 'n, 'sup': '1', 'CH═CH—O—R\ue8a0OH)\u2003\u2003(1)'}{'sup': '1', 'wherein Rrepresents an aliphatic hydrocarbon group having 1 to 10 carbon atoms or an alkoxy alkyl group having 3 to 7 carbon atoms, which is optionally branched and optionally comprises a cyclic structure; and n is 1 to 5.'}3. The method of production according to claim 1 , wherein said oil-soluble radical polymerization initiator is an organic peroxide or an organic azo compound.4. The method of production according to claim 1 , wherein said homopolymer or said random copolymer has a weight average molecular weight (Mw) within the range of 1000 to 100 claim 1 ,000.5. The method of production according to claim 1 , wherein a content of polyacetal in said homopolymer or said random copolymer is not more than 10% by weight.6. The method of production according to claim 1 , wherein said solvent is an organic solvent comprising at least one water-soluble organic solvent.7. The method of production according to claim 6 , wherein said water-soluble organic solvent is selected from the group consisting of alcohol claim 6 , alkyl amide claim 6 , alkyl sulfoxide and ketone. The present invention relates to a method of producing a vinyl ether (co)polymer having a hydroxyl group simply and conveniently. More specifically, the present invention relates to a method of producing a hydroxyl group-containing vinyl ether (co)polymer simply and conveniently by ...

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Номер записи: 17
14-01-2021 дата публикации

Method for fractionating liquid composition

Номер: US20210009733A1
Автор: Hiroyuki Watabe, Mitsuhisa Matsumoto
Принадлежит: Asahi Glass Co Ltd

To provide a method for fractionating a liquid composition, which is excellent in separability of the liquid composition. This method for fractionating a liquid composition comprises discharging, from a discharge port of a filling nozzle, a liquid composition containing a solvent and a polymer having ion exchange groups, and fractionating a predetermined amount of the liquid composition, characterized in that the temperature of the liquid composition is controlled so that the average tan δ1 of the liquid composition when discharged from the discharge port of the filling nozzle becomes to be at most 1.00.

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Номер записи: 18
10-01-2019 дата публикации

Use of hydrophobically associating copolymers as binders for pelletizing metal containing ores

Номер: US20190010577A1
Автор: Adrian Mauricio VILLANUEVA BERINDOAGUE, Alexej Michailovski, Dominic Rene BECHEN, Gregor Brodt, Rainer Packe-Wirth, Shane HOFF, Sylvia Von Krog
Принадлежит: BASF SE

The present invention relates to the use of hydrophobically associative copolymers as binders for pelletizing metal containing ores such as iron containing ores. The copolymers comprise monomer unitsderived from at least one hydrophobically as sociative monomer, preferably at least one unsaturated hydrophobically associating monomer.

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Номер записи: 19
09-01-2020 дата публикации

INITIATOR SYSTEM FOR CATIONIC POLYMERIZATION OF OLEFINS

Номер: US20200010644A1
Автор: Arsenault Gilles, Gates Derek, Khatera Hazin
Принадлежит:

A BrønstedLowry acid initiator system for cationic polymerization of an ethylenically unsaturated monomer involves an initiator having a structure of Formula (I) in an anhydrous polymerization medium (I) where: M is tantalum (Ta), vanadium (V) or niobium (Ni); each Ris independently H, OR, F, Cl, Br, I or alkyl, where Ris H or alkyl; R, R, Rand Rare independently H, F, Cl Br, I, alkyl or aryl, or two or more of R, R, Rand Ron a same benzene ring form a bicyclic, tricyclic or tetracyclic moiety with the benzene ring, with the proviso that all of R, R, Rand Ron the same benzene ring are not H; L is absent or a molecule that coordinates to H; and, x is 0 when L is absent, or x is 0.5 or more when L is present. 119.-. (canceled)21. The system according to claim 20 , wherein M is Ta.22. The system according to claim 20 , wherein Ris H claim 20 , F claim 20 , Cl claim 20 , OH claim 20 , OCHor CH; R claim 20 , R claim 20 , Rand Rare H claim 20 , F claim 20 , Cl or Br with the proviso that all of R claim 20 , R claim 20 , Rand Ron the same benzene ring are not H; L is an alkyl ether or a cycloalkyl ether; and claim 20 , x is 2.23. The system according to claim 21 , wherein: Ris H claim 21 , F claim 21 , Cl claim 21 , OH claim 21 , OCHor CH; R claim 21 , R claim 21 , Rand Rare H claim 21 , F claim 21 , Cl or Br with the proviso that all of R claim 21 , R claim 21 , Rand Ron the same benzene ring are not H; L is an alkyl ether or a cycloalkyl ether; and claim 21 , x is 2.24. The system according to claim 20 , wherein: M is Ta; both of Rare OH; R claim 20 , R claim 20 , Rand Rare Cl; L is EtO; and claim 20 , x is 2.25. The system according to claim 20 , wherein the polymerization medium comprises dicholoromethane or methyl chloride.26. The system according to claim 20 , containing substantially no water.27. The system according to claim 23 , containing substantially no water.281. A process for producing a polymer claim 23 , the process comprising polymerizing one or more ...

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Номер записи: 20
03-02-2022 дата публикации

COPOLYMERS OF PERFLUOROCYCLOALIPHATIC METHYL VINYL ETHER

Номер: US20220033673A1
Автор: Fukushi Tatsuo, Guerra Miguel A., Ryland Bradford L.
Принадлежит:

Described herein is a perfluoropolymer and compositions therefrom. The perfluoropolymer is derived from: (a) no more than 88 mol % tetrafluoroethylene monomer; and (b) a complementary amount of a perfluoro (cycloaliphatic methyl vinyl ether) monomer, and has substantially no melting point. 1. A perfluoropolymer , wherein the perfluoropolymer is derived from at least:(a) no more than 88 mol % tetrafluoroethylene monomer; and{'sub': 2', '3', '2', 'n', '2, 'claim-text': wherein Rf is a perfluorinated group comprising 6 carbon atoms and 11 fluorine atoms and a cycloaliphatic group, and n is 0, 1, or 2; and', 'wherein the perfluoropolymer has substantially no melting point., '(b) a complementary amount of a monomer according to Formula I Rf—CF—[OCF(CF)CF]O—CF═CF'}2. The perfluoropolymer according to claim 1 , wherein the monomer of Formula I comprises perfluoro(cyclohexyl methyl vinyl ether).3. The perfluoropolymer according to claim 1 , wherein the monomer of Formula I comprises at least one of perfluoro(cyclohexyl methyl vinyl ether) claim 1 , perfluoro(2-methyl cyclopentyl methyl vinyl ether) claim 1 , perfluoro(3-methyl cyclopentyl methyl vinyl ether) claim 1 , perfluoro(2-dimethyl cyclobutyl methyl vinyl ether) claim 1 , and perfluoro(3-dimethyl cyclobutyl methyl vinyl ether).4. The perfluoropolymer according to claim 1 , wherein the perfluoropolymer is further derived from at least one of hexafluoropropylene claim 1 , chlorotrifluoroethylene claim 1 , a perfluoroalkyl vinyl ether claim 1 , a perfluoroalkyl allyl ether claim 1 , and combinations thereof.5. The perfluoropolymer according to claim 4 , wherein the perfluoropolymer is further derived from at least 10 mol % of a perfluoroalkyl vinyl ether claim 4 , a perfluoroalkyl allyl ether claim 4 , or combinations thereof.6. The perfluoropolymer according to claim 1 , wherein the perfluoropolymer is derived from at least 15 mol % of the perfluoro(cycloaliphatic methyl vinyl ether) monomer.7. The perfluoropolymer ...

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Номер записи: 21
19-01-2017 дата публикации

HIGH TEMPERATURE AND HIGH PRESSURE CEMENT RETARDER COMPOSITION AND USE THEREOF

Номер: US20170015588A1
Автор: MELBOUCI Mohand, Wang Janice Jianzhao
Принадлежит: Hercules Incorporated

The presently disclosed and/or claimed inventive process concept(s) relates generally to a water soluble or water dispersible composition comprising a copolymer and use in oil field. More particularly, the presently disclosed and/or claimed inventive concept(s) relates to the copolymers comprising allyloxy linkage and its function derivatives and its use in oil field such as a high temperature cement retarder composition. 3. The composition of claim 1 , wherein the composition has a weight average molecular weight of from about 1 claim 1 ,000 to about 1 claim 1 ,000 claim 1 ,000 Daltons.4. The composition of claim 2 , wherein the composition has a weight average molecular weight of from about 1 claim 2 ,000 to about 1 claim 2 ,000 claim 2 ,000 Daltons.5. The composition of claim 1 , wherein the composition comprises a copolymer polymerizing from an alpha claim 1 , beta ethylenically unsaturated carboxylic acid claim 1 , an unsaturated dicarboxylic acid claim 1 , hydroxypolyethoxyl allyl ether claim 1 , and vinyl acetate.6. The composition of claim 2 , wherein the composition comprises a copolymer polymerizing from an alpha claim 2 , beta ethylenically unsaturated carboxylic acid claim 2 , an unsaturated dicarboxylic acid claim 2 , hydroxypolyethoxyl allyl ether claim 2 , vinyl acetate claim 2 , and vinyl alcohol.7. The composition of claim 5 , wherein the alpha claim 5 , beta ethylenically unsaturated carboxylic acid is acrylic acid or alkylacrylic acid.8. The composition of claim 6 , wherein the alpha claim 6 , beta ethylenically unsaturated carboxylic acid is acrylic acid or alkylacrylic acid.9. The composition of claim 5 , wherein the unsaturated dicarboxylic acid is maleic acid or anhydride.10. The composition of claim 6 , wherein the unsaturated dicarboxylic acid is maleic acid or anhydride.11. The composition of claim 7 , wherein the alkylacrylic acid is methacrylic acid.12. The composition of claim 8 , wherein the alkylacrylic acid is methacrylic acid. The ...

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Номер записи: 22
21-01-2021 дата публикации

RADIOPAQUE POLYMERS

Номер: US20210015963A1
Автор: Ashrafi Koorosh, Britton Hugh, Cuda Francesco, LEWIS Andrew Lennard, Parisi Cristian, TANG Yiqing, Willis Sean Leo
Принадлежит:

The present disclosure relates to radiopaque PVA polymers where the PVA has a first pendant group and a second pendant group, wherein the first pendant group comprises a first phenyl group bearing 1 to 5 iodine atoms, and the second pendant group comprises either (a) a second phenyl group bearing 1 to 3 substituents selected from the group W and optionally 1 to 4 iodine substituents, the group(s) W and the optional iodines being the sole substituents of the second phenyl group. Each W is selected from —OH, —COOH, —SOH, —OPOH, —O—(Calkyl), —O—(Calkyl)OH, —O—(Calkyl)R, —O—(CHO)R—(C═O)—O—Calkyl and —O—(C═O)Calkyl; wherein Ris H or Calkyl; Ris —COOH, —SOH, or —OPOH; q is an integer from 1 to 4; wherein the group W may be in the form of a pharmaceutically acceptable salt; or (b) a pyridyl group; which is optionally in the form of a pyridinium ion. 1. A polymer comprising polyvinyl alcohol (PVA) , the PVA having a first pendant group and a second pendant group ,wherein the first pendant group comprises a first phenyl group bearing 1 to 5 iodines as the sole substituent(s) of the first phenyl group, andwherein the second pendant group comprises a group selected from:(a) a second phenyl group bearing 1 to 3 substituents selected from the group W and optionally 1 to 4 iodine substituents, the group(s) W and the optional iodines being the sole substituents of the second phenyl group;{'sub': 3', '3', '2', '1-4', '1-4', '1-4', '2', '5', 'q', '1-4', '1-4', '1-4', '3', '3', '2, 'sup': 2', '1', '1', '2, 'wherein each W is independently selected from —OH, —COOH, —SOH, —OPOH, —O—(Calkyl), —O—(Calkyl)OH, —O—(Calkyl)R, —O—(CHO)R—(C═O)—O—Calkyl and —O—(C═O)Calkyl; wherein Ris H or Calkyl; Ris —COOH, —SOH, or —OPOH; wherein q is an integer from 1 to 4; and wherein the group W may be in the form of a pharmaceutically acceptable salt; and'}(b) a pyridyl group; which is optionally in the form of a pyridinium ion.2. A polymer according to claim 1 , wherein the first pendant group is coupled ...

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Номер записи: 23
21-01-2016 дата публикации

Compound for forming organic film, and organic film composition using the same, process for forming organic film, and patterning process

Номер: US20160018735A1
Автор: Daisuke Kori, Kazumi Noda, Seiichiro Tachibana, Takeru Watanabe, Toshiharu Yano, Tsutomu Ogihara
Принадлежит: Shin Etsu Chemical Co Ltd

The invention provides a compound for forming an organic film having a partial structure represented by the following formula (vii-2), wherein R 1 represents a linear, branched or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms, and a methylene group constituting R 1 may be substituted by an oxygen atom; a+b is 1, 2 or 3; c and d are each independently 0, 1 or 2; x represents 0 or 1, when x=0, then a=c=0; L 7 represents a linear, branched or cyclic divalent organic group having 1 to 20 carbon atoms, L 8′ represents the partial structure represented by the following formula (i), 0≦o<1, 0<p≦1 and o+p=1, wherein the ring structures Ar3 represent a substituted or unsubstituted benzene ring or naphthalene ring; R 0 represents a hydrogen atom or a linear, branched or cyclic monovalent organic group having 1 to 30 carbon atoms; and L 0 represents a divalent organic group. There can be provided an organic film composition for forming an organic film having high dry etching resistance as well as advanced filling/planarizing characteristics.

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Номер записи: 24
10-02-2022 дата публикации

ELASTOMER COMPOSITION AND SEALING MATERIAL

Номер: US20220041773A1
Автор: IMADA Hirohisa, Mochizuki Tomomitsu, Osumi Naoki
Принадлежит: VALQUA, LTD.

Provided are an elastomer composition including a first fluoroelastomer that is a copolymer of tetrafluoroethylene and perfluoro (alkoxyvinyl ether) and a second fluoroelastomer different from the first fluoroelastomer, and a sealing material including a crosslinked product of the elastomer composition. 1. An elastomer composition comprising:a first fluoroelastomer being a copolymer containing a constituent unit derived from tetrafluoroethylene and one or more constituent units derived from perfluoro (alkoxyvinyl ether); anda second fluoroelastomer different from the first fluoroelastomer, orcomprising two or more of the first fluoroelastomers.2. The elastomer composition according to claim 1 , wherein the second fluoroelastomer is a perfluoroelastomer.3. The elastomer composition according to claim 2 , wherein the second fluoroelastomer is a copolymer containing the constituent unit derived from tetrafluoroethylene and one or more constituent units derived from perfluoro (alkyl vinyl ether).4. The elastomer composition according to claim 1 , wherein the first fluoroelastomer and the second fluoroelastomer are contained in a mass ratio of 10:90 to 90:10.5. The elastomer composition according to claim 1 , further comprising a peroxide crosslinking agent and a co-crosslinking agent.6. A sealing material comprising a crosslinked product of the elastomer composition according to . The present invention relates to an elastomer composition and a sealing material using the elastomer composition.Sealing materials (gaskets, packings, and the like) are used for various applications, and characteristics according to the applications are required. For example, when sealing materials are used under a high-temperature environment, they are required for heat resistance. When sealing materials are used under an environment in which the sealing materials are exposed to a plasma, they are required for resistance to the plasma (plasma resistance).Meanwhile, ozone having strong ...

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Номер записи: 25
24-01-2019 дата публикации

RESIST MATERIAL AND PATTERN FORMING METHOD USING SAME

Номер: US20190023842A1
Автор: Kobayashi Kei, Morita Seiji
Принадлежит: Toshiba Memory Corporation

In one embodiment, a resist material to be used in an imprint process includes a diluent monomer having a hydroxyl group and at least one functional group selected from a vinyl ether group, an epoxy group and an oxetanyl group. The material further includes a dendrimer having at least two reactive groups for photo-cationic polymerization. The material further includes a photo-acid generator as a polymerization initiator. 120.-. (canceled)21. A resist material to be used in an imprint process , comprising:a diluent monomer having a hydroxyl group and at least one functional group selected from a vinyl ether group, an epoxy group and an oxetanyl group;a dendrimer with a globular structure having at least two reactive groups for photo-cationic polymerization; anda photo-acid generator as a polymerization initiator.22. The material of claim 21 , wherein the material comprises:50% or more and 90% or less by weight of the diluent monomer;5% or more and 50% or less by weight of the dendrimer; and0.3% or more and 10% or less by weight of the polymerization initiator.23. The material of claim 21 , wherein the dendrimer has a vinyl ether group claim 21 , an epoxy group or an oxetanyl group as the reactive groups for photo-cationic polymerization. This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No.2013-156007, filed on Jul. 26, 2013, the entire contents of which are incorporated herein by reference.Embodiments described herein relate to a resist material and a pattern forming method using the same.A method of performing an imprint process in the atmosphere of a condensable gas such as pentafluoropropane (PFP) is proposed to improve the yield of the imprint process. The condensable gas means a gas which is condensed and liquefied at a low pressure. When a template is pressed against a resist material under the condensable gas atmosphere, the condensable gas present between concave portions of patterns of the template ...

