Способ получения фотокатализатора на основе висмутата щелочноземельного металла

Изобретение относится к способу получения фотокатализатора на основе висмутата щелочноземельного металла, который заключается в растворении смеси порошков нитрата висмута Bi(NO)и неорганической соли щелочноземельного металла Me с последующим выстаиванием продуктов их гидролиза до образования частиц с равномерно распределенными в их объеме ионами висмута и неравномерно распределенными ионами щелочноземельного металла и удалением из продуктов гидролиза избыточной влаги, в нагреве полученных частиц до образования частиц в виде гетероструктуры из аморфного по структуре и стехиометричного по составу висмутата щелочноземельного металла и аморфного по структуре и стехиометричного по составу оксида висмута BiOс последующей их кристаллизацией. При этом в качестве неорганической соли щелочноземельного металла Me берут оксалат щелочноземельного металла MeCO, предварительно перед растворением оксалат щелочноземельного металла MeCOочищают от адсорбированных соединений и смешивают с нитратом висмута ...

Способ получения фотокатализатора на основе висмутата щелочноземельного металла

Verfahren und Katalysator, mit einer Lanthanidverbindung als Promotoradditiv für die Direktsynthese von Dimethyldichlorsilan.

PROCEDURE FOR THE PRODUCTION AN ANTIMONY OF AN ABSTENTION OF MIXTURE METALLIC OXIDE CATALYST AND SO RECEIVED CATALYST

Verfahren zur Herstellung von Carbonylverbindungen

Process of conversion of hydrocarbons

Selective hydrogenation process

A method and catalysts for selective hydrogenation and isomerization which involves contacting a feedstream with hydrogen and with various supported catalysts of metallic arsenides and antimonides, with carbon monoxide being optionally introduced into the reaction as a modifier.

CATALYST PRODUCTION AND OLEFIN CONVERSION

... 1488699 Oxidation or ammoxidation process MONSANTO CO 28 Oct 1974 46508/74 Heading C2C [Also in Division B1] Olefins are oxidized or ammoxidized in the presence of a catalyst comprising antimony, uranium and oxygen which has been prepared by a specified method involving precipitation from a mixture of the sulphates (see Division B1). The catalyst may contain further metals combined with oxygen, e.g. Fe, Co, Ni, Bi, W or Mo. Suitably, the reaction is effected in the vapour phase at 250-650‹ C. using a molar ratio of olefin to oxygen of 0À5 : 1 to 4 : 1 and, in the case of ammoxidation, a molar ratio of ammonia to olefin of 0À5 : 1 to 5 : 1. Several suitable olefin feeds are listed. The exemplified processes are the conversion of propylene to acrolein or acrylonitrile and isobutylene to methacrylonitrile. The conversion of isobutylene to methacrolein and 2-methylbutene-2 or isoprene to 2-cyano-1,3-butadiene are also mentioned.

PROCESS AND CATALYST COMPRISING A LANTHANIDE COMPOUND AS PROMOTER ADDITIVE FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE

OLEFIN SELECTIVE FT CATALYST COMPOSITION AND PREPARATION THEREOF

The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form a) Fe as catalytically active metal, b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal, c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, to a process for the synthesis of a hydrocarbon synthesis catalyst, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.

Ni hydrogenation catalysts, manufacture and use

Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m²/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

CATALYST, ACRYLIC ACID PRODUCTION METHOD, AND CATALYST PRODUCTION METHOD

The purpose of the present invention is to provide a catalyst capable of suppressing pressure loss to be a low level and producing an unsaturated carboxylic acid with high selectivity, when gas phase contact oxidation of an unsaturated aldehyde and an oxygen-containing gas is performed, using a catalyst, to produce a corresponding unsaturated carboxylic acid. The present invention pertains to a catalyst, formed in a ring shape or a cylindrical shape, that is used for performing a gas phase contact oxidation of an unsaturated aldehyde and an oxygen-containing gas to produce the corresponding unsaturated carboxylic acid and that has an outer peripheral part inclined with respect to the center line.

DEHYDROGENATION PROCESS AND CATALYST

A process and catalyst containing a lanthanide compound as an additive promoter for the dimethyldichlorosilane [...]

La présente invention concerne un procédé de fabrication de diméthyldichlorosilane par réaction de chlorure de méthyle sur une masse de contact solide formée de silicium et d'un catalyseur comportant (a) du cuivre métallique ou un composé à base de cuivre et (beta) un système promoteur comprenant: - 10 à 1 000 ppm (calculés en poids d'étain et/ou d'antimoine métal par rapport à la masse de silicium engagée) d'un additif beta1 consistant dans au moins un métal choisi parmi l'étain et l'antimoine ou d'au moins un composé à base d'étain et/ou d'antimoine, - 0 à 3 % en poids (calculés en zinc métal par rapport à la masse de silicium engagée) d'un additif facultatif beta2 consistant dans le zinc métallique ou un composé à base de zinc, ledit procédé étant caractérisé en ce que le système promoteur (beta) contient en outre 0,01 à 2 % en poids (calculés en lanthanide métallique par rapport à la masse de silicium engagée) d'un additif complémentaire beta3 consistant dans au moins un composé à base ...

Process of refining by hydrocarbon catalytic oil hydrogenation

НИКЕЛЕВЫЕ КАТАЛИЗАТОРЫ ГИДРИРОВАНИЯ, СПОСОБ ИХ ПОЛУЧЕНИЯ И ПРИМЕНЕНИЕ

Настоящее изобретение относится к катализаторам гидрирования, способу их получения и применению для гидрирования, такого как селективное гидрирование ацетиленовых примесей в неочищенных олефиновых и диолефиновых потоках. Описан селективный катализатор гидрирования для селективного гидрирования ацетиленовых примесей в неочищенных олефиновых или диолефиновых потоках, содержащий только никель или никель и один или больше элементов, выбранных из группы, состоящей из Cu, Re, Pd, Zn, Mg, Mo, Ca и Bi, нанесенных на носитель, представляющий оксид алюминия, имеющий следующие физические свойства: площадь поверхности по БЭТ от 30 до примерно 100 м2/г, общий объем пор по азоту от 0,4 до примерно 0,9 см3/г и средний диаметр пор от примерно 110 до 450 Å, где указанный катализатор содержит от примерно 4 до примерно 20 вес.% никеля. Описаны способ получения катализатора, включающий пропитку носителя, представляющего оксид алюминия, имеющего указанные выше физические свойства, растворимыми солями только ...

КАТАЛИЗАТОР, СПОСОБ ПОЛУЧЕНИЯ АКРИЛОВОЙ КИСЛОТЫ И СПОСОБ ПОЛУЧЕНИЯ КАТАЛИЗАТОРА

Целью настоящего изобретения является обеспечить катализатор, гарантирующий, что, в случае осуществления газофазного каталитического окисления ненасыщенного альдегида кислородсодержащим газом с использованием данного катализатора с получением соответствующей ненасыщенной карбоновой кислоты, падение давления может оставаться низким и ненасыщенная карбоновая кислота может получаться с высокой селективностью. Описан кольцеобразный или колончатый катализатор, применяемый во время выполнения газофазного каталитического окисления ненасыщенного альдегида кислородсодержащим газом с получением ненасыщенной карбоновой кислоты, в котором внешний периферийный край наклонен относительно центральной линии на угол от 45 до 85°, отношение (а/b) внешнего диаметра а (мм) к диаметру b нижней части (мм) составляет от 2,35 до 3,5, отношение (Н/b) длины Н (мм) прямого участка тела к диаметру b нижней части (мм) составляет от 1,35 или больше до 2,5 или меньше, длина Н (мм) прямого участка тела составляет от 2 ...

VAPOUR PHASE OXIDATION OF HYDROXY COMPOUNDS

... 1,272,592. Oxidizing hydroxy compounds to carbonyl compounds. LAPORTE CHEMICALS Ltd. 6 Aug., 1969 [6 May, 1968], No. 21422/68. Heading C2C. Carbonyl compounds are prepared by the vapour phase oxidation of corresponding hydroxy compounds by contacting at elevated temperature a gaseous mixture containing oxygen and the hydroxy compound with a catalyst containing as essential constituents one or more of Cu and Ag with P as a promoter. Au, As, Sb and/or Sn may also be present. The catalyst may be a mixture of particulate ingredients or may be an alloy, the surface of which may be oxidized prior to use. It may be supported. The oxygen may be introduced at more than one point along the reaction. A diluent gas may be present. The reaction product after removal of readily condensable products may be recycled. Examples oxidize ethylene glycol to glyoxal with some glycollic aldehyde, glycollic acid and formaldehyde, propylene - 1,2 - glycol to methylglyoxal and acetol, butene-2,3-diol to diacetyl ...

VAPOUR PHASE OXIDATION OF HYDROXY COMPOUNDS

METHOD AND CATALYST COMPRISING A LANTHANIDE COMPOUND AS AN ADDITIVE FOR THE DIRECT SYNTHESIS OF THE PROMOTER [...].

Nonmetallic catalyst compositions for oxidation of ammonia and process for making the catalyst

Nonmetallic catalyst compositions for oxidation of ammonia have the formula of Fe2O3-MAl2O4-Bi2O3-Ce2O3. Herein, M represents Mg, Mn, Ca, Sr or Ba. MAl2O4 is a spinel and has a role of carrier as well as that of assistant catalyst. Fe2O3 acts as main catalyst, Bi2O3 as assistant catalyst and Ce2O3 as stabilizer to extend the effective temperature range of the function of catalyst compositions. In the formula, the ratio of each component is as follows: Fe2O3: 10-40 wt % of spinel Bi2O3: 3.5-6 wt % of spinel Ce2O3: 0.5-2 wt % of spinel.

КОМПОЗИЦИИ КАТАЛИЗАТОРОВ БЕЗ БЛАГОРОДНЫХ МЕТАЛЛОВ

Изобретение относится к композиции для систем постобработки выхлопного газа дизельных двигателей, бензиновых двигателей сгорания, двигателей на обедненной смеси и электростанций, имеющей формулу Се1-a-b-cNaMbDcOx (I), в которой М обозначает калий, N обозначает Вi и/или Sb, D присутствует или отсутствует, и если присутствует, то выбирается из одного или нескольких элементов из Mg, Ca, Sr, Ba; Y, Lа, Рr, Nd, Sm, Gd, Еr; Fе, Zr, Nb, Аl; а является числом в интервале 0<а≤0,9, b является числом в интервале 0 Подробнее

Patent RU2017104108A3

’ВИ“” 2017104108” АЗ Дата публикации: 22.11.2018 Форма № 18 ИЗИМ-2011 Федеральная служба по интеллектуальной собственности Федеральное государственное бюджетное учреждение ж 5 «Федеральный институт промышленной собственности» (ФИПС) ОТЧЕТ О ПОИСКЕ 1. . ИДЕНТИФИКАЦИЯ ЗАЯВКИ Регистрационный номер Дата подачи 2017104108/04(007198) 24.07.2015 РСТ/ЕР2015/067010 24.07.2015 Приоритет установлен по дате: [ ] подачи заявки [ ] поступления дополнительных материалов от к ранее поданной заявке № [ ] приоритета по первоначальной заявке № из которой данная заявка выделена [ ] подачи первоначальной заявки № из которой данная заявка выделена [ ] подачи ранее поданной заявки № [Х] подачи первой(ых) заявки(ок) в государстве-участнике Парижской конвенции (31) Номер первой(ых) заявки(ок) (32) Дата подачи первой(ых) заявки(ок) (33) Код страны 1. 14178892.7 29.07.2014 ЕР* Название изобретения (полезной модели): [Х] - как заявлено; [ ] - уточненное (см. Примечания) КОМПОЗИЦИИ КАТАЛИЗАТОРОВ БЕЗ БЛАГОРОДНЫХ МЕТАЛЛОВ Заявитель: ТРАЙБАХЕР ИНДУСТРИ АГ, АТ 2. ЕДИНСТВО ИЗОБРЕТЕНИЯ [Х] соблюдено [ ] не соблюдено. Пояснения: см. Примечания 3. ФОРМУЛА ИЗОБРЕТЕНИЯ: [Х] приняты во внимание все пункты (см. п см. Примечания [ ] приняты во внимание следующие пункты: р [ ] принята во внимание измененная формула изобретения (см. Примечания) 4. КЛАССИФИКАЦИЯ ОБЪЕКТА ИЗОБРЕТЕНИЯ (ПОЛЕЗНОЙ МОДЕЛИ) (Указываются индексы МПК и индикатор текущей версии) ВО1.] 23/18 (2006.01) ВО01. 37/03 (2006.01) ВО1.] 37/10 (2006.01) ВОТ. 35/00 (2006.01) ВО01./ 37/08 (2006.01) ВО1.] 23/543 (2006.01) 5. ОБЛАСТЬ ПОИСКА 5.1 Проверенный минимум документации РСТ (указывается индексами МПК) ВО11 23/18, ВО13 35/00, ВО11 37/03, ВО14 37/08, ВО13 37/10, ВО11 23/843 5.2 Другая проверенная документация в той мере, в какой она включена в поисковые подборки: 5.3 Электронные базы данных, использованные при поиске (название базы, и если, возможно, поисковые термины): Езрасепее, Соозе, Рабеагсв, КОРТО, ОРТО 6. ДОКУМЕНТЫ, ОТНОСЯЩИЕСЯ К ПРЕДМЕТУ ...

НИКЕЛЕВЫЕ КАТАЛИЗАТОРЫ ГИДРИРОВАНИЯ, СПОСОБ ИХ ПОЛУЧЕНИЯ И ПРИМЕНЕНИЕ

... 1. Селективный катализатор гидрирования, содержащий только никель или никель и один или больше элементов, выбранных из группы, состоящей из Cu, Re, Pd, Zn, Mg, Mo, Ca и Bi, нанесенных на носитель, имеющий следующие физические свойства: площадь поверхности по БЭТ от 30 до примерно 100 м2/г, общий объем пор по азоту от 0,4 до примерно 0,9 см3/г и средний диаметр пор от примерно 110 до 450 Е. 2. Селективный катализатор гидрирования по п.1, в котором носитель выбирают из группы, состоящей из оксида алюминия, диоксида кремния, оксида циркония, талькита, диоксида кремния-оксида алюминия и угля. 3. Селективный катализатор гидрирования по п.1, в котором носителем является оксид алюминия. 4. Селективный катализатор гидрирования по п.3, в котором указанный оксид алюминия прокаливают в температурном интервале от примерно 750 до примерно 1200°С. 5. Селективный катализатор гидрирования по п.4, в котором указанный оксид алюминия имеет, по меньшей мере, 30% пор диаметром больше 100 Е и общий объем пор ...

КОМПОЗИЦИИ КАТАЛИЗАТОРОВ БЕЗ БЛАГОРОДНЫХ МЕТАЛЛОВ

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2017 104 108 A (51) МПК B01J 23/18 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2017104108, 24.07.2015 (71) Заявитель(и): ТРАЙБАХЕР ИНДУСТРИ АГ (AT) Приоритет(ы): (30) Конвенционный приоритет: 29.07.2014 EP 14178892.7 25 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 28.02.2017 EP 2015/067010 (24.07.2015) (87) Публикация заявки PCT: A WO 2016/016127 (04.02.2016) Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр. 3, ООО "Юридическая фирма Городисский и Партнеры" R U (57) Формула изобретения 1. Композиция с формулой Се1-a-b-cNaMbDcOx I, в которой М обозначает один или несколько элементов из группы щелочных металлов кроме натрия, N обозначает Вi и/или Sb, D присутствует или отсутствует, и если присутствует выбирается из одного или нескольких элементов из - Mg, Ca, Sr, Ba; - Y, Lа, Рr, Nd, Sm, Gd, Еr; - Fе, Zr, Nb, Аl; а является числом в интервале 0<а≤0,9, b является числом в интервале 0 Подробнее

OLEFIN SELECTIVE FT CATALYST COMPOSITION AND PREPARATION THEREOF

The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form a) Fe as catalytically active metal, b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal, c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, to a process for the synthesis of a hydrocarbon synthesis catalyst, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.

