POROUS NANOHYBRID COMPOSITE, MANUFACTURING METHOD THEREOF AND CARBON DIOXIDE ABSORBENT COMPRISING SAME
A, porous nano hybrid composite, said porous nano hybrid complexes of manufacturing method, and said porous nano hybrid composite relates to a carbon dioxide adsorber for use including. Recent to perform various metal organic structures in all of the studies of. but the method can not. Metal organic structure covering a very wide specific surface area structure having a porous structure that various material of such an environmental adsorption organic material can be applied as well as pore size according to selective gas adsorption are connected to the switching circuit is used and drinks, in particular in the fields of industrial. However organic ligands is generated based on the structure having crystal structure a high temperature, high pressure that has low may have stability when applying across the industrial an alternative solution to the. whereby. Since the stable physical/chemical property of metal oxides by winding the titanium oxide during hybridize the if the. (Anatase) anatase, as titanium oxide, rutile (rutile), , such as offers for repidocrosite (lepidocrocite) has crystal structure. For repidocrosite is selected from them in particular a portion of the sacrificial layer is crystal structure plate pbzrxti the active photocatalytic material which is chemically stable porous various sheet nano which is obtained for making compound, use can be made of, as building blocks. Now reacting the mixture by the addition of metal oxide, the engine thereby for reducing fuel consumption using titanium oxide hybrid composite metal organic but is made for repidocrosite structure and the analysis to the composite hybrid nano titanate in reported unmounted. no. Opening patent number 10-2013-0109830 25th which metal oxo and cationic metal call including ions rate of composite metal oxide including a carbon dioxide adsorber for use, a carbon dioxide adsorber for use of said manufacturing method, characterized said with respect to the modules a carbon dioxide scavenger including disclosure of wet liquid to flow down. Composite hybrid porous nano certain embodiments herein include, said porous nano hybrid complexes of manufacturing method, and said porous nano hybrid composite characterized including. provided. Just, the product embodiments herein include said constitution as which is not limited into, constitution in yet another technique. may be present. A number 1 aspect, layered titanium oxide nano sheet and said layered titanium oxide nano sandwiched between metal organic structure including, a composite hybrid porous nano. A number 2 aspect, layered titanium oxide nano sheet forming a solution of a colloidal; and said layered titanium oxide nano sheet colloidal solution metal cations and organic ligands reacting-soluble layered titanium oxide nano sandwiched between said metal organic structure including form a, porous nano hybrid complexes of provides manufacturing method. A number 3 aspect, a number 1 including composite hybrid porous nano according to side, provides characterized. A according to an exemplary embodiment, surface having negative charge 2 dimensional sheet phase structure containing metal cations oxide of titanium organic ligand hybrid porous nano by reacting solution may form a composite, an overall than the thermal stability after unit is off. A according to an exemplary embodiment, titanium oxide of 2 dimensional sheet phase structure pores and mesoporous were making up 3 dimensional structure in a low which have a containing therefore, metal organic structures in micro caused by the together contribute to manufactured by blowing air bubble can be a porous structure. High specific surface area and a gas formation carbon dioxide via robot body is reduced by increasing a adsorption activity, said porous nano hybrid composite each component a a carbon dioxide adsorber for use including nanoscale range combine in the catalytic activity and by. excellent in stability. Embodiment of Figure 1 herein: an porous nano hybrid composite powder XRD is graph indicating a pattern. Herein embodiment of Figure 2:an porous nano hybrid complexes of Fourier trans-infrared spectrometer (ft-IR spectroscopy) is graph. Figure 3 herein composite hybrid porous nano: an embodiment of micro-Raman (micro-Raman) is graph. Embodiment of Figure 4 herein: an porous nano hybrid complexes of transmission electron microscope Image is (transmission electron microscope, TEM). Embodiment of Figure 5 herein: an porous nano hybrid composite [...] isothermal curve graph is nitrogen. Embodiment of Figure 6 herein: an porous nano hybrid complexes of carbon dioxide adsorption activity is graph. Embodiment of Figure 7 herein: an porous nano hybrid complexes of is graph