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Номер записи: 26
28-01-2021 дата публикации

NOVEL PHOTOINITIATORS MADE FROM BIFUNCTIONAL SILANE

Номер: US20210024551A1
Автор: EL ROZ Mohamad, LAKHDAR Sami, TELEGEIEV Igor
Принадлежит:

The present invention relates to a compound of formula (I) below: 2. A compound according to claim 1 , wherein n=0.3. A compound according to claim 1 , wherein Rand Rrepresent a methyl group.4. Compound according to claim 1 , wherein R claim 1 , Rand Rrepresent an ethyl group.6. Compound according to claim 1 , wherein Rrepresents an alkylene group claim 1 , preferably a CHgroup.7. Compound according to claim 1 , wherein Rand Rrepresent H.8. Compound according to claim 1 , wherein Rrepresents H claim 1 , while Rrepresents an ORgroup as defined in .9. Compound according to claim 1 , wherein Rand Rtogether form a phenyl group with the carbon atoms which carry them.11. Use of a compound of formula (I) according to as a photoinitiator.12. Use of a compound of formula (I) according to to modify a silica surface.14. Silica surface comprising at least one group of formula (VI) or (VII) as defined in . The present invention relates to novel photoinitiators based on bifunctional silane, as well as their preparation process. It also relates to their use for the preparation of hybrid polymer/filler materials via photopolymerization.The incorporation of mineral fillers in polymers has become a very common industrial practice. These compounds are often essential, so as to give hybrid materials mechanical (impact resistance, abrasion resistance, attachment to wet surfaces, etc.), chemical (anticorrosion, anti-UV, etc.), or optical (opacity, color) properties. Silica nanoparticles (precipitated silica) are the used most often as fillers for the reinforcement of organic polymers. These materials are becoming essential in several industrial fields. In view of the hydrophilic nature of these materials and the hydrophobic nature of the polymers, it is not possible to use them directly as a filler in their raw state.This problem is solved by the use of bifunctional silanes as coupling agents, so as to modify the hydrophilic nature of the silica particles and to ensure a chemical bond ...

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Номер записи: 27
24-01-2019 дата публикации

FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND METHOD OF MAKING AN IONOMER

Номер: US20190027769A1
Автор: Dahlke Gregg D., Duchesne Denis, Hintzer Klaus, Lochhaas Kai Helmut, Thaler Arne, Zipplies Tilman C.
Принадлежит:

The copolymer includes divalent units represented by formula: (I), one or more independently selected fluorinated divalent units, and —SOX end groups. In this formula, b is 2 to 8, c is 0 to 2, and e is 1 to 8. In each SOX, X is independently F, —NZH, —NZSO(CF)SOX′, —NZ[SO(CF)SONZ]SOX′, or —OZ, wherein Z is a hydrogen, an alkali-metal cation or a quaternary ammonium cation, X′ is independently —NZH or —OZ, and each a is independently 1 to 6. The copolymer has an —SOX equivalent weight of up to 1000. The method includes copolymerizing components including fluorinated olefin and a compound represented by formula CF═CF—CF(O—CF)—O—(CF)—SOX′, wherein b, c, and e are as defined above. A method of making a membrane using the copolymer or ionomer is also provided. A polymer electrolyte membrane that includes the copolymer or the ionomer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided. 3. The copolymer of claim 1 , wherein b is 2 or 3 claim 1 , c is 0 or 1 claim 1 , and e is 2 or 4.4. The copolymer of claim 1 , wherein the other claim 1 , independently selected fluorinated divalent units are derived from at least one of a perfluoroalkyl vinyl ether claim 1 , perfluoroalkoxyalkyl vinyl ether claim 1 , or a fluorinated olefin represented by formula C(R)═CF—Rf claim 1 , wherein Rf is fluorine or a perfluoroalkyl having from 1 to 8 carbon atoms and each R is independently hydrogen claim 1 , fluorine claim 1 , or chlorine.5. The copolymer of claim 4 , wherein the other claim 4 , independently selected fluorinated divalent units are derived from at least one of tetrafluoroethylene claim 4 , hexafluorpropylene claim 4 , perfluoromethyl vinyl ether claim 4 , perfluoropropyl vinyl ether claim 4 , perfluoro-3-methoxy-n-propyl vinyl ether claim 4 , tetrafluoropropene claim 4 , and vinylidene fluoride.6. The copolymer of claim 5 , wherein the other claim 5 , independently selected fluorinated divalent units comprise —[CF—CF]—.7. The ...

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Номер записи: 28
29-01-2015 дата публикации

RESIST TOP COAT COMPOSITION AND PATTERNING PROCESS

Номер: US20150030983A1
Автор: Hatakeyama Jun, KIM Hyun-woo
Принадлежит:

A resist top coat composition includes a polymer including a base resin having a repeating unit p of styrene having a 1,1,1,3,3,3-hexafluoro-2-propanol group and a repeating unit q of acenaphthylene having chemical formula 1. R is hydrogen, hydroxyl. Ris hydrogen, hydroxyl, linear or branched C1-C10-alkyl, cycloalkyl, acyloxy, alkoxycarbonyl, carboxyl, —OC(═O)R. Ris linear or branched C1-C10-alkyl, cycloalkyl or fluorinated alkyl. m is 1 or 2. p and q are positive numbers satisfying the expressions 0 Подробнее

Номер записи: 29
02-02-2017 дата публикации

RESIST COMPOSITION AND PATTERNING PROCESS USING THE SAME

Номер: US20170029547A1
Автор: Hasegawa Koji, Hatakeyama Jun
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

The present invention provides a resist composition containing a base resin composed of a polymer compound having a repeating unit in which a hydrogen atom of a carboxyl group is substituted with one or more acid-labile groups selected from groups shown by the following general formulae (1-1) to (1-5), 3. The resist composition according to claim 1 , wherein the polymer compound is further copolymerized with one or more repeating units b each containing an adhesion group selected from a hydroxyl group claim 1 , a lactone ring claim 1 , an ether group claim 1 , an ester group claim 1 , a carbonyl group claim 1 , a cyano group claim 1 , a sulfonate ester group claim 1 , a sulfonamide group claim 1 , cyclic —O—C(═O)—S— claim 1 , and cyclic —O—C(═O)—NH— claim 1 , with a content ratio of the repeating unit b of 0 Подробнее

Номер записи: 30
02-02-2017 дата публикации

RESIST COMPOSITION AND PATTERN FORMING PROCESS

Номер: US20170031243A1
Автор: Hasegawa Koji, Hatakeyama Jun
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A resist composition is provided comprising a polymer comprising recurring units (a) having an oxazolidinedione, thioxooxazolidinone, thiazolidinedione or thioxothiazolidinone structure and recurring unit (b1) having an acid labile group-substituted carboxyl group and/or recurring units (b2) having an acid labile group-substituted phenolic hydroxyl group. The resist composition suppresses acid diffusion, exhibits a high resolution, and forms a pattern of satisfactory profile with low edge roughness. 3. The resist composition of wherein the polymer further comprises recurring units having an adhesive group selected from the group consisting of hydroxyl claim 1 , carboxyl claim 1 , lactone ring claim 1 , carbonate claim 1 , thiocarbonate claim 1 , carbonyl claim 1 , cyclic acetal claim 1 , ether claim 1 , ester claim 1 , sulfonic acid ester claim 1 , cyano claim 1 , amide claim 1 , and —O—C(═O)-G- wherein G is —S— or —NH—.5. The resist composition of claim 1 , further comprising an acid generator and an organic solvent.6. The resist composition of claim 5 , further comprising a basic compound and/or a surfactant.7. A pattern forming process comprising the steps of applying the resist composition of onto a substrate to form a coating claim 1 , baking claim 1 , exposing the coating to high-energy radiation claim 1 , and developing the exposed coating in a developer.8. The process of wherein the high-energy radiation is i-line claim 7 , KrF excimer laser claim 7 , ArF excimer laser claim 7 , electron beam or soft X-ray of wavelength 3 to 15 nm. This non-provisional application claims priority under 35 U.S.C. 5119(a) on Patent Application NO. 2015-148563 filed in Japan on Jul. 28, 2015, the entire contents of which are lo hereby incorporated by reference.This invention relates to a resist composition and a patterning process using the composition.To meet the demand for higher integration density and operating speed of LSIs, the effort to reduce the pattern rule is in ...

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Номер записи: 31
09-02-2017 дата публикации

POLYMER COMPOUND, POSITIVE RESIST COMPOSITION, LAMINATE, AND RESIST PATTERNING PROCESS

Номер: US20170037167A1
Автор: Domon Daisuke, Kotake Masaaki, Masunaga Keiichi, WATANABE Satoshi
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A polymer compound containing a repeating unit shown by the formula (1c) and one or more repeating units selected from a repeating unit shown by the formula (2) and a repeating unit shown by the formula (3), 5. A positive resist composition comprising the polymer compound according to .6. A positive resist composition comprising the polymer compound according to .7. A positive resist composition comprising the polymer compound according to .8. A positive resist composition comprising the polymer compound according .9. The positive resist composition according to claim 5 , further comprising a compound capable of generating an acid by irradiation with a high energy beam.10. The positive resist composition according to claim 6 , further comprising a compound capable of generating an acid by irradiation with a high energy beam.11. The positive resist composition according to claim 7 , further comprising a compound capable of generating an acid by irradiation with a high energy beam.12. The positive resist composition according to claim 8 , further comprising a compound capable of generating an acid by irradiation with a high energy beam.15. A laminate comprising a resist film formed from the positive resist composition according to on a photomask blank.16. The laminate according to claim 15 , further comprising an antistatic film on the resist film.17. A resist patterning process comprising the step of: forming a resist film on a substrate to be processed from the positive resist composition according to ; exposing the formed resist film to a high energy beam by pattern irradiation; developing the exposed resist film with an alkaline developer to form a resist pattern.18. The resist patterning process according to claim 17 , wherein the high energy beam is an EUV or an electron beam.19. The resist patterning process according to claim 17 , wherein the substrate to be processed is a photomask blank.20. The resist patterning process according to claim 19 , wherein an ...

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Номер записи: 32
09-02-2017 дата публикации

Compound, polymer compound, resist composition, and patterning process

Номер: US20170038683A1
Автор: Jun Hatakeyama, Masahiro Fukushima, Masaki Ohashi, Takayuki Fujiwara
Принадлежит: Shin Etsu Chemical Co Ltd

The present invention provides a compound shown by the formula (1), wherein R 1 represents a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group; A represents a single bond or a linear divalent hydrocarbon group having 1 to 30 carbon atoms or a branched or cyclic divalent hydrocarbon group having 3 to 30 carbon atoms, in which the hydrocarbon group may contain a heteroatom, and a part or all of hydrogen atoms in the hydrocarbon group may be substituted with a group containing a heteroatom; “n” represents 0 or 1, provided that “n” is 0 when A is a single bond; and M + represents a cation. This compound is suitable as a raw material of a polymer compound usable for a base resin of a resist composition that has high resolution and high sensitivity and is excellent in balance of lithography properties such as LWR and CDU.

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Номер записи: 33
08-02-2018 дата публикации

INSULATED ELECTRIC WIRE

Номер: US20180040390A1
Автор: Nonaka Tsuyoshi
Принадлежит:

Provided is an insulated electric wire having an insulating layer containing a fluororesin, the insulated electric wire having a high flexibility with the heat resistance of the fluororesin maintained. The insulated electric wire is obtained by covering a conductor with an insulating layer containing a copolymer of a monomer expressed by Formula (1) below and a monomer expressed by Formula (2) below. It is preferable that a copolymerization ratio of the monomer expressed by Formula (2) above in the copolymer is at least 10 mass %. 1. An insulated electric wire obtained by covering a conductor with an insulating layer containing a copolymer of a monomer expressed by Formula (1) below and a monomer expressed by Formula (2) below ,{'br': None, 'sub': 2', '2, 'CF═CF\u2003\u2003(1)'}{'br': None, 'sub': '2', 'CF═CF—O—Rf\u2003\u2003(2)'}where Rf represents a perfluoroalkyl group having at least 5 carbon atoms.2. The insulated electric wire according to claim 1 ,wherein a copolymerization ratio of the monomer expressed by Formula (2) above in the copolymer is at least 10 mass %.3. The insulated electric wire according to claim 1 ,wherein the copolymer is a thermoplastic.4. The insulated electric wire according to claim 1 ,wherein a copolymerization ratio of the monomer expressed by Formula (2) above in the copolymer is not more than 95 mass %.5. The insulated electric wire according to claim 1 ,wherein a copolymerization ratio of the monomer expressed by Formula (2) above in the copolymer is at least 15 mass %.6. The insulated electric wire according to claim 1 ,wherein the Rf represents a perfluoroalkyl group having at least 6 carbon atoms. This application claims the priority of Japanese patent application JP2015-016691 filed on Jan. 30, 2015, the entire contents of which are incorporated herein.The present invention relates to an insulated electric wire, and specifically to an insulated electric wire that is suitably used in a vehicle such as an automobile.A fluororesin ...

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Номер записи: 34
18-02-2021 дата публикации

Copolymer and method for producing same

Номер: US20210047451A1
Автор: Ryosuke Takechi, Yasuhiro Ono
Принадлежит: NIPPON SHOKUBAI CO LTD

The present invention provides a polymer having excellent dye transfer inhibition performance. The present invention relates to a copolymer containing a structural unit (a) derived from a N-vinyl lactam monomer (A) and a structural unit (b) derived from a monomer (B) represented by the following formula (1), (1′), or (1″). The structural unit (b) is present in a proportion of 1 to 99% by mass based on 100% by mass of all structural units.

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Номер записи: 35
19-02-2015 дата публикации

(meth) acrylic acid copolymer and method for manufacturing same

Номер: US20150051363A1
Автор: Masato Nakano, Yuki Sano
Принадлежит: NIPPON SHOKUBAI CO LTD

The (meth)acrylic acid-based copolymer of the present invention includes, as essential structural units: 16 mol % or more but 24 mol % or less of a structural unit (a) derived from a monomer represented by Formula (1): wherein R 2 represents a hydrogen atom or a methyl group; and X and Y each independently represent a hydroxy group, a sulfonic acid group, or a sulfonic acid salt group, at least one of X and Y representing a sulfonic acid group or a sulfonic acid salt group; and 76 mol % or more but 84 mol % or less of a structural unit (b) derived from (meth)acrylic acid or a salt thereof, each based on 100 mol % of all the structural units derived from monomers, the copolymer comprising a main chain having a sulfonic acid group or a sulfonic acid salt group at at least one end thereof, the copolymer having a weight average molecular weight of 1000 to 18000.

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Номер записи: 36
25-02-2016 дата публикации

USE OF SILICON-CONTAINING POLYMERS TO IMPROVE RED MUD FLOCCULATION IN THE BAYER PROCESS

Номер: US20160052807A1
Автор: Chen Huann-Lin Tony, Dai Qi, Heitner Howard I., Spitzer Donald Paul
Принадлежит: CYTEC TECHNOLOGY CORP.

The suspended solids content of a Bayer process stream is reduced by contacting the stream with silicon-containing polymers. 1. A flocculation method comprising:intermixing a silicon-containing polymer flocculant with a Bayer process stream in an amount effective to thereby flocculate at least a portion of a desilication product suspended therein; andseparating at least a portion of the flocculated desilication product thus formed.2. The flocculation method of claim 1 , wherein the silicon-containing polymer flocculant comprises a plurality of —Si(OR)3 groups claim 1 , wherein R is independently selected from the group consisting of hydrogen claim 1 , Calkyl claim 1 , Calkenyl claim 1 , Caryl claim 1 , Caralkyl claim 1 , a group I metal ion claim 1 , a group II metal ion claim 1 , and NR′wherein R′ is independently selected from the group consisting of hydrogen claim 1 , Calkyl claim 1 , Calkenyl claim 1 , Caryl claim 1 , and Caralkyl; and wherein R and R′ are independently unsubstituted claim 1 , hydroxy-substituted claim 1 , or beta hydroxy substituted.3. The flocculation method of claim 2 , where R is selected from the group consisting of Na claim 2 , K claim 2 , and NH.4. The flocculation method of claim 1 , wherein the silicon-containing polymer flocculant is selected from the group consisting of a silicon-containing polyethyleneimine claim 1 , a vinyl triethoxysilane copolymer claim 1 , a copolymer of acrylic acid and triethoxysilylpropylacrylamide claim 1 , a copolymer of acrylic acid and triethoxyvinylsilane claim 1 , a silicon-containing polysaccharide claim 1 , a silicon-containing styrene/maleic anhydride copolymer claim 1 , a silicon-containing maleic anhydride/alkyl vinyl ether copolymer claim 1 , and mixtures thereof claim 1 , a silicon-containing polysaccharide claim 1 , a silicon-containing maleic anhydride/alkyl vinyl ether copolymer claim 1 , and mixtures thereof.5. The flocculation method of claim 1 , wherein the silicon-containing polymer ...