METHOD OF PREPARATION OF STYRENE

СПОСОБ ПРИГОТОВЛЕНИЯ КАТАЛИЗАТОРА ДЛЯ ОКИСЛЕНИЯ И АММОКСИДАЦИИ ОЛЕФИНОВ

FIELD: chemistry. SUBSTANCE: mixed metal oxide catalyst based on antimonite in a catalytic active oxidation state has the empirical formula: Me a Sb b X c Q d R e O f, where Me is at least one element from the group: Fe, Co, Ni, Sn, U, Cr, Cu, Mn, Ti, Th, Ce, Pr, Sm, or Nd; X is at least one element from the group: V, Mo, or W; Q is at least one element from the group: Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, Sc, Y, La, Zr, Hf, Nb, Ta, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Tl, Ge, Pb, As, or Se; R is at least one element from the group: Bi, B, P, or Te; and the indices a, b, c, d, e and f denote atomic ratios: a has a value from 0.1 to 15; b has a value from 1 to 100; c has a value from 0 to 20; d has a value from 0 to 20; e has a value from 0 to 10 and f is a number, taken to fulfill the valency requirements of the metals answering for the oxidation degree they have in the composition of the catalyst. Method of obtaining such a catalyst includes the following stages. At first they are subjected to aqueous suspension of Sb 2 O 3 with HNO 3 and with one or more compounds of Me, and voluntarily with one or more compounds from the groups: X, Q or R, for obtaining the first mixture (a). The first mixture is then heated and dried to form a solid product (b). After this the solid product is calcinated forming the catalyst. The particular metal oxide catalyst based on antimonite in the catalytic active oxidation state as per the invention has the empirical formula: U a 'Fe a Sb b Mo c Bi e O f , where the indices a, a', b, c, e and f denote atomic ratios: a has a value from 0.1 to 5; a' has a value from 0.1 to 5; b has a value from 1 to 10; c has a value from 0.001 to 0.2; e has a value from 0.001 to 0.2; and f is a number, taken to fulfill the valency requirements of Sb, U, Fe, Bi, and Mo, answering for the oxidation degree they have in the composition of the catalyst. Method of obtaining such a catalyst includes the following stages. At ...

ПРОЦЕСС ПРИГОТОВЛЕНИЯ КАТАЛИЗАТОРА ДЛЯ ОКСИДАЦИИ И АМОКСИДАЦИИ ОЛЕФИНА

... 1. Способ приготовления смешанного металл-окисного катализатора на основе антимоната в каталитически активном окисленном состоянии, указанный катализатор имеет эмпирическую формулу MeaSbb XcQdReOf, где Me по меньшей мере один элемент из группы: Fe, Co, Ni, Sn, U, Cr, Cu, Mn, Ti, Th, Ce, Pr, Sm, или Nd; X по меньшей мере один элемент из группы: V, Мо, или W; Q по меньшей мере один элемент из группы: Li, Na, К, Rb, Cs, Be, Mg, Ca, Sr, Ba, Sc, Y, La, Zr, Hf, Nb, Та, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Tl, Ge, Pb, As, или Se; R по меньшей мере один элемент из группы: Bi, В, Р, или Те; а индексы а, b, с, d, е, и f обозначают атомные отношения: а имеет значения от 0,1 до 15; b имеет значения от 1 до 100; с имеет значения от 0 до 20; d имеет значения от 0 до 20; е имеет значения от 0 до 10; и f является числом, принятым для удовлетворения валентных требований металлов, отвечающих той степени окисления, которую они имеют в составе катализатора, способ включает (a) контакт ...

Catalytic hydrogenative refining of hydrocarbon oils

Hydrocarbon oils are hydrogenatively refined in a catalytic process which comprises passing the oil at elevated temperature together with hydrogen containing gas through a catalytic refining reaction zone, or zones, and heating the reaction mixture leaving the reaction zone, or one such zone, or a portion of such reaction mixture, to a temperature higher than the temperature at the beginning of the first, or only, reaction zone, preferably 10 DEG -50 DEG C. higher, bringing this heated stream into indirect heat exchange with the fresh oil to be refined, and introducing the thus heated fresh oil, after mixing with the hydrogen-containing gas if the latter has not already been added before the indirect heat exchange, without deliberate further heating or cooling into the first or only reaction zone. The use of more than one reaction zone in which different catalysts may be present is particularly suitable when it is desired to carry out various types of treatment in succession, for example ...

NOBLE METAL-FREE CATALYST COMPOSITIONS

A composition of formula (I) Ce1-a-b-cNaMbDcOx wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0 Подробнее

DEHYDROGENATION PROCESS AND CATALYST

PROCEDE DE PREPARATION DU STYRENE

La présente invention a pour objet la production de styrène à partir de 4-vinylcyclohexène par contact avec de l'oxygène moléculaire dans une phase gazeuse à une température élevée en présence d'un catalyseur. Elle est caractérisée en ce que ce catalyseur renferme de l'étain, de l'antimoine et de l'oxygène. Elle se rapporte à la production de styrène avec des rendements élevés, et éventuellement du tellurium et du fer ...

DEHYDROGENATION PROCESS AND CATALYST

... 1358125 Dehydrogenation catalysts PHILLIPS PETROLEUM CO 5 May 1972 [6 May 1971 (4) 7 March 1972] 21167/72 Heading B1E [Also in Division C5] Solid catalyst compositions having a surface area of at least 1m2/g comprise Fe, Co or Ni (20-75 wt %), Sn (1-50 wt %), P(0.5-10 wt %) alkali metal (0-6 wt %) As, Sb or Bi (O-10 wt %) and sulphur (0-5 wt%) each being chemically combined with oxygen. An additional 0.1-10 wt % of Sn (based on the total catalyst weight) may be added by impregnating the catalyst composition with a tin compound. Preferably the catalyst is formed by coprecipitating the Sn+Group VIII metal in the presence of any alkali metal and adding the P as H 3 PO 4 and As, Sb or Bi compound to the precipitate. S if present is derived from Ni SO 4 as the source of Ni. The resulting mixtures are calcined.

Process for the preparation of drifting aluminium alcoholates of alcohols with poin of boiling high

SELECTIVE ISOMERIZATION EMPLOYING METAL ARSENIDE CATALYST

Improvements in or relating to the catalytic isomerization of olefinic hydrocarbons

Unbranched or sparsely branched olefins are converted into branched or more highly branched hydrocarbons by contact, at elevated temperature and pressure in the presence of hydrogen, with a solid, acidic, isomerisation catalyst on which is supported one or more sulphides, selenides, tellurides, antimonides and/or arsenides of a Group VIa and/or VIII metal. The olefin preferably contains 3-8 carbon atoms and may be mixed with other hydrocarbons, alkynes and dienes present, being selectively hydrogenated; the product may contain branched hydrocarbons containing more or less carbon atoms per molecule and is partially or completely hydrogenated. A suitable starting material for producing a gasoline product is a catalytically cracked fraction having an end point of 80-130 DEG C. The catalyst base (acidic to butter yellow indicator) may be silica-alumina, silica-zirconia, boria-alumina, boria-silica or alumina-halogen and may contain 0.5-15% by weight of the total catalyst of the metal compound ...

Olefin selective FT catalyst composition and preparation thereof

A method for converting the carbon monoxide by means of hydrogen

عملية لتحضير محفز للأكسدة والأكسدة الأمينية ammoxidation للأوليفينات

Catalyst for oxidising ammonia

The invention relates to a metal-containing catalyst for oxidising ammonia, having the formula a Fe2O3-M Al2O4-b Bi2O3-c Ce2O3 , where Fe2O3-Bi2O3 are the base components of the composition, and M Al2O4 is a spinel and serves as the support and M represents Mn, Mg, Ca, Ba or Sr, and where a, b and c represent the % by weight based on the weight of the spinel, lying in the range from 10 to 40, 3.5 to 6 and 0.5 to 2.

Process for steam reforming of hydrocarbons

A process for the production of hydrogen and/or carbon monoxide rich gases by steam reforming of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock and steam with a catalyst comprising nickel as a main catalytic component, a refractory carrier material for the nickel, and at least one catalytic element for the steam reforming of the hydrocarbon feedstock, the element being selected from the group consisting of germanium, tin, lead, arsenic, antimony and bismuth.

CATALYST FOR STEAM REFORMING OF HYDROCARBONS

METHOD OF PREPARATION OF STYRENE

DEHYDROCYCLIZATION OF HYDROCARBONS

ISOMERIZATION AND DISPROPORTIONATION OF ALKYL AROMATICS

New oxidation catalysts

Oxidation catalysts contain an oxygenated As anion in association with one or more of the elements Fe, Bi, Al, Sn, Zr, Cr, Co, Pb, Ni, Mn, Sb, V, Cn, B, Mo and W as cations and which after preparation are thereupon actuated by heating to a temperature between 200 DEG and 500 DEG C. in the presence of air, ammonia, steam or mixtures thereof. In examples, arsenates or arsenites of Fe, Bi, Sn and Mo are prepared.ALSO:Unsaturated nitriles, aldehydes and acids are prepared by oxidation of a -olefins in the presence of catalysts containing an oxygenated As anion in association with one or more elements Fe, Bi, Al, Sn, Zr, Cr, Co, Pb, Ni, Mu, Sb, V, Cu, B, Mo and W as cations which are subjected to an activated pretreatment. The synthesis of acrolein from propylene is described with CH3.CHO as by-product. Also aminoxidation of propylene to acrylonitrile is described, with CH3CN as by-product. Examples are given.ALSO:Oxidation catalysts contain an oxygenated. As anion in association with one or ...

A process for the catalytic conversion of unbranched or sparsely branched hydrocarbons into hydrocarbons having a branched or more highly branched carbon chain

In the isomerization to more highly branched hydrocarbon product of an olefinic feed, usually with hydrogenation, as described in Specification 878,035, by contact with hydrogen and a solid acidic isomerization catalyst carrying one or more sulphides, selenides, tellurides, arsenides or antimonides of a Group VIa and/or VIII metal, cracking is reduced by treating the catalyst before and/or during the reaction with water and/or one or more compounds liberating water under the treating conditions, e.g. an alcohol. The feed may be a catalytically cracked or steam cracked gasoline or a C6-C15 propene polymer. The amount of water or its equivalent is 0.1-10% by wt. of the feed when added to the feed and conversion is effected at 200-500 DEG C. and 10-150 atm., preferably in the presence of 0.001-1%, based on feed, of added sulphur compound as described in Specification 917,091.

olefin selective FT catalyst composition and preparation thereof

SELECTIVE ISOMERIZATION EMPLOYING METAL ARSENIDE CATALYST

Catalytic conversion of hydrocarbons

Hydrocarbons are converted to lower boiling hydrocarbons in the presence of hydrogen with a catalyst comprising (1) a metallic hydrogenation component, e.g. Co, Ni, Pt or Dt; (2) a solid acidic cracking component; and (3) As, Sb or Bi. Typical conditions are heating a distillate B.pt. 300-850 DEG F., in the presence of hydrogen at a temperature of 500-700 DEG F., and pressure 200-2000 p.s.i.g. L.H.S.V. 0.1-10 v/v/hour. Additionally the catalyst may contain a halogen e.g. fluorine. Hydrogen to feedstock ratio is 1000 to 10,000 S.C.F./B. Details are disclosed of lowering the nitrogen contact of the feedstock before contact with the catalyst.ALSO:A hydrocarbon conversion catalyst comprises a Group VIII metal, one of Bi, As or Sb, and a halide supported on a solid acidic cracking component, the proportion of Bi, As or Sb to Group VIII metal being 0,01-2 gm. atoms per gm. atom. Preferred Group VIII metals are Ni, Co, Pt and Pd. The preferred halide is fluorine. Specified acid cracking components ...

CATALYST FOR STEAM REFORMING OF HYDROCARBONS

MAKING STYRENE

PROCESS AND CATALYST CONTAINING A LANTHANIDE COMPOUND AS PROMOTER FOR THE DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE.

VERFAHREN ZUR HERSTELLUNG VON STYROL

VERFAHREN ZUR OXYDATIVEN DEHYDRIERUNG EINES ACYCLISCHEN KOHLENWASSERSTOFFES

VERFAHREN ZUR AUFHEIZUNG VON KOHLENWASSERSTOFFOELEN ZWECKS KATALYTISCHER HYDRIERENDER RAFFINATION

Catalyst compositions and their preparation

Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst containing tin in an oxidized state in combination with at least one of the metals bismuth, cobalt, or nickel in an oxidized state. Representative of such conversions is the oxidative dehydrogenation of butane to 1,3-butadiene over a nickel stannate-containing catalyst. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.

CATALYST/PROMOTER FOR DIRECT SYNTHESIS OF DIMETHYLDICHLOROSILANE

Dimethyldichlorosilane is selectively and directly synthesized by reacting methyl chloride with silicon in the presence of ( alpha ) a catalytically effective amount of metallic copper or a copper compound and a promoter ( beta ) therefor, such promoter ( beta ) comprising ( beta 1) metallic tin and/or metallic anitmony or a tin and/or antimony compound, optionally, ( beta 2) metallic zinc or a zinc compound, and ( beta 3) at least one lanthanide compound; alternatively, the promoter ( beta ) comprises ( beta 1), optionally, ( beta 2), ( beta 3) and ( beta 4) at least one alkali metal or alkali metal compound.

Verfahren zur Herstellung von Carbonylverbindungen durch Dampfphasenoxydation von Hydroxyverbindungen

Process for the preparation of styrene

A process for producing styrene from 4-vinylcyclohexene by contacting it with molecular oxygen in a gaseous phase and at an elevated temperature in the presence of a catalyst which contains tin, antimony and oxygen.

METHOD FOR DIRECTLY SYNTHESIZING DIMETHYLDICHLOROSILANE WITH CATALYST CONTAINING LANTHANIDE COMPOUND AS ACCELERATOR

PURPOSE: To provide a direct synthesis method for producing dimethyldichlorosilane from methyl chloride with improved selectivity. CONSTITUTION: The objective dimethyldichlorosilane is selectively and directly synthesized by reacting methyl chloride with silicon in the presence of a catalytically effective amount of metallic copper or a copper compound, and a promoter comprising metallic tin and/or metallic antimony or a tin and/or antimony compound and at least one lanthanide compound, optionally metallic zinc or a zinc compound. COPYRIGHT: (C)1992,JPO ...

Dampfreformierung von Kohlenwasserstoffen.

NOBLE METAL-FREE CATALYST COMPOSITIONS

A composition of formula 2. A composition of wherein D is present.3. A composition of claim 1 , wherein D is Ca claim 1 , Sr claim 1 , or Ba.4. A composition of claim 1 , wherein D is Y claim 1 , Pr claim 1 , La claim 1 , or Nd.5. A composition of claim 1 , wherein D is Fe claim 1 , Zr claim 1 , Nb claim 1 , or Al.6. A composition of claim 1 , wherein c is a number within the range of 0≦c≦0.1.8. A composition of claim 7 , wherein N is Bi.9. A composition of claim 7 , wherein M is potassium.10. A composition of claim 7 , wherein a is a number within the range of 0.01≦a≦0.9.11. A composition of claim 7 , wherein b is a number within the range of 0.01≦b≦0.3.12. A composition of claim 11 , wherein b is a number within the range of 0.1≦b≦0.2.13. A composition of claim 7 , which is selected from the group consisting of{'sub': 0.45', '0.45', '0.10', '1.65-1.4, 'BiCeKO,'}{'sub': 0.40', '0.40', '0.20', '1.4-1.2, 'BiCeKO,'}{'sub': 0.30', '0.60', '0.10', '1.7-1.4, 'BiCeKO,'}{'sub': 0.80', '0.10', '0.10', '1.5-1.4, 'BiCeKO,'}{'sub': 0.10', '0.80', '0.10', '1.8-1.4, 'BiCeKO,'}{'sub': 0.4', '0.4', '0.1', '0.1', '1.55-1.35, 'BiCeKSrO,'}{'sub': 0.4', '0.4', '0.1', '0.1', '1.6-1.4, 'BiCeKPrO, and'}{'sub': 0.4', '0.4', '0.1', '0.1', '1.6-1.4, 'BiCeKFeO.'}14. (canceled)15. A composition of claim 3 , wherein D is Sr.16. A composition of claim 4 , wherein D is Pr.17. A composition of claim 5 , wherein D is Fe.18. A composition of claim 5 , wherein D is Al.19. An exhaust gas after treatment system of a diesel engine claim 1 , gasoline combustion engine claim 1 , lean burn engine claim 1 , or power plant comprising a catalyst that includes the composition of .20. An exhaust gas after treatment system of a diesel engine claim 7 , gasoline combustion engine claim 7 , lean burn engine claim 7 , or power plant comprising a catalyst that includes the composition of . The present invention relates to a noble metal-free catalyst composition, which is e.g. useful for the oxidation of particulate ...