analysis ten mass. Under reference to the drawing based on a text content of the herein in is in the field of the person with skill in the art easily embodiment embodiment a can be. as further described thereby, the cold air flows. However a variety of different is embodied in the form described where can be embodiment aspect is not limited. In drawing and herein described thereby unambiguously direct the portion that are independent of and described for the, specification similar parts throughout the drawing similar to he glued his code. Specification in an entire herein, certain with distinct portions of the emitting surface when seat but invisible from the driver are "connected", the "connected directly" as well as when, its intermediate separating members, wherein another element is "electrically connected" includes a double-is. Specification in an entire herein, any member is "on" the other member when to be located, is any member is when the other member is in contact with a between the two members as well as the presence of another member includes even in the case. Specification in an entire herein, certain on any configuration element when advisable to "includes", is especially opposite the substrate to which it is-free other features element is supported by the upper case and, excepting the other further include components to. meaning that it may be set. Herein used in entire specification of such a magnitude that induces terms "about", "substantially", or the like, that has unique to the meanings cited in manufacturing and material which the tolerance to be presented when at or values is used the widest sense of the proximity levels in relation to, to aid the comprehension of herein or an accurate absolute is numerical-is-mentioned disclosure content is per ' iphery of wrongly self conscience non use is used for the prevention of. Entire specification of such a magnitude that induces terms herein used in "-(a) step" or "-step" the "steps for-" does not mixture by the addition of an initiator. Specification in an entire herein, included in representation of format [...]"combinations thereof (are)" [...] term of components substrate to the representation of format selected from the group consisting of one or more mixed a by pushing a button to decide the meaning or a combination, of components which said selected from the group consisting of a means including one or more of. Specification in an entire herein, "B and/or A" of substrates "B or A, or A and B". mixture by the addition of an initiator. Hereinafter, but as further described embodiment hereof is herein include, is herein may be not limited to. A number 1 aspect, layered titanium oxide nano sheet and said layered titanium oxide nano sandwiched between metal organic structure including, a composite hybrid porous nano. Herein composite hybrid porous nano according to organic ligand generated based on the crystalline structure, has a low stability at elevated temperature and pressure in the alternatively organic structures in metal of the existing method, physical, chemically stable metal oxide layered structures by countering heat oxide of titanium has the effect that increased stability. A in one embodiment, said porous nano hybrid composite code input mode using his/her reacting in liquid carbon dioxide can be, may be not limited to. For example, a layered composite hybrid porous nano said titanium oxide nano sheet nanowire according to addition of a large scale sheet due to synergistic effect of specific surface area and a specific carbon dioxide adsorption activity can be improved but, may be not limited to. A in one embodiment, said layered titanium oxide nano sheet generally layered crystal structure titanium in an oxide form, , for example, comprise titanium oxide for repidocrosite can be degraded and, may be not limited to. Titanium oxide (anatase) anatase, as said, rutile (rutile), (lepidocrocite), such as offers for repidocrosite may have a crystal structure, a layered titanium oxide for repidocrosite and one of a portion of the sacrificial layer is crystal structure which is obtained the active photocatalytic material which is chemically stable nano sheet with use of porous compound for making, use can be made of, as building blocks. A in one embodiment, (mesoporous) mesoporous composite hybrid porous nano said pores and including 3 dimensional code input mode using his/her can be, may be not limited to. For example, titanium oxide of 2 dimensional sheet phase structure mesoporous were making up structures containing pores and therefore to have, metal organic structures in manufactured by blowing air bubble micro caused by the plurality of for the together contribute to 3 can be degraded and forming-dimensional structure, may be not limited to. For example, a layered composite