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Номер записи: 37
13-02-2020 дата публикации

COPOLYMERS SUITABLE FOR PLASTICIZING INORGANIC BINDER SYSTEMS

Номер: US20200048149A1
Автор: Kraus Alexander, MITKINA Tatiana, PULKIN Maxim
Принадлежит:

The present invention relates to copolymers that comprise salicylic acid derivative structural units and structural units having free polyether side chains. The copolymers are suitable to plasticize inorganic binder systems, construction chemical compositions comprising said copolymers and the use of said copolymers as a plasticizer for inorganic binder systems. Binder systems with a reduced amount of Portland cement comprising at least one copolymer of the invention provide a better liquefaction and processability as compared to said binder systems without a copolymer of the invention. 2. The copolymer according to claim 1 , wherein t is 0.4. The copolymer according to claim 1 , wherein Ris H or CH claim 1 , Ris H claim 1 , Ris H or COOM claim 1 , x is 0 claim 1 , y is 1 claim 1 , and z is 1.5. The copolymer according to claim 1 , wherein Ris H or CH claim 1 , Rand Rare H claim 1 , x is 0 claim 1 , 1 or 2 claim 1 , y is 0 and z is 1.7. The copolymer according to claim 1 , wherein the copolymer comprises: [{'sup': 10', '12', '11', '13, 'sub': 3', '1', '4, 'a) Z is O and E and G together are a chemical bond, Rand Rare H, Ris H or CH, n is 1 or 2 and Ris H or an unbranched or branched C-Calkyl group; or'}, {'sub': 1', '6', '1', '4, 'sup': 10', '11', '12', '13, 'b) Z is O, E is an unbranched or branched C-Calkylene group, G is O, R, Rand Rare H, n is 0 and Ris H or an unbranched or branched C-Calkyl group; or'}], 'structural units (IIa), wherein{'sup': '25', 'structural units (IIc), wherein W is O or NR.'}8. The copolymer according to claim 7 , wherein in structural units (IIc) Rand Rare H claim 7 , Ris H or CHand Ris H or an unbranched or branched C-Calkyl group.9. The copolymer according to claim 1 , wherein the copolymer comprises structural units (IId) claim 1 , wherein Ris H claim 1 , Q is O claim 1 , and Ris H or an unbranched or branched C-Calkyl group.10. The copolymer according to claim 6 , wherein a is 5 to 135.12. A construction chemical composition ...

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Номер записи: 38
08-05-2014 дата публикации

1,3-Diketoamide Functional Polymers and Compositions Employing the Same

Номер: US20140128537A1
Автор: Garry Kenneth Weakley, John Thorton Maddox, Peter Webb Raynolds, Stacey James Marsh
Принадлежит: Eastman Chemical Co

A 1,3-diketoamide functional monomer represented by the following formula (1): wherein R and Y are independently selected from the group consisting of hydrogen, an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 20 carbon atoms, and an aralkyl group having from 7 to 20 carbon atoms; and wherein X and Z are independently selected from the group consisting of an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 20 carbon atoms, and an aralkyl group having from 7 to 20 carbon atoms. Also disclosed are emulsion, suspension, and solution polymers comprising residues from the 1,3-diketoamide functional monomer of formula 1 and, optionally, one or more additional ethylenically unsaturated monomers. Both latex and self-curing coating compositions described herein exhibit excellent hydrolytic stability, including increased retention of 1,3-diketo functionality.

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Номер записи: 39
15-05-2014 дата публикации

MELT-FABRICABLE PERFLUOROPOLYMERS HAVING IMPROVED HEAT AGING PROPERTY

Номер: US20140135463A1
Автор: LAHIJANI JACOB
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

Heat aging of the composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, the alkyl containing 1 to 5 carbon atoms and melt flowable polytetrafluoroethylene is effective to cause thermal transformation of the composition in the solid state, which is epitaxial co-crystallization of the polymer components of the composition, and other valuable changes, such as increased continuous use temperature. 1. The heat aged composition of .214. The heat-aged composition of claim in the form of electrical insulation claim 1 , lining claim 1 , heat exchanger elements claim 1 , including tubes claim 1 , self-supporting articles claim 1 , including baskets and carriers claim 1 , and tubing.3. Heat-aged composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer claim 1 , wherein said perfluoroalkyl contains 1 to 5 carbon atoms claim 1 , and melt flowable polytetrafluoroethylene claim 1 , said heat aged composition exhibiting one or more of the following:(a) a continuous use temperature of at least 300° C.,(b) a reduced coefficient of friction,(c) a reduced permeation to gases by at least 50%,(d) a decrease in melt flow rate of at least 25% as compared to the melt flow rate of said composition prior to heat aging,(e) an increase of at least 30% in storage modulus at 300° C.(f) an increase in thickness of its crystalline layer characterized by an increase in long period of at least 25%,(g) an increased resistance to sagging and/or ballooning, an increase crystallinity index by at least 10%,(h) improvement in uniformity of crystal structure characterized by an increase in long period coherence of at least 10%,(i) an increase in thickness of crystalline layer characterized by an increase in long period of at least 25%,(j) epitaxial co-crystallization.4. Heat-aged composition comprising melt-fabricable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer claim 1 , wherein said perfluoroalkyl contains ...

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Номер записи: 40
05-03-2015 дата публикации

COPOLYMER FOR DISPERSANT FOR CEMENT, DISPERSANT FOR CEMENT, AND CEMENT COMPOSITION

Номер: US20150065615A1
Автор: HIRATA Tsuyoshi, Lange Alex, Plank Johann
Принадлежит:

An object of the present invention is to provide a novel copolymer capable of exerting excellent dispersibility to various kinds of cement including cement having low fluidity (difficult cement), and a dispersant for cement and cement composition including the copolymer. 3. The copolymer according to claim 1 ,{'sub': '3', 'claim-text': [{'sub': '3', 'a total amount of the component CA and the calcium oxide in the cement is more than 4% by weight, and'}, 'the amount of the calcium oxide in the cement is more than 0.2% by weight., 'wherein the copolymer is to be added to a cement containing component CA and calcium oxide,'}4. A dispersant for cement claim 1 , comprising the copolymer according to .5. A cement composition claim 1 , comprising the copolymer according to claim 1 , a cement claim 1 , and water claim 1 ,{'sub': '3', 'wherein the cement contains component CA and calcium oxide,'}{'sub': '3', 'a total amount of the component CA and calcium oxide in the cement is more than 4% by weight, and'}the amount of the calcium oxide in the cement is more than 0.2% by weight.6. The copolymer according to claim 2 ,{'sub': '3', 'wherein the copolymer is to be added to a cement containing component CA and calcium oxide,'}{'sub': '3', 'a total amount of the component CA and the calcium oxide in the cement is more than 4% by weight, and'}the amount of the calcium oxide in the cement is more than 0.2% by weight.7. A dispersant for cement claim 2 , comprising the copolymer according to .8. A cement composition claim 2 , comprising the copolymer according to claim 2 , a cement claim 2 , and water claim 2 ,{'sub': '3', 'wherein the cement contains component CA and calcium oxide,'}{'sub': '3', 'a total amount of the component CA and calcium oxide in the cement is more than 4% by weight, and'}the amount of the calcium oxide in the cement is more than 0.2% by weight. The present invention relates to a copolymer for a dispersant for cement, a dispersant for cement, and a cement ...

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Номер записи: 41
09-03-2017 дата публикации

Use of eugenol polyethers and eugenol polyether siloxanes as wetting agents

Номер: US20170065951A1
Автор: Katrin Roland, Matthias Lobert, Michael Ferenz, Thorsten SCHIERLE
Принадлежит: EVONIK DEGUSSA GmbH

The present invention relates to compositions comprising eugenol polyethers and/or eugenol polyethers modified with siloxanes, and to the use of eugenol polyethers in polyether siloxanes based on these eugenol polyethers as wetting agents.

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Номер записи: 42
11-03-2021 дата публикации

Binder aqueous solution for lithium-ion battery electrode, slurry for lithium-ion battery electrode, lithium-ion battery electrode, and lithium-ion battery

Номер: US20210075019A1
Автор: Hideki Goda, Katsuya OKUBO, Naoki Sasagawa, Satoru Aoyama
Принадлежит: Arakawa Chemical Industries Ltd

Provided are a binder aqueous solution for a lithium-ion battery electrode, a slurry for a lithium-ion battery electrode, a lithium-ion battery electrode, and a lithium-ion battery. The binder aqueous solution for a lithium-ion battery electrode contains a water-soluble polymer (A). The water-soluble polymer (A) is a polymer of a monomer group containing, with respect to 100 mol % of the monomer group, 5 mol % to 80 mol % of a hydroxyl group-containing vinyl ether (a). In one embodiment, the monomer group contains 20 mol % to 95 mol % of a (meth)acrylamide group-containing compound (b).

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Номер записи: 43
17-03-2016 дата публикации

CNSL-BASED HYDROCARBON RESINS, PREPARATION AND USES THEREOF

Номер: US20160075805A1
Автор: Natesh Anbazhagan, Pinto Mauricio, Wei Junhong, Xu Hong
Принадлежит:

The present invention is directed to resins made from cashew nutshell liquid and vinyl hydrocarbons and processes for manufacturing the resins. These resins exhibit lower viscosity than the phenol-based homologs. They also exhibit good compatibility with a wide range of solvents, mineral and natural oils, epoxy curing agents, liquid epoxy resins, and polymers, which make them suitable additives as non-reactive diluents for solvent-free coating formulations; tackifiers for structural adhesive, pressure sensitive and hot-melt adhesives; stabilizers for lubricants, fuel and polymer formulations; plasticizers for thermoplastic polymers and processing aid for rubber compounding and stabilizers for respective rubber artifacts. These resins are also valuable precursors for the manufacture of epoxy resins and polyols for coating, adhesive and composite omulations exhibiting ameliorated performance in water repellency, anti-corrosion, and fast hardness development during cure. 1. A Cashew Nut Shell Liquid based hydrocarbon resin comprising:a) between about 40% by weight to 90% by weight vinylated cardanols;b) between about 5% by weight to about 25% by weight vinylated cardol; andc) between about 5% by weight to about 30% by weight of one or more additional polymers.2. The hydrocarbon resin of claim 1 , wherein the vinylated cardanols comprise vinyl hydrocarbon monomers selected from the group consisting of styrene claim 1 , alpha-methylstyrene claim 1 , vinyltoluene claim 1 , indene claim 1 , alpha-vinylnaphthalene claim 1 , diisopropenylbenzene claim 1 , the C9 fraction from a petroleum cracking process claim 1 , divinylbenzene claim 1 , and mixtures of divinylbenzene and ethylvinylbenzenes.3. The hydrocarbon resin of claim 1 , wherein the vinylated cardanols comprise vinyl hydrocarbon monomers selected from the group consisting of isobutylene claim 1 , butadiene claim 1 , isoprene claim 1 , pentadiene claim 1 , cyclopendadiene claim 1 , dicyclopentadiene claim 1 , pinenes ...

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Номер записи: 44
07-03-2019 дата публикации

Fine and Uniform Methyl Vinyl Ether-Maleic Acid Inorganic Salt Copolymers and Their Use in Oral Care and Pharmaceutical Applications

Номер: US20190071521A1
Автор: Sun Jianxin, Sun Xudong, Ulmer Herbert Wilhelm, WANG Jianqiang, Wang Long, Yuan Guodong
Принадлежит:

The invention relates to fine and uniform copolymer powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having a defined particle size distribution. In particular; it relates to powders that are suitably used in the areas of oral care and pharmaceuticals and to methods for preparing the powders. Provided is a composition of powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having: (i) a Dv50 of less than or equal to 25 microns; a Dv90 of less than or equal to 50 microns; and (ii) a particle uniformity reflected by a Dv90/Dv10 ratio of less than or equal to 10. 1. A composition of powders of partial mixed metal salts of lower alkyl vinyl ether-maleic acid copolymers having:(i) a median particle size by volume (Dv50) of less than or equal to 25 microns; a maximum particle diameter below which 90% of the sample volume exists (Dv90) of less than or equal to 50 microns; and(ii) a particle uniformity reflected by a ratio between the maximum particle diameter below which 90% of the sample volume exists and the maximum particle diameter below which 10% of the sample volume exists (Dv90/Dv10 ratio) of less than or equal to 10, preferably wherein the Dv90/Dv10 ratio is less than or equal to 6.2. The composition of claim 1 , having a Dv50 of less than 15 microns claim 1 , a Dv90 of less than 25 microns and a Dv90/Dv10 ratio of less than 6.3. The composition of claim 1 , in which the oversize fraction equal to or less than 1% by volume is not greater than 75 microns.4. The composition of claim 1 , wherein from about 10 to about 90 mole % of the carboxylic units in the polymer are converted to a mixture of metal salts.5. The composition of wherein the metal salt is selected from the group consisting of sodium claim 4 , calcium claim 4 , strontium claim 4 , zinc claim 4 , magnesium claim 4 , iron and potassium.6. The composition of claim 5 , wherein the partial mixed metal salts are sodium and calcium salts.7 ...

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Номер записи: 45
24-03-2022 дата публикации

Ultra-Pure Methyl Vinyl Ether-Co-Maleic Anhydride Copolymers and Methods for Preparing Same

Номер: US20220089798A1
Автор: Sun Xudong, Ulmer Herbert Wilhelm, WANG Jianqiang
Принадлежит:

Ultra-pure methyl vinyl ether-co-maleic anhydride (PMVE/MA) copolymers and the process to produce such ultra-pure polymers by removing trace impurities are provided. A process to provide an ultra-pure methyl vinyl ether-co-maleic anhydride material by solvent washing PMVE/MA copolymer with a solvent, comprises the steps of: (1) providing a solvent system in which impurities in the copolymer matrix are soluble and in which the PMVE/MA copolymer is not soluble, and wherein the solvent system does not react with the copolymer; (2) washing a dry powder or wet filter cake of PMVE/MA copolymer with the solvent system to efficiently and effectively extract trace impurities from the matrix; (3) filtering said copolymer from the solvent system; and (4) drying the subsequent wet filter cake of said copolymer to obtain an ultra-pure methyl vinyl ether-co-maleic anhydride copolymer. 1. A process to provide an ultra-pure methyl vinyl ether-co-maleic anhydride material by solvent washing a methyl vinyl ether-co-maleic anhydride (PMVE/MA) copolymer with a solvent , comprising the steps of:(1) providing a solvent system in which one or more impurities in the copolymer matrix are soluble and in which the PMVE/MA copolymer is not soluble, and wherein the solvent system does not react with the copolymer;(2) washing a dry powder or wet filter cake of PMVE/MA copolymer with the solvent system to efficiently and effectively extract trace impurities from the copolymer matrix;(3) filtering said copolymer from the solvent system; and(4) drying the subsequent wet filter cake of said copolymer to obtain an ultra-pure methyl vinyl ether-co-maleic anhydride copolymer.2. The process according to claim 1 , wherein the one or more impurities comprise one or more of dimethoxy ethane (DME) claim 1 , trimethoxy butane (TMB) claim 1 , acetaldehyde and methanol.3. The process of claim 1 , wherein the solvent system is selected from the group consisting of chlorinated solvents claim 1 , hydrocarbon ...

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Номер записи: 46
24-03-2022 дата публикации

ADDITIVELY MANUFACTURED THERMOSET POLYMERS FOR METAL PLATING AND METAL PLATED PARTS FORMED THEREFROM

Номер: US20220089799A1
Автор: Bedard Robert D., Bollin Shannon Christine, Cassoli Matthew, Lee Ellen Cheng-chi, Wang Xiaojiang
Принадлежит: FORD GLOBAL TECHNOLOGIES, LLC

A thermoset resin for forming parts to be metal plated includes a vat photopolymerization (VPP) thermoset resin and an etchable phase disposed in the VPP thermoset resin. The etchable phase is etched from a surface of a part formed from the VPP thermoset resin such that a plurality of micro-mechanical locking sites is formed on the surface of the part. The etchable phase is at least one of organic particles, organic resins, inorganic particles, and copolymers of the VPP thermoset resin. For example, the etchable phase can be a polybutadiene phase and/or a mineral such as calcium carbonate. 1. A thermoset resin for forming parts to be metal plated , the thermoset resin comprising:a vat photopolymerization (VPP) thermoset resin; andan etchable phase disposed in the VPP thermoset resin, wherein the etchable phase is configured to be etched from a surface of a part formed from the VPP thermoset resin such that a plurality of micro-mechanical locking sites is formed on the surface of the part.2. The thermoset resin according to claim 1 , wherein the VPP thermoset resin comprises a mixture of at least one monomer claim 1 , at least one oligomer claim 1 , and at least one photoinitiator.3. The thermoset resin according to claim 1 , wherein the VPP thermoset resin comprises at least one monomer selected from the group consisting of an (meth)acrylate monomer and a vinyl ether.4. The thermoset resin according to claim 3 , wherein the (meth)acrylate monomer is at least one of a monofunctional monomer claim 3 , a difunctional monomer claim 3 , and a multifunctional monomer.5. The thermoset resin according to claim 3 , wherein the (meth)acrylate monomer is at least one of 2-Ethyl hexyl acrylate (EHA) claim 3 , n-butyl acrylates (BA) claim 3 , 1 claim 3 ,4-butanediol diacrylate (BDDA) claim 3 , diethyleneglycoldiacrylate (DEGDA) claim 3 , bisphenol A-glycidyl methacrylate (Bis-GMA) claim 3 , bisphenol A ethoxylate diacrylate (Bis-EDA) claim 3 , trimethylolpropane triacrylate (TTA ...