Method of preparing multicomponent bismuth molybdate catalysts comprising four metal components and method of preparing 1,3-butadiene using said catalysts

A method of preparing multicomponent bismuth molybdate catalysts composed of four metal components and a method of preparing 1,3-butadiene using the catalyst, and particularly, to multicomponent bismuth molybdate catalysts composed of a divalent cationic metal, a trivalent cationic metal, bismuth and molybdenum, a preparation method thereof, and a method of preparing 1,3-butadiene from a C4 mixture including n-butene and n-butane using oxidative dehydrogenation are described.

METHODS AND CATALYSTS FOR THE DEHYDROGENATION OF HYDROCARBONS

Catalyst for steam reforming of hydrocarbons

The present invention relates to a catalyst comprising nickel as its main catalytic component supported on a refractory carrier material, the catalyst including also at least one metal selected from Group IVa and Va of the periodic table, and to its use in the production of hydrogen and/or carbon monoxide rich gases by steam reforming of a hydrocarbon feedstock.

항바이러스성 조성물, 항바이러스제, 광촉매 및 바이러스 불활성화 방법

... 본 발명은 명소 및 암소에 있어서 단시간에 뛰어난 항바이러스성을 발현하는, 항바이러스성 조성물, 항바이러스제 및 광촉매, 및 바이러스 불활성화 방법을 제공한다. 본 발명의 항바이러스성 조성물은 BiVO4를 담지한 무기 화합물과, 2가 구리 화합물을 함유한다. 본 발명의 바이러스 불활성화 방법은 본 발명의 항바이러스성 조성물, 본 발명의 항바이러스제 또는 본 발명의 광촉매를 이용하여 바이러스를 불활화한다.

Ni hydrogenation catalysts, manufacture and use

Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m<2>/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

Steam reforming of hydrocarbons

Verfahren zur Aufheizung von Kohlenwasserstoffoelen zwecks katalytischer hydrierender Raffination

Verfahren und Katalysator, mit einer Lanthanidverbindung als Promotoradditiv für die Direktsynthese von Dimethyldichlorsilan.

Verfahren zur katalytischen Umwandlung unverzweigter oder schwach verzweigter Kohlenwasserstoffe

CATALYTIC COMPOSITION FOR OXIDATION OF AMMONIA

The catalyst increases mechanical strength & widens the range of available temp. and is inclined to supersede platinum catalyst maintaining continuance of catalyst function. Its catalytic composition for oxidation is Fe2O3-MA12O4-Bi2O3-Ce2O3. MA12O4, spinel structure, is used for a carrier and worked as a catalyst also. M in MA12O4 shows Mg, Ma, Ca, Br, Ba etc. Fe2O3 is used for for a main catalyst and Ce2O3 is worked as a stabilizer to maintain continuance of catalyst function. The carrier contains Fe2O3 10-40wt %, Bi2O3 3.5-6wt % Ce2O3 0.5-2wt%. Copyright 1997 KIPO ...

Process for preparing a catalyst for the oxidation and ammoxidation of olefins

A process for preparing an antimonate-based mixed metal oxide catalyst in a catalytically active oxidized state, wherein the catalyst is represented by the empirical formula Me_aSb_bX_cQ_dR_eO_f, wherein Me, X, Q, R, a, b, c, d, e, and f are as defined herein, comprising (a) contacting an aqueous Sb₂O₃ slurry with HNO₃ and one or more Me compounds, and, optionally, one or more compounds selected from X, Q, or R compounds to form a first mixture; (b) heating and drying the first mixture to form a solid product; and (c) calcining the solid product to form the catalyst, the catalysts prepared by the process, and the use of the catalysts in ammoxidation and oxidation processes. The catalysts of the invention are particularly useful for the production of acrylonitrile from propylene, ammonia, and an oxygen-containing gas.

Noble metal-free catalyst compositions

A composition of formula Ce1-a-b-cNaMbDcOx I wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0 Подробнее

Verfahren zur UEberfuehrung von hoehersiedenden Kohlenwasserstoffen in niedrigersiedende Kohlenwasserstoffe

Catalyst for gas phase contact oxidation reaction of an unsaturated aldehyde, method for producing acrylic acid method for producing the catalyst

Verfahren zur Herstellung von Glyoxal durch Dampfphasenoxydation von AEthylenglykol

Verfahren zur katalytischen Umwandlung unverzweigter oder schwach verzweigter Kohlenwasserstoffe in Kohlenwasserstoffe mit einer verzweigten oder staerker verzweigten Kohlenstoffkette

OLEFIN SELECTIVE FT CATALYST COMPOSITION AND PREPARATION THEREOF

The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form a) Fe as catalytically active metal, b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal, c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, to a process for the synthesis of a hydrocarbon synthesis catalyst, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.

Verfahren zur Herstellung eines Antimon enthaltenden Mischmetalloxidkatalysators und so erhaltener Katalysator

Nonmetallic catalyst compositions for oxidation of ammonia and process for making the catalyst

Nonmetallic catalyst compositions for oxidation of ammonia have the formula of Fe2 O3 -MAl2 O4 -Bi2 O3 -Ce2 O3. Herein, M represents Mg, Mn, Ca, Sr or Ba. MAl2 O4 is a spinel and has a role of carrier as well as that of assistant catalyst. Fe2 O3 acts as main catalyst, Bi2 O3 as assistant catalyst and Ce2 O3 as stabilizer to extend the effective temperature range of the function of catalyst compositions. In the formula, the ratio of each component is as follows: Fe2 O3 : 10-40 wt % of spinel Bi2 O3 : 3.5-6 wt % of spinel Ce2 O3 : 0.5-2 wt % of spinel.

CATALYTIC COMPOSITE AND IMPROVED PROCESS FOR DEHYDROGENATION OF HYDROCARBONS

A catalytic composite for a cyclic process of adiabatic, non-oxidative dehydrogenation of an alkane into an olefin, comprising a dehydrogenation catalyst, a semimetal and a carrier supporting the catalyst and the semimetal. During the reduction and/or regeneration stages of the adiabatic process, the semimetal releases heat which can be used to initiate the dehydrogenation reactions, which are endothermic in nature, thereby reducing the need for hot air flow and combustion of coke as heat input. The semimetal is inert towards the dehydrogenation reaction itself, alkane feed and olefin product as well as other side reactions of the cyclic process such as cracking and decoking.

Process and catalyst containing a lanthanide compound as promoter for the direct synthesis of dimethyldichlorosilane

Dampfreformierung von Kohlenwasserstoffen.

Ni hydrogenation catalysts, manufacture and use

Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m²/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

Katalysator,Verfahren zu dessen Herstellung und dessen Verwendung

Process for steam reforming of hydrocarbons

A process for the production of hydrogen and/or carbon monoxide rich gases by steam reforming of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock and steam with a catalyst comprising nickel as a main catalytic component, a refractory carrier material for the nickel, and at least one catalytic element for the steam reforming of the hydrocarbon feedstock, the element being selected from the group consisting of germanium, tin, lead, arsenic, antimony and bismuth.

Ni hydrogenation catalysts, manufacture and use

Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

Olefin selective FT catalyst composition and preparation thereof

The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form a) Fe as catalytically active metal, b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal, c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, to a process for the synthesis of a hydrocarbon synthesis catalyst, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.

Catalyst compositions and their preparation

Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst containing tin in an oxidized state in combination with at least one of the metals bismuth, cobalt, or nickel in an oxidized state. Representative of such conversions is the oxidative dehydrogenation of butane to 1,3-butadiene over a nickel stannate-containing catalyst. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.

Semiconductor photocatalyst for the photocatalytic reforming of biomass derivatives for hydrogen generation, and preparation and use thereof

Disclosed are a semiconductor photocatalyst for the photocatalytic reforming of biomass derivatives for hydrogen generation, and preparation and use thereof. The semiconductor photocatalyst has the atomic composition ratio of M˜N-Ax; wherein M˜N are IIB group elements to VIA group elements, or IIIA group elements to VA group elements, A being one element or more than two elements selected from the group consisting of cobalt, nickel, iron, copper, chromium, palladium, platinum, ruthenium, rhodium, iridium and silver; and 0.02%≦x≦1.0%. The method of in-situ preparation of the highly effective semiconductor photocatalyst and catalytically reforming biomass derivatives for hydrogen generation by driving photoreaction with visible light via quantum dots is simple, fast, highly effective, inexpensive and practical. The in situ reaction can occur in sunlight without the need of harsh conditions such as calcination.

BIOTEMPLATED PEROVSKITE NANOMATERIALS

A biotemplated nanomaterial can include a crystalline perovskite. 1. A method of making a nanomaterial comprising forming a perovskite in the presence of a biotemplate having affinity for a metal ion.2. The method of claim 1 , wherein the biotemplate includes a virus particle.3. The method of claim 2 , wherein the virus particle is an M13 bacteriophage.4. The method of claim 1 , wherein forming the perovskite includes forming an aqueous mixture including the biotemplate claim 1 , a first inorganic ion claim 1 , and a second inorganic ion.5. The method of claim 4 , further comprising forming an ion source including the first inorganic ion and the second inorganic ion before forming the aqueous mixture.6. The method of claim 4 , further comprising adjusting the pH of the aqueous mixture and incubating the aqueous mixture for a predetermined time at a predetermined temperature.7. The method of claim 4 , further comprising calcining the reaction products after incubating the aqueous mixture.8. The method of claim 1 , wherein the perovskite has the formula (I):{'br': None, 'sub': x', '1-x', 'y', '1-y', '3±δ, 'AA′BB′O\u2003\u2003(I)'}whereineach of A and A′, independently, is a rare earth, alkaline earth metal, or alkali metal;each of B and B′, independently, is a transition metal;x is in the range of 0 to 1;y is in the range of 0 to 1; andδ is in the range of 0 to 1.9. The method of claim 8 , wherein A and A′ claim 8 , independently claim 8 , are selected from the group consisting of Mg claim 8 , Ca claim 8 , Sr claim 8 , Ba claim 8 , Pb claim 8 , and Bi; and B and B′ claim 8 , independently claim 8 , are selected from the group consisting of Ti claim 8 , Zr claim 8 , V claim 8 , Nb claim 8 , Mn claim 8 , Fe claim 8 , Ru claim 8 , Co claim 8 , Rh claim 8 , Ni claim 8 , Pd claim 8 , Pt claim 8 , Al claim 8 , and Mg.10. The method of claim 8 , wherein the perovskite is a strontium titanate.11. The method of claim 8 , wherein the perovskite is a bismuth ferrite.12. The ...

Processes for preparing amines and catalysts for use therein

Processes for preparing an amine are described which comprise reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia, primary and secondary amines, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst. The catalytically active composition of the catalyst, before its reduction with hydrogen, comprises oxygen compounds of zirconium, of copper, of nickel, in the range from 1.0 to 5.0% by weight of oxygen compounds of cobalt, calculated as CoO, and in the range from 0.2 to 5.0% by weight of oxygen compounds of sulfur, of phosphorus, of gallium, of lead and/or of antimony, calculated in each case as H2SO4, H3PO4, Ga203, PbO and Sb203 respectively.

PROCESS FOR THE PRODUCTION OF NITRILES USING A CATALYST BASED ON ANTIMONY AND IRON

A compound of the formula SbFeO(1) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalysing the ammoxidation reaction of an alcohol of following formula (II) CH═C(R)—CH—OH (II) in which Rrepresents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH═C(R)—C≡N (III) in which Rhas the same meaning as in above formula (ii), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst. 1. A method for catalysing the ammoxidation reaction of an alcohol , said method comprising the steps of: {'br': None, 'sub': x', '1', 'y, 'SbFeO\u2003\u2003(I)'}, 'obtaining a compound having the formula (I)in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive,{'sub': 2', '2', '2, 'sup': 1', '1', '1', '1, 'catalysing the ammoxidation reaction of an alcohol using said compound, where said alcohol has the following formula (II) CH═C(R)—CH—OH (II), in which Rrepresents a hydrogen atom or a methyl radical, to give a nitrile of following formula (III) CH═C(R)—C≡N (III), in which Rhas the same meaning as in the above formula (II),'}wherein said reaction is carried out in the gas phase, the said gas phase having at least oxygen and ammonia.2. Process for the production of a nitrile from an alcohol in he presence of a catalyst , said method comprising: {'br': None, 'sub': 2', '2, 'sup': '1', 'CH═C(R)—CH—OH\u2003\u2003(II)'}, 'a stage of ammoxidation of an alcohol of following formula (II){'sup': '1', 'in which Rrepresents a hydrogen atom or a methyl radical,'} {'br': None, 'sub': '2', 'sup': '1', 'CH═C(R)—C≡N\u2003\u2003(III)'}, 'to result in a nitrile of following formula (III){'sup': '1', 'in which Rhas the same meaning as in the above formula (II),'} {'br': None, 'sub': x', '1', ...

METHOD FOR DEHYDROGENATING A HYDROCARBON STREAM WITH A BIMETALLIC CATALYST

A method of oxidative dehydrogenating a butane-containing hydrocarbon stream by contacting the same with a bimetallic catalyst in the presence of an oxidant, wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided. 120-. (canceled)21. A method of dehydrogenating a butane-containing hydrocarbon stream , comprising:pretreating a bimetallic catalyst in a fixed bed reactor by heating to a temperature above 500° C., then cooling to a temperature of 400-450° C., thencontacting the butane-containing hydrocarbon stream with the bimetallic catalyst in the presence of oxygen to form a product stream comprising a butene compound,wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support, andwherein the butane-containing hydrocarbon stream is contacted with the bimetallic catalyst at a temperature of 400 to 450° C.22. The method of claim 21 , wherein a molar ratio of oxygen to butane is in a range of 1:1 to 4:1.23. The method of claim 21 , wherein the bimetallic catalyst consists of nickel oxide and bismuth oxide on a titanium carbide catalyst support. The present invention relates to a method for oxidative dehydrogenation of a butane-containing hydrocarbon stream by contacting the same with a bimetallic catalyst that includes bismuth and nickel on a titanium carbide catalyst support.The “background” description provided herein is for the purpose of generally presenting the context of the disclosure. Work of the presently named inventors, to the extent it is described in this background section, as well as aspects of the description which may not otherwise qualify as prior art at the time of filing, are neither expressly or impliedly admitted as prior art against the present invention.Catalytic dehydrogenation of alkanes is a common step in the ...

HYDROGENATION AND ETHYNYLATION CATALYSTS

A process for preparing a catalyst includes impregnating a metal oxide carrier with an aqueous solution to form an impregnated carrier; drying the impregnated carrier to form a dried, impregnated carrier; and heat-treating the dried, impregnated carrier in air to form the catalyst; wherein: the aqueous solution includes a copper salt; and from about 3 wt % to about 15 wt % of a C-Cmultifunctional carboxylic acid; and the catalyst includes from about 5 wt % to about 50 wt % copper oxide. 1. A process for forming a catalyst for hydrogenation , dehydrogenation , hydrogenolysis , or ethynylation , the process comprising:impregnating a metal oxide carrier with an aqueous solution to form an impregnated carrier;drying the impregnated carrier to form a dried, impregnated carrier; andheat-treating the dried, impregnated carrier to form the catalyst; [ a copper salt; and', {'sub': 3', '6, 'from about 1 wt % to about 15 wt % of a C-Cmultifunctional carboxylic acid; and'}], 'the aqueous solution comprises, 'the catalyst comprises from about 5 wt % to about 50 wt % copper oxide., 'wherein2. The process of claim 1 , wherein the copper salt comprises copper nitrate claim 1 , copper sulfate claim 1 , copper acetate claim 1 , copper chloride claim 1 , or copper citrate.3. The process of claim 1 , wherein the catalyst is an ethynylation catalyst and the aqueous solution further comprises a bismuth salt and the catalyst comprises up to about 5 wt % BiO.4. The process of claim 3 , wherein the bismuth salt comprises bismuth nitrate claim 3 , bismuth sulfate claim 3 , bismuth acetate claim 3 , bismuth chloride claim 3 , or bismuth citrate.5. The process of claim 1 , wherein the multifunctional carboxylic acid is a C-Cmulti-carboxylic acid.67-. (canceled)8. The process of claim 1 , wherein the catalyst is a hydrogenation claim 1 , dehydrogenation claim 1 , or hydrogenolysis catalyst and the aqueous solution consists essentially of the copper salt claim 1 , from about 1 wt % to about 15 ...