hybrid porous nano said titanium oxide nano sheet even after addition of 3 dimensional pore structure. can be maintained. A number 2 aspect, layered titanium oxide nano sheet forming a solution of a colloidal; and said layered titanium oxide nano sheet colloidal solution metal cations and organic ligands reacting-soluble layered titanium oxide nano sandwiched between said metal organic structure including form a, porous nano hybrid complexes of provides manufacturing method. Said a number 2 side according to porous nano hybrid complexes of herein to manufacturing method of the user to the number 1 against the sides described. may be applied to both. A in one embodiment, a surface sheet oxide nano titanium layered said negative charge can be code input mode using his/her, may be not limited to. A in one embodiment, said surface bearing a negative charge is organic ligands said layered titanium oxide nano sheet metal cations in combination with said said metal organic structure is connected to the one end can be, may be not limited to. For example, said metal organic structure said metal cation said organic ligand and a coordination bond-forming can be structure, may be not limited to. A in one embodiment, a organic ligands said 2-methyl imidazoles (2-methylimidazole), [...] idle (isophthalic acid), tree meth acid (trimesic acid), or it can be for including terephthalic acid (terephthalic acid), may be not limited to. A in one embodiment, said metal the cations Zn2+, Ni2+, Mn2+, Co2+, Fe2+, cu2+, Fe3+, Cr3+, Mn3+, Ga3+, Co3+, or Ni3+ for including it can be, may be not limited to. A in one embodiment, said metal the cations relative to the weight of said layered titanium oxide nano sheet can be about 30 weight % hereinafter, may be not limited to. For example, a in one embodiment, said metal the cations relative to the weight of said layered titanium oxide nano sheet about 30 weight % hereinafter, about 1 weight % to about 30 weight %, about 1 weight % to about 25 weight %, about 1 weight % to about 20 weight %, about 1 weight % to about 15 weight %, about 1 weight % to about 10 weight %, about 5 weight % to about 30 weight %, about 5 weight % to about 25 weight %, about 5 weight % to about 20 weight %, about 5 weight % to about 15 weight %, or 2 weight % to 20 weight %, the logical source including the device, may be not limited to. A in one embodiment, said reaction is room temperature can be carried out in, may be not limited to. For example, solution phase at room temperature through mixing reactor said porous nano hybrid composite may be to but, not limited to blood. A in one embodiment, said layered titanium oxide nano sheet the step of forming colloidal solution, protonated layered titanium oxide is formed tetraalkyl ammonium hydroxide using a solution containing is processed with a performed by a process including can be, may be not limited to. A in one embodiment, included in said tetraalkyl ammonium hydroxide Wednesday 10 to 1 water but carbon diffusibility of a movable ion, may be not limited to. For example, said tetraalkyl ammonium hydroxide (tetramethylammonium hydroxide) a tetramethyl ammonium hydroxide, tetra ethyl ammonium hydroxide (tetraethylammonium hydroxide), tetra profile ammonium hydroxide (tetrapropylammonium hydroxide), or butyl ammonium hydroxide (tetrabutylammonium hydroxide) can be it including a, may be not limited to. A in one embodiment, said porous nano hybrid complexes of the manufacturing method, said layered titanium oxide nano sheet colloidal solution and metal cations and organic ligand-soluble after reacting said additional and removing the filtration reactants may be including but, not limited to blood. A in one embodiment, said filtration separation after separate reaction for drying a surface-it can be herein further including, not limited to blood. A number 3 aspect, a number 1 including composite hybrid porous nano according to side, provides characterized. The present side according to said carbon dioxide for the adsorbents due to the side and said a number 1 number 2 against the sides the user to the described. may be applied to both. A in one embodiment, a carbon dioxide adsorber for use said a, layered titanium oxide nano sheet and said layered titanium oxide nano sandwiched between metal organic structure including porous nano hybrid composite can be degraded and, may be not limited to. A in one embodiment, (mesoporous) mesoporous composite hybrid porous nano said pores and including 3 dimensional code input mode using his/her can be, may be not limited to. For example, titanium oxide of 2 dimensional sheet phase structure mesoporous were making up structures containing pores and therefore to have, metal organic structures in manufactured by blowing air bubble micro caused by the plurality of for the