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Номер записи: 47
05-06-2014 дата публикации

HYDROPHILIC CROSSLINKED POLYMER

Номер: US20140155565A1
Автор: JOEHNCK Matthias, SABROWSKII Eckhard
Принадлежит: Merck Patent GmBH

The present invention relates to a hydrophilic crosslinked polymer, preferably in the form of porous particles, and to the preparation and use thereof. The polymer according to the invention is produced by polymerisation from chain-forming hydrophilic vinyl ethers and crosslinking, preferably heterocyclic divinyl ethers. 120-. (canceled)22. A polymer according to claim 21 , wherein R4 in formula I is a straight-chain or branched C1 to C10 alkyl radical claim 21 , in which one or more non-adjacent methylene groups may be replaced by O claim 21 , C═O claim 21 , S claim 21 , S═O claim 21 , SO claim 21 , NH claim 21 , NOH claim 21 , or N and/or in which one or more H atoms may be substituted claim 21 , independently of one another claim 21 , by C1-C6-alkyl claim 21 , C5-C10-aryl claim 21 , halogen claim 21 , NH claim 21 , NH(C1-C8)alkyl claim 21 , N(C1-C8)alkyl claim 21 , C1-C6-alkoxy or C1-C6-alkyl-OH and in which at least one OH group is present either on the C1 to C10 alkyl radical or on a substituent claim 21 , or{'sub': 2', '2', '2, 'a cycloaliphatic radical, in which one or more non-adjacent methylene groups may be replaced by O, C═O, S, S═O, SO, NH, NOH, or N and/or in which one or more H atoms of the cycloaliphatic radical may be substituted, independently of one another, by C1-C6-alkyl, C5-C10-aryl, halogen, NH, NH(C1-C8)alkyl, N(C1-C8)alkyl, C1-C6-alkoxy or C1-C6-alkyl-OH, where at least one OH group is present either on the cycloaliphatic ring or on a side chain or substituent, or'}{'sub': 2', '2, 'a C6 to C18 aryl radical, where one or more H atoms in the aryl radical may be substituted, independently of one another, by hydroxyl, C1-C6-alkyl, C5-C10-aryl, halogen, NH, NH(C1-C8)alkyl, N(C1-C8)alkyl, C1-C6-alkoxy or C1-C6-alkyl-OH, where at least one OH group is present either on the aryl radical or on a side chain or substituent, or'}{'sub': 2', '2, 'a C5 to C18 heteroaryl radical, where one or more H atoms in the heteroaryl radical may be substituted, ...

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Номер записи: 48
26-03-2015 дата публикации

ACTINIC RAY-SENSITIVE OR RADIATION-SENSITIVE RESIN COMPOSITION, RESIST FILM AND PATTERN FORMING METHOD USING THE SAME, MANUFACTURING METHOD OF SEMICONDUCTOR DEVICE, AND SEMICONDUCTOR DEVICE

Номер: US20150086912A1
Автор: Kawabata Takeshi, Takizawa Hiroo, TSUBAKI Hideaki, YOKOKAWA Natsumi
Принадлежит: FUJIFILM Corporation

There is provided an actinic ray-sensitive or radiation-sensitive resin composition comprising (P) a resin having a repeating unit (A) represented by the specific formula (I) capable of generating an acid on the side chain of the resin upon irradiation with an actinic ray or radiation, and a resist film formed with the actinic ray-sensitive or radiation-sensitive resin composition, and a pattern forming method comprising: exposing the resist film, and developing the exposed resist film, and a method for manufacturing a semiconductor device, containing the pattern forming method, and a semiconductor device manufactured by the manufacturing method of the semiconductor device. 2. The actinic ray-sensitive or radiation-sensitive resin composition as claimed in claim 1 ,{'sup': 1', '2, 'wherein each of Xand Xis —O—.'}3. The actinic ray-sensitive or radiation-sensitive resin composition as claimed in claim 1 ,{'sub': '1', 'wherein in formula (I), the number of atoms for constituting the main structure of the alkylene group, the ankenylene group, the divalent aliphatic hydrocarbon cyclic group, the divalent aromatic cyclic group, or the group formed by combining two or more of these groups represented by Lin formula (I) is 2 to 7.'}4. The actinic ray-sensitive or radiation-sensitive resin composition as claimed in claim 1 ,wherein the resin (P) is a resin further having (B) a repeating unit having a group capable of decomposing by an action of an acid to generate a polar group.8. The actinic ray-sensitive or radiation-sensitive resin composition as claimed in claim 1 , which is exposed with an electron beam or an extreme ultraviolet ray.9. A resist film formed with the actinic ray-sensitive or radiation-sensitive resin composition as claimed in .10. A pattern forming method comprising:{'claim-ref': {'@idref': 'CLM-00009', 'claim 9'}, 'exposing the resist film claimed in , and'}developing the exposed resist film.11. The pattern forming method as claimed in claim 10 ,wherein ...

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Номер записи: 49
31-03-2022 дата публикации

COATED COLORANT, COLORING COMPOSITION, AND COATED COLORANT MANUFACTURING METHOD

Номер: US20220098415A1
Автор: AOTANI Tomoyuki, SUZUKI Tomohiko
Принадлежит:

A purpose of the present disclosure is to provide a coated colorant and a coloring composition that have superior dispersion stability, high compatibility with binder resins, low viscosity after being made into an ink, good preservation stability, and a good film gloss value. Provided is a coated colorant in which a surface of a colorant is coated with a resin (P), the resin (P) contains a colorant adsorption group-containing monomer unit, a maleic acid (anhydride) unit, and a (meth)aryl monomer unit, and the colorant adsorption group-containing monomer unit contains at least one of an α-olefin unit and a ring-containing monomer unit. 1. A coated colorant , comprising:a resin (P) which is coated on a surface of a colorant,wherein the resin (P) contains a colorant adsorption group-containing monomer unit, a maleic acid (anhydride) unit, and a (meth)allyl monomer unit, andthe colorant adsorption group-containing monomer unit contains at least one of an α-olefin unit and a ring-containing monomer unit.2. The coated colorant according to claim 1 ,wherein the (meth)allyl monomer unit has a (poly)alkyleneoxy group.3. The coated colorant according to claim 1 ,wherein a number average molecular weight of the resin (P) is 2,000 to 35,000.4. The coated colorant according to claim 2 ,wherein a number average molecular weight of the resin (P) is 2,000 to 35,000.5. The coated colorant according to claim 1 ,wherein the maleic acid (anhydride) unit of the resin (P) has an ester binding site, an amide binding site, or an imide binding site.6. The coated colorant according to claim 2 ,wherein the maleic acid (anhydride) unit of the resin (P) has an ester binding site, an amide binding site, or an imide binding site.7. The coated colorant according to claim 3 ,wherein the maleic acid (anhydride) unit of the resin (P) has an ester binding site, an amide binding site, or an imide binding site.8. The coated colorant according to claim 4 ,wherein the maleic acid (anhydride) unit of the ...

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Номер записи: 50
29-03-2018 дата публикации

Monomer composition containing unsaturated polyalkylene glycol ether-based monomer, method for producing composition thereof, polymer obtained using composition thereof, and method for producing polymer thereof

Номер: US20180086912A1
Автор: Hiroshi Kawabata
Принадлежит: NIPPON SHOKUBAI CO LTD

A monomer composition containing an unsaturated polyalkylene glycol ether-based monomer is provided having excellent stability. The monomer composition contains an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1): YO(R 1 O) n R 2   (1) [in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R 1 O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition, mole number of oxyalkylene groups and is a number of 5 to 500; and R 2 represents a hydrogen atom, or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

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Номер записи: 51
31-03-2016 дата публикации

Cross-linkable polymers comprising sulfonic acid functional groups

Номер: US20160090429A1
Автор: Claudio Oldani, Cristiano Monzani, Luca Merlo, Vito Tortelli
Принадлежит: Solvay Specialty Polymers Italy SpA

The present invention pertains a fluoropolymer [polymer (F)] comprising: —recurring units derived from at least one ethylenically unsaturated fluorinated monomer [monomer (FM)]; —from 5% to 60% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived at least one ethylenically unsaturated fluorinated monomer containing at least one —SO 2 F functional group [monomer (IO)]; and —from 0.01% to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a cross-linkable composition comprising the same, to a process for cross-linking the same and to articles comprising the cross-linked polymer.

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Номер записи: 52
30-03-2017 дата публикации

RAPID AZEOTROPIC PHOTO-COPOLYMERIZATION OF STYRENE AND METHACRYLATE DERIVATIVES AND USES THEREOF

Номер: US20170088656A1
Автор: Sun Jirun
Принадлежит:

A composition of matter includes a mixture of styrene derivative monomers and methacrylate/acrylate derivative monomers, which have one or more urethane, carbamate, amide, and/or amine functional groups, and initiators, and the compositions are used to achieve composition control of the forming polymer, with the mole fraction of acrylate/methacrylate and styrene moieties in the forming polymer determined preferably by the chemistry and composition of the feeding monomers rather than the viscosity of the monomers. 1. A composition of matter , comprising:two or more vinyl-containing monomer(s); andone or more initiators, wherein the two or more vinyl-containing monomers undergo vinyl conversion to form a composition-controlled resin.2. The composition of matter of claim 1 , wherein:the two or more vinyl-containing monomer(s) are chosen from a group consisting of mixtures of methacrylate derivatives and styrene derivatives, and mixtures of acrylate derivatives and styrene derivatives; andthe methacrylate and styrene moieties or the acrylate and styrene moieties are in a same monomer or different monomers.3. The composition of matter of claim 1 , wherein one or more of the vinyl-containing monomer(s) have functional groups selected from a group consisting of:one or more carbamate groups and/or derivatives;one or more urethane groups and/or derivatives; andone or more amine groups and/or derivatives.4. The composition of matter of claim 1 , wherein the initiators are selected from a group consisting of:photo-initiator(s) including camphorquinone or derivatives,a combination of camphorquinone or derivatives and amine(s), including ethyl-4-N,N-dimethyl-aminobenzonate; orPhenylpropanedione or derivatives, including 1-phenyl-1,2-propanedione; orBisacrylphosphine oxide or derivatives, including bis(2,4,6-trimethylbenzoyl)-phenylphosphineoxide (Irgacure 819), bis(2,6-dimethoxy benzoyl)-trimethylpentyl phosphine oxide, and 1-hydroxycyclohexyl phenyl ketone, wherein the ...

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Номер записи: 53
05-04-2018 дата публикации

IMPROVED MEMBRANES FOR SEPARATION OF ALKENES FROM ALKANES

Номер: US20180093230A1
Автор: KOIZUMI YOSUKE
Принадлежит:

Improved membranes which can separate alkanes and alkenes, and have at least one layer of a Group 11 metal ionomer, are made by exposing the ionomer to a strong Bronsted acid having a pKa of about 1 or less. The membranes have longer useful lives and have better initial permeances of alkenes. 1. A process for making a silver ionomer , comprising ,(a) contacting, in a liquid medium, a fluorinated polymer containing pendant sulfonic acid groups with a silver salt whose anion's conjugate Bronsted acid has a pKa in water at 25° C. of less than 1.0, provided that in said fluorinated copolymer at least 10% of the total of the carbon-hydrogen groups and carbon fluorine groups present are carbon-fluorine groups; and(b) optionally filtering a solution to remove insoluble materials.2. A process from separating one or more alkanes from one or more alkenes , comprising:(a) forming a silver ionomer by contacting, in a liquid medium, a fluorinated polymer containing pendant sulfonic acid groups with a silver salt whose anion's conjugate Bronsted acid has a pKa in water at 25° C. of less than 1.0, and provided that said fluorinated copolymer at least 10% of the total of the carbon-hydrogen groups and carbon fluorine groups present are carbon-fluorine groups;(b) making a membrane from said silver ionomer, said membrane having a first side and a second side; and(c) exposing said first side of said membrane to a first mixture of one or more alkenes and one or more alkanes;(d) providing a driving force;(e) producing a second mixture, on a second side of said membrane, having a higher ratio of alkene to alkane than said first mixture.3. A process for making a silver ionomer , comprising ,(a) contacting, in a liquid medium, a fluorinated polymer containing pendant sulfonic acid groups with a silver salt, provided that in said fluorinated copolymer at least 10% of the total of the carbon-hydrogen groups and carbon fluorine groups present are carbon-fluorine groups; and(b) contacting said ...

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Номер записи: 54
09-04-2015 дата публикации

Cnsl-based hydrocarbon resins, preparation and uses thereof

Номер: US20150099851A1
Автор: Anbazhagan Natesh, HONG XU, Junhong Wei, Mauricio Pinto
Принадлежит: Cardolite Corp

The present invention is directed to resins made from cashew nutshell liquid and vinyl hydrocarbons and processes for manufacturing the resins. These resins exhibit lower viscosity than the phenol-based homologs. They also exhibit good compatibility with a wide range of solvents, mineral and natural oils, epoxy curing agents, liquid epoxy resins, and polymers, which make them suitable additives as non-reactive diluents for solvent-free coating formulations; tackifiers for structural adhesive, pressure sensitive and hot-melt adhesives; stabilizers for lubricants, fuel and polymer formulations; plasticizers for thermoplastic polymers and processing aid for rubber compounding and stabilizers for respective rubber artifacts. These resins are also valuable precursors for the manufacture of epoxy resins and polyols for coating, adhesive and composite formulations exhibiting ameliorated performance in water repellency, anti-corrosion, and fast hardness development during cure.

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Номер записи: 55
28-03-2019 дата публикации

COPOLYMER, ANTITHROMBOTIC COATING AGENT USING SAME AND MEDICAL DEVICE

Номер: US20190091380A1
Автор: TANAKA Masaru, YOSHIDA Norihiro
Принадлежит:

A biocompatible material, which has excellent film formation properties and resistance to water dissolution, and is easily applied on various bases as a coating, while having excellent antithrombotic properties, and to provide an antithrombotic coating agent and an antithrombotic coating film produced by using the biocompatible material, and a medical device provided with the antithrombotic coating film. A copolymer, containing at least one repeating unit (A) represented by formula (1) (wherein, n represents an integer of 2 to 10 and Rrepresents a methyl group or an ethyl group), and at least one repeating unit (B) represented by formula (2) (wherein Rrepresents an aliphatic hydrocarbon group); an antithrombotic coating agent containing the copolymer and an organic solvent; an antithrombotic coating film formed of the copolymer; and a medical device provided with the coating film. 2: The copolymer according to claim 1 , wherein the composition ratio (molar ratio) of the repeating unit (A) to the repeating unit (B) is 90/10 to 1/99.3: The copolymer according to claim 1 , wherein Ris a linear or branched alkyl group or alkenyl group having 2 to 10 carbon atoms or a monocyclic or polycyclic alkyl group or alkenyl group having 5 to 15 carbon atoms.4: The copolymer according to claim 1 , wherein Ris a linear or branched alkyl group or alkenyl group having 2 to 10 carbon atoms.5: A biocompatible material claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the copolymer according to .'}6: An antithrombotic coating agent claim 1 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'the copolymer according to and'}an organic solvent.7: The antithrombotic coating agent according to claim 6 , wherein the organic solvent is at least one selected from the group consisting of an aromatic hydrocarbon claim 6 , an aliphatic hydrocarbon claim 6 , a halogenated hydrocarbon claim 6 , an ether claim 6 , an alcohol claim 6 , a ketone claim 6 , and an ester. ...

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Номер записи: 56
08-04-2021 дата публикации

HYDROPHILIC COPOLYMER AND MEDICAL DEVICE

Номер: US20210102019A1
Автор: KURAMOTO Masanori, YOKOTE Narumi
Принадлежит: TERUMO KABUSHIKI KAISHA

Disclosed is a hydrophilic copolymer including more than 50% by mol of a structural unit derived from a polymerizable monomer (A) from which a homopolymer having a lower critical solution temperature (LCST) is formed, a structural unit derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (−SOH), a sulfate group (−OSOH), a sulfurous acid group (−OSOH), and a group of salts thereof, and a structural unit derived from a polymerizable monomer (C) having a photoreactive group. Also disclosed is a medical device including the hydrophilic copolymer. The medical device exhibits high sliding property until it reaches a target lesion, and low sliding property after reaching the target lesion. Methods of making and using the hydrophilic copolymer and medical device are also described. 1. A medical device comprising:a base material layer that possesses a surface; and{'sub': 3', '3', '2, 'a coating layer which is formed on at least a part of the surface of the base material layer and contains a hydrophilic copolymer, the hydrophilic copolymer comprising more than 50% by mol of a structural unit derived from a polymerizable monomer (A) from which a homopolymer having a lower critical solution temperature is formed, a structural unit derived from a polymerizable monomer (B) having at least one group selected from the group consisting of a sulfonic acid group (—SOH), a sulfate group (—OSOH), a sulfurous acid group (—OSOH), and a group of salts thereof, and a structural unit derived from a polymerizable monomer (C) having a photoreactive group.'}2. The medical device according to claim 1 , the medical device being a balloon claim 1 , a catheter claim 1 , a guide wire claim 1 , a micro balloon claim 1 , a micro catheter claim 1 , a micro guide wire claim 1 , a stent delivery catheter claim 1 , or an ablation catheter.3. The medical device according to claim 1 , wherein the lower critical solution temperature is ...

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Номер записи: 57
04-04-2019 дата публикации

MELT SPINNABLE COPOLYMERS FROM POLYACRYLONITRILE, METHOD FOR PRODUCING FIBERS OR FIBER PRECURSORS BY MEANS OF MELT SPINNING, AND FIBERS PRODUCED ACCORDINGLY

Номер: US20190100856A1
Автор: KNOOP Mats Timothy, LIESKE Antje
Принадлежит: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V.