Hydrogenation and ethynylation catalysts

A process for preparing a catalyst includes impregnating a metal oxide carrier with an aqueous solution to form an impregnated carrier; drying the impregnated carrier to form a dried, impregnated carrier; and heat-treating the dried, impregnated carrier in air to form the catalyst; wherein: the aqueous solution includes a copper salt; and from about 3 wt % to about 15 wt % of a C3-C6 multifunctional carboxylic acid; and the catalyst includes from about 5 wt % to about 50 wt % copper oxide.

PRODUCTION OF LIGHT ALKENES FROM ALKANE

A method of oxidative dehydrogenating of butane stream comprises contacting the same with a bimetallic catalyst in the presence of oxygen, wherein the bimetallic catalyst containing nickel and bismuth or oxides thereof supported on solid support such as zirconium oxide, low aluminum MFI zeolite, and mesoporous silica foam. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided. 1. A method of dehydrogenating a butane-containing hydrocarbon stream , comprising:contacting a mixture of the butane-containing hydrocarbon stream and oxygen with a bimetallic catalyst supported on a solid support of low aluminum MFI zeolite to form a product stream comprising one or more oxygenated products, ethylene, and propylene,wherein the bimetallic catalyst consists of nickel oxide and bismuth oxide,wherein the bimetallic catalyst has an average particle size in a range of 0.1 to 2 mm, andwherein the low aluminum MFI zeolite comprises aluminum and has a silicon to aluminum atomic ratio of at least 250.2. The method of claim 1 , further comprising separating the ethylene and the propylene from the oxygenated products.3. The method of claim 1 , wherein the butane-containing hydrocarbon stream comprises butane claim 1 , isobutene claim 1 , raffinate-I claim 1 , raffinate-II claim 1 , rafinate-III claim 1 , rafinate-IV claim 1 , or a combination thereof.4. The method of claim 1 , wherein the butane is n-butane.5. The method of claim 3 , wherein the nickel oxide and bismuth oxide is prepared by impregnating un-calcined solid support.6. (canceled)7. The method of claim 1 , wherein the solid support is modified with Fe claim 1 , Co claim 1 , Ga claim 1 , Mo and/or W.8. The method of claim 1 , wherein a weight percent of nickel in the bimetallic catalyst is within a range of 15 wt % to 25 wt % claim 1 , andwherein a weight percent of bismuth in the bimetallic catalyst is within a range of 25 wt % to ...

CATALYSTS AND METHODS FOR METHANOL SYNTHESIS FROM DIRECT HYDROGENATION OF SYNGAS AND/OR CARBON DIOXIDE

Nano-sized mixed metal oxide catalysts capable of producing methanol (CHOH) from carbon dioxide (CO) and hydrogen (H) or from carbon dioxide (CO), carbon monoxide (CO), and hydrogen (H), methods of making the catalyst, and uses thereof are described herein. The nano-sized mixed metal oxide catalysts can have a formula of: [CuZnAlM]Owhere a is 20 to 80, b is 15 to 60, c is 1 to 25, d is 0 to 15 and n is determined by the oxidation states of the other elements is determined by the oxidation states, and Mcan be yttrium (Y), cerium (Ce), tin (Sn), sodium (Na), bismuth (Bi), magnesium (Mg), or gadolinium (Gd). 1. A mixed metal catalyst capable of producing methanol (CHOH) from hydrogen (H) and carbon dioxide (CO) or from hydrogen (H) , carbon dioxide (CO) and carbon monoxide (CO) , the catalyst having a general formula of:{'br': None, 'sub': a', 'b', 'c', 'n, 'sup': '1', '[CuZnAlMd]O'}where a is 20 to 80, b is 15 to 60, c is 1 to 25, d is 0 to 15 and n is determined by the oxidation states of the other elements; and{'sup': '1', 'where Mis yttrium (Y), cerium (Ce), tin (Sn), sodium (Na), magnesium (Mg), bismuth (Bi), or gadolinium (Gd).'}2. The mixed metal catalyst of claim 1 , wherein Mis Y.3. The mixed metal catalyst of claim 1 , wherein Mis Ce.4. The mixed metal catalyst of claim 1 , wherein Mis Sn.5. The mixed metal catalyst of claim 1 , wherein Mis Na.6. The mixed metal catalyst of claim 1 , wherein Mis Bi.7. The mixed metal catalyst of claim 1 , wherein Mis Gd.8. The mixed metal catalyst of claim 1 , wherein Mis Mg.9. The mixed metal catalyst of claim 1 , where in d is 0 and the catalyst has the formula of: [CuZnAl]O10. The mixed metal oxide catalyst of claim 1 , wherein the catalyst has a particle size of 2 to 12 nm.11. A method of producing methanol (CHOH) from hydrogen (H) and carbon dioxide (CO) or from hydrogen (H) claim 1 , carbon dioxide (CO) and carbon monoxide (CO) claim 1 , the method comprising contacting a reactant gas stream that includes Hand COor H ...

METHOD FOR DEHYDROGENATING A BUTENE-CONTAINING HYDROCARBON STREAM

A method of oxidative dehydrogenating a butane-containing hydrocarbon stream by contacting the same with a bimetallic catalyst in the presence of an oxidant, wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided. 1. A method of dehydrogenating a butane-containing hydrocarbon stream , comprising:pretreating a bimetallic catalyst in a fixed bed reactor by heating to a temperature above 500° C., then cooling to a temperature of 400-450° C., thencontacting the butane-containing hydrocarbon stream with the bimetallic catalyst in the presence of oxygen to form a product stream comprising a butene compound,wherein the bimetallic catalyst consists of nickel oxide and bismuth oxide on a titanium carbide catalyst support.2. The method of claim 1 , wherein the butene compound is one or more of 1-butene claim 1 , cis-2-butene claim 1 , trans-2-butene claim 1 , 1 claim 1 ,3-butadiene claim 1 , and isobutylene.3. The method of claim 1 , wherein a weight percent of nickel in the bimetallic catalyst is within a range of 15 wt % to 25 wt % claim 1 , relative to the total weight of the bimetallic catalyst.4. The method of claim 1 , wherein a weight percent of bismuth in the bimetallic catalyst is within a range of 25 wt % to 35 wt % claim 1 , relative to the total weight of the bimetallic catalyst.5. (canceled)6. The method of claim 1 , wherein a volume fraction of butane in the butane-containing hydrocarbon stream is at least 0.9.7. The method of claim 1 , wherein a molar ratio of oxygen to butane is in a range of 1:1 to 4:1.8. The method of claim 1 , wherein the bimetallic catalyst has an average particle size in a range of 0.1 to 2 mm.9. (canceled)10. The method of claim 1 , wherein the product stream further comprises non-butene compounds claim 1 , and wherein a molar ratio of the ...

Mesoporous composite catalysts containing bismuth silicate and transition metal oxide

Composite catalysts having bismuth silicate(s) (e.g. Bi 2 SiO 5 ) and transition metal oxide(s) (e.g. nickel oxide) impregnated on mesoporous silica supports such as SBA-15, mesoporous silica foam, and silica sol. Methods of making and characterizing the composite catalysts as well as processes for oxidatively dehydrogenating alkanes (e.g. n-butane) and/or alkenes (e.g. 1-butene, 2-butene) to corresponding dienes (e.g. butadiene) employing the composite catalysts are also described.

BIOTEMPLATED PEROVSKITE NANOMATERIALS

A biotemplated nanomaterial can include a crystalline perovskite. 129-. (canceled)30. A method of making a perovskite nanomaterial comprising:combining an aqueous solution of a biotemplate having affinity for a metal ion and an inorganic precursor of a perovskite material to form an aqueous mixture, andreacting the inorganic precursor and the biotemplate to form the perovskite nanomaterial,wherein the perovskite comprises strontium titanate, bismuth ferrite, sodium tantalate, zirconium oxide/tantalum oxynitride, zirconium tantalum oxynitride, tantalum oxynitride, or zirconium tantalum nitride.31. The method of claim 30 , wherein the biotemplate includes a virus particle.32. The method of claim 31 , wherein the virus particle is an M13 bacteriophage.33. The method of claim 30 , wherein the inorganic precursor comprises a first inorganic ion and a second inorganic ion.34. The method of claim 33 , further comprising forming an ion source including the first inorganic ion and the second inorganic ion before forming the aqueous mixture.35. The method of claim 33 , further comprising adjusting the pH of the aqueous mixture and incubating the aqueous mixture for a predetermined time at a predetermined temperature.36. The method of claim 33 , further comprising incubating the aqueous mixture and then calcining the reaction products.37. A method of making a perovskite nanomaterial comprising:combining an aqueous solution of a biotemplate having affinity for a metal ion and an inorganic precursor of a perovskite material to form an aqueous mixture, andreacting the inorganic precursor and the biotemplate to form the perovskite nanomaterial, {'br': None, 'sub': x', '1-x', 'y', '1-y', '3±δ, 'AA′BB′O\u2003\u2003(I)'}, 'wherein the perovskite has the formula (I)whereineach of A and A′, independently, are selected from the group consisting of Mg, Pb, and Bi;each of B and B′, independently, are selected from the group consisting of Zr, V, Nb, Mn, Fe, Ru, Rh, Ni, Pd, Pt, Al, and Mg;x ...

Catalyst, acrylic acid production method, and catalyst production method

An object of the present invention is to provide a catalyst ensuring that in the case of causing gas-phase catalytic oxidation of an unsaturated aldehyde and an oxygen-containing gas with use of the catalyst to produce a corresponding unsaturated carboxylic acid, the pressure loss can be kept low and an unsaturated carboxylic acid can be produced with high selectivity. The present invention relates to a ring-shaped or columnar catalyst, which is used at the time of producing a corresponding unsaturated carboxylic acid by causing gas-phase catalytic oxidation of an unsaturated aldehyde and an oxygen-containing gas, wherein the outer peripheral edge part is inclined relative to the center line.

CATALYSTS FOR PREPARATION OF BUTADIENE BY OXYDEHYDROGENATION OF BUTENE IN FLUIDIZED BED REACTOR AND METHOD OF PREPARING SAME AND USE OF SAME

The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%. 1. A method of preparing a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor , said method comprising the steps of:(1) reacting a metal precursor with an alkaline substance to obtain a slurry containing an insoluble compound, followed by filtering and washing the slurry;(2) adding an appropriate amount of a binder and deionized water, followed by agitating to regulate the solid content of the slurry to 10-50%, wherein the percentage is calculated by mass;(3) subjecting the ...

Catalyst for polyol hydrogenolysis

Ethylene glycol and propylene glycol may be made by hydrogenolysis of a polyol comprising the steps of reacting a polyol with hydrogen in the presence of a hydrogenolysis catalyst. The hydrogenolysis comprises nickel, one or more promoter, and one or more support. The promoter is selected from bismuth, silver, tin, antimony, gold, lead, thallium, cerium, lanthanum, and manganese. The support is selected from zirconia and carbon. A zirconia support comprises a zirconia textual promoter, which is selected from Cr, Mo, W, Nb, Ce, Ca, Mg, La, Pr, Nd, Al, and P. If the support comprises carbon, then the promoter is selected from bismuth and antimony. In another embodiment, if the support comprises carbon, then both the promoter is selected from bismuth and antimony, and the catalyst comprises copper. In another embodiment, the catalyst additionally comprises copper.

Novel Ethynylation Catalyst And Method Of Making Same

A novel catalyst useful in the ethynylation of formaldehyde to butynediol is formed by precipitating copper and bismuth from a salt solution of such metals, utilizing an alkali metal hydroxide as the precipitating agent to deposit copper and bismuth hydroxide as a coating around a siliceous carrier particle. 1. A method of preparing a catalyst for the ethynylation of formaldehyde which comprises: depositing by precipitation copper hydroxide , over a particulate siliceous carrier and calcining the treated carrier to yield a copper oxide coating around the carrier.2. The method of claim 1 , wherein a mixture of copper and bismuth hydroxides are deposited on said carrier.3. The method of claim 1 , wherein the copper hydroxide is formed by adding an alkali metal hydroxide to an acidic copper salt solution.4. The method of claim 3 , wherein an acidic solution is made of a mixture of copper nitrate and bismuth nitrate.5. The method of claim 3 , wherein said alkali metal hydroxide is sodium hydroxide.6. The method of claim 5 , wherein the sodium hydroxide is provided in a separate vessel from the acidic solution claim 5 , and the siliceous carrier particles are provided in water in a precipitation vessel separate from the sodium hydroxide and acidic solution.7. The method of claim 6 , wherein the acidic solution and the sodium hydroxide are added simultaneously to the precipitation vessel.8. The method of claim 6 , wherein the precipitation is carried out at a constant pH of between about 6 to about 10.9. The method of claim 6 , wherein the precipitation is carried out at a contrast pH of between 7.5 to 9.5.10. The method of claim 6 , wherein the precipitation is carried out at a temperature of about 40° C. to 90° C.11. The method of claim 10 , wherein the temperature is between 45° C. to 65° C.12. The method of claim 1 , wherein the precipitate is filtered claim 1 , washed and dried and the dried material calcined in air at a temperature between about 250 to about 550° C. ...

Metal Oxide-Stabilized Zirconium Oxide Ceramic Materials

The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder, extrusion aid or additional stabilizing agent. 2. The method of claim 1 , wherein the reduction is conducted at a temperature within the range of 180° C. to 600° C. claim 1 , and a pressure within the range of about 1 bar to about 150 bar.3. The method of claim 1 , wherein the reduction is conducted at a temperature in the range of 50° C. to 325° C. and a pressure in the range of about 10 bar to about 250 bar.3. The method of claim 3 , wherein the reduction is conducted at a pH in the range of about 2 to about 6.4. The method of claim 1 , wherein the ceramic material comprises nickel oxide present in an amount within the range of about 5 wt. % to about 40 wt. % of the ceramic material claim 1 , as calculated on metallic basis.5. The method of claim 4 , wherein the nickel oxide is present in the ceramic material in an amount within the range of about 5 wt. % to about 25 wt. % of the ceramic material claim 4 , as calculated on metallic basis.6. The method of claim 4 , wherein the nickel oxide is present in the ceramic material in an amount within the range of about 15 wt. % to about 40 wt. % of the ceramic material claim 4 , as calculated on metallic basis.7. The method of claim 4 , wherein the total amount of zirconium oxide and nickel oxide is at least about 95 wt. % of the ceramic material claim 4 , as calculated on ...

MESOPOROUS SILICA SUPPORTED CATALYST FOR OXIDATIVE DEHYDROGENATION

Oxidative dehydrogenation catalysts comprising bismuth and nickel oxides impregnated on mesoporous silica supports such as SBA-15 and mesoporous silica foam. Methods of preparing and characterizing the catalysts as well as processes for oxidatively dehydrogenating n-butane to butadiene using the catalysts are also described. The disclosed catalysts demonstrate higher n-butane conversion and butadiene selectivity than catalysts supported by conventional silica. 1: A catalyst , comprising:a mesoporous silica support which is at least one selected from the group consisting of SBA-15 and mesoporous silica foam; anda catalytic material comprising nickel oxide and bismuth oxide impregnated on the mesoporous silica support;wherein the nickel and bismuth atoms of the nickel oxide and the bismuth oxide are present in amounts of 2-30 wt % and 5-40 wt %, each relative to a weight of the mesoporous silica support.2: The catalyst of claim 1 , wherein the mesoporous silica support has a pore volume of 0.2-3 cm/g and a BET surface area of 200-1 claim 1 ,000 m/g.3: The catalyst of claim 1 , wherein the mesoporous silica support is SBA-15.4: The catalyst of claim 1 , wherein 50-99.9 wt % of the bismuth oxide is present as a non-stoichiometric bismuth oxide relative to a total weight of the bismuth oxide.5: The catalyst of claim 4 , wherein the non-stoichiometric bismuth oxide has a formula of BiO claim 4 , in which x ranges from 0.2 to 0.4.6: The catalyst of claim 1 , which has an average pore diameter of 2-20 nm.7: The catalyst of claim 1 , which has a pore volume of 0.2-2 cm/g.8: The catalyst of claim 1 , which has a BET surface area of 200-700 m/g.9: A method of preparing the catalyst of claim 1 , the method comprising:mixing the mesoporous silica support with an aqueous solution comprising a nickel salt and a bismuth salt to form a mixture;drying the mixture to form a dried mass; andcalcining the dried mass in air at a temperature of 300-700° C. thereby producing the catalyst.10 ...

