06-07-2017 дата публикации
Номер: US20170190806A1
Provided are new functionalized nitrile rubbers, which may optionally also be in partially or wholly hydrogenated form, and also a process for preparing them by metathesis of nitrile rubbers in the presence of a metathesis catalyst and at least one functionalized allyl compound. The new functionalized nitrile rubbers are suitable for producing vulcanizable mixtures and allow the production of vulcanizates having very stable networks. Also made possible, in particular, is the synthesis of block copolymers. 4. Process according to or , characterized in that in the functionalized olefin of the general formula (I) or (II){'sup': 1', '1, 'sub': 1', '12', '7', '18', '1', '6', '7', '12, 'claim-text': [{'sub': 2', '2', 'n', '1', '12', '7', '18', '1', '6', '7', '12, 'sup': 2', '2, 'O—(CH—CH—O)—R, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl, C-Caralkyl or phenyl, and n is 1 to 20 and preferably 1 to 6,'}, {'sub': 2', '3', 'n', '1', '12', '7', '18', '1', '6', '7', '12, 'sup': 3', '3, 'O—(CH—CH(CH)—O)—R, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl, C-Caralkyl or phenyl and n is 1 to 20 and preferably 1 to 6,'}, {'sup': 4', '4, 'sub': 1', '12', '7', '18', '1', '6', '7', '12, 'O—C(═O)—R, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl, C-Caralkyl or phenyl,'}, {'sub': 6', '12', '1', '12', '7', '18', '1', '6', '7', '12, 'sup': 5', '5, 'C-Caryl, which is substituted by at least one radical OR, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl, C-Caralkyl or phenyl, or'}, {'sup': 6', '6, 'sub': 1', '18', '7', '24', '1', '6', '7', '12, 'NH—C(═O)—OR, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl, C-Caralkyl or phenyl, and'}], 'X is OR, in which Ris H, C-Calkyl, C-Caralkyl, phenyl, naphthyl or fluorenyl and preferably is H, C-Calkyl ...
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