The invention relates to a method for the production of thermally stabilised melt-spun fibres in which polyacrilonitrile (PAN) fibres or PAN fibre precursors produced by melt-spinning are treated in an aqueous alkaline solution, comprising in addition a solvent for PAN. Likewise, the invention relates to fibres which are producible according to this method. 118-. (canceled)20. The copolymer according to claim 19 , which is spinnable in a temperature range of 160 to 240° C. with an addition of at least one external plasticizer.21. The copolymer according to claim 19 , which has a melt viscosity which is constant or decreases with increasing temperature up to 240° C.22. The copolymer according to claim 20 , wherein the at least one external plasticizer is selected from the group consisting of water claim 20 , acetonitrile claim 20 , nitroalkanes claim 20 , alkyl alcohols claim 20 , ionic liquids claim 20 , glycols claim 20 , dimethyl sulphoxide claim 20 , dimethylformamide claim 20 , dimethylacetamide claim 20 , N-methylpyrrolidone claim 20 , ethylene carbonate claim 20 , propylene carbonate claim 20 , aqueous sodium rhodanide solution claim 20 , and mixtures thereof.23. The copolymer according to claim 19 , wherein the copolymerisation is effected by a precipitation polymerisation in an aqueous medium claim 19 , an emulsion polymerisation in an aqueous medium claim 19 , and/or a polymerisation in a solvent.24. The copolymer according to claim 23 , wherein the solvent is selected from the group consisting of dimethylsulphoxide claim 23 , dimethylformamide claim 23 , dimethylacetamide claim 23 , N-methylpyrrolidone claim 23 , ethylene carbonate claim 23 , propylene carbonate claim 23 , aqueous sodium rhodanide solution claim 23 , and mixtures thereof.25. The copolymer according to claim 19 , wherein comonomer a) is present in an amount of 3.0 to 4.9% by mol.26. The copolymer according to claim 19 , wherein comonomer in b) is present in an amount of 1 to 5% by mol.27. ...

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Номер записи: 58
29-04-2021 дата публикации

AQUEOUS POLYMER COMPOSITION AND COPOLYMER

Номер: US20210122862A1
Автор: CHAMPAGNE Clementine, Melas Michel, PARRENIN Laurie, Suau Jean-Marc
Принадлежит:

The invention relates to an aqueous composition comprising a copolymer obtained by a specific polymerisation reaction using an anionic monomer comprising a polymerisable olefinic unsaturation and a carboxylic acid function and a monomer of formula (I): 2: The composition according to claim 1 , comprising no homopolymer of monomer (a) or comprising a reduced claim 1 , small or very small amount by weight of homopolymer of monomer (a) with respect to the amount by dry weight of copolymer.3: The composition according to claim 1 , wherein the polymerisation reaction uses:from 1 to 25% by weight of monomer (a) andfrom 75 to 99% by weight of monomer (b).4: The composition according to claim 1 , wherein the copolymer comprises:from 1 to 25% by weight of monomer (a) andfrom 75 to 99% by weight of monomer (b).5: The composition according to claim 1 , comprising less than 2 claim 1 ,000 ppm by weight of residual monomer (a) with respect to the amount by dry weight of copolymer.6: The composition according to claim 1 , wherein the monomer (a) used is selected from the group consisting of acrylic acid claim 1 , methacrylic acid claim 1 , itaconic acid claim 1 , maleic acid claim 1 , an acrylic acid salt claim 1 , a methacrylic acid salt claim 1 , an itaconic acid salt claim 1 , a maleic acid salt and mixtures thereof.7: The composition according to claim 1 , wherein x is strictly greater than y+z.8: The composition according to claim 1 , wherein the radical polymerisation reaction in water is performed at a temperature ranging from 30 to 85° C.9: The composition according to claim 1 , wherein the polymerisation reaction also uses another anionic monomer.10: The composition according to claim 1 , wherein the polymerisation reaction also uses at least one other monomer (c) selected from the group consisting of:another anionic monomer,a non-ionic monomer comprising at least one polymerisable olefinic unsaturation,2-acrylamido-2-methylpropanesulphonic acid, a salt of 2-acrylamido-2 ...

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Номер записи: 59
29-04-2021 дата публикации

PROTEIN ADSORPTION PREVENTING AGENT, PROTEIN ADSORPTION PREVENTING FILM, AND MEDICAL TOOL USING SAME

Номер: US20210122867A1
Автор: NISHIURA Takao
Принадлежит: MARUZEN PETROCHEMICAL CO., LTD.

To provide a protein adsorption preventing agent having an excellent film forming property and excellent water solubility, capable of easily coating various substrates, and having an excellent protein adsorption preventing property, and also to provide a protein adsorption preventing film using the protein adsorption preventing agent and a medical tool including the protein adsorption preventing film. A protein adsorption preventing agent containing an aqueous solvent and a polymer having at least a structural unit (A) represented by the following formula (1) (wherein Rrepresents a methyl group or an ethyl group and n represents an integer of 1 to 10), and further containing a hydrophobic group, a protein adsorption preventing film using the protein adsorption preventing agent, and a medical tool including the protein adsorption preventing film. 4: The protein adsorption preventing agent according to claim 3 , wherein a compositional ratio of the structural unit (A) and the structural unit (B) and/or the structural unit (C) is from 99/1 to 10/90 in molar ratio.5: The protein adsorption preventing agent according to claim 2 , wherein the group Rin the formula (5) is a linear or branched alkyl group or alkenyl group having 2 to 10 carbon atoms claim 2 , or a monocyclic or polycyclic alkyl group or alkenyl group having 5 to 15 carbon atoms.6: The protein adsorption preventing agent according to claim 2 , wherein the polymer has at least one hydrophobic group of formula (4) at a terminal thereof.7: The protein adsorption preventing agent according to claim 1 , wherein:a blending amount of the polymer is from 0.05 to 99 parts by mass; anda blending amount of the aqueous solvent is from 1 to 99.95 parts by mass.8: The protein adsorption preventing agent according to claim 1 , wherein the aqueous solvent is at least one selected from the group consisting of water claim 1 , an alcohol claim 1 , and a ketone.9: A protein adsorption preventing film formed from the protein ...

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Номер записи: 60
02-04-2020 дата публикации

Fluorinated elastic copolymer and method for its production, fluorinated elastic copolymer composition, and crosslinked rubber article

Номер: US20200102411A1
Автор: Takehiro Kose, Yukiko HATTORI
Принадлежит: Asahi Glass Co Ltd

To provide a fluorinated elastic copolymer having a low content of metal elements and being excellent in crosslinkability. This fluorinated elastic copolymer has iodine atoms and has units a based on tetrafluoroethylene, units b based on a monomer having one polymerizable unsaturated bond (but excluding tetrafluoroethylene), and units c based on a fluorinated monomer having at least two polymerizable unsaturated bonds, wherein the metal content is at least 0.3 ppm by mass and at most 20.0 ppm by mass.

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Номер записи: 61
11-04-2019 дата публикации

Monomer composition and curable composition containing same

Номер: US20190106540A1
Автор: Keizo Inoue, Tomoya Mizuta
Принадлежит: Daicel Corp

Provided is a monomer composition that has rapid curability and can be cured rapidly, even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention contains a vinyl ether compound (A). The vinyl ether compound (A) includes a vinyl ether compound (a) having a cyclic ether skeleton. The monomer composition further contains at least one compound selected from the group consisting of a vinyl ether compound (a′) having a chain hydrocarbon skeleton, a divinyl ether compound (a″-1) having a cyclic hydrocarbon skeleton, an oxetane compound (B), and an epoxy compound (C).

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Номер записи: 62
26-04-2018 дата публикации

Thin film composite membranes for separation of alkenes from alkanes

Номер: US20180111098A1
Автор: Andrew Edward Feiring, Ning Shangguan, Sudipto Majumdar, Yosuke Koizumi
Принадлежит: Compact Membrane Systems Inc

Composite membranes comprised of at least two layers, one of the layers being a silver ionomer and a second layer which is a fluorinated polymer with certain permeability properties, are especially useful for the separation of alkanes from alkenes, Particularly useful is a three-layer composite membrane in which a porous layer is laminated to the second layer.

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Номер записи: 63
26-04-2018 дата публикации

COPOLYMER FOR USE IN ALKENE-ALKANE SEPARATION MEMBRANES

Номер: US20180111099A1
Автор: Feiring Andrew Edward, LOUSENBERG ROBERT DANIEL, SHANGGUAN NING
Принадлежит:

Described herein are copolymers derived from certain perfluorinated sulfonyl fluoride monomers, cyclic or cyclizable perfluorinated monomers, and one or both of ethylene and/or vinyl fluoride. Group 11 metal sulfonate ionomers of these copolymers, especially silver ionomers, are useful in membranes which separate olefins from alkanes. 1. A copolymer , consisting essentially of repeat units derived from a monomer of the formula CF═CF(OR)SOF , one or more cyclic or cyclizable perfluorinated monomers , and one or both of vinyl fluoride and ethylene , wherein Ris perfluoroalkylene or ether containing perfluoroalkylene having 2 to 20 carbon atoms , and provided that repeat units derived from CF═CF(OR)SOF are at least one mole percent of total repeat units , units derived from one or more cyclic or cyclizable perfluorinated monomers are at least 1 mole percent of total repeat units , and repeat units derived from both ethylene and vinyl fluoride are in total at least 1 percent of total repeat units.3. The copolymer as recited in wherein Y is —OM claim 2 , and M is a silver cation Ag.4. The copolymer of where said cyclic or cyclizable perfluorinated monomer is perfluoro(2 claim 1 ,2-dimethyl-1 claim 1 ,3-dioxole).5. The copolymer as recited in wherein CF═CF(OR)SOF is one or more of CF═CFOCFCFSOF claim 4 , CF═CFOCHCFCFSOF claim 4 , CF═CFOCFCF(CF)OCFCFSOF claim 4 , CF═CFOCFCF(CF)OCFCFSOF and CF═CFOCFCFSOF.6. The copolymer as recited in wherein repeat units from only one type of monomer with the formula CF═CF(OR)SOF is present.7. The copolymer as recited in wherein repeat units derived from CF═CF(OR)SOF are about 10 mole percent to about 40 mole present of total repeat units in the polymer claim 1 , repeat units derived from one or more cyclic or cyclizable perfluorinated monomers are about 5 mole percent to about 30 mole present of total repeat units in the polymer claim 1 , and the total repeat units derived from ethylene and vinyl fluoride are about 10 mole percent to ...

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Номер записи: 64
10-07-2014 дата публикации

RUBBER COMPOSITION, CROSSLINKED RUBBER COMPOSITION, PNEUMATIC TIRE, AND METHOD FOR PRODUCING ISOBUTYLENE POLYMER

Номер: US20140194576A1
Автор: CHIBA Tatsuya, JIN Zhengzhe, Takashima Tsutomu, Yamaguchi Tsuyoshi
Принадлежит: JX NIPPON OIL & ENERGY CORPORATION

A rubber composition containing a rubber component having an olefinic double bond, and an isobutylene polymer having a structural unit represented by the following formula (1) and a structural unit represented by the following formula (2), wherein the content of a low molecular weight substance whose molecular weight is 1000 or less in the isobutylene polymer is 5% by mass or less based on the total amount of the isobutylene polymer. 4. The rubber composition according to claim 1 , wherein the rubber component contains at least one selected from the group consisting of a natural rubber claim 1 , a butadiene rubber claim 1 , a nitrile rubber claim 1 , a silicone rubber claim 1 , an isoprene rubber claim 1 , a styrene-butadiene rubber claim 1 , an isoprene-butadiene rubber claim 1 , a styrene-isoprene-butadiene rubber claim 1 , an ethylene-propylene-diene rubber claim 1 , a halogenated butyl rubber claim 1 , a halogenated isoprene rubber claim 1 , a halogenated isobutylene copolymer claim 1 , a chloroprene rubber claim 1 , a butyl rubber and a halogenated isobutylene-p-methylstyrene rubber.5. The rubber composition according to claim 1 , wherein a content of the isobutylene polymer is 0.5 to 70 parts by mass per 100 parts by mass of the rubber component.6. The rubber composition according to claim 1 , wherein the rubber component is substantially a styrene-butadiene rubber.7. The rubber composition according to claim 1 , further containing a crosslinking agent.8. A crosslinked rubber composition obtained from the rubber composition according to claim 1 , having a structure in which the rubber component and the isobutylene polymer are crosslinked.9. A pneumatic tire containing the crosslinked rubber composition according to in a tread part.11. The method for producing an isobutylene polymer according to claim 10 , wherein the Lewis acid catalyst is selected from the group consisting of a boron halide compound claim 10 , a titanium halide compound claim 10 , a tin ...

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Номер записи: 65
26-04-2018 дата публикации

HOSE WITH TUNABLE FLEXIBILITY USING CYCLIZABLE, PHOTOCHROMIC MOLECULES

Номер: US20180112018A1
Автор: Czaplewski Sarah K., Kobilka Brandon M., Wertz Jason T., Zhang Jing
Принадлежит:

Embodiments of the disclosure generally provide compositions and methods related to articles that display reversible photoresponsive behavior. 1. An article , comprising:a polymer with photoreactive groups, the polymer having a modulus that changes when the polymer is irradiated with ultraviolet or visible light.2. The article of claim 1 , wherein the photoreactive groups absorb ultraviolet radiation of wavelengths from 100 nm to 400 nm.3. The article of claim 2 , wherein the polymer has at least one photoreaction product of ultraviolet radiation absorption.4. The article of claim 3 , wherein the photoreaction product includes a cyclic carbon group.5. The article of claim 4 , wherein the cyclic carbon group is a product of a cycloaddition reaction.6. The article of claim 5 , wherein the cycloaddition reaction is a [2π+2π] cycloaddition reaction.7. The article of claim 4 , wherein the cyclic carbon group forms ring-open reaction products.8. The article of claim 3 , wherein the modulus increases upon radiation absorption.9. The article of claim 1 , wherein the polymer comprises photoreactive groups that absorb visible radiation of wavelengths from 400 nm to 700 nm.10. The article of claim 9 , wherein the photoreactive groups comprise ring-open reaction products.11. The article of claim 9 , modulus decreases upon light absorption.12. The article of claim 10 , wherein the reaction products are photo-cleavage reaction products.13. The article of claim 1 , wherein the article is a tube.14. A pump comprising the article of .15. A microfluidic device comprising the article of .16. The article of claim 1 , wherein the article is cylindrical.17. The article of claim 1 , comprising a conducting polymer.18. The article of claim 17 , comprising an electrical semiconductor.19. A method for producing a photoreactive polymer with variable modulus claim 17 , comprising:forming a reaction mixture comprising photoreactive monomers and non-photoreactive monomers, at least one catalyst, ...

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Номер записи: 66
18-04-2019 дата публикации

Copolymer, thickening agent containing said copolymer, and cosmetic preparation in which said popolymer is blended

Номер: US20190110975A1
Автор: Ayako Kuramoto, Takatoshi Matsuura, Yasuyoshi Mori
Принадлежит: Fujifilm Wako Pure Chemical Corp

wherein R1 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and m represents an integer of 2 to 4.

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Номер записи: 67
27-04-2017 дата публикации

Resin composition, resist pattern-forming method and polymer

Номер: US20170115570A1
Автор: Hayato Namai
Принадлежит: JSR Corp

A resin composition comprises a polymer comprising a structural unit that comprises a group represented by formula (1), and a solvent. In the formula (1), R 1 to R 4 each independently represent a hydrogen atom, a fluorine atom or a monovalent organic group having 1 to 20 carbon atoms, wherein at least one of R 1 to R 4 has the fluorine atom or a group including the fluorine atom. R 5 represents a substituted or unsubstituted trivalent chain hydrocarbon group having 1 to 7 carbon atoms. * denotes a binding site to other moiety of the structural unit. The structural unit is preferably represented by any one of formulae (2-1) to (2-3). In the formulae (2-1) to (2-3), Z represents a group represented by formula (1).

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Номер записи: 68
25-04-2019 дата публикации

Polymers and Methods for Ophthalmic Applications

Номер: US20190119425A1
Автор: Mentak Khalid
Принадлежит:

Novel methods and materials particularly useful for ophthalmic applications and to methods for making and using the same are disclosed herein. More particularly, relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and implanting IOLs made therefrom are disclosed. 1. A copolymer comprising: (a) a monomer comprising an aromatic , carbazole or naphthyl moiety , carbazole , naphthalene or a naphthyl group; (b) a first hydrophilic monomer; and (c) a second hydrophilic monomer.2. The copolymer of claim 1 , wherein the copolymer further comprises a crosslinker.3. The copolymer of claim 1 , wherein the copolymer further comprises an ultraviolet light absorbing material.4. The copolymer of claim 1 , wherein the monomer comprising an aromatic claim 1 , carbazole or naphthyl moiety is vinyl naphthalene or vinyl carbazole.5. The copolymer of claim 1 , wherein the first and second hydrophilic monomers are selected from the group consisting of 2-hydroxy-ethylacrylate claim 1 , 2-hydroxyethylmethacrylate claim 1 , acrylamide claim 1 , N-ornithine acrylamide claim 1 , N-(2-hydroxypropyl)acrylamide claim 1 , polyethyleneglycolacrylates claim 1 , polyethyleneglycol methacrylates claim 1 , N-vinyl pyrolidone claim 1 , N-phenylacrylamide claim 1 , dimethylaminopropyl methacrylamide claim 1 , acrylic acid claim 1 , benzylmeth-acrylamide claim 1 , 4-hydroxybutylmethacrylate claim 1 , glycerol mono methacrylate claim 1 , glycerol monoacrylate claim 1 , 2-sulfoethylmethacrylate claim 1 , phenoxyethyl acrylate claim 1 , phenoxy-ethyl methacrylate claim 1 , 2-(2-ethoxyethoxy)ethyl acrylate claim 1 , 2-(2-ethoxyethoxy)ethyl methacrylate claim 1 , furfuryl acrylate claim 1 , furfuryl methacrylate claim 1 , and methylthioethylacrylamide.6. The copolymer of claim 1 , wherein the first hydrophilic monomer is 2-(2-ethoxyethoxy ...