ANTIMONATE ELECTROCATALYST FOR AN ELECTROCHEMICAL REACTION

Disclosed are stable, active non-precious metal oxide catalysts, such as transition metal antimonates (TMAs), for electrochemical reactions in harsh media conditions, such as the chlorine evolution reaction (CER). A disclosed electrocatalyst includes a metal oxide film containing a crystalline transition metal antimonite (TMA). The crystalline TMA may include NiSbO, CoSbO, or MnSbO. The metal oxide film may be formed on a conductive substrate, for example, a substrate including an antimony-doped tin oxide (ATO) film, using an annealing process. 1. A method of manufacturing an electrocatalyst usable for an electrochemical reaction , comprising:depositing an antimony-doped tin oxide (ATO) film onto a substrate;depositing a metallic film onto the ATO film; andannealing the ATO film and the metallic film to form a metal oxide film containing a crystalline transition metal antimonite (TMA).2. The method of claim 1 , wherein the TMA is selected from the group consisting of NiSbO claim 1 , CoSbO claim 1 , and MnSbO claim 1 , where x is greater than zero and less than or equal to six.3. The method of claim 1 , wherein the TMA is selected from the group consisting of NiSbO claim 1 , CoSbO claim 1 , and MnSbO.4. The method of claim 1 , wherein the metallic film includes a metal or alloy selected from the group consisting of Ni claim 1 , Co claim 1 , Mn claim 1 , Sb claim 1 , NiSb claim 1 , CoSb claim 1 , and MnSb.5. The method of claim 1 , wherein depositing the metallic film onto the ATO film includes sputtering a metal onto the ATO film.6. The method of claim 1 , wherein depositing the metallic film onto the ATO film includes co-sputtering a plurality of metals onto the ATO film.7. The method of claim 1 , wherein the metallic film includes a transition metal and antimony claim 1 , where the transition metal (M) loading and stoichiometry to antimony (Sb) is a bulk M:Sb atomic ratio of approximately 1:2.8. The method of claim 1 , wherein the metallic film includes a ...

SPRAY-DRIED BUTYNEDIOL CATALYSTS

A process of forming an ethynylation catalyst includes providing a slurry including water, a copper-containing material, a bismuth-containing material, a structural material, and a binder; spray-drying the slurry to form particles; and calcining the particles to form the ethynylation catalyst. 1. A process of forming an ethynylation catalyst , the process comprising:providing an aqueous slurry comprising water, a copper-containing material, a bismuth-containing material, a structural material, and a binder;spray-drying the slurry to form particles; andcalcining the particles to form the ethynylation catalyst.2. The process of claim 1 , wherein the copper-containing material comprises copper carbonate claim 1 , copper oxalate claim 1 , copper hydroxide claim 1 , cupric oxide claim 1 , or cuprous oxide.3. The process of claim 1 , wherein the bismuth-containing material comprises bismuth carbonate claim 1 , bismuth oxalate claim 1 , bismuth hydroxide claim 1 , bismuth oxide claim 1 , and bismuth acetate.4. The process of claim 1 , wherein the structural material comprises a clay claim 1 , talc claim 1 , calcium silicate claim 1 , kieselguhr claim 1 , alumina claim 1 , carbon claim 1 , or silica.5. The process of claim 1 , wherein the binder comprises a silica sol claim 1 , an alumina sol claim 1 , sodium silicate claim 1 , or aluminum chlorohydrate.6. The process of claim 1 , wherein the particles have an average particle diameter of about 5 μm to about 100 μm.7. The process of claim 1 , wherein the particles have an average particle diameter of about 5 μm to about 60 μm.8. The process of claim 1 , wherein the particles have an average particle diameter of about 15 μm.9. The ethynylation catalyst formed according to .10. A process of activating an ethynylation catalyst claim 1 , the process comprising:{'claim-ref': {'@idref': 'CLM-00009', 'claim 9'}, 'providing the ethynylation catalyst of ;'}exposing the ethynylation catalyst to formaldehyde to form a mixture; ...

NOVEL ETHYNYLATION CATALYST AND METHOD OF MAKING SAME

A novel catalyst useful in the ethynylation of formaldehyde to butynediol is formed by precipitating copper and bismuth from a salt solution of such metals, utilizing an alkali metal hydroxide as the precipitating agent to deposit copper and bismuth hydroxide as a coating around a siliceous carrier particle. 1. A method of preparing a catalyst for the ethynylation of formaldehyde which comprises: depositing by precipitation copper hydroxide via the reaction of an acidic copper salt solution with an alkaline metal hydroxide , on a particulate siliceous carrier , and calcining the treated carrier to yield a copper oxide coating around said particulate siliceous carrier.2. The method of claim 1 , wherein a mixture of copper and bismuth hydroxides are deposited on said carrier.3. (canceled)4. The method of claim 1 , wherein said acidic solution is made of a mixture of copper nitrate and bismuth nitrate.5. The method of claim 1 , wherein said alkali metal hydroxide is sodium hydroxide.6. The method of claim 5 , wherein the sodium hydroxide is provided in a separate vessel from the acidic solution claim 5 , and the siliceous carrier particles are provided in water in a precipitation vessel separate from the sodium hydroxide and acidic solution.7. The method of claim 5 , wherein said acidic solution and said sodium hydroxide are added simultaneously to the precipitation vessel.8. The method of claim 6 , wherein said precipitation is carried out at a constant pH of between about 6 to about 10.9. The method of claim 6 , wherein said precipitation is carried out at a contrast pH of between 7.5 to 9.5.10. The method of claim 6 , wherein said precipitation is carried out at a temperature of about 40° C. to 90° C.11. The method of claim 10 , wherein said temperature is between 45° C. to 65° C.12. The method of claim 1 , wherein said precipitate is filtered claim 1 , washed and dried and the dried material calcined in air at a temperature between about 250 to about 550° C.13. The ...

Processes for stabilizing antimony catalysts

The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375° C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.

SIMULTANEOUS REACTION AND SEPARATION OF CHEMICALS

The reaction rate of hydrocarbon pyrolysis can be increased to produce solid carbon and hydrogen by the use of molten materials which have catalytic functionality to increase the rate of reaction and physical properties that facilitate the formation and contamination-free separation of the solid carbon. Processes, materials, reactor configurations, and conditions are disclosed whereby methane and other hydrocarbons can be decomposed at high reaction rates into hydrogen gas and carbon products without any carbon oxides in a single reaction step. The process also makes use of specific properties of selected materials with unique solubilities and/or wettability of products into (and/or by) the molten phase to facilitate generation of purified products and increased conversion in more general reactions. 142.-. (canceled)43. A multiphase reaction system comprising:a feed stream comprising one or more hydrocarbon gas phase reactants;a liquid phase comprising a molten salt;a solid phase disposed within the liquid phase; andone or more products, wherein the one or more products comprise solid carbon and hydrogen.44. The system of claim 43 , wherein the solid comprises a solid phase catalyst.45. The system of claim 43 , wherein the solid phase is assembled as a packed bed of solid particles claim 43 , pellets claim 43 , or structure with the liquid phase between the solid particles claim 43 , and wherein the solid particles have catalytic activity to the one or more gas phase reactants.46. The system of claim 43 , wherein the solid phase comprises a metal claim 43 , wherein the metal comprises nickel claim 43 , iron claim 43 , cobalt claim 43 , copper claim 43 , platinum claim 43 , ruthenium claim 43 , rhodium claim 43 , or any combination thereof.47. The system of claim 43 , wherein the solid phase comprises a mixed metal oxide claim 43 , wherein the metal oxide comprises titanium oxide claim 43 , zirconia claim 43 , tungsten oxide claim 43 , or any combination thereof.48. ...

METHOD OF OXIDATIVE DEHYDROGENATION OF HYDROCARBON COMPOUNDS

A method of oxidative dehydrogenating a butane-containing hydrocarbon stream by contacting the same with a bimetallic catalyst in the presence of an oxidant, wherein the bimetallic catalyst comprises nickel and bismuth on a titanium carbide catalyst support. Various embodiments of the method of oxidative dehydrogenating the butane-containing hydrocarbon stream and the bimetallic catalyst are also provided. 1. A method of dehydrogenating a butane-containing hydrocarbon stream , comprising:contacting the butane-containing hydrocarbon stream with a bimetallic catalyst in the presence of oxygen to form a product stream comprising a butene compound,wherein the bimetallic catalyst consists of nickel oxide and bismuth oxide on a titanium carbide catalyst support.2. The method of claim 1 , wherein the butene compound is one or more of 1-butene claim 1 , cis-2-butene claim 1 , trans-2-butene claim 1 , 1 claim 1 ,3-butadiene claim 1 , and isobutylene.3. The method of claim 1 , wherein a weight percent of nickel in the bimetallic catalyst is within a range of 15 wt % to 25 wt % claim 1 , relative to the total weight of the bimetallic catalyst.4. The method of claim 1 , wherein a weight percent of bismuth in the bimetallic catalyst is within a range of 25 wt % to 35 wt % claim 1 , relative to the total weight of the bimetallic catalyst.5. The method of claim 1 , wherein the butane-containing hydrocarbon stream is contacted with the bimetallic catalyst at a temperature of 400 to 450° C.6. The method of claim 1 , wherein a volume fraction of butane in the butane-containing hydrocarbon stream is at least 0.9.7. The method of claim 1 , wherein a molar ratio of oxygen to butane is in a range of 1:1 to 4:1.8. The method of claim 1 , wherein the bimetallic catalyst has an average particle size in a range of 0.1 to 2 mm.9. (canceled)10. The method of claim 1 , wherein the product stream further comprises non-butene compounds claim 1 , and wherein a molar ratio of the butene compound to ...

METAL OXIDE-STABILIZED ZIRCONIUM OXIDE CERAMIC MATERIALS

The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder or additional stabilizing agent. 1. A ceramic material comprising zirconium oxide and metal oxide , whereinthe zirconium oxide is present in an amount within the range of about 50 wt. % to about 99 wt. % of the material;the metal oxide is one or more of nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide; andthe metal oxide is present in an amount within the range of about 1 wt. % to about 50 wt. % of the material, calculated on metallic basis.2. The ceramic material of claim 1 , whereinthe zirconium oxide is present in an amount within the range of about 75 to about 99 wt. % of the material;the metal oxide is present in an amount within the range of about 1 wt. % to about 25 wt. % of the material, calculated on metallic basis; andwherein the ceramic material optionally includes one or more additional metal oxides present in an amount up to about 20 wt. % of the material, calculated on metallic basis.3. The ceramic material of claim 1 , substantially free of chromium.4. The ceramic material of claim 1 , substantially free of manganese.5. The ceramic material of claim 1 , substantially free of silicon oxide claim 1 , aluminum compounds claim 1 , silica-alumina compounds claim 1 , graphite and carbon black.6. The ceramic material of claim 1 , wherein the zirconium oxide is predominantly in a tetragonal phase ...

SUPPORTED INTERMETALLIC COMPOUNDS AND USE AS CATALYST

A composition comprising a ternary intermetallic compound XYZ, wherein X, Y, and Z are different from one another; X being selected from the group consisting of Mn, Fe, Co, Ni, Cu, and Pd; Y being selected from the group consisting of Cr, Co, and Ni; and Z being selected from the group consisting of Al, Si, Ga, Ge, In, Sn, Zn, and Sb; wherein the ternary intermetallic compound is supported on a porous oxidic support material. The composition may be prepared by providing a liquid mixture of sources of X, Y, and Z, and the porous oxidic support material, removing the liquid and heating the resulting mixture in a reducing atmosphere. The composition is useful as catalyst. 1: A composition comprising a ternary intermetallic compound XYZ , whereinX, Y, and Z are different from one another;X being selected from the group consisting of Mn, Fe, Co, Ni, Cu, and Pd;Y being selected from the group consisting of Cr, Co, and Ni; andZ being selected from the group consisting of Al, Si, Ga, Ge, In, Sn, Zn, and Sb;wherein the ternary intermetallic compound is supported on a porous oxidic support material.2: The composition of claim 1 , wherein the porous oxidic support material comprises one or more selected from the group consisting of:silica,alumina,titania,zirconia, anda mixed oxide of one or more selected from the group consisting of Si, Al, Ti, and Zr.3: The composition of claim 1 , wherein X or Y is Co claim 1 , and wherein Z is selected from the group consisting of Al claim 1 , Ga claim 1 , In claim 1 , and Zn.4: The composition of claim 1 , wherein the porous oxidic support material comprises a mixed oxide of Si and Al.5: The composition of claim 1 , wherein in the composition claim 1 , the weight ratio of the ternary intermetallic compound relative to the porous oxidic compound is in the range of from 0.5:99.5 to 30:70.6: The composition of claim 1 , wherein Y is Ni claim 1 , and wherein Z is Al claim 1 , Si claim 1 , Ga claim 1 , In claim 1 , Sn claim 1 , or Sb.7: The ...

METHOD FOR OXIDIZING AMMONIA AND SYSTEM SUITABLE THEREFOR

A system suitable for oxidizing ammonia with oxygen in the presence of catalysts is described. The system includes a reactor equipped with at least one supply line for a reactant gas mixture and at least one discharge line for a process gas; a catalyst comprising at least one transition metal oxide that is not an oxide of a platinum metal; and a device for adjusting a molar ratio of oxygen to ammonia of less than or equal to 1.75 mol/mol in the reactant gas mixture by mixing an oxygen-containing gas stream having an Ocontent of <20% by volume with a chosen amount of ammonia. The oxygen-containing gas stream is produced by a device for: diluting an air stream with a gas stream comprising less than 20% by volume oxygen; or depleting oxygen from an oxygen-containing gas mixture, preferably from air; or by a combination thereof. 1. A system for oxidizing ammonia , comprising:A) a reactor for ammonia oxidation, equipped with at least one supply line for a reactant gas mixture and with at least one discharge line for a process gas;B) a catalyst arrangement inside the reactor, the catalyst comprising at least one transition metal oxide that is not an oxide of a platinum metal; and{'sub': '2', 'claim-text': c1) by a device for diluting an air stream with a gas stream that comprises less than 20% by volume oxygen; or', 'c2) by a device for depleting oxygen from an oxygen-containing gas mixture, preferably from air; or', 'c3) by a combination of measures c1 and c2., 'C) a device for adjusting a molar ratio of oxygen to ammonia in the reactant gas mixture of less than or equal to 1.75 mol/mol by mixing an oxygen-containing gas stream having an Ocontent of <20% by volume with a chosen amount of ammonia, wherein the oxygen-containing gas stream is produced2. The system as claimed in claim 1 , further comprising:D) a device for adjusting an outlet temperature of a product gas from the reactor based on a concentration of ammonia of the reactant gas mixture at an inlet of the ...

Preparation of a hydrocarbon synthesis catalyst

The present invention therefore provides a process for the preparation of a hydrocarbon synthesis catalyst, especially a Fischer-Tropsch catalyst, comprising the following steps: (a) providing a solution of iron or a suspension of a precipitated, non-calcined iron-containing solid in a solvent in which a precursor of a promoter P1 is present, the promoter P1 comprising one or more element(s) selected from the group of boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, (b) removing the solvent from the solution or suspension, and (c) subjecting the product of step (b) to a calcination treatment, wherein - the amount of the precursor of promoter P1 is selected so that the one or more element(s) selected from boron, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium is(are) present in an amount of at least 0.02 g/100 g Fe in the catalyst, and - a precursor of an alkali metal- and/or alkaline earth metal containing promoter P2 is added before, after or during any of the steps of the process so that promoter P2 is present in the catalyst, to a catalyst obtainable by such a process, to a hydrocarbon synthesis process carried out in the presence of such a catalyst and to the use of the catalyst in a hydrocarbon synthesis process.