together contribute to 3 can be degraded and forming-dimensional structure, may be not limited to. For example, a layered composite hybrid porous nano said titanium oxide nano sheet even after addition of 3 dimensional pore structure. can be maintained. Hereinafter, a embodiment to the present invention more rapidly and to reduce a memory to one, of the following embodiment relate to assist the comprehension of herein exemplified one only, to the contents of embodiment herein aspect limited not. [In the embodiment] Layered titanium oxide nano sheet colloidal for preparing a solution with a Reported as prior to, a systematic solid 1 M HCL and a continuous (solid state reaction) subjecting the film to a treatment by layered cesium titanate or protonized titanate in said layered cesium been is synthesized derivatives (protonated). After tetra butyl ammonium hydroxide (TBA, OH) using protonized titanate by reacting said said layered titanate in and the stripped nano sheet have been synthesised. And the stripped titanate nano sheet higher speeds and in a colloidal solution of pure centrifugal through separation of incompletely and the stripped particles of small fraction been obtained by removing the. Porous nanohybrid for the manufacture of composite materials Said synthetic layered titanium oxide nano sheet colloidal solution (0.754 mg/mL) for Zn (NO3), 6H2 O Zn metal cation content in each contrast to 2, 5, 10, 20 weight % added Zn (NO3), 6H2 O (50 ml per methanol is dissolved 0.732 g) added to solution. Zn metal cations mass: layered titanium oxide mass 100:2,100 : 5, you in 100:20 and 100:10, and the solution of types have been prepared. Furthermore, said solution 2-methyl imidazoles (1.622 g per by dissolved in 50 ml methanol) solution and main is reacted time 2 at room temperature. After completion of reaction, as a result said powder obtained product is a been isolated by filtration, residual wherein ions are removed using methanol for complete a massage cream, an essence, is cleaned, 12 in an oven in 50 °C in dryness of time. 2, 5, 10, 20 weight % after (Zn metal cations mass: layered titanium oxide mass) have a ratio of said each composite hybrid porous nano obtained ZT1, ZT2, ZT3, and are presented as ZT4. For comparison said porous nano hybrid composite colloidal solution sheet oxide nano titanium in the manufacturing process without adding the control group ZIF-8 of the metal organic structure have been synthesised. Said metal organic structure organic ligand said metal cation said Zn 2-methyl imidazoles of four imidazole rate ring (imidazolate ring) and a tetrahedral coordination bond-forming structure, said metal organic structures in space group Can be expressed as. Crystal structure analysis Crystal structure of composite hybrid porous nano said powder X-ray diffraction (XRD, PC/Max-2000/Rigaku D, cu Kα radiation) been irradiated by. Also, as shown to 1, a have a ratio of various said produced porous nano hybrid composite organic structures in metal soldiers captures an Image of the both ZIF-8 and exhibits a peak XRD and the typical bandwiths and, this hybrid porous nano: an embodiment herein include metal in the conjugate organic structures in the for ccr9. gas jet, both of which are is ZIF-8. Said layered titanium oxide phase corresponding to any peak WIPO of:an embodiment cannot be recognised implying XRD data, without resolution this said layered titanium oxide nano sheets exhibits excellent distribution. Layered titanium oxide nano sheet is distinguished by increased concentrations of by XRD peak based on organic structures in metal the calculated perspectives and a ZIF-8 nano particle collector general formula (1) such as been calculated based on Scherrer equation. T = 0.9 λ / B cos θ (1) Wherein, the organic structures in metal t size of nanoparticles, with the wavelength of a-said X a λ, the XRD B refractive of peaks (full-width at half-maximum, FWHM), and θ is angle (Brag) that only lp01. Such from the calculation, said metal organic structures in soldiers contrast ZIF-8 nanoparticles sized plant sterol, and thus said nano hybrid composite ZT1, ZT2, ZT3, and 23.4 nm for each ZT4,25.2 nm, 22.9 nm, and has been determined to 21.7 nm. The results indicate that layered titanium oxide nano sheet metal produced by the conditions same before adding organic structures in a nano particle collector ZIF-8 less than value 28.7 nm, layered titanium oxide nano sheet metal according to addition of organic structures in a reduction nano particle collector show that. Chemical bonding properties analysis Said porous nano hybrid composite titanium oxide a layered presence organic structures in and metal presence of polymer nanofibers grains to make sure that chemical bonding (also 2) and IR-ft (micro-Raman)-Raman spectroscopic analysis (also 3) of