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Номер записи: 69
24-07-2014 дата публикации

Removable Polymer Compositions

Номер: US20140205714A1
Автор: Prakash Mallya, Sujith CHACKO, xiang-ya Li
Принадлежит: Avery Dennison Corp

The present invention relates to various polymer compounds and/or formulations and to methods for the synthesis of same. In one embodiment, the present invention is related to polymer compounds and/or formulations that enable one to more easily remove sticky articles (e.g., chewing gum) from various surfaces.

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Номер записи: 70
27-05-2021 дата публикации

Fluoropolymers, Fluoropolymer Compositions and Fluoropolymer Dispersions

Номер: US20210155790A1
Автор: Dadalas Michael C., Fukushi Tatsuo, Hintzer Klaus, Jing Naiyong, Jochum Florian, Kaspar Harald, Schrooten Jens, Weilandt Karl D., Zipplies Tilman C.
Принадлежит:

A tetrafluoroethene copolymer having a melting point of from about 240° C. to 325° C., a melt flow index (MFI at 372° C. and 5 kg load) of 0.5-80 grams/10 minutes and having at least 70% by weight of units derived from tetrafluoroethene and further comprising units derived from at least one perfluorinated alkyl allyl ether (PAAE) comonomer corresponding to the general formula: CF═CF—CF—O—Rf (I) where Rf is a perfluorinated alkyl residue having from 1 to 10 carbon atoms and wherein the alkyl chain of the residue may be interrupted once or more than once by an oxygen atom and further, optionally, comprising units derived from perfluoromethyl vinyl ether (PMVE), perfluoroethyl vinyl ether (PEVE) and a combination thereof and wherein the content of units CA derived PAAEs and, optionally, PMVE, PEVE or a combination thereof, is at least 1.0% by weight. 2. The tetrafluoroethene copolymer of having a melting point between 265° C. and 325° C. claim 1 , a melt flow index between 1 and 80 g/10 mins claim 1 , tensile strength of at least 17 MPa and an elongation at break of at least 230% claim 1 , and wherein the tetrafluoroethene copolymer comprises at least 90% by weight of units derived from TFE.3. The tetrafluoroethene copolymer of having a melting point between 265° C. and 325° C. claim 1 , a melt flow index between 1 and 80 g/10 mins claim 1 , a tensile strength of at least 17 MPa and an elongation at break of at least 230% claim 1 , wherein the tetrafluoroethene copolymer comprises at least 95% by weight of units derived from TFE claim 1 , and wherein Rf is a perfluorinated alkyl residue selected from the group consisting of: perfluoromethyl (—CF) claim 1 , perfluoroethyl (—CF) claim 1 , perfluoropropyl (—CF) and perfluorobutyl (CF).4. The tetrafluoroethene copolymer of wherein the polymer comprises a PAAE selected from CF═CF—CF—O—CF—CF—CF(MA-3).5. The tetrafluoroethene copolymer of having a melting point between 240° C. and 280° C. claim 1 , a melt flow index between 0 ...

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Номер записи: 71
16-04-2020 дата публикации

Binder, method of preparing the same, electrode for secondary battery including the binder, and secondary battery including the electrode

Номер: US20200119356A1
Автор: Heechul Jung, Kanghee Lee, Koichi Takei, Seongho JEON, Sungsoo HAN, Woojin Bae
Принадлежит: SAMSUNG ELECTRONICS CO LTD, Samsung SDI Co Ltd

A binder including a metal salt of a graft copolymer, which is a polymerization product of polyvinyl alcohol, an ethylenically unsaturated carboxylic acid, and a polymerizable monomer having a long-chain alkyl group.

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Номер записи: 72
11-05-2017 дата публикации

Monomer composition and curable composition containing same

Номер: US20170130079A1
Автор: Keizo Inoue, Tomoya Mizuta
Принадлежит: Daicel Corp

Provided is a monomer composition that has rapid curability and can be rapidly cured even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention includes vinyl ether compounds (A). The monomer composition contains a monofunctional monomer in an amount of 20 to 80 weight percent, a hydroxy-free multifunctional vinyl ether compound in an amount of 5 to 80 weight percent, and a hydroxy-containing vinyl ether compound in an amount of 0.1 weight percent to less than 10 weight percent, where all weight percentages are based on the total weight of the monomer composition.

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Номер записи: 73
02-05-2019 дата публикации

METHOD FOR PRODUCING COPOLYMER

Номер: US20190127504A1
Автор: Kobayashi Nobuhiro, OKADA Atsushi
Принадлежит:

A method of producing a copolymer of the present invention is a method of producing a specific copolymer and includes: a pure water production step of producing pure water having an electric conductivity of from 0.1 μS/cm to 100 μS/cm; a pure water transfer step of introducing the pure water into a reaction kettle for producing the copolymer through a transfer pipe using, as a material therefor, a resin or a substance forming a passive state in water; and a polymerization step of performing polymerization of the monomer (a), the monomer (b), and the monomer (c) in the reaction kettle, the pure water transfer step including setting the electric conductivity of the pure water at a site where the pure water is introduced from the transfer pipe toward the reaction kettle within a range of from 0.1 μS/cm to 100 μS/cm. 2. The production method according to claim 1 , wherein the material for the transfer pipe comprises at least one kind selected from a resin containing at least one kind selected from the group consisting of polyethylene claim 1 , polypropylene claim 1 , polystyrene claim 1 , polyvinyl chloride claim 1 , polyester claim 1 , and Teflon (trademark) claim 1 , and an alloy containing at least one kind selected from the group consisting of chromium claim 1 , aluminum claim 1 , and titanium.3. The production method according to claim 1 , wherein in the pure water transfer step claim 1 , a length L (m) of the transfer pipe claim 1 , a flow velocity V (m/sec) of the pure water claim 1 , and an inner radius R (m) of the transfer pipe have a relationship of 1.0×10sec/m≤(L/V)/(2π×R)≤3.0×10sec/m.4. The production method according to claim 1 , wherein Rforming Yin the general formula (1) represents a hydrogen atom or a methyl group.5. The production method according to claim 1 , wherein the unsaturated monocarboxylic acid-based monomer (b) comprises a (meth)acrylic acid-based monomer.6. The production method according to claim 1 , wherein a ratio between the unsaturated ...

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Номер записи: 74
23-04-2020 дата публикации

METHODS FOR PRODUCING FLUORINATED POLYMER, FLUORINATED POLYMER HAVING FUNCTIONAL GROUP AND ELECTROLYTE MEMBRANE

Номер: US20200123337A1
Автор: Saito Susumu, WATAKABE Atsushi
Принадлежит: AGC Inc.

To provide a method for producing a fluorinated polymer which enables stable production of a fluorinated polymer having a high molecular weight at a high polymerization rate with good productivity and reduced environmental burdens, a method for producing a fluorinated polymer having functional groups, and a method for producing an electrolyte membrane. A method for producing a fluorinated polymer, which comprises polymerizing a monomer mixture containing tetrafluoroethylene and a fluorinated monomer having a group convertible to a sulfonic acid group or a carboxylic acid group in a polymerization medium, wherein the polymerization medium contains as the main component a Ccyclic hydrofluorocarbon. Further, a method for producing a fluorinated polymer having functional groups and a method for producing an electrolyte membrane, employing the production method. 1. A method for producing a fluorinated polymer , which comprises polymerizing a monomer mixture containing tetrafluoroethylene and a fluorinated monomer having a group convertible to a sulfonic acid group or a carboxylic acid group in a polymerization medium , wherein the polymerization medium contains as the main component a Ccyclic hydrofluorocarbon.2. The method for producing a fluorinated polymer according to claim 1 , wherein the fluorinated monomer is a vinyl ether having a group convertible to a sulfonic acid group or a carboxylic acid group.3. The method for producing a fluorinated polymer according to claim 1 , wherein the proportion of tetrafluoroethylene is from 5 to 70 mol % claim 1 , and the proportion of the fluorinated monomer is from 30 to 95 mol % to the total amount of the monomer mixture.4. The method for producing a fluorinated polymer according to claim 1 , wherein the fluorinated polymer has a TQ value of from 150 to 340° C.6. The method for producing a fluorinated polymer according to claim 1 , wherein the fluorinated monomer is CF═CFOCFCF(CF)OCFCFSOF claim 1 , CF═CFOCFCFSOF claim 1 , CF═ ...

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Номер записи: 75
19-05-2016 дата публикации

SURFACE TREATMENT AGENT

Номер: US20160137765A1
Автор: Fukumori Masaki, FUKUMOTO Kanako, Miyahara Masahiro, Uehara Tetsuya, Yamamoto Ikuo
Принадлежит: DAIKIN INDUSTRIES, LTD.

A fluorine-containing polymer having (a) a repeating unit derived from a fluorine-containing monomer indicated by the formula CH═C(—X)—C(═O)—Y—Z—Rf, (b) a repeating unit derived from a cyclic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH═CQ-C(═O)—O-Q, and (c) a repeating unit derived from an aliphatic-hydrocarbon-group-containing acrylate ester monomer indicated by the formula CH═CQ-C(═O)—O-Q. The fluorine-containing polymer is produced by polymerizing in the presence of one or both of (d) a silicon-containing monomer and a silicon-containing chain transfer agent. 2. The fluorine-containing composition according to claim 1 , wherein the fluorine-containing monomer (a) is represented by the formula:{'br': None, 'sub': '2', 'CH═C(—X)—C(═O)—Y—Z—Rf\u2003\u2003(1)'}{'sup': 1', '2', '1', '2, 'claim-text': Y is —O— or —NH—;', 'Z is an aliphatic group having 1-10 carbon atoms, an aromatic group or cycloaliphatic group having 6-18 carbon atoms,, 'wherein X is a linear or branched alkyl group having 2-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a CFXXgroup (where Xand Xare a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom or an iodine atom), a cyano group, a linear or branched fluoroalkyl group having 1-21 carbon atoms, a substituted or unsubstituted benzyl group, or a substituted or unsubstituted phenyl group;'}{'sub': 2', '2', '2, 'sup': 1', '1, 'a —CHCHN(R)SO— group (where Ris an alkyl group having 1-4 carbon atoms),'}{'sub': 2', '2, 'sup': 1', '1, 'a —CHCH(OZ)CH— group (where Zis a hydrogen atom or an acetyl group),'}{'sub': 2', 'm', '2', '2', 'n', '2', 'm', '2', 'n, 'claim-text': 'Rf is a linear or branched fluoroalkyl group having 1 to 6 carbon atoms.', 'a —(CH)—SO—(CH)— group or a —(CH)—S—(CH)— group (where m is 1-10 and n is 0-10),'}3. The fluorine-containing polymer according to claim 1 , wherein in the fluorine-containing monomer (a) claim 1 , X is a chlorine atom.4. The ...

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Номер записи: 76
21-05-2015 дата публикации

CURABLE FLUORINATED POLYMER, PROCESS FOR ITS PRODUCTION, AND FLUORINATED POLYMER CURED PRODUCT

Номер: US20150141604A1
Автор: KUNIMOTO Akinobu, OHKURA Masahiro, SUGIYAMA Norihide, YAMAMOTO Hiromasa
Принадлежит: Asahi Glass Company, Limited

To provide a curable fluorinated polymer which is excellent in curability, and a fluorinated polymer cured product which is excellent in heat resistance and chemical resistance and which exhibits excellent properties as an elastomer. 1. A curable fluorinated polymer having constituent units (A) based on fluoromonoenes (a) and constituent units (B) based on a non-cyclopolymerizable fluorodiene (b) , in which the content of polymerizable double bonds is from 0.01 to 0.5 mmol/g , and of which the intrinsic viscosity is from 0.1 to 1 dL/g.2. The curable fluorinated polymer according to claim 1 , wherein the fluoromonoenes (a) are at least two types selected from the group consisting of tetrafluoroethylene claim 1 , hexafluoropropylene claim 1 , vinylidene fluoride and CF═CFO—R(wherein Ris a Cfluoroalkyl group claim 1 , or a Cfluoroalkyl group having at least one etheric oxygen atom between carbon atoms).3. The curable fluorinated polymer according to claim 1 , which further has constituent units (C) based on at least one monomer (c) selected from the group consisting of propylene claim 1 , ethylene and isobutylene.4. The curable fluorinated polymer according to claim 1 , wherein the content of the constituent units (A) is from 90 to 99.9 mol % to the total number of moles of the constituent units (A) and the constituent units (B).5. The curable fluorinated polymer according to claim 1 , wherein the content of the constituent units (B) is from 0.1 to 10 mol % to the total number of moles of the constituent units (A) and the constituent units (B).6. The curable fluorinated polymer according to claim 3 , which contains the constituent units (C) and in which the content of the constituent units (C) is from 0.1 to 100 mol % to the total number of moles of the constituent units (A) and the constituent units (B).7. The curable fluorinated polymer according to claim 1 , wherein the constituent units (B) having polymerizable double bonds are present at a terminal of a molecular ...

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Номер записи: 77
18-05-2017 дата публикации

Transition metal catalysts for olefin polymerization

Номер: US20170137549A1
Автор: Brad P. CARROW, Wei Zhang
Принадлежит: PRINCETON UNIVERSITY

In one aspect, a chelating phosphine-phosphonic diamide (PPDA) ligand is described herein for constructing transition metal complexes operable for catalysis of olefin polymerization, including copolymenzation of ethylene with polar monomer.

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Номер записи: 78
28-05-2015 дата публикации

NEGATIVE RESIST COMPOSITION AND PATTERN FORMING PROCESS

Номер: US20150147698A1
Автор: Hatakeyama Jun, Sagehashi Masayoshi
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A negative resist composition comprising a polymer comprising recurring units (a) of formula (1) and having a Mw of 1,000-500,000 as base resin is provided. Ris H or methyl, X is a single bond or —C(═O)—O—R—, Ris a single bond or C-Calkylene, Ris C-Calkylene, Ris a single bond or C-Calkylene, and 0 Подробнее

Номер записи: 79
30-04-2020 дата публикации

Preparation Method for Fluorine- and Chlorine-Containing Conductive Polymer Resin and Single- or Double-Sided Filled Composite Thin Film Prepared Using Same and the Preparation Method Therefor

Номер: US20200131290A1
Автор: Wu Huisheng, Yang Ying
Принадлежит: Zhejiang Hyproof Technology Co., Ltd.

Disclosed are a method for a preparing fluorine- and chlorine-containing conductive polymer resin, a single-side or double-side filled composite film prepared using the fluorine- and chlorine-containing conductive polymer resin, and a method for preparing the film. The fluorine- and chlorine-containing conductive polymer single-side or double-side filled composite film comprises a microporous film skeleton and the fluorine- and a chlorine-containing conductive polymer resin. The composite film is mechanically stronger, more waterproof, more impervious to water and toxic and harmful chemicals, and more moisture permeability. When applied to biochemical protective clothing, it can greatly enhance the combat effectiveness of the soldiers because it is light and more impervious to water and toxic and harmful chemicals, brings about comfort, and keeps the soldiers warm. When applied to fuel cells, it can provide better electrical properties due to its high conductivity and can allow the fuel, such as hydrogen or alcohol, to burn more completely. 1. A method for preparing a fluorine- and chlorine-containing conductive polymer resin , comprising:adding, to a reaction vessel, 1%-20% by weight of a fluorine-containing sulfonyl fluoride liquid phase monomer which is capable of free radical polymerization, 79%-98% by weight of purified water, and 0.01%-1% by weight of a fluorine-containing surfactant, and stirring the mixture at a high speed to give a prepolymer emulsion;introducing, into the reaction vessel, a gaseous monomer mixture of one or both of tetrafluoroethylene and vinylidene fluoride and chlorotrifluoroethylene under a reaction pressure of 5 kg or more, introducing a radical initiator, and allowing the reaction to proceed at a temperature of 20-120° C., under a reaction pressure of 5-25 kg, for 15-180 min to give the reaction product which is an emulsion of a fluorine- and chlorine-containing sulfonyl fluoride polymer, wherein the fluorine-containing sulfonyl ...