Hydrocarbon synthesis catalyst and process with improved selectivity to short chain products

The present invention relates to a hydrocarbon synthesis catalyst comprising in its unreduced form a) Fe as catalytically active metal, b) an alkali metal and/or alkaline-earth metal in an alkali metal- and/or alkaline-earth metal-containing promoter, the alkali metal being present in an amount of from 0.1 to 1.0 g/100 g Fe, c) and a further promoter comprising, or consisting of, one or more element(s) selected from the group of boron, silicon, germanium, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium and tellurium, the element(s) being present in an amount of from 0.03 to 0.2 g/100 g Fe, and wherein the catalyst in its unreduced form has a surface area of less than 50 m 2 /g, to a hydrocarbon synthesis process which is operated in the present of such a catalyst and to the use of such a catalyst in a hydrocarbon synthesis process.

올레핀 선택적 ｆｔ 촉매 조성물 및 그의 제조방법

본 발명은 a)촉매 활성을 가진 금속으로서 Fe, b)알칼리 금속- 및/또는 알칼리 토금속을 함유하는 촉진제 내의 알칼리 금속 및/또는 알칼리-토금속, 및 c) 및 붕소, 게르마늄, 질소, 인, 비소, 안티몬, 황, 셀레늄 및 텔루륨의 군으로부터 선택된 하나 이상의 성분으로 구성되거나, 또는 이를 포함하는 추가의 촉진제를 포함하는 비환원 형태의 탄화수소 합성 촉매, 상기 탄화수소 합성 촉매의 합성방법, 상기 촉매의 존재 하에 수행되는 탄화수소 합성 방법 및 탄화수소 합성 방법 중의 상기 촉매의 용도에 관한 것이다.

烯烃选择性ft催化剂组合物及其制备方法

本发明涉及一种烃合成催化剂，在其未还原形式中，所述催化剂包括：a)作为催化活性金属的Fe，b)含有碱金属的促进剂中的碱金属，c)以及含有硼元素或由硼元素组成的其他促进剂。本发明还涉及烃合成催化剂的合成方法、在所述催化剂的存在下进行的烃合成方法以及所述催化剂在烃合成方法中的用途。

烯烃选择性ft催化剂组合物及其制备方法

本发明涉及一种烃合成催化剂，在其未还原形式中所述催化剂包括：a)作为催化活性金属的Fe，b)含碱金属和/或碱土金属的促进剂中的碱金属和/或碱土金属，所述碱金属，c)和含有一种或多种选自硼、锗、氮、磷、砷、锑、硫、硒和碲的组中的元素或由上述元素组成的其他促进剂。本发明还涉及烃合成催化剂的合成方法、在所述催化剂的存在下进行的烃合成方法以及所述催化剂在烃合成方法中的用途。

Olefin selective ft catalyst composition and preparation thereof

烯烃选择性ft催化剂组合物及其制备方法

本发明涉及一种烃合成催化剂，在其未还原形式中，所述催化剂包括：a)作为催化活性金属的Fe，b)含有碱金属的促进剂中的碱金属，c)以及含有硼元素或由硼元素组成的其他促进剂。本发明还涉及烃合成催化剂的合成方法、在所述催化剂的存在下进行的烃合成方法以及所述催化剂在烃合成方法中的用途。

一种用于流化床反应器的丁烯氧化脱氢制丁二烯催化剂及其制备方法和用途

本发明涉及一种用于流化床反应器的丁烯氧化脱氢制丁二烯催化剂及其制备方法和用途，该方法包括：将金属前躯体和碱性物质反应得到含不溶性化合物的浆料，过滤并洗涤；加入粘结剂、去离子水搅拌，调节浆料固含量为10%~50%；然后进行喷雾干燥造粒，控制进料口温度200℃~400℃，出料口温度100℃~160℃，得到催化剂微球，然后在80℃~200℃干燥1~24h后，在500℃~900℃焙烧4~24h，得到催化剂的通式为FeX a Y b Z c O d ，含Fe、Mg、Zn、Bi、Mo、Mn、Ni、Co、Ba、Ca等金属。本发明制得的催化剂颗粒流动性强、粒径分布合适，具有很高机械强度和催化活性，适合于工业化的流化床丁烯氧化脱氢制丁二烯反应。该催化剂用于丁烯氧化脱氢制丁二烯，丁二烯产率为76%~86%，丁二烯选择性94%~97%。

Production of attrition resistant solid catalysts containing antimony oxide suitable for use in a fluidized bed reaction

PROCESS FOR PREPARING AN ATTRITION RESISTANT SOLID CATALYST CONTAINING ATIMONY OXIDE, SUITABLE FOR USE IN A FLUIDIZED BED ESSENTIALLY COMPRISING THE HEAT TREATMENT OF A SLURRY CONTAINING AN ANTIMONY COMPOUND, A FERRIC COMPOUND, A POLYVALENT METAL COMPOUND AND A SILICA SOL.

Process for producing particulate iron-antimony containing oxide composition having high compressive strength

There is provided a process for producing a particulate iron-antimony containing oxide composition having high compressive strength, comprising the steps of: providing an aqueous slurry containing iron ions, nitrate ions and antimony trioxide; adjusting the slurry to a pH value in the range of 0.5 to 3 as measured at 40° C.; heating the slurry; spray-drying the heated slurry; and calcining the resultant particles.

Process for production of attrition resistant antimony oxide containing fluidized bed catalyst having controlled particle size distribution

A process for producing an attrition resistant antimony oxide containing fluidized bed catalyst comprising particles within a controlled particle size distribution comprising: (a) preparing a slurry containing a pentavalent antimony compound, one or more polyvalent metal compounds and a silica sol as essential components; (b) adjusting the pH of the above slurry to not more than 7 and heating the slurry at a temperature of from about 40° C to about 150° C for at least 20 minutes while keeping the mixture in a slurry state to form a slurry containing pentavalent antimony; (c) spray-drying the thus obtained slurry to form substantially spherical particles; (d) separating extremely fine particles and/or coarse particles unsuitable for practical use from the above obtained particles and returning these separated particles to the slurry prior to the spray-drying in step (c) as they are or after the pulverization thereof; and (e) calcining the particles from which the extremely fine particles and/or coarse particles have been removed at a temperature of from about 400° C to about 1100° C.

Butadiene catalyst for fluidized bed reactor prepared by oxidizing and dehydrogenating butylene, and preparation method and use thereof

Catalysts for preparation of butadiene by oxydehydrogenation of butene in fluidized bed reactor and method of preparing same and use of same

The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

THE COMPLEX OXIDE CATALYST OF Bi/Mo/Fe FOR THE OXIDATIVE DEHYDROGENATION OF 1-BUTENE TO 1,3-BUTADIENE AND PROCESS THEREOF

본 발명은 비스무스 몰리브덴 철 복합 산화물 촉매 및 이를 이용한 1-부텐의 산화/탈수소화 반응 촉매에 관한 것으로 기존의 비스무스 몰리브덴 촉매에 비해, 철의 첨가로 인해 열적, 기계적으로 안정성이 우수하며, 전환율과 1,3-부타디엔의 선택도가 높고, 활성 저하가 느린 촉매에 관한 것이다. The present invention relates to a bismuth molybdenum iron composite oxide catalyst and a catalyst for oxidizing / dehydrogenation of 1-butene using the same, compared to the conventional bismuth molybdenum catalyst, due to the addition of iron, thermal and mechanical stability is excellent, and the conversion rate is 1 The present invention relates to a catalyst having high selectivity of, 3-butadiene and a slow activity degradation. 1-부텐, 1,3-부타디엔, 산화/탈수소화 반응, 비스무스, 몰리브덴, 철, 촉매 1-butene, 1,3-butadiene, oxidation / dehydrogenation reaction, bismuth, molybdenum, iron, catalyst

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Improved metal passivator/trap for fcc processes

FIELD: metallurgy. SUBSTANCE: present invention relates to a method of passivating and/or trapping at least one metal impurity from a liquid oil product in cracking apparatus on fluidised catalyst, comprising: contacting said liquid oil product, which contains at least one metal impurity, with a catalytic mixture containing 1) cracking catalyst on fluidised catalyst and 2) metal passivator/trap, which contain mixed metal oxide alloy of R, Sb, and optionally M, where R is Fe 2+/3+ and M is an optional activator. EFFECT: technical result is increased output of end products (selectivity with respect to transport fuel) due to reduced effect of catalyst deactivation by means of metal impurities in liquid oil products. 20 cl, 3 dwg, 6 tbl, 4 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 603 964 C2 (51) МПК C10G 11/18 (2006.01) B01J 38/00 (2006.01) B01J 29/90 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2014125128/04, 21.11.2011 (24) Дата начала отсчета срока действия патента: 21.11.2011 (72) Автор(ы): ХОФФЕР Брам У. (US), СТОКУЭЛЛ Дейвид М. (US) (73) Патентообладатель(и): БАСФ КОРПОРЕЙШН (US) (43) Дата публикации заявки: 27.12.2015 Бюл. № 36 R U Приоритет(ы): (22) Дата подачи заявки: 21.11.2011 (45) Опубликовано: 10.12.2016 Бюл. № 34 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 23.06.2014 (86) Заявка PCT: 2 6 0 3 9 6 4 (56) Список документов, цитированных в отчете о поиске: US 4321129 A, 23.03.1982. US 4370220 А, 25.01.1983. US 6110357 A, 29.08.2000. US 4335021 A, 15.06.1982. RU 2283177 C2, 10.09.2006. EP 0461851 A2, 18.12.1991. 2 6 0 3 9 6 4 R U (87) Публикация заявки PCT: WO 2013/077836 (30.05.2013) Адрес для переписки: 105082, Москва, Спартаковский пер., д. 2, стр. 1, этаж 3, "ЕВРОМАРКПАТ" (54) УСОВЕРШЕНСТВОВАННЫЙ ПАССИВАТОР/ЛОВУШКА МЕТАЛЛА ДЛЯ ПРОЦЕССОВ КФК (57) Реферат: Настоящее изобретение относится к способу которые содержат смешанный сплав оксида пассивирования и/или ...

一种钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂及其制备方法

本发明公开了一种钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂，它由碱式碳酸铋和氯氧化铋组成，其重量百分含量为：Bi 2 O 2 CO 3 ，55％～90％；BiOCl 10％～45％，所述钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂为不规则的片形，粒径100‑200nm，钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂形成碱式碳酸铋/氯氧化铋异质结；以上各组分的质量百分含量之和为100％。本发明还公开了钴氧化物掺杂的碱式碳酸铋/氯氧化铋光催化剂的制备方法，本发明方法简单快速，能提高催化剂的催化效率，适合于工业化生产，可广泛用于降解有机污染物、光催化分解水制氢等领域。

包含四种金属组分的多组分钼酸铋催化剂的制备方法以及使用该催化剂制备1,3-丁二烯的方法

本发明涉及一种制备由四种金属组分组成的多组分钼酸铋催化剂的方法，以及使用该催化剂制备1，3-丁二烯的方法，更具体的说，本发明涉及一种由二价阳离子金属、三价阳离子金属、铋和钼组成的多组分钼酸铋催化剂、其制备方法、以及通过氧化脱氢反应由含有正丁烯和正丁烷的C4混合物来制备1，3-丁二烯的方法。与具有由金属组分构成的复杂组成的常规多组分金属氧化物催化剂不同的是，根据本发明，通过对金属组分的种类和比例进行系统的研究，可以仅使用四种金属组分就制得用于1，3-丁二烯制备工艺的高活性多组分钼酸铋催化剂。

一种中间体2-氨基吡啶-4-甲酸乙酯的合成方法

本发明公开了一种中间体2‑氨基吡啶‑4‑甲酸乙酯的合成方法，包括以下步骤：将2‑氨基‑4‑甲基吡啶与水混合，加热至60‑80℃，加入Cu‑Ce‑Bi‑SiO 2 催化剂，搅拌后向其中通入O 2 ，反应完成后，停止通入O 2 ，降至室温后，过滤，将滤液调节pH为9‑10；加入乙醇，加热回流反应1‑2h后，减压蒸馏去除乙醇，利用二氯甲烷进行多次萃取，合并有机相，去除二氯甲烷，制得2‑氨基吡啶‑4‑甲酸乙酯。本申请的合成方法操作简单，条件温和，副产物较少，产物纯度高，产物收率较高。

一种纳米Cu-Bi合金催化剂的制备方法及应用

一种纳米Cu‑Bi合金催化剂的制备方法及应用，它涉及一种Cu‑Bi纳米合金材料的制备方法及应用。本发明的目的是要解决现有Cu催化还原CO 2 存在过电位高、产物选择性低、稳定性差的问题。制备方法：一、制备前驱体盐溶液；二、还原；三、分离、清洗、干燥，得到纳米Cu‑Bi合金催化剂。纳米Cu‑Bi合金催化剂作为原料制备工作电极，用于电催化还原CO 2 制CH 4 。优点：具有很好的物理化学性能和稳定性；Bi的加入有效提升对CH 4 的产物选择性，同时抑制乙烯的生成及析氢的竞争；电催化还原CO 2 制CH 4 时过电位低。

用于二烯和炔类的选择性加氢的方法和催化剂

一种对来自热解蒸气裂化装置的混合烃流中的炔类和二烯进行选择性加氢的方法，在该方法中，在对炔类和二烯进行选择性加氢的温度和压力条件下使用催化剂进行头部一步式炔类加氢，所述催化剂包含沉积在载体(B)上的催化剂组分(A)：催化剂组分(A)以催化剂的总重量为基准计，1-30重量％的仅含镍的催化组分、或者包含镍和一种或多种选自以下的元素的催化组分：铜、铼、钯、锌、金、银、镁、钼、钙和铋, 载体(B)的BET表面积为1-100米 2 /克，总氮孔体积为0.2-0.9立方厘米/克，平均孔径约为110-450 。该方法将二烯和炔类加氢成烯烃，而不会使轻产物和重产物中的乙烯和丙烯损失，该方法无需对较重组分流进行进一步的处理。另外，还减少了蒸馏塔反应器下部中的聚合量。

制备1,4-丁炔二醇催化剂的方法

本发明公开一种制备1,4-丁炔二醇催化剂的方法，包括如下步骤：（1）配制铜硅混合溶液、铜铋混合溶液、沉淀剂溶液Ⅰ和沉淀剂溶液Ⅱ；（2）往反应釜中加入底水，升温加热至反应温度；并流滴加共沉淀；（3）将物料经过过滤、洗涤，干燥后，过筛；收集过筛产物并将其加入反应釜中；（4）向步骤（3）中的反应釜加入底水，将铜铋混合溶液和沉淀剂溶液Ⅱ并流滴加共沉淀；（5）将物料过滤，洗涤后按固含量10%~40%，加入适量蒸馏水；（6）浆液采用喷雾干燥，干燥、焙烧得到生产1,4-丁炔二醇的催化剂。该催化剂具有耐磨性好、催化剂颗粒均匀、使用过程中不易流失、制备方法简单、易行、重复性好等优点。

一种用于甘油氢解制备1,3-丙二醇的催化剂

本发明公开了一种用于甘油氢解制备1,3-丙二醇的催化剂，以氧化铝为载体，活性组分为金属钴，助剂包括硅钨酸，磷钨酸和磷钼酸等，其中活性组分的含量为载体质量的30％，助剂的含量为催化剂质量的5％。所述催化剂具有催化活性好，1,3-丙二醇收率高等优点，它能够在150～300℃反应温度和1～10MPa氢气压力下实现甘油氢解高选择性制备1,3-丙二醇。制备该催化剂的原料丰富、价格低廉、工艺简单、且可重复使用。

Cupreous catalyst and process for making same

Improved catalyst is made by including in a grind charge of cupreous particulates a small proportion of hydrated refractory metal oxide such as hydrated alumina. Said grind charge contains a major proportion of cuprous and cupric oxides, a minor proportion of elemental copper, and up to about 10% of promoter material. Such charge is subjected to high energy comminution with concomitant crystal lattice distortion. The catalyst is useful for the production of alkyl and aryl halosilanes.