the embodiment. Also according to embodiment a Figure 3 and 2 produced porous nano hybrid composite body containing at least one layer, (a) ZT-1, (b) ZT-2, (c) ZT-3 (d) ZT-4, ZIF-8 the control group (e), (f) and exhibits and layered titanium oxide nano sheet. Micro-Raman spectrum using excitation wavelength of 785 nm JY LabRam HR been collected using spectroscope. Result IR-ft -500 cm-1 and -2960 cm-1 included in the titanium oxide layered in overhangs (hydrocarbon) carbon of TBA is detected peak associated with constitution: a section confirms with, the porous nano hybrid composite layered in the manufacturing process for ccr9. the addition of titanium oxide nano sheet. In addition the control group synthesized by organic structures in metal ZIF-8 and a, which throughout the composite hybrid porous nano ft-IR peak hybrid porous nano provided organic structures in metal in the conjugate ZIF-8 nanoparticles provided an opening well.. Characterised in that the flanges provide 3135 cm-1, 2925 cm-1 imidazole peak occurring in the C-H with an aliphatic aromatic each (imidazole) exhibits stretching, 1584 cm-1 C=N the picks occurring in the. stretching. Indicative of the in Figure 3 600-650 cm-1 the synthetic resin cover micro-Raman the picks of trioctahedral TiO6 Ti-O expansion vibration (stretching vibration) meaning, 750 cm-1 region. stretching Ti-O-Ti of corner-shared TiO6 the picks. Prior i.e. ft-IR and micro-Raman spectroscopy the results of the analysis of the porous nano hybrid in the conjugate layered titanium oxide nano sheet identify the presence of the. HR-TEManalysis Said porous nano hybrid composite 200 kV a voltage is applied a grain size crystal forms of photon pumping-tem (high resolution-transmission electron microscopy, HR-TEM) analysis been irradiated using a (Jeol JEM-2100F). According to Figure 4 a embodiment produced porous nano hybrid composite body containing at least one layer, (a) ZT-1, (b) ZT-2, (c) ZT-3, (d) ZT-4, and blades, presenting a ZIF-8 the control group (e). , As shown in Figure 4, porous nano hybrid composite thin titanium oxide a layered both nano -20-25 nm on the surface of sheet have a smaller size of metallic-organic structure ZIF-8 looked presence of nanoparticles, this layered titanium oxide nano seat support on said organic structures in metal nanoparticles ZIF-8. concerns a of stabilizing. The present embodiment: an HR-TEM result a layered titanium oxide nano sheet metal organic structures in organic structures in metal such as nanoparticles ZIF-8 portion capable of storing particles of polymer nanofibers also to highly effective matrix of the second processor with the known to that it is possible for. Such soldiers captures an Image of the inspection subsystem Image HR-TEM said metal organic structures in layered size of nanoparticles ZIF-8 by the addition of titanium oxide nano sheet showed that small. These observations said XRD the particle size data computational said result in an amount of in accord. Specific surface area and poresdistribution analysis Said porous nano hybrid composite of specific surface area and a specific to see distribution and pores, nitrogen [...] embodiment the isothermal measurement. Embodiment of Figure 5 (a) to (e) herein of hybrid porous nano produced according to (a) ZT-1 composite body containing at least one layer, (b) ZT-2, (c) ZT-3, (d) ZT-4, and blades, presenting a the control group (e). , As shown in Figure 5, in the case of organic structures in metal soldiers contrast ZIF-8 BET to 100,000. I type graph. A low relative pressure suction is due pores in a microcomputer shown that high relative pressure appears in the nano-particles are emitter some tenths arrangement, produced by adsorption due to a structure pore/micro mesoporous. curve. Prime, of a porous nano hybrid composite sample confirm the corresponding schedule moreover, is a layered titanium oxide nano sheet despite added allowed during a manufacturing process of micro pores. shown that is maintained well. The porous nano hybrid composite ZT-1 (1995 m2/g), ZT-2 (1915 m2/g), ZT-3 (1829 m2/g), ZT-4 (1803 m2/g) non has a surface area, existing organic structures in metal soldiers ver input from the verification and check ZIF-8 (1797 m2/g) is show a specific surface area of at least. Is a layered titanium oxide nano sheet metal made into small liquid due to addition of organic structures in extended in size nanoparticles ZIF-8 due layered and a specific surface area of at least titanium oxide nano sheet having a wide large area by coding an rise of specific surface area and a specific analysis taken as a result. Carbon dioxide adsorbing performance evaluation Said porous nano hybrid complexes of carbon dioxide adsorbing performance in 25 °C and 0 °C to assess specific surface measurement device (liquid nitrogen