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Номер записи: 80
28-05-2015 дата публикации

METHOD FOR PRODUCING AQUEOUS FLUORINE-CONTAINING POLYMER DISPERSING ELEMENT, AND PURIFIED AQUEOUS FLUORINE-CONTAINING POLYMER DISPERSING ELEMENT

Номер: US20150148482A1
Автор: INO Tadashi, KONDO Masahiro, OHTSUKA Kazuhiro, SHINOKI Noriyuki, Yoshimura Takashi
Принадлежит:

A method for preparing a fluoropolymer aqueous dispersion, including: step (A) of preparing a fluoropolymer aqueous dispersion comprising a fluoropolymer having at least one selected from the group consisting of —SOY and —COOR (wherein Y is a halogen, and R is a C1 to C4 alkyl) by emulsion polymerization; step (B) of heating the fluoropolymer aqueous dispersion to 50° C. or higher; and step (C) of contacting the fluoropolymer aqueous dispersion with an ion exchange resin for cation exchange after step (B), thereby providing a purified fluoropolymer aqueous dispersion, the fluoropolymer aqueous dispersion being adjusted to pH 7 or lower from the end of the polymerization in step (A) to the end of step (C). 1. A method for preparing a fluoropolymer aqueous dispersion , comprising:{'sub': '2', 'step (A) of preparing a fluoropolymer aqueous dispersion comprising a fluoropolymer having at least one selected from the group consisting of —SOY and —COOR (wherein Y is a halogen, and R is a C1 to C4 alkyl) by emulsion polymerization;'}step (B) of heating the fluoropolymer aqueous dispersion to 50° C. or higher; andstep (C) of contacting the fluoropolymer aqueous dispersion with an ion exchange resin for cation exchange after step (B), thereby providing a purified fluoropolymer aqueous dispersion,the fluoropolymer aqueous dispersion being adjusted to pH 7 or lower from the end of the polymerization in step (A) to the end of step (C).2. The method for preparing a fluoropolymer aqueous dispersion according to claim 1 ,wherein the heating in step (B) is continued for 1 hour or more.3. The method for preparing a fluoropolymer aqueous dispersion according to claim 1 ,wherein the heating of the fluoropolymer aqueous dispersion to 50° C. or higher in step (B) is performed in such a manner as to lower the pH of the fluoropolymer aqueous dispersion to 2 or lower.4. The method for preparing a fluoropolymer aqueous dispersion according to claim 1 ,wherein the purified fluoropolymer ...

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Номер записи: 81
28-05-2015 дата публикации

CURABLE FLUOROELASTOMER COMPOSITION

Номер: US20150148493A1
Автор: HUNG MING-HONG
Принадлежит:

Compositions comprising fluoroelastomers having copolymerized units of a cyano-containing cure site monomer are cured (i.e. crosslinked) with certain aromatic diazide curatives. The crosslinks are tetrazole rings formed by the reaction of the aromatic diazide with pendant cyano groups on the fluoroelastomer. 1. A curable composition comprising:A) a fluoroelastomer comprising copolymerized units of a cyano group-containing cure site monomer; and{'sub': 3', '3', '6', '4', '6', '4', '2', '10', '6', '6', '4', '6', '4', '3', '2', '2', '3', '2, 'B) at least one aromatic diazide curative having the formula N—R—N, wherein R is an aromatic moiety selected from the group consisting of CH, (CH), CHand CH—X—CH, and wherein X is selected from the group consisting of C(CF), O, SO, SO, CO and C(CH).'}2. A cured article made from the curable composition of . This application claims the benefit of U.S. Provisional Application No. 61/908,293, filed Nov. 25, 2013, now pending, the entire disclosure of which is incorporated herein by reference.This invention relates to curable fluoroelastomer compositions wherein the fluoroelastomer has cyano group cure sites and the curative is an aromatic diazide.Fluoroelastomers have achieved outstanding commercial success and are used in a wide variety of applications in which severe environments are encountered, in particular those end uses where exposure to high temperatures and aggressive chemicals occurs. For example, these polymers are often used in seals for aircraft engines, in oil-well drilling devices, and in sealing elements for industrial equipment that operates at high temperatures.The outstanding properties of fluoroelastomers are largely attributable to the stability and inertness of the copolymerized fluorinated monomer units that make up the major portion of the polymer backbones in these compositions. Such monomers include vinylidene fluoride, hexafluoropropylene, tetrafluoroethylene and perfluoro(alkyl vinyl) ethers. In order to ...

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Номер записи: 82
07-06-2018 дата публикации

ALKENYL ETHER-VINYL ESTER COPOLYMER

Номер: US20180155477A1
Автор: Sugihara Shinji
Принадлежит: MARUZEN PETROCHEMICAL CO., LTD.

An alkenyl ether-vinyl ester copolymer contains a repeating unit derived from a hydroxyl group-containing alkenyl ether represented by the following formula (1), and a repeating unit derived from a vinyl ester represented by the following formula (2): 2. The alkenyl ether-vinyl ester copolymer according to claim 1 , wherein the alkenyl ether-vinyl ester copolymer has a lower critical solution temperature water of from 1° C. to 99° C.3. The alkenyl ether-vinyl ester copolymer according to claim 1 , wherein the hydroxyl group-containing alkenyl ether is a vinyl ether containing an oxyethylene unit.4. The alkenyl ether-vinyl ester copolymer according to claim 1 , wherein the vinyl ester is an aliphatic vinyl ester comprising a number of carbon atoms of from 4 to 6.5. The alkenyl ether-vinyl ester copolymer according to claim 2 , wherein the hydroxyl group-containing alkenyl ether is a vinyl ether containing an oxyethylene unit.6. The alkenyl ether-vinyl ester copolymer according to claim 2 , wherein the vinyl ester is an aliphatic vinyl ester comprising a number of carbon atoms of from 4 to 6.7. The alkenyl ether-vinyl ester copolymer according to claim 3 , wherein the vinyl ester is an aliphatic vinyl eater comprising a number of carbon atoms of from 4 to 6. The present invention relates to an alkenyl ether-vinyl ester copolymer, and more specifically relates to an alkenyl ether-vinyl eater copolymer that contains a hydroxyl group on the side chain thereof and exhibits temperature responsiveness in a temperature range of from 1° C. to 99° C.The studies on temperature responsive polymers showing a reversible change of from hydrophilicity on a low temperature side to hydrophobicity on a high temperature side on temperature stimulation are receiving attention. The polymers are expected to be applied to a drug carrier, a wound dressing material, an artificial muscle, a microcapsule, a biomachine, a biosensor, a separation membrane, and the like, by utilizing the property ...

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Номер записи: 83
08-06-2017 дата публикации

Monomer composition and curable composition containing same

Номер: US20170158812A1
Автор: Keizo Inoue, Tomoya Mizuta
Принадлежит: Daicel Corp

Provided is a monomer composition that has rapid curability and can be cured rapidly, even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention contains a vinyl ether compound (A). The vinyl ether compound (A) includes a vinyl ether compound (a) having a cyclic ether skeleton. The monomer composition further contains at least one compound selected from the group consisting of a vinyl ether compound (a′) having a chain hydrocarbon skeleton, a divinyl ether compound (a″-1) having a cyclic hydrocarbon skeleton, an oxetane compound (B), and an epoxy compound (C).

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Номер записи: 84
18-06-2015 дата публикации

Functionalized Amphiphilic Plant-Based Polymers

Номер: US20150166701A1
Автор: Bezbaruah Achintya, Chisholm Bret Ja, Kalita Harjyoti
Принадлежит: NDSU RESEARCH FOUNDATION

Amphiphilic copolymers formed from plant oil-derived vinyl ether monomers and polyethylene glycol alkyl vinyl ethers are provided. Nanoparticles coated with these amphiphilic polymers are well-suited for water remediation applications. 2. The copolymer of wherein the first monomer is derived from a plant oil.3. The copolymer of wherein the plant oil-derived monomer comprises a plurality of monomers claim 2 , and wherein for each of the plurality of monomers claim 2 , Ris independently a C8-C21 aliphatic group derived from a plant oil.4. The copolymer of wherein the aliphatic group comprises at least one functional group selected from the group consisting of an epoxide group claim 1 , an acrylate-functional group claim 1 , a vinyl group claim 1 , and an alcohol group.5. The copolymer further comprising at least one functional group comprising a chelating or coordinating group.6. The copolymer of wherein the aliphatic group comprises the at least one functional group comprising a chelating or coordinating group.7. The copolymer of wherein the chelating or coordinating group is directly attached to the polymer backbone.8. The copolymer of further comprising at least one third monomer comprising an electron-poor double bond.9. The copolymer of wherein the third monomer comprises maleic anhydride claim 8 , citraconic anhydride claim 8 , maleic acid claim 8 , itaconic acid claim 8 , citraconic acid claim 8 , or fumaric acid.11. The copolymer of wherein the polymer comprises a plurality of plant oil-derived monomers claim 10 , and wherein for each of the plurality of monomers claim 10 , Ris independently a C8-C21 aliphatic group derived from a plant oil.12. The copolymer of wherein the aliphatic group comprises at least one functional group selected from the group consisting of an epoxide group claim 10 , an acrylate-functional group claim 10 , a vinyl group claim 10 , and an alcohol group.13. The copolymer of further comprising at least one functional group comprising a ...

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Номер записи: 85
16-06-2016 дата публикации

POLYMER, RESIST COMPOSITION, AND PATTERN FORMING PROCESS

Номер: US20160168296A1
Автор: Adachi Teppei, Funatsu Kenji, Hatakeyama Jun
Принадлежит: SHIN-ETSU CHEMICAL CO., LTD.

A polymer comprising recurring units having an acid generator bound to the backbone, and recurring units having an optionally acid labile group-substituted carboxyl group and/or recurring units having an optionally acid labile group-substituted hydroxyl group is obtained by polymerizing corresponding monomers under such illumination that the quantity of light of wavelength up to 400 nm is up to 0.05 mW/cm. The polymer avoids photo-decomposition of the acid generator during polymerization and concomitant deprotection reaction of the acid labile group when used in positive resist compositions. A pattern with high dissolution contrast and rectangularity is formed after development. 1. A polymer comprising recurring units having an acid generator bound to the backbone , and recurring units of at least one type selected from recurring units having a carboxyl group optionally substituted with an acid labile group and recurring units having a hydroxyl group optionally substituted with an acid labile group , said polymer being obtained from polymerization of monomers corresponding to the recurring units under such illumination that the quantity of light of wavelength up to 400 nm is 0.05 mW/cmor less.2. The polymer of wherein the quantity of light of wavelength up to 400 nm is 0.02 mW/cmor less.3. The polymer of wherein the quantity of light of wavelength up to 400 nm is 0.01 mW/cmor less.4. The polymer of wherein the illumination is provided by an LED or organic EL.6. The polymer of wherein at least one of Rand R claim 5 , at least one of R claim 5 , Rand R claim 5 , or at least one of R claim 5 , Rand Ris an optionally substituted phenyl group.8. A chemically amplified resist composition comprising the polymer of claim 1 , and an organic solvent.9. The resist composition of claim 8 , further comprising a basic compound and/or surfactant.10. A pattern forming process comprising the steps of applying the resist composition of onto a substrate claim 8 , baking claim 8 , ...

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Номер записи: 86
14-05-2020 дата публикации

ELECTROLYTE SOLUTION AND METHOD FOR PRODUCING SAME, CONTINUOUSLY DISSOLVING FACILITY, ELECTROLYTE MEMBRANE, ELECTRODE CATALYST LAYER, MEMBRANE ELECTRODE ASSEMBLY AND FUEL CELL

Номер: US20200153018A1
Автор: MURAKAMI Tetsuya, OHTSUKA Kazuhiro, TAGO Takahiro
Принадлежит:

A method for producing an electrolyte solution including a supply step of continuously supplying an emulsion based a polymer electrolyte and a solvent into a dissolution facility, and a dissolution step of continuously dissolving the polymer electrolyte in the solvent by heating the interior of the dissolution facility to obtain the electrolyte solution. 1. An electrolyte solution comprising:{'sub': 3', '1', '2', '3', '4', '1', '2', '3', '4, 'a fluorine-based polymer electrolyte which contains a —SOX group where X is hydrogen, an alkali metal, an alkaline-earth metal or NRRRRwhere R, R, Rand Rare each independently an alkyl group having 1 to 3 carbon atoms or hydrogen; and'}a water-containing solvent,{'sup': '−2', 'wherein in a dynamic light scattering particle-size measurement, at least one particle-size peak top (A) is present in a range of 0.10 μm or more and less than 5.0 μm and at least one particle-size peak top (B) is present in a range of 5.0 μm or more and 50.0 μm or less, a scattering intensity ratio (A/B) of the particle-size peak top (A) to the particle-size peak top (B) is 1.0×10or more and 1.0×10 or less, and a fluorine ion concentration is 500 ppm or less based on a solid-content mass of the fluorine-based polymer electrolyte.'}2. The electrolyte solution according to claim 1 , wherein no scattering peak is present in the laser diffraction/scattering particle size distribution measurement.3. The electrolyte solution according to claim 1 , wherein the fluorine-based polymer electrolyte contains a copolymer having a repeating unit represented by the following formula (1) and a repeating unit represented by the following formula (2):{'br': None, 'sub': '2', '—(CFZ-CF)—\u2003\u2003(1)'} {'br': None, 'sub': 2', '2', '3', 'n', '2', 'm', '3, '—(CF—CF(—O—(CFCF(CF)O)—(CF)—SOX))—\u2003\u2003(2)'}, 'where Z represents H, Cl, F or a perfluoroalkyl group having 1 to 3 carbon atoms,'}{'sub': 1', '2', '3', '4', '1', '2', '3', '4, 'where X is hydrogen, an alkali ...

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Номер записи: 87
14-06-2018 дата публикации

FLUORINATED POLYMER, METHOD FOR ITS PRODUCTION, AND CURED PRODUCT OF THE FLUORINATED POLYMER

Номер: US20180162974A1
Автор: OHKURA Masahiro, SUGIYAMA Norihide
Принадлежит: Asahi Glass Company, Limited

To provide a curable fluorinated polymer excellent in solubility in an alcohol, a method for its production and a cured product of the fluorinated polymer. A fluorinated polymer comprising units represented by the following formula (1), wherein in at least some of the units represented by the formula (1), Zis NRNRH or NROR: 2. The fluorinated polymer according to claim 1 , wherein at least some of the units represented by the formula (1) are —[CF—CF(O(CF)CONHNH)]— or —[CF—CF(O(CF)CONHOH)]—.3. The fluorinated polymer according to claim 1 , which comprises units wherein Zis NRNRH and units wherein Zis OR.4. The fluorinated polymer according to claim 1 , which comprises units wherein Zis NROR.5. The fluorinated polymer according to claim 1 , which further contains units derived from fluoroethylene.6. The fluorinated polymer according to claim 1 , which further contains units represented by the following formula (3) (but excluding units derived from fluoroethylene):{'br': None, 'sup': 3', '4', '1', '2, '—[CXX—CYY]—\u2003\u2003(3)'}{'sup': 3', '4', '1', '2, 'in the formula (3), Xand Xare each independently a hydrogen atom, a fluorine atom or a chlorine atom, Yis a hydrogen atom, a fluorine atom or a chlorine atom, and Yis a hydrogen atom, a fluoroalkyl group, a fluoroalkyl group with at least 2 carbon atoms, having an etheric oxygen atom between carbon-carbon atoms, a fluoroalkoxy group, a fluoroalkoxy group with at least 2 carbon atoms, having an etheric oxygen atom between carbon-carbon atoms, a fluoroalkenyl group, or a fluoroalkenyl group with at least 2 carbon atoms, having an etheric oxygen atom between carbon-carbon atoms.'}7. The fluorinated polymer according to claim 1 , wherein the proportion of the group represented by —COZis from 0.1 to 4 mmol/g.9. A method for producing a cured product of a fluorinated polymer claim 1 , characterized by subjecting the fluorinated polymer as defined in to at least one of heating and active energy ray irradiation.10. A light ...

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Номер записи: 88
14-06-2018 дата публикации

MONOCHROMATIC ACTINIC RADIATION CURABLE COATINGS FOR OPTICAL FIBER

Номер: US20180163075A1
Автор: CAO Huimin, CATTRON Wendell Wayne, PAPACHRISTOPOULOS Robin, REN Kangtai
Принадлежит:

Described herein is a method for coating optical fiber where the coating has been cured by application of a source of monochromatic actinic radiation, such as a light emitting diode, wherein the coating contains a urethane(meth)acrylate oligomer; a (meth)acrylate diluent monomer; a diluent monomer having an electron donating group adjacent to the vinyl group, such as a vinyl ether monomer; and a photoinitiator. Also described are compositions which are capable of undergoing photopolymerization when coated on an optical fiber and when irradiated by a light emitting diode (LED) with improved surface cure and reduced yellowing. Also described are the coated optical fibers produced by such processes and compositions. 1. A method of coating an optical fiber comprising the steps of:(a) drawing a glass optical fiber through a draw tower;(b) applying a primary coating composition onto the surface of the glass optical fiber;(c) optionally, exposing the primary coating composition to a first light emitting diode (LED) capable of emitting ultraviolet radiation to affect curing of said primary coating composition;(d) applying a secondary coating composition to the primary coating composition;(e) exposing the primary coating composition and the secondary coating composition to at least one of the group consisting of the first light emitting diode (LED) and a second light emitting diode (LED) capable of emitting ultraviolet radiation to affect curing of said primary coating composition and said secondary coating composition, to form a cured primary coating on the surface of the optical fiber, and a cured secondary coating on the surface of the cured primary coating;wherein the secondary coating composition comprises:i. from about 5 wt. % to about 20 wt. %, relative to the total weight of the secondary coating composition, of a vinyl ether monomer, wherein the vinyl ether monomer contains a backbone selected from the group consisting of an ethylene oxide, propylene oxide or ...