Bismuth-molybdenum-iron complex oxide catalyst for producing 1,3-butadiene by oxidative dehydrogenation of 1-butene and method for producing the same

A kind of catalyst and its preparation method and application handling methylene blue dye wastewater

本发明公开了一种处理亚甲基蓝染料废水的催化剂及其制备方法和应用。所述的催化剂的通式为：CuNiSbSnSi 4 O 13 . 5 ，该方法将硝酸铜、硝酸镍、三氯化锑和四氯化锡在常温常压下完全溶解在水中，在搅拌下滴加硅酸四乙酯，滴加完毕后，继续搅拌直至生成凝胶，然后烘干凝胶并研磨成粉末，经煅烧后获得通式为CuNiSbSnSi 4 O 13 . 5 的催化剂粉体。本发明的催化剂活性高，能在较短的时间内快速高效降解污染物，且废水处理方法在常温常压，无需光照或氧化剂存在下即可进行。工艺流程简单，无二次污染产生，并且运行费用低等特点，有很高的实际应用价值。

Catalyst and catalyst group

FIELD: chemistry.SUBSTANCE: present invention relates to a catalyst and a catalyst group which are used in carrying out a gas-phase catalytic oxidation reaction of an olefin or tertiary butanol in order to obtain a corresponding unsaturated aldehyde and/or unsaturated carboxylic acid, and to catalyst and catalyst group, which are used in gas-phase reaction of catalytic oxidation of unsaturated aldehyde in order to obtain corresponding unsaturated carboxylic acid, as well as to methods of producing acrolein and/or acrylic acid. Ring-like catalyst contains at least molybdenum and bismuth or molybdenum and vanadium and has straight part of housing and hollow part of housing, where: length of straight part of body is less than length of hollow part of body, and at least at one end part area from end part of straight part of body to end part of hollow part of body has concave curvature. Catalyst group comprising 200 or more ring-shaped catalysts contains at least molybdenum and bismuth or molybdenum and vanadium, wherein said catalyst group satisfies following conditions (1), (2) and (3): (1) catalyst group contains catalyst (A), in which the body straight part length is less than the hollow part length of the body, straight part of housing is located between surface including one end part of hollow part of housing and surface including other end part of hollow part of housing, and at least at one end part the area from the end part of the body straight part to the hollow part end part of housing is linear and/or has concave curvature; (2) proportional part of number of end parts, in which area from end part of housing straight part to end part of hollow part of housing has concave curvature, relative to the total number of end parts of catalyst (A) is 40 % or more, and (3) the portion of the upper position in accordance with the sample for shaking the catalyst group is 70 % or less.EFFECT: technical result is reduced loss of pressure, delayed coke formation and high ...

A kind of activation persulfate tire C catalyst and preparation and application

本发明公开了一种可以高效活化过硫酸盐的轮胎碳催化剂的制备方法，包括以下步骤：先用废旧轮胎经过破碎、磁选和低温热解等过程制得催化剂的载体轮胎碳，然后将CuO、CeO 2 、Fe 2 O 3 、Bi 2 O 3 、Co 2 O 3 再经过浸渍、混捏、热解等过程后得到一种新型高效适用于过硫酸盐体系的催化剂。本发明制备的催化剂在过硫酸盐体系中具有活性高、活性组分浸渍量少、制备简单、技术成熟、稳定性好及成本低等优点，可应用于污水处理和环境治理等领域。本发明制备催化剂所用原料为废旧轮胎，可以将废轮胎变废为宝，充分资源化利用，实现以废治废，具有显著的经济效益。本发明还提供了该催化剂用于降解有机废水的方法，对有机废水去除率可达到95％以上，均可满足国家一级废水排放标准。

Spray-dried butynediol catalyst

A kind of heterogeneous lightwave CATV catalyst of trielement composite material and its preparation and application

本发明涉及一种以焙烧后的城市污泥残渣为载体，以三种高活性金属为活性组分制备负载型催化剂的制备方法。本发明通过将城市生活污泥高温焙烧后，得到具有高比表面积，高孔隙率的污泥催化剂载体，以TiO 2 、AgNO 3 、MnO 2 、Fe(NO 3 ) 3 ·9H 2 O、InN 3 O 9 ·xH 2 O(X＝2)、Sr(NO 3 ) 2 、Bi(NO 3 ) 3 等金属化合物中任意三种金属成分，按照一定的元素摩尔比将三种金属成分混合制得三元金属复合物前驱体，将该类三元金属复合物前驱体负载于污泥载体上，经过再次高温焙烧获得具有高催化活性，高稳定性的污泥催化剂。此类催化剂应用于非均相光Fenton体系处理难降解高浓度工业有机废水，属于水处理技术和环境功能材料领域。

The method of fixed bed preparing low-carbon olefins

本发明涉及固定床制取低碳烯烃的方法，主要解决现有技术中存在的合成气制低碳烯烃反应中CO转化率低和低碳烯烃选择性低的问题。本发明采用固定床制取低碳烯烃的方法，包括以合成气为原料，原料与催化剂接触反应生成含C 2 ～C 4 的烯烃，所述催化剂以重量份数计包括以下组分：a)5～40份铁系元素或其氧化物；b)1～25份包括VA族中的至少一种元素或其氧化物；c)40～90份由钾霞石和氧化镁、氧化铝中的至少一种高温烧结而成的混合物的技术方案，较好地解决了该问题，可用于固定床制取低碳烯烃的工业生产。

METHOD FOR PRODUCING AMINE

1. Способ получения амина посредством реакции первичного или вторичного спирта, альдегида и/или кетона с водородом и азотсодержащим соединением, выбранным из группы аммиака, первичных и вторичных аминов, в присутствии цирконий-диоксид- и никельсодержащего катализатора, отличающийся тем, что каталитически активная масса катализатора перед его восстановлением водородом содержит кислородсодержащие соединения циркония, меди, никеля и кобальта и кислородсодержащие соединения одного или нескольких металлов, выбранных из Sb, Pb, Bi и In. ! 2. Способ по п.1, отличающийся тем, что каталитически активная масса катализатора перед его восстановлением водородом содержит в интервале от 0,1 до ! 10 вес.% кислородсодержащих соединений одного или нескольких металлов, выбранных из Sb, Pb, Bi и In, рассчитанных соответственно как Sb2O3, PbO, Bi2O3 или In2O3. ! 3. Способ по п.1, отличающийся тем, что каталитически активная масса катализатора перед его восстановлением водородом содержит в интервале от 0,2 до ! 7 вес.% кислородсодержащих соединений одного или нескольких металлов, выбранных из Sb, Pb, Bi и In, рассчитанных соответственно как Sb2O3, PbO, Bi2O3 или In2O3. ! 4. Способ по п.1, отличающийся тем, что каталитически активная масса катализатора перед его восстановлением водородом содержит в интервале от 0,4 до ! 5 вес.% кислородсодержащих соединений одного или нескольких металлов, выбранных из Sb, Pb, Bi и In, рассчитанных соответственно как Sb2O3, PbO, Bi2O3 или In2O3. !5. Способ по п.1, отличающийся тем, что каталитически активная масса катализатора перед его восстановлением водородом содержит в интервале ! от 10 до 75 вес.% кислородсодержащих соединений циркония, рассчитанных как ZrO2, от 1 РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2009 104 983 (13) A (51) МПК C07C 209/16 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ, ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21), (22) Заявка: 2009104983/04, 04.07.2007 (71) Заявитель(и): БАСФ СЕ (DE) (30) Конвенционный ...

Demetallization of hydrocarbon feed streams with nickel arsenide

Metals contained in a hydrocarbon containing feed stream are at least partially removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising an alumina-containing support and nickel arsenide, NiAs x . The life and activity of the catalyst composition can be increased by introducing a decomposable compound of a metal selected from the group consisting of the metals of Group IV-B, Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream during or prior to contacting the feed stream with hydrogen and the catalyst composition. The preferred nickel arsenide catalyst composition is prepared by reduction of alumina-supported nickel arsenate with hydrogen gas.

Catalytic conversion of propene into higher boiling hydrocarbons

A kind of environmental friendliness sections antimony composite oxides denitrating catalyst and preparation method thereof

本发明公开一种环境友好型铁锑复合氧化物催化剂，该催化剂在制备过程中采用均相共沉淀法和水热法相结合的处理工艺，同时利用共沸精馏的技术手段进行后处理，在该金属复合氧化物中铁和锑的氧化物能形成固溶体，其中以金属元素的摩尔比计，铁和锑的摩尔比为0.5~2.0。本发明所制备的催化剂可以在200~400℃范围内显示出优异的脱硝活性、N 2 选择性、反应稳定性及抗水耐硫性能。

ADVANCED PASSIVATOR / METAL TRAP FOR KFK PROCESSES

1. Способ пассивирования и/или улавливания по меньшей мере одной металлической примеси из жидкого нефтепродукта в установке КФК, содержащий: контактирование указанного жидкого нефтепродукта, который содержит по меньшей мере одну металлическую примесь, с каталитической смесью, содержащей 1) катализатор КФК, и 2) пассиватор/ловушку металла, которые содержат смесь R, Sb, и необязательно М, где R представляет собой окислительно-восстановительный элемент и М представляет собой необязательный активатор.2. Способ по п. 1, где указанный жидкий нефтепродукт выбирают из сжиженных нефтяных газов, нефти без легких фракций, остаточных нефтепродуктов, слабо крекированной нефти, и их смеси.3. Способ по п. 1, где указанный окислительно-восстановительный элемент R выбирают из Fe, Ce, Cr, U, Sn, или Mn.4. Способ по п. 1, где указанный активатор М выбирают из оксидов Na, Zn, W, Те, Мо, Са, Ва, Mg, Mn, Sn, или Cu.5. Способ по п. 1, где по меньшей мере одну указанную металлическую примесь выбирают из никеля, ванадия или их смесей.6. Способ по п. 1, где указанный жидкий нефтепродукт содержит остаточный нефтепродукт.7. Способ по п. 1, где указанная металлическая примесь присутствует в указанном жидком нефтепродукте в количестве, которое составляет по меньшей мере приблизительно 0,1 млн.ч.8. Способ по п. 1, где указанная металлическая примесь присутствует в указанном жидком нефтепродукте в количестве, которое составляет до 200 млн.ч.9. Способ по п. 1, где после контактирования указанного жидкого нефтепродукта с указанной каталитической смесью, указанный катализатор КФК имеет отложение, которое составляет по меньшей мере 300 млн.ч. указанной металлической примеси.10. Способ по п. 1, РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2014 125 128 A (51) МПК C10G 11/18 (2006.01) B01J 38/00 (2006.01) B01J 29/90 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2014125128/04, 21.11.2011 (71) Заявитель(и): БАСФ КОРПОРЕЙШН (US) Приоритет(ы): (22) Дата ...

A kind of catalysis material and preparation method thereof

本发明提供了一种光催化材料及其制备方法，本发明提供的催化材料，为金属掺杂的球形δ‑Bi 2 O 3 ，其中，所述金属为镍、铝和锌中的一种或几种，其中，本发明通过将镍、铝和锌中的一种或几种金属掺杂在球形δ‑Bi 2 O 3 中，使得得到的光催化材料对NO氧化的反应的催化效率大大提高，且催化稳定性好。

A kind of bulky grain copper bismuth catalyst and its preparation method and application

本发明公开一种大颗粒铜铋催化剂的制备方法，包括以下步骤：（1）配制含有铜盐和铋盐的酸性溶液；（2）配制沉淀剂溶液；（3）往反应釜中加入底水，升温加热至反应温度；（4）采取并流的方式，将步骤（1）的酸性溶液和步骤（2）的沉淀剂溶液滴加到反应釜中；（5）当剩余酸性溶液为步骤（1）配制酸性溶液总量的4/5~9/10时，停止反应，进行老化；（6）老化结束后，继续进行反应并从反应釜底部继续通入气体CO 2 ；（7）当剩余酸性溶液为步骤（1）配制酸性溶液总量的1/5‑1/10时，提高向反应体系加水的流量；（8）待反应结束后，进行老化，老化结束后，洗涤，过滤。该方法制备的催化剂具有耐磨性好，催化剂颗粒大小均匀适中、活性稳定性高，丙炔醇的产量高等优点。

Catalyst composition

1364587 Production of acrylonitrile BP CHEMICALS INTERNATIONAL Ltd 12 March 1973 [17 March 1972] 12607/72 Heading C2C Acrylonitrile is produced by the reaction at elevated temperature in the vapour phase of propylene, molecular oxygen and ammonia over a catalyst which is an oxide composition comprising Sb, Sn, Cu and/or Fe with, one or more of Be, Mg, Ca, Zn, Sr, Cd and Ba.

Photocatalyst containing Barium doped Bismuth ferrite, and water treatment method using the same

본 발명은 광촉매 및 이를 이용한 수처리 방법에 관한 것으로, 상기 광촉매는 바륨(Ba)이 도핑된 비스무스 산화철(BiFeO 3 )을 포함하여 약 2.1 eV 미만의 밴드갭을 나타내므로 가시광 영역의 광에 대하여 높은 광촉매 활성을 나타내고, 상온에서 3.0 emu/g 이상의 높은 포화 자화(M s )를 나타내어 수중에서의 회수가 용이하고 재사용이 가능하므로 수처리용 광촉매 소재로 유용하게 사용될 수 있다. The present invention relates to a photocatalyst and a water treatment method using the same, wherein the photocatalyst comprises a barium (Ba) -doped bismuth iron oxide (BiFeO 3 ) and exhibits a band gap of less than about 2.1 eV, so that it has a high photocatalyst for light in the visible region. It exhibits activity and exhibits a high saturation magnetization (M s ) of 3.0 emu / g or higher at room temperature, making it easy to recover and reuse in water, so it can be usefully used as a photocatalyst material for water treatment.

Catalyst for oxidizing carbon monoxide for reformer used in for fuel cell, and fuel cell system comprising same

A carbon monoxide oxidizing catalyst for a reformer used in a fuel cell system, and a fuel cell system comprising the carbon monoxide oxidizing catalyst are provided to have excellent carbon monoxide oxidizing activities and selectivity and to be highly efficient even at low temperatures. A carbon monoxide oxidizing catalyst for a reformer used in a fuel cell system includes as an active material a solid solution, the solid solution comprising: a compound selected from the group consisting of selenium oxide, tellurium oxide, bismuth oxide, and combinations thereof; copper oxide; and cesium oxide. A fuel cell system(100) comprises: a reformer(30) having a reforming reaction part(32) that generates hydrogen gas from a fuel through a reforming catalytic reaction by thermal energy, and at least one carbon monoxide reduction part(33) that reduces the concentration of carbon monoxide containing the hydrogen gas through an oxidation reaction of carbon monoxide and an oxidizer, the carbon monoxide reduction part comprising the carbon monoxide oxidizing catalyst; at least one electricity generating part(11) that generates electrical energy through an electrochemical reaction of the hydrogen gas and an oxidizer; a fuel supply part(50) that supplies the fuel into the reforming reaction part; and an oxidizer supply part(70) that supplies an oxidizer to the carbon monoxide reduction part and the electricity generating part.

A kind of iron oxide-bismuth oxide-bismuth sulfide visible light catalytic film and its preparation method and application

本发明公开了一种氧化铁‑氧化铋‑硫化铋可见光催化薄膜的制备方法：(1)以Fe 2+ 的前驱体溶液作为电解液，导电基底为工作电极采用三电极体系进行电沉积后煅烧处理制得Fe 2 O 3 薄膜；(2)以Bi 3+ 的前驱体溶液作为电解液，Fe 2 O 3 薄膜作为工作电极采用三电极体系进行电沉积，干燥后置于硫脲水溶液中进行水热反应，经洗涤制得Fe 2 O 3 ‑Bi 2 O 3 ‑Bi 2 S 3 可见光催化薄膜。本发明还包括采用上述方法制得的Fe 2 O 3 ‑Bi 2 O 3 ‑Bi 2 S 3 可见光催化薄膜及利用该膜在处理含酚废水中的应用。所得可见光催化薄膜成膜均匀，稳定性好，活性成分不易剥落，光生电子和空穴分离效率高，具有良好的光电催化活性。

Prussic acid manufacturing method

Process for the production of hydrogen cyanide

내용 없음. No content.