temperature with a gas sorption analyzer, ASAP 2020) experiment was carried out to and adsorbing using. The results of Figure 6 shown in an which, measuring carbon dioxide adsorption result of utility for sensitive motor hybrid porous nano through was assessed. According to embodiment a Figure 6 produced porous nano hybrid composite body containing at least one layer, (triangle) ZT-1, ZT-2 (rectangular), (diamond) ZT-3, ZT-4 (inverse triangle), / correlation group blades, presenting a ZIF-8 (won). Herein each composite hybrid porous nano according to 0 °C (273 K) and 25 °C (298 K) was assessed for reduced in adsorption of desorption of the carbon dioxide in the. Temperature range before made in porous nano hybrid composite organic structures in metal soldiers captures an Image of the high activity than ZIF-8 precursor and CaO precursor such a hybrid results after maintained even manufactured by blowing air bubble structure and rather enhanced reactor a specific surface area of at least because of heat transfer area analysis him. Stability evaluation: ten massanalysis For evaluating stability ten mass spectrometries 5 °C/min speed of each sample at elevated temperatures (TA Instruments SDT Q600) it was determined that while in nitrogen atmosphere to. According to Figure 7 a embodiment produced porous nano hybrid composite body containing at least one layer, (red) ZT-1, ZT-2 (blue), (pink) ZT-3, ZT-4 (green), / correlation group (black) ZIF-8 blades, presenting a. Also, as shown to 7, the control group ZIF-8 a sleeve 63 °C -100 ° C indicative of the in a sample composite hybrid porous nano pores of section, after removal of a methanol solution thereof having a in, contrast is ZIF-8 organic structures in metal soldiers in 570 °C to 410 °C have shown that loss mass gradually. Such results (imidazolate) imidazole rate because failing by heat of the framework of the canopy shelter analysis him. Both sample before composite hybrid porous nano while 545 °C start loss is occurring the masses in temperature after corresponding advertisement based on the shown list, layered a metal oxide is titanium oxide nano sheet due to the addition of a because characteristic improving thermal stability analysis as. Herein aforementioned description of which is for the exemplary, herein person with skill in the art, to which a mobile station belongs art essentially or technical idea of the present application without changing the features form the is possible easily deformed may understand that the is. Therefore in the embodiment described or more exemplary on all sides are defined and there has the main. must understood. For example, is described single stored in a dispersed component may be embodiment, is dispersed into the similarly is made also described in the form of a binding elements can be embodiment. Rather than the range of said description herein refers to are represented by claim, claim meaning of equalization and and range modification or all derived from general outline of an altered form is included within the scope of herein should interpreted to. The present invention relates to a porous nanohybrid composite, a manufacturing method of the porous nanohybrid composite, and a carbon dioxide absorbent comprising the porous nanohybrid composite. The porous nanohybrid composite comprises layered titanium oxide nanosheets and a metal organic structure inserted between the layered titanium oxide nanosheets. COPYRIGHT KIPO 2016 Layered titanium oxide nano sheet and said layered titanium oxide nano sandwiched between including metal organic structure, porous nano hybrid composite. According to Claim 1, mesoporous (mesoporous) pores and including 3 a code input mode using his/her dimensional, porous nano hybrid composite. According to Claim 1, said porous nano hybrid composite a having reacting in liquid carbon dioxide, porous nano hybrid composite. Layered titanium oxide nano sheet forming a solution of a colloidal; and said layered titanium oxide nano sheet colloidal solution metal cations and organic ligands reacting-soluble layered titanium oxide nano sandwiched between said metal organic structure including form a, porous nano hybrid complexes of manufacturing method. According to Claim 4, said reaction is purpose: provided is a at room temperature, porous nano hybrid complexes of manufacturing method. According to Claim 4, said layered titanium oxide nano sheet a having negative charge surface, porous nano hybrid complexes of manufacturing method. According to Claim 4, said metal the cations Zn2+, Ni2+, Mn2+, Co2+, Fe2+, cu2+, Fe3+, Cr3+, Mn3+, Ga3+, Co3+, or Ni3+ for including a, porous nano hybrid complexes of manufacturing method. Number 1 anti to number 3 anti either including anti according to porous nano hybrid composite, a carbon dioxide adsorber for use.