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Номер записи: 89
25-06-2015 дата публикации

AMPHIPHILIC CYCLOBUTENES AND CYCLOBUTANES

Номер: US20150175519A1
Автор: Barletta Raul, Dussault Patrick H., Powers Robert, Sittiwong Wantanee
Принадлежит:

This disclosure relates to amphiphilic compounds containing a cyclobutene or cyclobutane moiety. In some embodiments, the compounds are useful for treating infection by such as . Cyclobutene containing compounds are also useful as monomers in the preparation of amphiphilic polymers. 2. The compound of claim 1 , wherein Rand Rare independently selected from the group consisting of: H claim 1 , halo claim 1 , OH and ═O.4. The compound of claim 1 , wherein Ris a C-Calkyl.5. (canceled)6. The compound of claim 1 , wherein Ris a C-Calkyl.7. (canceled)8. The compound of claim 1 , wherein Ris H.9. The compound of claim 1 , wherein Z is COR.16Mycobacterium tuberculosisMycobacterium aviumMycobacterium gordonaeMycobacterium kansasiiMycobacterium nonchromogenicum/terraeMycobacterium simiaeMycobacterium chelonaeMycobacterium fortuitumMycobacterium parafortuitumMycobacterium vaccae. The method of claim 15 , wherein the mycobacterial infection is a member of a group selected from: complex (MTBC) claim 15 , complex (MAC) claim 15 , clade claim 15 , clade claim 15 , clade claim 15 , Mycolactone-producing mycobacteria claim 15 , clade claim 15 , clade claim 15 , clade claim 15 , clade claim 15 , clade claim 15 , and CF.17M. tuberculosis.. The method of claim 15 , wherein the mycobacterial infection is18. A method comprising:reacting an unsaturated fatty acid or derivative thereof having a backbone comprising at least one carbon-carbon double bond with dihaloketene to achieve a stereospecific cycloaddition across the at least one carbon-carbon double bond, thereby yielding a cycloketone-containing fatty acid derivative comprising a cycloketone along the backbone, wherein the cycloketone comprises at least four carbon atoms, with at least two of the at least four carbon atoms being part of the backbone of the cycloketone-containing fatty acid derivative;reducing the cycloketone-containing fatty acid derivative to yield an amphiphilic cycloalkene-containing fatty acid derivative having ...

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Номер записи: 90
21-05-2020 дата публикации

Fluorine-containing copolymer

Номер: US20200157372A1
Автор: Takumi FUKADA, Yoshimasa HIKOBE, Yoshitaka Matsuda
Принадлежит: Kanto Denka Kogyo Co Ltd

The present invention is a fluorine-containing copolymer including (A) a fluoroolefin in an amount of 15 to 85 mol % of all constituent monomers; (B) a specific organosilicon compound in an amount of 0.001 to 10 mol % of all the constituent monomers; (C) one or more monomers selected from vinyl ethers, vinyl esters, methacrylic esters and acrylic esters, the one or more monomers not having a curing reactive group and having an aliphatic saturated hydrocarbon group with 1 to 20 carbons, a glass transition temperature of a homopolymer of the monomer being lower than 0° C., in an amount of 5 to 40 mol % of all the constituent monomers; and (D) one or more monomers selected from vinyl ethers, vinyl esters, allyl ethers, methacrylic esters and acrylic esters, and having a curing reactive group, in an amount of 1 to 25 mol % of all the constituent monomers, wherein the fluorine-containing copolymer has a glass transition temperature of −30° C. to 20° C., a number average molecular weight of 2.0×10 4 to 7.0×10 4 , and a weight average molecular weight of 1.0×10 5 to 3.0×10 5 .

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Номер записи: 91
01-07-2021 дата публикации

Method for producing pellets, pellets and ion exchange film

Номер: US20210198397A1
Автор: Hiromitsu Kusano
Принадлежит: Asahi Glass Co Ltd

To provide a method for producing pellets from which an ion exchange membrane excellent in stability of the electrolysis voltage can be formed, pellets, and an ion exchange membrane. The method for producing pellets of the present invention is a method for producing pellets, which comprises extruding a melt containing a fluorinated polymer having groups convertible to ion exchange groups from a die of a melt-extruder to obtain a strand containing the fluorinated polymer, and cutting the strand to obtain pellets containing the fluorinated polymer, wherein the temperature of the die when the melt containing the fluorinated polymer is extruded from the die is less than 200° C., and when the groups convertible to ion exchange groups of the fluorinated polymer are converted to ion exchange groups, the ion exchange capacity of the resulting fluorinated polymer is at least 1.1 milliequivalent/g dry resin.

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Номер записи: 92
06-06-2019 дата публикации

FLUOROPOLYMERS FOR COATING APPLICATIONS

Номер: US20190169338A1
Автор: Ding Zhe, Duan Linlin, JIANG WANCHAO, Xu Gang, ZHANG SIYUAN
Принадлежит:

Copolymers formed by copolymerization of: (1) one or more hydrofluoroolefin monomer(s) selected from the group consisting of hydrofluoroethylenes, hydrofluoropropenes, hydrofluorobutenes, hydrofluoropentenes and combinations of these; (2) one or more aromatic vinyl ester monomer(s); (3) one or more vinyl ester monomer(s); and (4) one or more vinyl ether monomer(s), wherein at least a portion of said vinyl ether monomer is a hydroxyl group-containing vinyl ether monomer. 1. A fluorocopolymer formed by copolymerization of:(1) one or more hydrofluoroolefin monomer(s) selected from the group consisting of hydrofluoroethylenes, hydrofluoropropenes, hydrofluorobutenes, hydrofluoropentenes and combinations of these;(2) one or more aromatic vinyl ester monomer(s);(3) one or more vinyl ester monomer(s); and(4) one or more vinyl ether monomer(s), wherein at least a portion of said vinyl ether monomer is a hydroxyl group-containing vinyl ether monomer.2. The fluorocopolymer of claim 1 , wherein the one or more aromatic vinyl ester monomers comprises a monomer represented by the formula CH═CH—O(C═O)-(A) claim 1 , wherein (A) represents a phenyl group with or without a side group.3. The fluorocopolymer of claim 1 , wherein the one or more aromatic vinyl ester monomers comprises vinyl benzoate.4. The fluorocopolymer of claim 1 , wherein the one or more hydrofluoroolefin monomer(s) is selected from hydrofluoropropenes.5. The fluorocopolymer of claim 4 , wherein the one or more hydrofluoroolefin monomer(s) is selected from 2 claim 4 ,3 claim 4 ,3 claim 4 ,3-tetrafluoropropene claim 4 , 1 claim 4 ,3 claim 4 ,3 claim 4 ,3-tetrafluoropropene claim 4 , and combinations thereof.6. The fluorocopolymer of claim 5 , wherein the one or more hydrofluoroolefin monomer(s) is 1 claim 5 ,3 claim 5 ,3 claim 5 ,3-tetrafluoropropene.7. The fluorocopolymer of claim 6 , wherein the 1 claim 6 ,3 claim 6 ,3 claim 6 ,3-tetrafluoropropene comprises trans-1 claim 6 ,3 claim 6 ,3 claim 6 ,3- ...

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Номер записи: 93
02-07-2015 дата публикации

PROCESS FOR PRODUCING FLUORINATED COPOLYMER

Номер: US20150183946A1
Автор: ABE Kaori, Saito Susumu, Shimohira Tetsuji
Принадлежит: Asahi Glass Company, Limited

To provide a process by which from a mixture containing a fluorinated copolymer, an unreacted monomer and a polymerization medium, the unreacted monomer and the polymerization medium can efficiently be recovered, and a lower polymer contained in the obtainable fluorinated copolymer can readily be reduced. 1. A process for producing a fluorinated copolymer , which comprises the following steps (I) to (III):(I) a step of polymerizing a fluorinated monomer having a carboxylic acid functional group or a sulfonic acid functional group and a fluorinated olefin in a polymerization medium to obtain a mixture containing a fluorinated copolymer, the unreacted monomer and the polymerization medium;(II) a step of continuously or intermittently transferring the mixture obtained in the step (I) to an evaporation container equipped with a stirring machine and heating the mixture in the evaporation container with stirring to evaporate and recover the unreacted monomer and the polymerization medium and to obtain the fluorinated copolymer; and(III) a step of washing the fluorinated copolymer obtained in the step (II) with a washing medium.2. A process for producing a fluorinated copolymer , which comprises the following steps (I′) to (III′):(I′) a step of polymerizing a fluorinated monomer having a carboxylic acid functional group or a sulfonic acid functional group and a fluorinated olefin to obtain a mixture containing a fluorinated copolymer and the unreacted monomer;(II′) a step of continuously or intermittently transferring the mixture obtained in the step (I′) to an evaporation container equipped with a stirring machine and heating the mixture in the evaporation container with stirring to evaporate and recover the unreacted monomer and to obtain the fluorinated copolymer; and(III′) a step of washing the fluorinated copolymer obtained in the step (II′) with a washing medium.3. The process for producing a fluorinated copolymer according to claim 1 , wherein the proportion of ...

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Номер записи: 94
28-05-2020 дата публикации

AQUEOUS POLYMER COMPOSITION AND COPOLYMER

Номер: US20200165367A1
Автор: Melas Michel, PARRENIN Laurie, Suau Jean-Marc
Принадлежит: COATEX

The invention relates to an aqueous composition comprising a copolymer obtained by a particular polymerization reaction using an anionic monomer comprising a polymerizable olefinic unsaturation and a carboxylic acid function and a monomer of formula (I): 2: The aqueous composition of claim 1 , comprising no homopolymer of the at least one anionic monomer (a) or comprising a reduced amount of homopolymer of the at least one anionic monomer (a) with respect to an amount by dry weight of copolymer.3: The aqueous composition of claim 1 , wherein the at least one polymerization reaction comprises:from 1 to 25% by weight of the at least one anionic monomer (a); andfrom 75 to 99% by weight of the at least one monomer (b).4: The aqueous composition of claim 1 , wherein the at least one copolymer comprises:from 1 to 25% by weight of the at least one anionic monomer (a); andfrom 75 to 99% by weight of the at least one monomer (b).5: The aqueous composition of claim 1 , comprising less than 2 claim 1 ,000 ppm by weight of residual at least one anionic monomer (a) with respect to an amount by dry weight of copolymer.6: The aqueous composition of claim 1 , wherein the at least one radical polymerization reaction comprises a mineral compound or hypophosphorus acid (HPO) or a derivative of hypophosphorus acid (HPO).7: The aqueous composition of claim 1 , wherein the at least one radical polymerization reaction further comprises another anionic monomer.9: The aqueous composition of claim 1 , wherein x is strictly greater than y+z.10: The aqueous composition of claim 1 , wherein the at least one radical polymerization reaction is implemented at a temperature ranging from 30 to 85° C.14: The copolymer of claim 13 , comprising:from 1 to 25% by weight of the at least one anionic monomer (a); andfrom 75 to 99% by weight of the at least one monomer (b).15: A formulation claim 13 , comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'at least one aqueous composition of , or the ...

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Номер записи: 95
30-06-2016 дата публикации

AMPHOTERIC BETAINE-TYPE POLYCARBOXYLATE SUPERPLASTICIZER AND PREPARATION METHOD THEREOF

Номер: US20160185663A1
Автор: Chen Chengbin, Chen Shaojun, CHEN Shiguo, Ge Zaochuan, Gu Lidan
Принадлежит:

An amphoteric betaine-type polycarboxylic acid water reducer and a preparation method therefor are provided in the present invention. An unsaturated betaine-type monomer A and an acrylic acid-type polyethylene glycol monomer B are placed in a reaction container, stirred until uniform and then an acrylic acid-type monomer C is added, the stirring is continued and water is added to make adjustments so as to make the total mass of the monomers account for 10%-20% of the total mass of the aqueous solution; and under the protection of an inert gas, the temperature is raised to 60° C.-100° C., an aqueous initiator solution is added, maintaining the temperature and reacting for 4-6 h, and after the reaction is completed, the solution is cooled to room temperature, and the pH value thereof is adjusted to 5-7 to prepare the amphoteric betaine-type polycarboxylic acid water reducer. 3. The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to claim 2 , wherein the initiator is a water soluble free radical initiator claim 2 , and has a total amount accounting for 0.5-2.0% of the total weight of the monomers.4. The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to claim 2 , wherein the initiator is at least one of ammonium persulfate claim 2 , potassium persulfate claim 2 , or a redox initiator.5. The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to claim 2 , wherein the initiator is formulated into an aqueous solution before addition claim 2 , and is added in a manner such that ⅓ of the total weight of the aqueous initiator solution is added dropwise per hour.6. The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to claim 2 , wherein the adjusting of the pH to 5-7 is achieved by adding 1-3 mol/L of a basic aqueous NaOH solution.7. The method for preparing an amphoteric betaine-type polycarboxylate ...

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Номер записи: 96
30-06-2016 дата публикации

Fluorinated compounds containing a -osf5 group and process for their preparation

Номер: US20160185719A1
Автор: Cristiano Monzani, Vito Tortelli
Принадлежит: Solvay Specialty Polymers Italy SpA

A process for the preparation of fluorinated compounds having at least one —OSF 5 group, said method comprising the step of reacting SOF 4 with a fluorinated 3- or 4-membered cyclic ether in the presence of a fluoride catalyst.

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Номер записи: 97
30-06-2016 дата публикации

Resin composition, resist pattern-forming method and polymer

Номер: US20160185999A1
Автор: Hayato Namai
Принадлежит: JSR Corp

A resin composition comprises a polymer comprising a structural unit that comprises a group represented by formula (1), and a solvent. In the formula (1), R 1 to R 4 each independently represent a hydrogen atom, a fluorine atom or a monovalent organic group having 1 to 20 carbon atoms, wherein at least one of R 1 to R 4 has the fluorine atom or a group including the fluorine atom. R 5 represents a substituted or unsubstituted trivalent chain hydrocarbon group having 1 to 7 carbon atoms. * denotes a binding site to other moiety of the structural unit. The structural unit is preferably represented by any one of formulae (2-1) to (2-3). In the formulae (2-1) to (2-3), Z represents a group represented by formula (1).

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Номер записи: 98
15-07-2021 дата публикации

METHODS AND COMPOSITIONS FOR FORMING THREE-DIMENSIONAL OBJECTS BY ADDITIVE FABRICATION

Номер: US20210213679A1
Автор: Bückmann Alfred Jean Paul, BUIJSEN Paulus Franciscus Anna, Derks Franciscus Johannes Marie, JANSEN Johan Franz Gradus Antonius, PEPELS Mark Petrus Franciscus, VAN BENTHEM Rudolfus Antonius Theodorus Maria
Принадлежит:

A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component. 1) A method of forming a three-dimensional object comprising the steps of: i. a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group,', 'ii. a thermal radical initiator dispersed or dissolved in the resin component, and', 'iii. a retardant dispersed or dissolved in the resin component;, 'a. forming a layer of a particulate composition, the particulate composition comprising a plurality of first particles that comprise 'i. a first liquid polymerizable component, the first liquid polymerizable component comprising a first liquid polymerizable group, the first liquid polymerizable group comprising a carbon-carbon double bond that is able to (co)polymerize with the first resin polymerizable group;', 'b. selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, the liquid composition ...

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Номер записи: 99
07-07-2016 дата публикации

DEGRADABLE POLYMER RESINS AND METHODS FOR THEIR PREPARATION

Номер: US20160194417A1
Автор: Carlson William Brenden, Casasanta, III Vincenzo, Phelan Gregory D.
Принадлежит: EMPIRE TECHNOLOGY DEVELOPMENT LLC

Disclosed are polymers having one or more two-photon absorbing chromophores in a backbone of the polymers. The polymers degrade upon two-photon excitation, which allows for easy decomposition of polymeric products made therefrom. The decomposition can occur when the polymer is exposed to light of intensities sufficient to induce the two-photon excitation, which in turn cleaves the polymer at one or more sites where the chromophores are attached. 1. A polymer resin having a polymeric backbone , the polymer resin comprising a first repeating unit and a second repeating unit , wherein the first repeating unit has a two-photon absorbing chromophore in the polymeric backbone.4. The resin of claim 1 , wherein the first repeating unit is present in the polymer resin in an amount of not more than about 2% by weight.5. The resin of claim 1 , wherein the second repeating unit comprises —(CH)n-O— claim 1 , —CH(Me)-CH—O— claim 1 , —CH—CH(OH)—CH—O— claim 1 , —CH(CHOH)—CH—O— claim 1 , —CH—C(Me)-CH—O— claim 1 , —CH—C(CHOH)—CH—O— claim 1 , or a combination thereof claim 1 , wherein n=2-6.6. The resin of claim 1 , wherein the second repeating unit comprises —C(═O)—Ar—C(═O)—CH—CH—O— claim 1 , —C(═O)—NH—Ar—CH—Ar—NH—C(═O)—O—CH—CH—O— claim 1 , —C(═O)—X—NH— claim 1 , or —C(═O)—X—O— claim 1 , wherein:{'sub': 3', '1', '6', '2', '2', '2, 'Xis —CH((C-C)alkyl)-, —(CH)n-, —Ar—C(═O)—NH—Ar—, or —(CH)n-C(═O)—NH—(CH)m-C(═O)—;'}Ar is 1,4-phenylene, 1,3-phenylene, or 1,2-phenylene;m=2, 3, 4, 5, or 6; andn=2, 3, 4, 5, or 6.7. The resin of claim 1 , wherein the resin further comprises a third repeating unit claim 1 , wherein the third repeating unit comprises —C(═NH)—Ar—C(═NH)—O— claim 1 , —C(═O)—Ar—C(═O)—O— claim 1 , —C(═O)—CH—CH—CH—CH—C(═O)—O— claim 1 , or a combination thereof claim 1 , whereinAr is 1,4-phenylene, 1,3-phenylene, or 1,2-phenylene.8. The resin of claim 1 , wherein the second repeating unit comprises —R—O—X—O—R—O— claim 1 , wherein:{'sup': '7', 'sub': 2', '2, 'Ris —CH—CHOH—CH—; and ...

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Номер записи: 100