Method for producing hollow microspheres of bismuth ferrite

Изобретение может быть использовано для получения наноструктурированных порошков феррита висмута BiFeO, применяемых в микроэлектронике, спинтронике, устройствах для магнитной записи информации, в производстве фотокатализаторов, материалов для фотовольтаики. Способ получения полых микросфер феррита висмута включает ультразвуковое воздействие на смесь нитратов железа и висмута, взятых в стехиометрическом соотношении, сушку и последующее прокаливание. Ультразвуковому воздействию подвергают водный раствор смеси нитратов железа и висмута с концентрацией 0,24-0,48 моль/л в пересчете на феррит висмута. Водный раствор переводят во взвешенное состояние с образованием аэрозоля, частицы которого подаются в зону сушки, а затем в зону прокаливания. Частота ультразвукового воздействия 1,7–3,0 МГц, скорость подачи воздуха 0,150–0,185 м/с. Полученный продукт сушат при 250-350°С и прокаливают при 800-820°С. Изобретение позволяет сократить процесс получения полых микросфер феррита висмута до нескольких секунд. 4 ил., 4 пр. РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 663 738 C1 (51) МПК C01G 29/00 (2006.01) C01G 49/00 (2006.01) B01J 13/04 (2006.01) B01J 19/10 (2006.01) B22F 9/16 (2006.01) B82B 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА B82Y 30/00 (2011.01) ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ B01J 23/843 (2006.01) B01J 35/08 (2006.01) (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C01G 29/00 (2018.05); C01G 49/0018 (2018.05); B01J 13/043 (2018.05); B01J 13/0095 (2018.05); B01J 19/10 (2018.05); B22F 9/16 (2018.05); B82B 3/00 (2018.05); B82Y 30/00 (2018.05); B01J 23/8437 (2018.05); B01J 35/08 (2018.05) 2017140965, 24.11.2017 (24) Дата начала отсчета срока действия патента: 24.11.2017 (73) Патентообладатель(и): Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук (RU) 09.08.2018 Приоритет(ы): (22) Дата подачи заявки: 24.11.2017 2 6 6 3 7 3 8 R U Адрес для переписки: 620990, Сверловская обл., г. Екатеринбург, ул. Первомайская, 91 ...

Patent JPH0247264B2

Process and catalyst for selective hydrogenation of dienes and acetylenes

一种对来自热解蒸气裂化装置的混合烃流中的炔类和二烯进行选择性加氢的方法，在该方法中，在对炔类和二烯进行选择性加氢的温度和压力条件下使用催化剂进行头部一步式炔类加氢，所述催化剂包含沉积在(B)上的(A)：(A)以催化剂的总重量为基准计，1－30重量％的仅含镍的催化组分、或者包含镍和一种或多种选自以下的元素的催化组分：铜、铼、钯、锌、金、银、镁、钼、钙和铋，(B)载体，其BET表面积为1－约100米 2 /克，总氮孔体积为0.2－约0.9立方厘米/克，平均孔径约为110－450。该方法将二烯和炔类加氢成烯烃，而不会使轻产物和重产物中的乙烯和丙烯损失，该方法无需对较重组分流进行进一步的处理。另外，还减少了蒸馏塔反应器下部中的聚合量。

A kind of composite catalyst for handling the waste gas containing NO and preparation method thereof

本发明涉及一种处理含NO废气的复合催化剂及其制备方法，由氧化催化剂、还原催化剂和催化剂载体组成，所述的氧化催化剂是Sb 2 O 3 和Bi 2 O 3 ；所述的还原催化剂是钙钛矿结构的LaSb 1‑x B x O 3 或LaBi 1‑x B x O 3 ，其中,B代表过渡金属Cr、Mn、Fe、Co,x=0.5‑0.9；所述的催化剂载体是TiO 2 、ZrO 2 、SiO 2 、SnO 2 、Al 2 O 3 、沸石和堇青石之一或二种的混合物。用其10g装填在固定床催化反应器中，在300℃下处理氧化法制备乙醛酸产生的含NO废气，NO的清除率为84%‑93%。本发明复合催化剂不依赖外加NH 3 和CO等还原组分进行NO还原，没有二次污染，具有耐水分和抗硫污染性能好，使用寿命长，运行成本低的特点。

Fe-doped modified Fe-Bi 2 O 4 Method for preparing piezoelectric catalyst

本发明公开了一种Fe掺杂改性的Fe‑Bi 2 O 4 压电催化剂的制备方法，包括以下步骤：(1)在内衬有聚四氟乙烯的反应釜中，在超纯水中加入九水合硝酸铁和二水合铋酸钠，并搅拌分散形成悬浊液；(2)得到的悬浊液加热至433±5K进行水热合成反应10～15h；(3)水热合成后的反应产物先经过超纯水反复离心洗涤至中性，最后用乙醇洗涤若干次，得到的产物经过烘干和干燥处理，得到Fe‑Bi 2 O 4 压电催化剂。本发明采用水热合成法制备的Fe‑Bi 2 O 4 ，操作简单，能够快速降解污染物，可以广泛应用，在降解磺胺甲基嘧啶方面具有显著的优点。本发明催化剂具有合成便利、环境友好、性能稳定、效率高等优点。

Method of obtaining acrylnitrile

Catalyst for preparing chloroethylene by calcium carbide method and preparation method thereof

本发明提供一种用于电石法制氯乙烯的催化剂及其制备方法，其制备方法包括：制备含氮活性炭、配置吸附液、制备催化剂；所述制备含氮活性炭，包括：活性炭的选取、酸洗、浸渍。本发明的催化剂，具有好的低温反应活性和选择性；在反应温度仅为100℃时，乙炔空速为30‑40h ‑1 条件下，其乙炔初始转化率大于99.0%，氯乙烯选择性大于99.5%；所述催化剂在使用1600小时后，其催化性能与新催化剂的催化性能无明显区别；所述催化剂成分配比简洁，成本低廉，对环境危害小；能够适用于大规模工业生产。

A kind of preparation method of bismuth ferrate nano hollow ball

本发明公开了一种铁酸铋纳米空心球的制备方法，包括以下步骤：室温下将十二烷基苯磺酸钠和苯乙烯加入到装有去离子水的加热容器中，搅拌下加入过硫酸钾恒温反应2h；加入苯乙烯、丙烯酸、过硫酸钾和碳酸氢钠，反应2～5h后离心，得到聚(苯乙烯‑丙烯酸)纳米球；超声分散使聚(苯乙烯‑丙烯酸)纳米球完全分散在水中，加入聚乙烯吡咯烷酮，同时加入摩尔比为1:1的九水硝酸铁和五水硝酸铋，超声分散成悬浊液；加入尿素水溶液，恒温反应后抽滤得到聚(苯乙烯‑丙烯酸)铁酸铋复合纳米球，高温煅烧后得到铁酸铋纳米空心球。本发明所制备的铁酸铋纳米空心球，尺寸均匀，分散性较好，无团聚，比表面积较大，对可见光吸收效果比较明显，是一种新型的光催化和光伏新材料。

Method of producing ethylene glycol via fluidised bed catalytic reaction of oxalate

FIELD: chemistry. SUBSTANCE: present invention relates to a method of producing ethylene glycol in a fluidised bed reactor by bringing oxalate raw material into contact with a catalyst under the following conditions: reaction temperature of about 170°C to about 270°C, oxalate bulk speed of about 0.2 h -1 to about 7 h -1 , hydrogen/ester molar ratio of about20-200:1, reaction pressure of about 1.5 MPa to about 10 MPa, and reaction temperature difference ΔT of about 1°C to about 15°C, to obtain an ethylene glycol-containing stream; wherein said fluidised bed catalyst is a catalyst contains the following, pts.wt: 5-80 copper and an oxide thereof, 10-90 at least one filler selected from silicon oxide, a molecular sieve or aluminium oxide, 0.01-30 bismuth and tungsten metal or oxides thereof, or cerium and niobium metal or oxides thereof, where the average specific surface area of the fluidised bed catalyst varies in the range of about 50 m 2 /g to about 800 m 2 /g, and the average particle diameter of the fluidised bed catalyst varies in the range of about 20 mcm to about 300 mcm. EFFECT: high degree of conversion of oxalate, selectivity of ethylene glycol and high stability of the catalyst. 11 cl, 12 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 565 074 C2 (51) МПК C07C 31/20 (2006.01) C07C 29/149 (2006.01) B01J 23/72 (2006.01) B01J 29/48 (2006.01) B01J 29/46 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2013143309/04, 24.02.2012 (24) Дата начала отсчета срока действия патента: 24.02.2012 Приоритет(ы): (30) Конвенционный приоритет: (43) Дата публикации заявки: 27.03.2015 Бюл. № 9 (56) Список документов, цитированных в отчете о поиске: CN 101474561 А, 07.08.2009 . CN 101475443 A, 08.07.2009. US 4112245 А, 09.05.1978 . RU 2058285 C1, 20.04.1996 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 25.09.2013 2 5 6 5 0 7 4 (45) Опубликовано: 20.10.2015 Бюл. № 29 (73) Патентообладатель(и): ЧАЙНА ...

By the method for the clay standby antimony adsorbent of Fenton and series production nitro reducing catalyst

本发明属于环保、化工领域，涉及一种由水处理领域里产生的芬顿泥废渣的资源化利用方法。该方法的原料为芬顿泥废渣以及葡萄糖等物质，经酸解、水热、共沉淀、烘干、工艺步骤，转变为吸附剂，该吸附剂可有效吸附水中的污染物——重金属锑。吸附锑之后的含锑吸附剂通过磁分离收回，再经过煅烧、活化等工艺步骤，转变为催化剂，用于催化肼致硝基还原反应。本发明给出由芬顿泥制备吸附剂、以及由用过的吸附剂制备催化剂的工艺条件，并验证催化剂具有良好的活性。利用本发明使芬顿泥以及污水中的锑都可以得到良好的治理，并得到资源化利用。

Method for producing an amine

Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of one or more metals selected from the group consisting of Sb, Pb, Bi, and In.

Process for preparing amines and zirconium dioxide- and nickel-containing catalysts for use therein

Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In.

Processes for preparing amines and catalysts for use therein

Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, and 0.2 to 40% by weight of an oxygen compound of cobalt, calculated as CoO, 0.1 to 5% by weight of an oxygen compound of iron, calculated as Fe 2 O 3 , and 0.1 to 5% by weight of at least one oxygen compound of lead, tin, bismuth or antimony, calculated as PbO, SnO, Bi 2 O 3 and Sb 2 O 3 respectively.

Method for producing an amine

Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, nickel, and iron, and 0.2 to 5.5% by weight of at least one oxygen compound of tin, lead, bismuth, molybdenum, antimony or phosphorus, calculated as SnO, PbO, Bi 2 O 3 , MoO 3 , Sb 2 O 3 and H 3 PO 4 respectively; and wherein the catalytically active composition of the catalyst does not comprise any copper.

Processes for preparing amines and catalysts for use therein

Processes for preparing an amine, the processes comprising: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, 1.5 to 4.5% by weight of an oxygen compound of cobalt, calculated as CoO, and 0.2 to 5.0% by weight of at least one oxygen compound of niobium, sulfur, phosphorus, gallium, boron, lead or antimony, calculated in each case as Nb 2 O 5 , H 2 SO 4 , H 3 PO 4 , Ga 2 O 3 , B 2 O 3 , PbO and Sb 2 O 3 respectively, and wherein the catalytically active composition does not comprise any molybdenum.

Processes for preparing amines and zirconium dioxide- and nickel-containing catalysts for use therein

A catalytically active composition comprising, prior to reduction with hydrogen: 10 to 75% by weight of an oxygen compound of zirconium, calculated as ZrO 2 ; 1 to 30% by weight of an oxygen compound of copper, calculated as CuO; 10 to 50% by weight of an oxygen compound of nickel, calculated as NiO; 10 to 50% by weight of an oxygen compound of cobalt, calculated as CoO; and 0.1 to 10% by weight of one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In, calculated as PbO, Bi 2 O 3 , SnO, Sb 2 O 3 or In 2 O 3 , respectively.

Method for producing an amine

The invention relates to a method for producing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound, selected from the group including ammonia, primary and secondary amines, in the presence of a zirconium dioxide-containing, copper-containing and nickel-containing catalyst, the catalytically active mass of the catalyst prior to its reduction with hydrogen containing oxygen-containing compounds of zirconium, copper, nickel, 0.2 to 40% by weight of oxygen-containing compounds of cobalt, calculated as CoO, 0.1 to 5% by weight of oxygen-containing compounds of iron, calculated as Fe2O3, and 0.1 to 5% by weight of oxygen-containing compounds of lead, tin, bismuth and/or antimony, each calculated as PbO, SnO, Bi2O3 or Sb2O3. The invention also relates to catalysts of the above type.

Method for producing an amine

Method for producing an amine

Verfahren zur Herstellung eines Amins durch Umsetzung eines primären oder sekundären Alkohols, Aldehyds und/oder Ketons mit Wasserstoff und einer Stickstoffverbindung, ausgewählt aus der Gruppe Ammoniak, primäre und sekundäre Amine, in Gegenwart eines Zirkoniumdioxid- und nickelhaltigen Katalysators, wobei die katalytisch aktive Masse des Katalysators vor dessen Reduktion mit Wasserstoff sauerstoffhaltige Verbindungen des Zirkoniums, Nickels und Eisens und im Bereich von 0,2 bis 5,5 Gew.-% sauerstoffhaltige Verbindungen des Zinns, Bleis, Bismuths, Molybdäns, Antimons und/oder Phosphors, jeweils berechnet als SnO, PbO, Bi2O3, MoO3, Sb2O3 bzw. H3PO4, enthält, sowie Katalysatoren wie oben definiert.

Method for producing an amine

Method for oxidising ammonia and system suitable therefor

FIELD: chemistry. SUBSTANCE: group of inventions refers to inorganic chemistry and may be used in the chemical industry to produce products of ammonia oxidation. System for oxidising ammonia, contains a reactor (3), equipped with at least one feed line (120) for a reactant gas mixture and with at least one discharge line for a process gas. Catalyst (3c) in the interior of the reactor (3) that contains at least one transition metal oxide that is not an oxide of a platinum metal. System also comprises a device for setting a molar ratio of oxygen to ammonia in the reaction gas mixture from 1.25 to 1.75 mol/mol by mixing an oxygen-containing gas flow having an O 2 content < 20 vol % with a selected quantity of ammonia. Oxygen-containing gas flow being produced 1) by a device for diluting an air flow with a gas flow (line 220); 2) by a device for depleting oxygen from an oxygen-containing gas mixture, preferably from air (line 210); 3) by a combination of measures 1 and 2. Temperature of the produced gas at the exit from the catalyst bed is from 700 °C to 950 °C. EFFECT: production of ammonia oxidation products. 30 cl, 6 dwg, 2 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 646 643 C2 (51) МПК C01B 21/26 (2006.01) C01B 21/28 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C01B 21/26 (2017.08); C01B 21/28 (2017.08) (21)(22) Заявка: 2015140607, 13.03.2014 (24) Дата начала отсчета срока действия патента: Дата регистрации: 06.03.2018 14.03.2013 DE 10 2013 004 341.7 (43) Дата публикации заявки: 20.04.2017 Бюл. № 11 (45) Опубликовано: 06.03.2018 Бюл. № 7 (86) Заявка PCT: EP 2014/000669 (13.03.2014) (87) Публикация заявки PCT: R U 2 6 4 6 6 4 3 WO 2014/139678 (18.09.2014) Адрес для переписки: 191036, Санкт-Петербург, а/я 24, "НЕВИНПАТ" (54) Способ окисления аммиака и система, подходящая для его осуществления (57) Реферат: Группа изобретений относится к значений от 1,25 до 1,75 моль/моль посредством неорганической ...